CN108101468A - A kind of tile grout - Google Patents

A kind of tile grout Download PDF

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Publication number
CN108101468A
CN108101468A CN201711262368.5A CN201711262368A CN108101468A CN 108101468 A CN108101468 A CN 108101468A CN 201711262368 A CN201711262368 A CN 201711262368A CN 108101468 A CN108101468 A CN 108101468A
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China
Prior art keywords
tile grout
mesh
tile
fineness
grout
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Granted
Application number
CN201711262368.5A
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Chinese (zh)
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CN108101468B (en
Inventor
韩朝辉
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Vasa Mortar Co Ltd
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Vasa Mortar Co Ltd
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Priority to CN201711262368.5A priority Critical patent/CN108101468B/en
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/02Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
    • C04B28/06Aluminous cements
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00474Uses not provided for elsewhere in C04B2111/00
    • C04B2111/00663Uses not provided for elsewhere in C04B2111/00 as filling material for cavities or the like
    • C04B2111/00672Pointing or jointing materials
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2201/00Mortars, concrete or artificial stone characterised by specific physical values
    • C04B2201/50Mortars, concrete or artificial stone characterised by specific physical values for the mechanical strength

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)
  • Sealing Material Composition (AREA)

Abstract

The invention discloses a kind of tile grouts, are related to building material technical field.The gap filler of the present invention includes each component of following mass percent:Superfine aluminate cement 20.0% 25.0%, high strength gypsum 3.0% 5.0%, precipitated calcium carbonate 5.0% 10.0%, aggregate 55.0% 61.0%, cellulose ether 0.05% 0.15%, adhesive 1.0% 3.0%, retarder 0.02% 0.05%, hollow glass microbead 3.0 5.0%, modifying agent 0.1 0.3%, pigment 0.02 3.0%.The tile grout waterproof impervious characteristic that the present invention develops is excellent, will not generate the accumulation of salt in the surface soil/salt, the white phenomenon of stream, cost is relatively low, easy for construction, can promote the use of a large area.

Description

A kind of tile grout
Technical field
The present invention relates to building material field more particularly to a kind of tile grouts.
Background technology
Ceramic tile is as one of the most frequently used finishing material in building decoration area, and gap needs special material between ceramic tile and ceramic tile Material, which is filled, can just obtain aesthetic effect, and this proprietary material is known as tile grout.The development of underfill materials with should With and understanding improve and constantly develop, polymer-modified cement-based gap filler, epoxy joint filling till now is developed by initial white cement Agent, joint trimming agent etc..There are various problems in these material application processes, as cement base gap filler is easy to the accumulation of salt in the surface soil, stream occur in vain now As epoxy gap filler higher price is not readily adapted to be widely applied, and joint trimming agent construction is cumbersome, it is necessary to use cement base joint filling in advance Agent is filled, and water resistance is poor.
The prior art proposes a kind of patent using epoxy resin and curing agent, can reach fine desired effect, but its into This height is not suitable for exterior wall large area and uses.It is most of in the prior art to use portland cement as inorganic coagulation material, aquation Product alkalescence is higher.And the gap filler used as ceramic tile should have preferable impermeability, and it is existing the accumulation of salt in the surface soil, stream hundred can't occur As, while cost need to control relatively low, facilitate construction, can economically vigorously promote the use.But current ceramic tile disclosed on the market Gap filler cannot reach requirements above simultaneously;Therefore, it is badly in need of a kind of water proof type ceramic tile for having both above-mentioned overall merit of exploitation to fill out Stitch agent.
The content of the invention
In view of this, an embodiment of the present invention provides a kind of tile grout, main purpose is to solve tile grout to resist The problem of oozing poor performance and the serious accumulation of salt in the surface soil/salt phenomenon.
In order to achieve the above objectives, invention broadly provides following technical solutions:
On the one hand, an embodiment of the present invention provides a kind of tile grout, each component of following mass percent is included:
Preferably, the superfine aluminate cement marked as C70 or C80;The superfine aluminate cement specific surface Product is more than or equal to 300m2/kg。
Preferably, the whiteness of the high strength gypsum is more than 90%, fineness is 800 mesh;The precipitated calcium carbonate is work Industry grade, fineness are 1250 mesh.
Preferably, the aggregate is washing quartz sand, fineness is -120 mesh of 80 mesh;The retarder is citric acid Sodium, 325 mesh of fineness.
Preferably, the cellulose ether is ethoxyl methyl cellulose ether and/or hydroxypropyl methyl cellulose ether, glue It spends for 25000mPa.s-45000mPa.s.
Preferably, the adhesive is acrylate and styrene copolymerized rubber powder and/or acrylic acid homopolymerization rubber powder.
Preferably, the bulk density of the hollow glass microbead is 0.20g/cm3-0.27g/cm3, real density is 0.38g/cm3-0.48g/cm3
Preferably, the modifying agent is polycarboxylate water-reducer and polyethylene glycol esters wetting agent with mass ratio 2:1 mixing It forms.
Preferably, the pigment is titanium dioxide or inorganic oxide iron series.
Compared with prior art, the beneficial effects of the invention are as follows:
The present invention for tile grout there is technical issues that the impervious poor and easy accumulation of salt in the surface soil/, each group in being formulated to it Dividing and its matching to be improved makes that between each component better synergistic effect can be played, obtained tile grout waterproof impervious characteristic It is excellent, the accumulation of salt in the surface soil/salt, the white phenomenon of stream will not be generated, cost is relatively low, easy for construction, can promote the use of a large area.
Specific embodiment
For further illustrate the present invention to reach the technological means and effect that predetermined goal of the invention is taken, below with compared with Good embodiment to specific embodiment, technical solution, feature and its effect according to the present patent application, is described in detail as after.Under State it is bright in multiple embodiments in special characteristic, structure or feature can be combined by any suitable form.
Each raw material sources that the embodiment of the present invention is selected are as follows:
Superfine aluminate cement is selected from the C70 and C80 that spring scenery Refractory Co., ltd of Gongyi City provides;
High strength gypsum is selected from Jinan Xin Guan chemical products Co., Ltd;
Precipitated calcium carbonate is selected from one mining industry processing factory of Lingshou County ore deposit, 1250 mesh of mesh number;
It washes quartz sand and is selected from Hebei Sheng fortune mining industry;
Cellulose ether is selected from the ethoxyl methyl cellulose ether and hydroxypropyl methyl fiber of Beijing Long Hu Science and Technology Ltd.s Plain ether, viscosity is respectively in 25000mPa.s and 40000mPa.s;
Adhesive is selected from the acrylate of Akzo Nobel N.V. and styrene copolymerized rubber powder;
Sodium citrate is selected from the crack chemical textile Co., Ltd in Wujiang;
Hollow glass microbead is selected from Zhengzhou Sheng Laite cenosphere new materials Co., Ltd;
Polycarboxylate water-reducer powder is selected from Yueyang east Yu Hong Co., Ltds;
Polyethylene glycol esters wetting agent is selected from Australia's Chinese and contains river chemical industry (Beijing) Co., Ltd;
Pigment is selected from the iron oxide series of Shanghai Yipin Pigments Co., Ltd..
Embodiment 1
Prepare each raw material according to formula:Superfine aluminate cement C80 200kg, high strength gypsum 30kg, precipitated calcium carbonate 100kg, 80-120 mesh quartz sand 605kg, 25000mPa.s cellulose ether 1.5kg, acrylate and styrene copolymerized rubber powder 30kg, sodium citrate 0.2kg, hollow glass microbead 30kg, modifying agent 3kg, iron oxide black 0.3kg;Above-mentioned each raw material are mixed Conjunction, which stirs evenly, obtains tile grout.
Embodiment 2
Prepare each raw material according to formula:Superfine aluminate cement C70 250kg, high strength gypsum 50kg, precipitated calcium carbonate 50kg, 80-120 mesh quartz sand 580kg, 40000mPa.s cellulose ether 0.5kg, acrylate and styrene copolymerized rubber powder 20kg, sodium citrate 0.5kg, hollow glass microbead 45kg, modifying agent 1kg, iron oxide red 3kg;Above-mentioned each raw material are mixed It stirs evenly and obtains tile grout.
Embodiment 3
Prepare each raw material according to formula:Superfine aluminate cement C70 225kg, high strength gypsum 40kg, precipitated calcium carbonate 75kg, 80-120 mesh quartz sand 600kg, 40000mPa.s cellulose ether 1kg, acrylate and styrene copolymerized rubber powder 10kg, Sodium citrate 0.3kg, hollow glass microbead 30kg, modifying agent 2kg, iron oxide brown 16.7kg;Above-mentioned each raw material are mixed and are stirred It mixes and uniformly obtains tile grout.
Embodiment 4
Prepare each raw material according to formula:Superfine aluminate cement C80 230kg, high strength gypsum 40kg, precipitated calcium carbonate 80kg, 80-120 mesh quartz sand 565kg, 25000mPa.s cellulose ether 1kg, acrylate and styrene copolymerized rubber powder 15kg, Sodium citrate 0.3kg, hollow glass microbead 40kg, modifying agent 2kg, iron oxide brown 26.7kg;Above-mentioned each raw material are mixed and are stirred It mixes and uniformly obtains tile grout.
According to JC/T1004-2006《Ceramic wall gap filler》Middle cement base gap filler pertinent regulations detect embodiment 1-4 systems The indexs such as the anti-folding and compression strength of standby gap filler, water absorption;Meanwhile with reference to JC/T 984-2011《Polymer cement waterproof Mortar》The impervious detection method of film detects the anti-permeability performance of gap filler prepared by each embodiment in standard, and specific testing result is shown in Table 1.
Each performance test results of tile grout prepared by 1. embodiment 1-4 of table
By above-mentioned 1 testing result of table, the anti-folding of the tile grout of the invention prepared, compression strength, water absorption Etc. indexs be satisfied by industry using standard, film anti-permeability performance reaches more than 0.5MPa, and data above demonstrates the present invention's Gap filler has good water impermeability.
Further to verify the anti-accumulation of salt in the surface soil performance of embodiment, simulating chamber external pasting ceramic tile construction of the present invention and gap filling, The gap filler prepared through each embodiment of simplation verification is respectively provided with good anti-accumulation of salt in the surface soil performance, and surface does not have apparent blushing.
The present invention ceramic tile joint filling agent prescription be:Superfine aluminate cement 20.0%-25.0%, high strength gypsum 3.0%- 5.0%, precipitated calcium carbonate 5.0%-10.0%, aggregate 55.0%-61.0%, cellulose ether 0.05%-0.15%, adhesive 1.0%-3.0%, retarder 0.02%-0.05%, hollow glass microbead 3.0-5.0%, modifying agent 0.1-0.3%, pigment 0.02-3.0%.
Further preferably:Superfine aluminate cement 22.0%-25.0%, high strength gypsum 4.0%-5.0%, lightweight carbonic acid Calcium 7.0%-10.0%, aggregate 58.0%-61.0%, cellulose ether 0.1%-0.15%, adhesive 1.5%-3.0%, slow setting Agent 0.03%-0.05%, hollow glass microbead 4.0-5.0%, modifying agent 0.2-0.3%, pigment 0.5-3.0%.
Modifying agent in ceramic tile joint filling agent prescription of the present invention is polycarboxylate water-reducer and polyethylene glycol esters wetting agent with matter Measure ratio 2:1 mixes, and can play improves high alumina cement system gap filler anti-permeability performance, and moisture is prevented to be more difficult to enter mortar It is internal.
Ultra-fine high alumina cement, high strength gypsum and precipitated calcium carbonate in ceramic tile joint filling agent prescription of the present invention add in, and can be promoted The apparent effect of gap filler, presentation is fuller, and surface is brighter;Abundant water can be ensured using ultra-fine high alumina cement and high strength gypsum Change, reduce itself dosage.
Hollow glass microbead in ceramic tile joint filling agent prescription of the present invention not only reduces gap filler proportion, but also plays certain journey Degree inhibits the accumulation of salt in the surface soil or salt effect.
The precipitated calcium carbonate added in ceramic tile joint filling agent prescription of the present invention not only acts as filler effect, and increases Workability, while increase to aggregate encapsulation.
The tile grout that the present invention develops is improved by each component in being formulated it and its proportioning making each component Play preferably synergistic effect, improve waterproof impervious characteristic, will not generate the accumulation of salt in the surface soil/salt, stream it is white phenomena such as, and its cost compared with It is low, it is easy for construction, it can promote the use of a large area.
Part, those skilled in the art can not select from the prior art to the greatest extent in the embodiment of the present invention.
Disclosed above is only the specific embodiment of the present invention, but protection scope of the present invention is not limited thereto, and is appointed What those familiar with the art in the technical scope disclosed by the present invention, can readily occur in change or replacement, all should It is included within the scope of the present invention.Therefore, protection scope of the present invention should using above-mentioned scope of the claims as It is accurate.

Claims (9)

1. a kind of tile grout, which is characterized in that the gap filler includes the component of following mass percent:
2. a kind of tile grout as described in claim 1, which is characterized in that the superfine aluminate cement marked as C70 or C80;The specific surface area of the superfine aluminate cement, which is more than, is equal to 300m2/kg。
3. a kind of tile grout as described in claim 1, which is characterized in that the whiteness of the high strength gypsum is more than 90%, Its fineness is 800 mesh;The precipitated calcium carbonate is technical grade, and fineness is 1250 mesh.
4. a kind of tile grout as described in claim 1, which is characterized in that the aggregate is to wash quartz sand, fineness For -120 mesh of 80 mesh;The retarder be sodium citrate, 325 mesh of fineness.
5. a kind of tile grout as described in claim 1, which is characterized in that the cellulose ether is hydroxyethyl methyl fiber Plain ether and/or hydroxypropyl methyl cellulose ether, viscosity 25000mPa.s-45000mPa.s.
6. a kind of tile grout as described in claim 1, which is characterized in that the adhesive is acrylate and styrene It is copolymerized rubber powder and/or acrylic acid homopolymerization rubber powder.
7. a kind of tile grout as described in claim 1, which is characterized in that the bulk density of the hollow glass microbead is 0.20g/cm3-0.27g/cm3, real density 0.38g/cm3-0.48g/cm3
8. a kind of tile grout as described in claim 1, which is characterized in that the modifying agent is polycarboxylate water-reducer with gathering Ethylene glycol ester wetting agents are with mass ratio 2:1 mixes.
9. a kind of tile grout as described in claim 1, which is characterized in that the pigment is titanium dioxide or inorganic oxide Iron series.
CN201711262368.5A 2017-12-04 2017-12-04 Tile joint mixture Active CN108101468B (en)

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Application Number Priority Date Filing Date Title
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Application Number Priority Date Filing Date Title
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Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108726971A (en) * 2018-06-06 2018-11-02 科顺防水科技股份有限公司 A kind of high-strength ceramic tile gap filler of the anti-accumulation of salt in the surface soil
CN108947436A (en) * 2018-07-31 2018-12-07 合肥尚涵装饰工程有限公司 Cement base underfill composition and its application
CN109293315A (en) * 2018-11-28 2019-02-01 华砂砂浆有限责任公司 A kind of Polymer cement materials and preparation method thereof
CN109437794A (en) * 2018-11-22 2019-03-08 大自然生物集团有限公司 A kind of method and jointing agent preparing jointing agent using citric acid waste
CN110845964A (en) * 2019-11-26 2020-02-28 江西鹏腾实业有限公司 Device and method for producing floor tile adhesive by using polyaluminium chloride sludge
CN110981395A (en) * 2019-12-23 2020-04-10 广东博智林机器人有限公司 Gap filler, preparation method thereof and application of gap filler in filling gaps between wall and floor ceramic tiles by robot
CN113683992A (en) * 2021-08-17 2021-11-23 湖南美吉邦建材有限公司 Weather-resistant texture seam beautifying agent and preparation method thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20010053809A (en) * 1999-12-01 2001-07-02 정환진 The method for manufacturing of composition of joint mortar
CN102180646A (en) * 2011-01-31 2011-09-14 北京东方雨虹防水技术股份有限公司 Non-base-return color ceramic tile joint mixture
CN106348715A (en) * 2016-08-30 2017-01-25 派丽(上海)管理有限公司 Quick-drying caulking agent with stain-resistant function

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20010053809A (en) * 1999-12-01 2001-07-02 정환진 The method for manufacturing of composition of joint mortar
CN102180646A (en) * 2011-01-31 2011-09-14 北京东方雨虹防水技术股份有限公司 Non-base-return color ceramic tile joint mixture
CN106348715A (en) * 2016-08-30 2017-01-25 派丽(上海)管理有限公司 Quick-drying caulking agent with stain-resistant function

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108726971A (en) * 2018-06-06 2018-11-02 科顺防水科技股份有限公司 A kind of high-strength ceramic tile gap filler of the anti-accumulation of salt in the surface soil
CN108947436A (en) * 2018-07-31 2018-12-07 合肥尚涵装饰工程有限公司 Cement base underfill composition and its application
CN109437794A (en) * 2018-11-22 2019-03-08 大自然生物集团有限公司 A kind of method and jointing agent preparing jointing agent using citric acid waste
CN109293315A (en) * 2018-11-28 2019-02-01 华砂砂浆有限责任公司 A kind of Polymer cement materials and preparation method thereof
CN109293315B (en) * 2018-11-28 2022-03-22 华砂砂浆有限责任公司 Polymer cement waterproof mortar and preparation method thereof
CN110845964A (en) * 2019-11-26 2020-02-28 江西鹏腾实业有限公司 Device and method for producing floor tile adhesive by using polyaluminium chloride sludge
CN110981395A (en) * 2019-12-23 2020-04-10 广东博智林机器人有限公司 Gap filler, preparation method thereof and application of gap filler in filling gaps between wall and floor ceramic tiles by robot
CN110981395B (en) * 2019-12-23 2022-03-18 广东博智林机器人有限公司 Gap filler, preparation method thereof and application of gap filler in filling gaps between wall and floor ceramic tiles by robot
CN113683992A (en) * 2021-08-17 2021-11-23 湖南美吉邦建材有限公司 Weather-resistant texture seam beautifying agent and preparation method thereof

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