CN1080976A - The catalysis cleaning device of waste gas - Google Patents

The catalysis cleaning device of waste gas Download PDF

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Publication number
CN1080976A
CN1080976A CN93106045A CN93106045A CN1080976A CN 1080976 A CN1080976 A CN 1080976A CN 93106045 A CN93106045 A CN 93106045A CN 93106045 A CN93106045 A CN 93106045A CN 1080976 A CN1080976 A CN 1080976A
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CN
China
Prior art keywords
tail end
end sections
honeycomb body
brazing filler
filler metal
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN93106045A
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Chinese (zh)
Other versions
CN1035894C (en
Inventor
J·拜尔
B·亨波力克
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Vitesco Technologies Lohmar Verwaltungs GmbH
Original Assignee
Emitec Gesellschaft fuer Emissionstechnologie mbH
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Publication of CN1080976A publication Critical patent/CN1080976A/en
Application granted granted Critical
Publication of CN1035894C publication Critical patent/CN1035894C/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/92Chemical or biological purification of waste gases of engine exhaust gases
    • B01D53/94Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
    • B01D53/9445Simultaneously removing carbon monoxide, hydrocarbons or nitrogen oxides making use of three-way catalysts [TWC] or four-way-catalysts [FWC]
    • B01D53/9454Simultaneously removing carbon monoxide, hydrocarbons or nitrogen oxides making use of three-way catalysts [TWC] or four-way-catalysts [FWC] characterised by a specific device
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/50Catalysts, in general, characterised by their form or physical properties characterised by their shape or configuration
    • B01J35/56Foraminous structures having flow-through passages or channels, e.g. grids or three-dimensional monoliths
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N3/00Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/08Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
    • F01N3/10Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust
    • F01N3/24Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by constructional aspects of converting apparatus
    • F01N3/28Construction of catalytic reactors
    • F01N3/2803Construction of catalytic reactors characterised by structure, by material or by manufacturing of catalyst support
    • F01N3/2807Metal other than sintered metal
    • F01N3/281Metallic honeycomb monoliths made of stacked or rolled sheets, foils or plates
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A50/00TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
    • Y02A50/20Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02TCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
    • Y02T10/00Road transport of goods or passengers
    • Y02T10/10Internal combustion engine [ICE] based vehicles
    • Y02T10/12Improving ICE efficiencies

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Biomedical Technology (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Environmental & Geological Engineering (AREA)
  • Toxicology (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Exhaust Gas After Treatment (AREA)
  • Catalysts (AREA)

Abstract

The method of a kind of catalysis cleaning device of waste gas and this device of manufacturing.A honeycomb body of being made up of many sheetmetals that are partly with structural form at least is provided, be formed with the groove that many fluids therefrom flow through on the sheetmetal, they are positioned in the sleeve, the outward edge of sheetmetal is on honeycomb body periphery, at least some sheetmetals have straight tail end sections, the tail end sections that at least some are straight overlaps on the tail end sections of at least one adjacent straight separately, and two adjacent straight tail end sections outward edge contact sleeves, thereby between tubular sleeve and two equitant straight tail end sections, form the capillary tube cavity.

Description

The catalysis cleaning device of waste gas
The present invention relates to a kind of catalysis cleaning device and a kind of method of making this device of waste gas.
Publish useful sheetmetal level and smooth and ripple on European patent EP 0245737 B1 and make the metal supporting body, and the tail end of thin plate is a level and smooth sections, these level and smooth tail end sections roughly extend between the adjacent metal thin plate, and with its outer end brazing filler metal or on the sleeve around being welded on.
A major defect of this metal supporting body is exactly to have only indivisible sheetmetal area to be connected on the sleeve.
Among the embodiment who on German patent DE 4016276 C1 and European patent EP 0245736 B1, is narrated also there be similar the connection.
One object of the present invention is exactly to strengthen sleeve to be connected with brazing filler metal between the honeycomb body in said apparatus.
This purpose is reached like this, promptly provide one to have the honeycomb body that the sheetmetal of structural form is formed by many at least a portion, be formed with the groove that many fluids therefrom flow through on the sheetmetal of band structure form, they are positioned in the sleeve, the outward edge of described sheetmetal is on the periphery of described honeycomb body, here at least some described sheetmetals have straight tail end sections, at least some described straight tail end sections overlap on the tail end sections of at least one adjacent straight separately, and the outward edge of the tail end sections of two adjacent straight contact is on described sleeve, thereby forms axially extended a plurality of first capillary tube cavitys between the sleeve of tubulose and two equitant straight tail end sections.
According to the present invention, corrugated sheet metal has level and smooth sections at their tail end place, these sections since the operation of reversing or twining fit together mutually, thereby form an overlapping sheetmetal skin at peripheral position.The capillary tube cavity of Yan Shening is present between the adjacent tail end sections inwardly.Between the tail end of the sheetmetal that adjoins sleeve, promptly between the level and smooth tail end sections and sleeve below the sleeve, on axial direction, be formed with a plurality of cavitys, these cavitys communicate with the capillary tube cavity.The brazing filler metal material enters cavity and is sucked in the cavity by capillarity when the brazing filler metal operation.Like this, just be formed with a brazing filler metal material layer along the circle edge of metal supporting body, the tail end sections of sheetmetal just is embedded in this material layer.
The length of level and smooth tail end sections depends on the wave amplitude of corrugated sheet metal, and its value is 3 to 12 times of wave amplitude, and preferably 5 to 10 times, this numerical value can be suitable for its how much environment.In its cross section is not that the distribution around circle edge of sheetmetal tail end is uneven in the catalyst of circle, therefore requires level and smooth tail end sections correspondingly to add longer.
In the embodiment of another metal supporting body, corrugated sheet metal does not have level and smooth tail end sections and is shorter than level and smooth sheetmetal, thus the tail end contact of after sheetmetal is by coiling, having only level and smooth sheetmetal they on the attached tubular sleeve.Corrugated sheet metal is clamped between the level and smooth sheetmetal by frictional force, also can be connected on the level and smooth sheetmetal with brazing filler metal on its end face.The long section of the outstanding sections of level and smooth sheetmetal approximately is 8 to 12 times of corrugated sheet wave amplitude.
To narrate the manufacture method of this exhaust fume catalytic cleaning device below.
This method is made up of mechanicalness manufacturing and a brazing filler metal operation.In mechanicalness was made, corrugated metal thin slice or ripple and level and smooth sheet metal slices mutually overlapped together, and are wound into definite shape then, and the metal supporting body that this is prefabricated into just is inserted in the sleeve and must covers one deck brazing filler metal material.The brazing filler metal material that is stamped on the metal supporting body can be the brazing filler metal film that can buy on one deck market, and its thickness is preferably 0.025mm to 0.15mm.It must contact with metal supporting body and sleeve by rights.A kind of method that simply covers the brazing filler metal material is to apply a brazing filler metal film on its end face.This can be by being connected on one or two end face of supporting body this film is deposited after connecting metal supporting body and sleeve, and fixed thereon, for example realizes with the such mode of dot welding method in case of necessity.Because the gas that produces in the metal supporting body in the brazing filler metal process can expand in heating process, most convenient be with a porose brazing filler metal film, the gas that may produce in the metal supporting body just can be overflowed like this.The degree of depth that the brazing filler metal material infiltrates vertically is subjected to the influence of the thickness of brazing filler metal film in certain limit, this is because the brazing filler metal material is to be drawn in the space between the sheetmetal by capillary force to go.
The another kind of possible method that connects the brazing filler metal material of applying is that bag is wrapped one deck brazing filler metal film with the brazing filler metal film around the whole like this metal supporting body on the metal supporting body that is prefabricated into, and then metal supporting body and brazing filler metal film is inserted in the sleeve simultaneously.The brazing filler metal film that is in like this between metal supporting body and the sleeve is liquefied in welding, thereby the metal supporting body can expand slightly and the internal surface of sleeve is classified close applying as.Squeezed the brazing filler metal material that and flow into the first capillary tube cavity and neutralize in the second capillary tube cavity, formed a good connection.The method of this insertion brazing filler metal film make the metal supporting body can or along its whole length or almost on one or several narrow position, for example on the center portion of metal supporting body, with the brazing filler metal film its clad is lived in so-called belly coating mode.
In another preferred embodiment, the metal supporting body is covered by a box-like brazing filler metal film.This is that the brazing filler metal film is placed on the end face of metal supporting body, and the projection contact that makes the brazing filler metal film if necessary, and connects thereon on the periphery of metal supporting body.The metal supporting body that is covered with the brazing filler metal material now is inserted in the sleeve, and the brazing filler metal film is then still stayed on the end face and on the peripheral position between metal supporting body and the sleeve.This metal supporting body that has covered the brazing filler metal material of brazing filler metal is proved to be very easily, because independent sheet metal layers is connected very goodly owing to covered the brazing filler metal material on their peripheries with sleeve, but also, also connect very strongly each other owing to be stamped the brazing filler metal material on their end face.Box-like brazing filler metal film can only be connected on the termination, also can be on two terminations.
From following narration and accompanying drawing, can recognize additional embodiments of the present invention and application, wherein:
Fig. 1 is the sectional view of a related sleeved metal supporting body;
Fig. 2 is folded a ripple and a level and smooth sheetmetal with level and smooth tail end sections; With
Fig. 3 is the schematic representation of metal supporting body in sleeve that includes the brazing filler metal film of insertion.
Fig. 1 shows the part of metal supporting body of the present invention.Have tail end sections 5,5 ' level and smooth and corrugated sheet metal 3,4 push away folded mutually and be wound into a metal supporting body or honeycomb body 1 along same direction, metal supporting body 1 is inserted in the sleeve 2.The level and smooth tail end sections 5,5 of level and smooth and corrugated sheet 3,4 ' outward edge 6 and the internal surface of sleeve 2 fit closely.The level and smooth tail end sections 5,5 of the sheet metal layers 3,4 below sleeve ' outward edge 6 and sleeve 2 between be formed with the first capillary tube cavity 7, this cavity in axial direction is arranged on the circle edge of metal supporting body 1, and extends in continuously on the whole length of metal supporting body 1.These first capillary tube cavitys 7 with adjacent level and smooth tail end sections 5,5 ' between the second capillary tube cavity 8 that extends internally be connected.In the brazing filler metal operation, the first capillary tube cavity 7 and the second capillary tube cavity 8 are filled up by the brazing filler metal material whole or in part, cause the tail end of sheetmetal 3,4 reach each other with sleeve 2 between firm the connection.
Fig. 2 is the schematic representation of a folded level and smooth and corrugated sheet metal 3,4.Total length 1ges is a length 1 AWith 1 BAnd, altogether in length 1 BBe level and smooth tail end sections 5, the 5 ' part of total length.Length 1 BThe wave amplitude X that depends on corrugated sheet metal 4 submits to following rough relation:
1 B=10x
Fig. 3 schematically demonstrates before brazing filler metal operation brazing filler metal film 10 and is clipped in various configurations between metal supporting body 1 and the sleeve 2.In Fig. 3 a, brazing filler metal film 10 is placed on the end face 11 of metal supporting body 1.The brazing filler metal film is only with its cut edge contact sleeve 2.
Fig. 3 b shows a metal supporting body 1, and periphery 12 is encased by brazing filler metal film 10 fully therein, thereby the latter is sandwiched between metal supporting body 1 and the sleeve 2.
Brazing filler metal film 10 also is to be sandwiched between metal supporting body 1 and the sleeve 2 in Fig. 3 c.Brazing filler metal film 10 is on the central position of the circle edge of metal supporting body 1, forms a belly and coats 13, thereby having only this position to be connected on the sleeve 2 after the brazing filler metal.Like this, two of metal supporting body 1 terminations can be along axial expansion under heat load.
Fig. 3 d and 3e show box-like 14 configuration modes of brazing filler metal film 10.Brazing filler metal film 10 is attached on the end face of metal supporting body, and the periphery of the side projection of brazing filler metal film 10 and metal supporting body 1 is fitted closely there.The edge of box-like brazing filler metal film 14 can cover the major part or the fraction of the periphery of metal supporting body 1 as requested.Fig. 3 d shows box-like brazing filler metal film 14 collocation methods of a kind of " flat ", respectively disposes one on each end face of metal supporting body 1 therein; Fig. 3 e shows single box-like brazing filler metal film 14 collocation methods, and in this situation, the edge covers the major part of the periphery of metal supporting body 1.

Claims (13)

1, a kind of honeycomb body (1), it is had the sheetmetal (3 of structural form by many at least a portion, 4) form, be formed with the groove that many fluids therefrom flow through on the sheetmetal of band structure form, they are positioned in the sleeve (2), described sheetmetal (3,4) outward edge (6) is on the periphery of described honeycomb body (1), at least some described sheetmetals (3 here, 4) has straight tail end sections (5,5 '), at least some described straight tail end sections (5,5 ') overlap on the tail end sections of at least one adjacent straight separately, and two adjacent straight tail end sections (5,5 ') outward edge contact on described sleeve (2), thereby between the sleeve (2) of tubulose and two equitant straight tail end sections (5,5 ') the axially extended a plurality of first capillary tube cavitys (7) of formation.
2, according to the honeycomb body (1) of claim 1, it is characterized in that: the sheetmetal (3,4) that wherein said at least a portion has a structural form be alternately be essentially the level and smooth thin plate (3) and the thin plate (4) of ripple.
3, according to the honeycomb body (1) of claim 2, it is characterized in that wherein only having describedly being essentially level and smooth thin plate (3) and having straight tail end sections, these sections are given prominence on the outward edge of described corrugated sheet (4).
4,, it is characterized in that honeycomb body (1) described here is the part with the catalyst in the vehicle of internal-combustion engine according to the honeycomb body of aforementioned any claim.
5, according to the honeycomb body (1) of claim 1 or 2, it is characterized in that: it has the second capillary tube cavity (8) that extends internally that is connected with the described first capillary tube cavity (7).
6, according to the honeycomb body (1) of claim 3, the ripple that it is characterized in that wherein said corrugated sheet (4) has the wave amplitude (X) of a certain altitude and described straight tail end sections has a length (1 B), the length of straight tail end sections described here is 3 to 12 times of height of described wave amplitude, preferably 5 to 10 times.
7,, it is characterized in that wherein to the interior filling of the described first capillary tube cavity (7) of small part brazing filler metal material (10) according to the honeycomb body (1) of claim 1 or 3.
8,, it is characterized in that wherein to the interior filling of the described second capillary tube cavity (8) of small part brazing filler metal material (10) according to the honeycomb body (1) of claim 5.
9, make the method for honeycomb body (1), this honeycomb body is had the sheetmetal (3 of structural form by many at least a portion, 4) form, be formed with the groove that many fluids therefrom flow through on the sheetmetal of band structure form, they are positioned in the sleeve (2), described sheetmetal (3,4) outward edge (6) is on the periphery of described honeycomb body (1), at least some described sheetmetals (3 here, 4) has straight tail end sections (5,5 '), at least some described straight tail end sections (5,5 ') overlap separately on the tail end sections of at least one adjacent straight, and the contact of the outward edge (6) of two adjacent straight tail end sections is on described sleeve (2), thereby sleeve (2) and two equitant straight tail end sections (5 at tubulose, 5 ') between form axially extended a plurality of first capillary tube cavitys (7), wherein filled brazing filler metal material (10) to the described first capillary tube cavity (7) of small part, described method is characterised in that the following step:
Brazing filler metal material (10) be the form with a film one of be attached at least in sleeve (2) and the described straight tail end sections (5,5 ') above,
Described sheetmetal (3,4) is placed in the described sleeve (2),
Both are heated to the brazing filler metal temperature of brazing filler metal material (10) together.
10,, it is characterized in that brazing filler metal material described here (10) is attached at least one end face (11) of described honeycomb body (1) according to the method for claim 9.
11,, it is characterized in that brazing filler metal material described here (10) is attached on the peripheral position (12) of described honeycomb body (1) according to the method for claim 9.
12,, it is characterized in that form that brazing filler metal material described here (10) coats (13) with belly is above described honeycomb body (1) according to the method for claim 9.
13, according to the method for claim 9, it is characterized in that brazing filler metal material described here (10) with the form of box-like lid (14) above described honeycomb body (1).
CN93106045A 1992-05-14 1993-05-14 Apparatus for catalytic exhaust gas cleaning Expired - Fee Related CN1035894C (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DEP4215986.5 1992-05-14
DE4215986A DE4215986A1 (en) 1992-05-14 1992-05-14 Automotive catalytic converter sheet metal layers - have smooth overlapping ends creating channels through which solder flows in mfg. then improving join to mantle

Publications (2)

Publication Number Publication Date
CN1080976A true CN1080976A (en) 1994-01-19
CN1035894C CN1035894C (en) 1997-09-17

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Application Number Title Priority Date Filing Date
CN93106045A Expired - Fee Related CN1035894C (en) 1992-05-14 1993-05-14 Apparatus for catalytic exhaust gas cleaning

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KR (1) KR100219389B1 (en)
CN (1) CN1035894C (en)
DE (1) DE4215986A1 (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103429345A (en) * 2011-03-10 2013-12-04 株式会社F.C.C. Exhaust gas cleaning device
CN109694042A (en) * 2017-10-20 2019-04-30 中国石化工程建设有限公司 A kind of reforming hydrogen-preparation reactor and its method of reburner and reformation hydrogen production reaction

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5846495A (en) * 1995-07-12 1998-12-08 Engelhard Corporation Structure for converter body
DE19928237A1 (en) * 1999-06-21 2000-12-28 Emitec Emissionstechnologie Stress-free engine exhaust catalyst structure in flat and corrugated sheet metal, has arrangement of diametrically-opposite layers with no connections to casing
DE102005043196A1 (en) * 2005-09-09 2007-03-15 Emitec Gesellschaft Für Emissionstechnologie Mbh Method for producing an annular honeycomb body, and annular honeycomb body

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ATE45781T1 (en) * 1986-05-12 1989-09-15 Interatom HONEYCOMB BODY, IN PARTICULAR CATALYST CARRIER|BODY, WITH METAL SHEET LAYERS INTERLOCKED IN OPPOSITIONS AND PROCESS FOR ITS MANUFACTURE.
ATE45780T1 (en) * 1986-05-12 1989-09-15 Interatom METALLIC CATALYST CARRIER WITH INVOLVENT LAYERS.
DE4016276C1 (en) * 1990-05-21 1991-06-20 Behr Gmbh & Co

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103429345A (en) * 2011-03-10 2013-12-04 株式会社F.C.C. Exhaust gas cleaning device
CN103429345B (en) * 2011-03-10 2015-11-25 株式会社F.C.C. Exhaust gas purification apparatus
CN109694042A (en) * 2017-10-20 2019-04-30 中国石化工程建设有限公司 A kind of reforming hydrogen-preparation reactor and its method of reburner and reformation hydrogen production reaction
CN109694042B (en) * 2017-10-20 2021-03-05 中国石化工程建设有限公司 Reforming hydrogen production reactor, reforming furnace thereof and reforming hydrogen production reaction method

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Publication number Publication date
DE4215986A1 (en) 1993-11-18
KR100219389B1 (en) 1999-09-01
KR940005313A (en) 1994-03-21
CN1035894C (en) 1997-09-17

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