CN108096129A - A kind of preparation method of novel alga clay mask - Google Patents
A kind of preparation method of novel alga clay mask Download PDFInfo
- Publication number
- CN108096129A CN108096129A CN201810179360.0A CN201810179360A CN108096129A CN 108096129 A CN108096129 A CN 108096129A CN 201810179360 A CN201810179360 A CN 201810179360A CN 108096129 A CN108096129 A CN 108096129A
- Authority
- CN
- China
- Prior art keywords
- polyurethane
- particle
- film
- release paper
- clay
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/96—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution
- A61K8/97—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution from algae, fungi, lichens or plants; from derivatives thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/0212—Face masks
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/36—Carboxylic acids; Salts or anhydrides thereof
- A61K8/365—Hydroxycarboxylic acids; Ketocarboxylic acids
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q17/00—Barrier preparations; Preparations brought into direct contact with the skin for affording protection against external influences, e.g. sunlight, X-rays or other harmful rays, corrosive materials, bacteria or insect stings
- A61Q17/04—Topical preparations for affording protection against sunlight or other radiation; Topical sun tanning preparations
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/02—Preparations for care of the skin for chemically bleaching or whitening the skin
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/08—Anti-ageing preparations
Abstract
The invention discloses a kind of preparation methods of novel alga clay mask.The present invention is mainly that polyurethane hydrogel particle, thermoplastic polyurethane particle, solvent are placed in reactor, and constant temperature, which stirs, causes polyurethane hydrogel particle and thermoplastic polyurethane particle to be completely dissolved in solvent, and polyurethane solutions are made after cooling；Algae clay powder is added in polyurethane solution to stir evenly, and obtains solidliquid mixture；By solidliquid mixture vacuum defoaming, then rapid even application immerses release paper in deionized water in release paper, treats that solidliquid mixture is fully cured film forming and is placed on drying in 50 DEG C of drying boxes, release paper is removed after release paper and film cooling；Film is immersed in licorice extract and Glycolic acid mixed solution after 3h, then film is taken out from mixed solution；Film is cut into suitably sized shape to get product according to practical application request.Material of the present invention is easy to get, equipment is simple, product energy cleaning skin, increases skin humidity, wrinkle reduction.
Description
Technical field
The invention belongs to composite organic-inorganic material technical fields, and in particular to a kind of preparation of novel alga clay mask
Method.
Background technology
Modern environment pollutes and itself facial cleansing is improper easily melanin deposition is caused to cause skin intensely dark, even
Infection is be easy to cause, causes allergic phenomena.Algae clay and mineral clay mask at present on the market is aiming at this phenomenon
And design, but when using algae clay with mineral clay mask, facial mask easily siphons away the moisture of skin in itself instead, causes flesh
Skin is dried, and is not easily cleaned after use totally, and effect is often run counter to desire.Table can either be cleaned by lacking one kind on the market at present
Chrotoplast metabolism product and excess oil, and replenishing water and preserving moisture and bright color and other effects are capable of providing, and easy cleaning will not
Cause remaining facial mask.
The content of the invention
It is easy to get it is an object of the invention to provide a kind of material, the preparation method of the simple novel alga clay mask of equipment.
The method of the present invention includes following steps in sequence：
(1) the polyurethane hydrogel particle for drying 10~18 parts by weight, the thermoplastic polyurethane of 25~35 parts by weight
Grain, the solvent of 110 parts by weight are placed in reactor, and constant temperature is in 50~80 DEG C of stirrings so that polyurethane hydrogel particle and thermoplastics type
Polyurethane particles are completely dissolved in solvent, and after being cooled to room temperature, polyurethane solutions are made；
(2) the drying algae clay powder stirring that 30~50 parts by weight are added in polyurethane solutions made from step (1) is equal
It is even, obtain solidliquid mixture；
(3) by solidliquid mixture vacuum defoaming 0.5h obtained by step (2), then rapid even application will in release paper
Release paper is immersed in deionized water, treats that solidliquid mixture is fully cured film forming and is placed in 50 DEG C of drying box, dry 1~2h,
Release paper is removed after release paper and film cooling；
(4) film made from step (3) is immersed in licorice extract and Glycolic acid mixed solution after 3h, then by film from mixing
It is taken out in solution；
(5) film made from step (4) is cut into right dimensions and shapes according to practical application request, that is, one kind is made
Novel alga clay mask.
Preferably, step (1) the polyurethane hydrogel particle is cation type polyurethane hydrogel particle.
Preferably, step (1) the thermoplastic polyurethane particle be polyether polyurethane particle, shore hardness 70A
Or 75A.
Preferably, step (1) described solvent is at least one in n,N-Dimethylformamide and n,N-dimethylacetamide
Kind.
Preferably, the algae clay powder described in step (2) is the brown powder of 500~2000 mesh numbers.
Preferably, in solidliquid mixture obtained by step (2), polyurethane hydrogel, thermoplastic polyurethane, solvent, algae clay
The weight percent of powder is：Polyurethane hydrogel accounts for 5.7%~8.5%, and thermoplastic polyurethane accounts for 14.3%~16.4%, molten
Agent accounts for 51.6%~62.9%, and algae clay powder accounts for 17.1%~23.5%.
Preferably, in step (4), the weight percent of licorice extract and Glycolic acid mixed solution is：Licorice extract
11~15% are accounted for, Glycolic acid accounts for 11~15%, and deionized water accounts for 70~78%.
Preferably, facial mask appearance is brown obtained by step (5), by being coated on consolidating in release paper in regulating step (3)
Liquid mixture thickness control facial mask thickness is between 0.50~0.80mm.
Seaweed cement content height (accounting for weight ratio 37.5%-56.3%), the seaweed clay mask can inhale in product of the present invention
Attached excess oil and dead skin, so as to play the role of cleaning skin；Meanwhile can to increase skin wet for the algae clay ingredient in facial mask
Degree promotes skin elasticity.Facial mask impregnates 3h in Glycolic acid and licorice, has adsorbed wherein substantial amounts of active ingredient, energy
Enough increase skin humidity, promote skin elasticity, desalinate blackspot, wrinkle reduction, additionally it is possible to effectively avoid damage of the ultraviolet light to skin
Wound.
Specific embodiment
Below by specific embodiment, the present invention is described in further detail, wherein, the raw material is medical
Grade product, equipment are the production equipment of general industry.
Embodiment 1：
Weigh 10 kilograms of cation type polyurethane hydrogel particles, the thermoplastic polyurethane that 25 kilograms of shore hardnesses are 70A
Particle, 110 kilograms of n,N-Dimethylformamide are added in reactor together, make polyurethane hydrogel by 50 DEG C of stirrings of constant temperature
Particle and thermoplastic polyurethane particle are completely dissolved, and obtain polyurethane solutions after cooling；Add 30 kilograms of 500 mesh seaweed
Mud powder is uniformly mixing to obtain solidliquid mixture with high speed agitator；After vacuum defoaming processing 0.5h, by solidliquid mixture with one
Then fixed thickness immerses release paper in deionized water coated in release paper, when film-forming is placed in drying box, in
50 DEG C of dry 1h remove release paper after release paper and film cooling；It is thick coated on the solidliquid mixture in release paper by adjusting
The thickness for spending to control facial mask is 0.50mm；Film is immersed into licorice extract and Glycolic acid mixed solution (licorice extract weight
Percentage composition is 11%, Glycolic acid weight percentage 11%, and deionized water weight percentage composition impregnates 3h to be 78%) middle, will
Film takes out from mixed solution；Film is finally cut into get to new sea by appropriate size and shape according to practical application request
Alga clay mask.
In the present embodiment, the weight percentage of cation type polyurethane hydrogel is 5.7% in gained solidliquid mixture,
The weight percentage of thermoplastic polyurethane particle is 14.3%, and the weight percentage of n,N-Dimethylformamide is
62.9%, the weight percentage of algae clay powder is 17.1%.Gained mask product color be brown, thickness 0.50mm.
Embodiment 2：
Weigh 12 kilograms of cation type polyurethane hydrogel particles, the thermoplastic polyurethane that 27 kilograms of shore hardnesses are 70A
Particle, 110 kilograms of n,N-dimethylacetamide are added in reactor together, make polyurethane hydrogel by 60 DEG C of stirrings of constant temperature
Particle and thermoplastic polyurethane particle are completely dissolved, and obtain polyurethane solutions after cooling；Add 35 kilograms of 1500 mesh sea
Algal gel powder is uniformly mixing to obtain solidliquid mixture with high speed agitator；Vacuum defoaming processing 0.5h after, by solidliquid mixture with
Then certain thickness immerses release paper in deionized water coated in release paper, when film-forming is placed in drying box,
In 50 DEG C of dry 1h, release paper is removed after release paper and film cooling；By adjusting coated on the solidliquid mixture in release paper
Thickness come control the thickness of facial mask be 0.60mm；Film is immersed into licorice extract and Glycolic acid mixed solution (licorice extract weight
It is 12% to measure percentage composition, Glycolic acid weight percentage 12%, and deionized water weight percentage composition impregnates 3h to be 76%) middle,
Film is taken out from mixed solution；Film is finally cut into get to new by appropriate size and shape according to practical application request
Seaweed clay mask.
The weight percentage of cation type polyurethane hydrogel is 6.5% in gained solidliquid mixture in the present embodiment,
The weight percentage of thermoplastic polyurethane particle is 14.7%, and the weight percentage of n,N-dimethylacetamide is
59.8%, the weight percentage of algae clay powder is 19.0%.Gained mask product color be brown, thickness 0.60mm.
Embodiment 3：
Weigh 14 kilograms of cation type polyurethane hydrogel particles, the thermoplastic polyurethane that 30 kilograms of shore hardnesses are 75A
Particle, 110 kilograms of n,N-Dimethylformamide are added in reactor together, make polyurethane hydrogel by 70 DEG C of stirrings of constant temperature
Particle and thermoplastic polyurethane particle are completely dissolved, and obtain polyurethane solutions after cooling；Add 40 kilograms of 1500 mesh sea
Algal gel powder is uniformly mixing to obtain solidliquid mixture with high speed agitator；Vacuum defoaming processing 0.5h after, by solidliquid mixture with
Then certain thickness immerses release paper in deionized water coated in release paper, when film-forming is placed in drying box,
50 DEG C of dry 1h remove release paper after release paper and film cooling；It is thick coated on the solidliquid mixture in release paper by adjusting
The overall thickness for spending to control facial mask is 0.70mm；Film is immersed into licorice extract and Glycolic acid mixed solution (licorice extract weight
It is 14% to measure percentage composition, Glycolic acid weight percentage 14%, and deionized water weight percentage composition impregnates 3h to be 72%) middle,
Film is taken out from mixed solution；Film is finally cut into get to new by appropriate size and shape according to practical application request
Seaweed clay mask.
The weight percentage of cation type polyurethane hydrogel is 7.2% in gained solidliquid mixture in the present embodiment,
The weight percentage of thermoplastic polyurethane particle is 15.5%, and the weight percentage of n,N-Dimethylformamide is
56.7%, the weight percentage of algae clay powder is 20.6%.Gained mask product color be brown, thickness 0.70mm.
Embodiment 4：
Weigh 16 kilograms of cation type polyurethane hydrogel particles, the thermoplastic polyurethane that 32 kilograms of shore hardnesses are 75A
Particle, 110 kilograms of n,N-Dimethylformamide are added in reactor together, make polyurethane hydrogel by 80 DEG C of stirrings of constant temperature
Particle and thermoplastic polyurethane particle are completely dissolved, and obtain polyurethane solutions after cooling；Add 45 kilograms of 2000 mesh sea
Algal gel powder is uniformly mixing to obtain solidliquid mixture with high speed agitator；Vacuum defoaming processing 0.5h after, by solidliquid mixture with
Then certain thickness immerses release paper in deionized water coated in release paper, when film-forming is placed in drying box,
In 50 DEG C of dry 2h, release paper is removed after release paper and film cooling；By adjusting coated on the solidliquid mixture in release paper
Thickness come control the thickness of facial mask be 0.80mm；Film is immersed into licorice extract and Glycolic acid mixed solution (licorice extract weight
It is 15% to measure percentage composition, Glycolic acid weight percentage 15%, and deionized water weight percentage composition impregnates 3h to be 70%) middle,
Film is taken out from mixed solution；Film is finally cut into get to new by appropriate size and shape according to practical application request
Seaweed clay mask.
The weight percentage of cation type polyurethane hydrogel is 7.9% in gained solidliquid mixture in the present embodiment,
The weight percentage of thermoplastic polyurethane particle is 15.8%, and the weight percentage of n,N-Dimethylformamide is
54.2%, the weight percentage of algae clay powder is 22.1%.Gained mask product color be brown, thickness 0.80mm.
Embodiment 5：
Weigh 18 kilograms of cation type polyurethane hydrogel particles, the thermoplastic polyurethane that 35 kilograms of shore hardnesses are 75A
Particle, 110 kilograms of n,N-dimethylacetamide are added in reactor together, make polyurethane hydrogel by 50 DEG C of stirrings of constant temperature
Particle and thermoplastic polyurethane particle are completely dissolved, and obtain polyurethane solutions after cooling；Add 50 kilograms of 2000 mesh sea
Algal gel powder is uniformly mixing to obtain solidliquid mixture with high speed agitator；Vacuum defoaming processing 0.5h after, by solidliquid mixture with
Then certain thickness immerses release paper in deionized water coated in release paper, when film-forming is placed in drying box,
In 50 DEG C of dry 2h, release paper is removed after release paper and film cooling；By adjusting coated on the solidliquid mixture in release paper
Thickness come control the overall thickness of facial mask be 0.80mm；Film is immersed into licorice extract and Glycolic acid mixed solution (licorice extract
Weight percentage is 15%, Glycolic acid weight percentage 15%, and deionized water weight percentage composition impregnates to be 70%) middle
3h takes out film from mixed solution；Film is finally cut into get to new by appropriate size and shape according to practical application request
Type seaweed clay mask.
The weight percentage of cation type polyurethane hydrogel is 8.5% in gained solidliquid mixture in the present embodiment,
The weight percentage of thermoplastic polyurethane particle is 16.4%, and the weight percentage of n,N-dimethylacetamide is
51.6%, the weight percentage of algae clay powder is 23.5%.Gained mask product color be brown, thickness 0.80mm.
Claims (8)
1. a kind of preparation method of novel alga clay mask, it is characterised in that including following steps in sequence：
(1) the polyurethane hydrogel particle for drying 10~18 parts by weight, the thermoplastic polyurethane particle of 25~35 parts by weight,
The solvent of 110 parts by weight is placed in reactor, and constant temperature is in 50~80 DEG C of stirrings so that polyurethane hydrogel particle and thermoplastics type gather
Urethane particle is completely dissolved in solvent, and after being cooled to room temperature, polyurethane solutions are made；
(2) the drying algae clay powder that 30~50 parts by weight are added in polyurethane solutions made from step (1) stirs evenly, and obtains
To solidliquid mixture；
(3) by solidliquid mixture vacuum defoaming 0.5h obtained by step (2), rapid even application, then will be release in release paper
Paper is immersed in deionized water, treats that solidliquid mixture is fully cured film forming and is placed in 50 DEG C of drying box, dry 1~2h, treat from
Release paper is removed after type paper and film cooling；
(4) film made from step (3) is immersed in licorice extract and Glycolic acid mixed solution after 3h, then by film from mixed solution
Middle taking-up；
(5) film made from step (4) is cut into right dimensions and shapes according to practical application request, that is, is made a kind of new
Seaweed clay mask.
2. the preparation method of novel alga clay mask according to claim 1, it is characterised in that：Step (1) described polyurethane
Hydrogel particle is cation type polyurethane hydrogel particle.
3. the preparation method of novel alga clay mask according to claim 1, it is characterised in that：Step (1) described thermoplastics type
Polyurethane particles are polyether polyurethane particle, and shore hardness is 70A or 75A.
4. the preparation method of novel alga clay mask according to claim 1, it is characterised in that：Step (1) described solvent is
At least one of N,N-dimethylformamide and DMAC N,N' dimethyl acetamide.
5. the preparation method of novel alga clay mask according to claim 1, it is characterised in that：Seaweed described in step (2)
Mud powder is the brown powder of 500~2000 mesh numbers.
6. the preparation method of novel alga clay mask according to claim 1, it is characterised in that：Solid-liquid obtained by step (2) mixes
It closes in object, polyurethane hydrogel, thermoplastic polyurethane, solvent, the weight percent of algae clay powder are：Polyurethane hydrogel accounts for
5.7%~8.5%, thermoplastic polyurethane accounts for 14.3%~16.4%, and solvent accounts for 51.6%~62.9%, and algae clay powder accounts for
17.1%~23.5%.
7. the preparation method of novel alga clay mask according to claim 1, it is characterised in that：In step (4), Radix Glycyrrhizae extraction
The weight percent of liquid and Glycolic acid mixed solution is：Licorice extract accounts for 11~15%, and Glycolic acid accounts for 11~15%, deionization
Water accounts for 70~78%.
8. the preparation method of novel alga clay mask according to claim 1, it is characterised in that：Obtained by step (5) outside facial mask
See as brown, by be coated in regulating step (3) the solidliquid mixture thickness control facial mask thickness in release paper 0.50~
Between 0.80mm.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810179360.0A CN108096129A (en) | 2018-03-05 | 2018-03-05 | A kind of preparation method of novel alga clay mask |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810179360.0A CN108096129A (en) | 2018-03-05 | 2018-03-05 | A kind of preparation method of novel alga clay mask |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108096129A true CN108096129A (en) | 2018-06-01 |
Family
ID=62205988
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810179360.0A Pending CN108096129A (en) | 2018-03-05 | 2018-03-05 | A kind of preparation method of novel alga clay mask |
Country Status (1)
| Country | Link |
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Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103251511A (en) * | 2013-04-15 | 2013-08-21 | 武汉华卫科技有限公司 | Skin-simulating function film and preparation method thereof |
| CN103720619A (en) * | 2013-12-24 | 2014-04-16 | 上海海洋大学 | Sargassum horneri boiled alga clay mask and preparation method thereof |
| CN107108837A (en) * | 2014-10-31 | 2017-08-29 | 路博润先进材料公司 | For delivering activating agent to the thermoplastic polyurethane film of skin surface |
-
2018
- 2018-03-05 CN CN201810179360.0A patent/CN108096129A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103251511A (en) * | 2013-04-15 | 2013-08-21 | 武汉华卫科技有限公司 | Skin-simulating function film and preparation method thereof |
| CN103720619A (en) * | 2013-12-24 | 2014-04-16 | 上海海洋大学 | Sargassum horneri boiled alga clay mask and preparation method thereof |
| CN107108837A (en) * | 2014-10-31 | 2017-08-29 | 路博润先进材料公司 | For delivering activating agent to the thermoplastic polyurethane film of skin surface |
Non-Patent Citations (3)
| Title |
|---|
| 牛尔著: "《牛尔的嫩白书》", 31 October 2006, 北京出版社 * |
| 王昌涛等编: "《化妆品植物添加剂的开发与应用》", 30 April 2013, 中国轻工业出版社 * |
| 薛巍等编: "《生物医用水凝胶》", 31 December 2012, 暨南大学出版社 * |
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Application publication date: 20180601 |
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