CN108085982A - A kind of textile material for having antibacterial functions - Google Patents
A kind of textile material for having antibacterial functions Download PDFInfo
- Publication number
- CN108085982A CN108085982A CN201711239031.2A CN201711239031A CN108085982A CN 108085982 A CN108085982 A CN 108085982A CN 201711239031 A CN201711239031 A CN 201711239031A CN 108085982 A CN108085982 A CN 108085982A
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- Prior art keywords
- parts
- textile material
- antibacterial functions
- tool
- ammonium chloride
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
- D06M15/03—Polysaccharides or derivatives thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/144—Alcohols; Metal alcoholates
- D06M13/148—Polyalcohols, e.g. glycerol or glucose
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
- D06M15/03—Polysaccharides or derivatives thereof
- D06M15/05—Cellulose or derivatives thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
- D06M15/15—Proteins or derivatives thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/507—Polyesters
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/04—Vegetal fibres
- D06M2101/06—Vegetal fibres cellulosic
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/16—Synthetic fibres, other than mineral fibres
- D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M2101/32—Polyesters
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/40—Fibres of carbon
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- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The present invention relates to a kind of ingredient natural degradables, the textile material of tool antibacterial functions that are environmentally safe and possessing strong antibiotic property and excellent mechanical performance, the healthy green non-pollution of the raw materials used composition of textile material of tool antibacterial functions is provided, it is environmentally friendly and to human body without ill effect, compared to common textile material, the textile material of tool antibacterial functions provided by the present invention has excellent antibiotic property, it is raw materials used inexpensively, cost is relatively low, with low-cost advantage while with excellent properties, with high cost performance, great popularization, and to inherently a kind of recycling of pineapple numb material, reduce the wasting of resources.
Description
Technical field
The present invention relates to a kind of textile field more particularly to a kind of ingredient natural degradable, environmentally safe and tools
The textile material of the tool antibacterial functions of standby strong antibiotic property and excellent mechanical performance.
Background technology
Present textile fabric has highly embodied the characteristics of novelty, complexity, variation and functionalization of product, city
Huge demand is generated for high-performance, high added value, the clothes of specific function, dress ornament and family textile fabric, especially clothes,
In terms of dress ornament, present people generate increasing need while pursuit clothes, dress ornament are beautiful to its comfort level and security
It asks.
Patent Office of the People's Republic of China discloses a kind of application for a patent for invention of textile material on December 14th, 2016, applies for notification number
For CN106213637A, which coordinates copper ammonia fiber using chitosan fiber, is added for conventional textile material certain
Antibiotic property and antibacterial ability, but it does not improve textile material flexibility, elasticity etc., and copper ammonia fiber price is held high
It is expensive, textile material is prepared using copper ammonia fiber and inherently causes cost increase.
The content of the invention
To solve novelty, complexity, variation and the function that above-mentioned present textile fabric has highly embodied product
The characteristics of change, market generate huge demand for high-performance, high added value, the clothes of specific function, dress ornament and family's textile fabric,
Especially in terms of clothes, dress ornament, present people generate its comfort level and security while pursuit clothes, dress ornament are beautiful
The problem of increasing demand, the present invention provides a kind of ingredient natural degradables, environmentally safe and possess strong antibacterial
Property and excellent mechanical performance tool antibacterial functions textile material.
To achieve the above object, the present invention uses following technical scheme：
A kind of textile material for having antibacterial functions, the textile material of the tool antibacterial functions include the raw material of following parts by weight：
95~120 parts of cotton fiber, 65~90 parts of terylene, wooden 75~90 parts of carbon fiber, 35~45 parts of chitosan, guar gum hydroxypropyl
40~50 parts of base trimethyl ammonium chloride, 57~65 parts of polyadipate/butylene terephthalate, 2~5 parts of glycerine and pina surpass
5~8 parts of micro mist suspension.
Preferably, the textile material of the tool antibacterial functions includes the raw material of following parts by weight：Cotton fiber 105~
120 parts, 75~90 parts of terylene, wooden 80~85 parts of carbon fiber, 40~45 parts of chitosan, guar hydroxypropyltrimonium chlorine
Change 40~45 parts of ammonium, 60~65 parts of polyadipate/butylene terephthalate, 3~4 parts of glycerine and pina Ultramicro-powder suspension 6
~7 parts.
Preferably, the textile material of the tool antibacterial functions includes the raw material of following parts by weight：115 parts of cotton fiber,
85 parts of terylene, wooden 80 parts of carbon fiber, 42 parts of chitosan, 43 parts of guar hydroxypropyltrimonium ammonium chloride, polyadipate/
7 parts of 65 parts of butylene terephthalate, 3 parts of glycerine and pina Ultramicro-powder suspension.
Preferably, the deacetylation of the chitosan is 80~95%.
Preferably, the guar hydroxypropyltrimonium ammonium chloride preferred molecular weight is 2.2 × 106~2.4 × 106's
Guar hydroxypropyltrimonium ammonium chloride is as raw material.
Preferably, the pina Ultramicro-powder suspension is the mixed liquor of pina Ultramicro-powder, casein and water.
Preferably, the casein is 0.7~0.9wt%, the total solid content of the pina Ultramicro-powder suspension for 9~
11%, surplus is water.
Preferably, the cotton fiber is preferably bombax cotton.
Polyadipate/butylene terephthalate abbreviation PBAT, is by tetramethylene adipate（PBA）And terephthalic acid (TPA)
Butanediol ester（PBT）Copolymer, tetramethylene adipate and the characteristic of mutual-phenenyl two acid bromide two alcohol ester are had both, with 3- hydroxyl fourths
Acid -4 hydroxybutyric acid copolyesters has biodegradability, is a kind of to human body and the non-harmful green environmental protection degradable of environment
Material, it is anti-strengthening tool also with good heat resistance, ductility and elongation at break as one of main basis material
Play the role of in every mechanical property of the textile material of bacterium function great.
Individual chitosan material is not suitable for preparing textile material, the textile material flexibility being prepared separately
Low, poor toughness, even if thus chitosan material textile material possess good antibiotic property, microbial resistance, antiviral
The excellent specific properties such as property and cancer resistance can not be but widely used always, in the present invention, Guar be added in into chitosan
Glue hydroxypropyl-trimethyl ammonium chloride mix so that textile material matrix flexibility rise, while increase textile material water imbibition and
Gas permeability can give textile material more outstanding absorbing sweat performance, and can further promote weaving with the addition of glycerine
Water imbibition, gas permeability and the flexibility index of material, this is because glycerol molecule can disperse and be embedded in chitosan with
Between the macromolecular of guar hydroxypropyltrimonium ammonium chloride mixed system, weaken molecule hydrogen bond, to big point in mixed system
Minor structure has certain adjustment effect, and can increase the relatively long of chitosan macromolecular chain after glycerol molecule insertion
Degree forms Filamentous tissue, further improves the flexibility of textile material.
Pina（Pineapple Leaf Fiber, PALF）It is a kind of extremely excellent natural plant fibre of mechanical property
Material has the characteristics that antibacterial deodourizing, good absorption property, degradable, is a kind of environmentally protective natural material of health.
Pina has longitudinal crack, and rough surface has protrusion, there is substantial amounts of hole in protrusion, forms a kind of minimum ruler
Very little three-dimensional structure considerably increases its specific surface area, makes it have good capillary effect, adsorptivity and gas permeability.
But since pina is a kind of natural plant fibre, and it is used less, in many cases due to pineapple grower
The processing such as do not know its purposes and it is burned or is filled, make it discarded, not only polluted environment but also wasted resource, thus this
Invention is also a kind of protection to environment and the recycling of resource to the utilization of pina.
Bombax cotton is most thin, most light, degree of hollowness highest, most warming Fiber Materials in natural ecological fiber, has light
Clean, antibacterial, mothproof, mould proof, soft, not good characteristics such as easy entanglement, ecology, warming and moisture-absorbing moisture-keeping.
The present invention excellent effect be：
1）The healthy green non-pollution of the raw materials used composition of textile material of tool antibacterial functions provided by the present invention, it is environmentally friendly
And to human body without ill effect；
2）Compared to common textile material, the textile material of tool antibacterial functions provided by the present invention has excellent antibacterial
Property；
3）Raw materials used inexpensively cost is relatively low, with low-cost advantage while with excellent properties, has
High cost performance, great popularization；
4）To inherently a kind of recycling of pineapple numb material, reduce the wasting of resources.
Specific embodiment
Embodiment 1
A kind of textile material for having antibacterial functions, the textile material of the tool antibacterial functions include the raw material of following parts by weight：
95 parts of cotton fiber, 65 parts of terylene, wooden 75 parts of carbon fiber, 35 parts of chitosan, guar hydroxypropyltrimonium ammonium chloride 40
5 parts of part, 57 parts of polyadipate/butylene terephthalate, 2 parts of glycerine and pina Ultramicro-powder suspension.
Embodiment 2
A kind of textile material for having antibacterial functions, the textile material of the tool antibacterial functions include the raw material of following parts by weight：
120 parts of cotton fiber, 90 parts of terylene, wooden 90 parts of carbon fiber, 45 parts of chitosan, guar hydroxypropyltrimonium ammonium chloride 50
8 parts of part, 65 parts of polyadipate/butylene terephthalate, 5 parts of glycerine and pina Ultramicro-powder suspension.
Embodiment 3
A kind of textile material for having antibacterial functions, the textile material of the tool antibacterial functions include the raw material of following parts by weight：
105 parts of cotton fiber, 75 parts of terylene, wooden 80 parts of carbon fiber, 40 parts of chitosan, guar hydroxypropyltrimonium ammonium chloride 40
6 parts of part, 60 parts of polyadipate/butylene terephthalate, 3 parts of glycerine and pina Ultramicro-powder suspension.
Embodiment 4
A kind of textile material for having antibacterial functions, the textile material of the tool antibacterial functions include the raw material of following parts by weight：
120 parts of cotton fiber, 90 parts of terylene, wooden 85 parts of carbon fiber, 45 parts of chitosan, guar hydroxypropyltrimonium ammonium chloride 45
7 parts of part, 65 parts of polyadipate/butylene terephthalate, 4 parts of glycerine and pina Ultramicro-powder suspension.
Embodiment 5
A kind of textile material for having antibacterial functions, the textile material of the tool antibacterial functions include the raw material of following parts by weight：
115 parts of cotton fiber, 85 parts of terylene, wooden 80 parts of carbon fiber, 42 parts of chitosan, guar hydroxypropyltrimonium ammonium chloride 43
7 parts of part, 65 parts of polyadipate/butylene terephthalate, 3 parts of glycerine and pina Ultramicro-powder suspension.
Anti-microbial property detection is carried out to the textile material of the tool antibacterial functions obtained by Examples 1 to 5, testing result is such as
Under：
Gram positive staphylococcus aureus and Gram-E. coli are selected as test strain, by two kinds of bacteriums point
Be not suspended in 100 μm of ol/L of concentration, prepared in the phosphate buffer of pH=7 needed for bacterium solution, bacterium solution is dropped in obtained by embodiment
Tool antibacterial functions textile material on, and by obtained by another embodiment tool antibacterial functions textile material with sandwich
Form superposition, be subject to sterile weight pressure and ensure that bacterium comes into full contact with the weaving for treating measuring tool antibacterial functions obtained by embodiment
Material, contact 5-30min after will receive antibiotic property test embodiment obtained by tool antibacterial functions textile material be put into it is dense
It spends in the centrifuge tube for the sterile hypo solution of 0.02mol/L and vibrates 2min, rear 100 μm of ol/L, the phosphorus of pH=7
The above-mentioned solution of phthalate buffer serial dilution is placed solution when being in culture medium, the constant temperature incubation under the conditions of 37 DEG C
For 24 hours, surviving bacteria colony counts are finally counted and calculate antibiotic rate；Test is obtained as a result, the tool obtained by above example resists
The textile material of bacterium function is all killing two kinds of bacteriums in 5min, has very excellent antibiotic property.
Claims (8)
1. a kind of textile material for having antibacterial functions, which is characterized in that the textile material of the tool antibacterial functions includes following heavy
Measure the raw material of number：95~120 parts of cotton fiber, 65~90 parts of terylene, wooden 75~90 parts of carbon fiber, chitosan 35~45
Part, 40~50 parts of guar hydroxypropyltrimonium ammonium chloride, 57~65 parts of polyadipate/butylene terephthalate, glycerine 2~
5 parts and 5~8 parts of pina Ultramicro-powder suspension.
2. a kind of textile material for having antibacterial functions according to claim 1, which is characterized in that the tool antibacterial functions
Textile material includes the raw material of following parts by weight：105~120 parts of cotton fiber, 75~90 parts of terylene, wooden carbon fiber 80~85
Part, 40~45 parts of chitosan, 40~45 parts of guar hydroxypropyltrimonium ammonium chloride, polyadipate/terephthalic acid (TPA)
6~7 parts of 60~65 parts of fourth diester, 3~4 parts of glycerine and pina Ultramicro-powder suspension.
3. a kind of textile material for having antibacterial functions according to claim 1, which is characterized in that the tool antibacterial functions
Textile material includes the raw material of following parts by weight：115 parts of cotton fiber, 85 parts of terylene, wooden 80 parts of carbon fiber, chitosan
42 parts, 43 parts of guar hydroxypropyltrimonium ammonium chloride, 65 parts of polyadipate/butylene terephthalate, 3 parts of glycerine and pineapple
Numb 7 parts of Ultramicro-powder suspension.
4. the textile material of a kind of tool antibacterial functions according to claim 1,2 or 3, which is characterized in that described deacetylated
The deacetylation of chitin is 80~95%.
A kind of 5. textile material of tool antibacterial functions according to claim 1,2 or 3, which is characterized in that the guar gum
Hydroxypropyl-trimethyl ammonium chloride preferred molecular weight is 2.2 × 106~2.4 × 106Guar hydroxypropyltrimonium ammonium chloride conduct
Raw material.
A kind of 6. textile material of tool antibacterial functions according to claim 1,2 or 3, which is characterized in that the pina
Ultramicro-powder suspension is the mixed liquor of pina Ultramicro-powder, casein and water.
7. a kind of textile material for having antibacterial functions according to claim 6, which is characterized in that the casein is 0.7
~0.9wt%, the total solid content of the pina Ultramicro-powder suspension is 9~11%, and surplus is water.
A kind of 8. textile material of tool antibacterial functions according to claim 1,2 or 3, which is characterized in that the cotton fiber
Preferably bombax cotton.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711239031.2A CN108085982A (en) | 2017-11-30 | 2017-11-30 | A kind of textile material for having antibacterial functions |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711239031.2A CN108085982A (en) | 2017-11-30 | 2017-11-30 | A kind of textile material for having antibacterial functions |
Publications (1)
| Publication Number | Publication Date |
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| CN108085982A true CN108085982A (en) | 2018-05-29 |
Family
ID=62173509
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201711239031.2A Pending CN108085982A (en) | 2017-11-30 | 2017-11-30 | A kind of textile material for having antibacterial functions |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108842255A (en) * | 2018-07-11 | 2018-11-20 | 广州迪柯尼服饰股份有限公司 | A kind of antibacterial pro-skin textile material |
| CN112978987A (en) * | 2021-02-19 | 2021-06-18 | 北京九泉科技有限公司 | Novel water purification unit made of environment-friendly materials |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105671742A (en) * | 2016-03-31 | 2016-06-15 | 杜敏 | Bamboo carbon fiber fabric and processing method thereof |
| CN107385539A (en) * | 2016-05-17 | 2017-11-24 | 宁波禾素纤维有限公司 | Applications of the PHA as new type natural anti-biotic material in textile preparation |
-
2017
- 2017-11-30 CN CN201711239031.2A patent/CN108085982A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105671742A (en) * | 2016-03-31 | 2016-06-15 | 杜敏 | Bamboo carbon fiber fabric and processing method thereof |
| CN107385539A (en) * | 2016-05-17 | 2017-11-24 | 宁波禾素纤维有限公司 | Applications of the PHA as new type natural anti-biotic material in textile preparation |
Non-Patent Citations (1)
| Title |
|---|
| 周蓉、聂建斌主编: "《纺织品设计》", 30 September 2011, 东华大学出版社 * |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108842255A (en) * | 2018-07-11 | 2018-11-20 | 广州迪柯尼服饰股份有限公司 | A kind of antibacterial pro-skin textile material |
| CN112978987A (en) * | 2021-02-19 | 2021-06-18 | 北京九泉科技有限公司 | Novel water purification unit made of environment-friendly materials |
| CN112978987B (en) * | 2021-02-19 | 2021-11-12 | 北京九泉科技有限公司 | Novel water purification unit made of environment-friendly materials |
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