CN108085976A - A kind of easily emulsification and crude oil - Google Patents
A kind of easily emulsification and crude oil Download PDFInfo
- Publication number
- CN108085976A CN108085976A CN201711369581.6A CN201711369581A CN108085976A CN 108085976 A CN108085976 A CN 108085976A CN 201711369581 A CN201711369581 A CN 201711369581A CN 108085976 A CN108085976 A CN 108085976A
- Authority
- CN
- China
- Prior art keywords
- crude oil
- emulsification
- acid
- polyoxyethylene ether
- aeo
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/224—Esters of carboxylic acids; Esters of carbonic acid
- D06M13/2246—Esters of unsaturated carboxylic acids
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/165—Ethers
- D06M13/17—Polyoxyalkyleneglycol ethers
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
- D06M13/203—Unsaturated carboxylic acids; Anhydrides, halides or salts thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/53—Polyethers
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/10—Animal fibres
- D06M2101/12—Keratin fibres or silk
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/40—Reduced friction resistance, lubricant properties; Sizing compositions
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Detergent Compositions (AREA)
- Emulsifying, Dispersing, Foam-Producing Or Wetting Agents (AREA)
Abstract
The invention discloses a kind of easily emulsification and crude oil, the easy emulsification and crude oil include：Methyl oleate 55 65%；Vegetable fatty acid 2 5%；Polyethers emulsifier 20 40%；Emulsion stabilizer 0.1 3%；Water 5 10%.Methyl oleate content of the present invention is high, has the performances such as preferable lubricity, convergence, antistatic property, easy cleaning；The present invention is more environmentally-friendly without using induced by alkyl hydroxybenzene surfactant；The present invention is reconstituted in winter, 0 DEG C of water, rapid to emulsify without stirring, and emulsion stability, can keep 48 it is small when it is not stratified.
Description
Technical field
The invention belongs to textile process fields, and in particular to a kind of easily emulsification and crude oil.
Background technology
Wool is the important source material of textile industry, it has many advantages, such as that elasticity is good, hygroscopicity is strong, warmth retention property is good, in top grade
Extensive application in terms of woven fabric.Wool textile is famous with its luxurious graceful, natural style comfortable and easy to wear, particularly sheep
Suede has the good name of " soft gold ".It is a kind of wherein important finish that wool process, which will pass through pre-treatment and crude oil,.Property
Can superior and crude oil can make to pass through the equipment such as carding, spinning in wool process, prevent scattered hair, winding,
Phenomena such as broken end, can assign the performances such as smooth, soft, the antistatic, boundling of wool.
Generally required with crude oil and be diluted to stable lotion and could use, conventional and crude oil needed in dilution plus
Water is vigorously stirred later；It waits in winter, it is also necessary to which hot water can just emulsify, together with this just makes to use with crude oil and adds
Process loses time also to need to increase equipment.In addition, existing and crude oil is often using induced by alkyl hydroxybenzene surfactant, this kind of surface
Activating agent emulsifiability is good, but harmful, prohibites use by European Union.
The content of the invention
For problems of the prior art, the present invention is intended to provide a kind of easily emulsifying and crude oil, it can be at 0 DEG C
Under the conditions of emulsify rapidly, form homogeneous latex emulsion, greatly save with the cost of crude oil emulsification and time, and without using alkyl phenol
Class surfactant, it is more environmentally-friendly.
In order to achieve the above objectives, the present invention proposes following technical scheme：A kind of easily emulsification and crude oil, component and content
For：
Wherein, the vegetable fatty acid is selected from cocinic acid, palmitoleic acid, myristic acid, lauric acid, linoleic acid, Asia
One or more in numb acid.
The polyethers emulsifier is selected from AEO, isooctanol polyethoxylate, heterogeneous ten alcohol polyoxyethylene ether, isomery 13
At least two in alcohol polyoxyethylene ether.
The polyethers emulsifier is selected from AEO, isooctanol polyethoxylate, heterogeneous ten alcohol polyoxyethylene ether, isomery 13
At least two in alcohol polyoxyethylene ether.
EO value=7~9 of the AEO；EO value=5~9 of the isooctanol polyethoxylate；The ten alcohol polyoxy of isomery
EO=3~9 of vinethene；EO=3~12 of the isomerous tridecanol polyoxyethylene ether.
The polyethers emulsifier is selected from AEO fatty alcohol polyoxyethylene ether (EO=7-9), isooctanol polyethoxylate (EO
=5-9), heterogeneous ten alcohol polyoxyethylene ether (EO=3-9), at least two in isomerous tridecanol polyoxyethylene ether (EO=3-12)
Kind.
The polyethers emulsifier is selected from AEO-3, AEO-7, E-1003, E-1307, E-1309, E-1007, E-1312, E-
1303rd, at least two in the isooctanol polyethoxylate of E-1009, EO=9, the isooctanol polyethoxylate of EO=7.
EO values are between 3-12 in the polyether-type emulsifier that the present invention selects, and EO values are lipophilic emulsifier in 3-5, EO
Value is hydrophilic emulsifier between 9-12, and hydrophilic emulsifier and lipophilic emulsifier are used in mixed way, the HLB of regulation system
Value, makes methyl oleate can be very good to emulsify；Wherein EO values can also play the performance for helping emulsification between 5-9, have easy
The performance of cleaning.
One kind in octanol, isooctanol, laruyl alcohol, ten alcohol of isomery, isomerous tridecanol of the emulsion stabilizer or
It is a variety of.
The content ratio of the methyl oleate and polyethers emulsifier is at least 1.5: 1.Such ratio can emulsify system
It is more rapid and stable.
It is provided by the invention it is easy emulsification and crude oil can under the conditions of 0-80 DEG C quick emulsification, even if in winter, 0 DEG C of water into
Row reconstitute, can also emulsify rapidly, the emulsion-stabilizing after emulsification, can keep 48 it is small when it is not stratified；The present invention uses polyethers breast
Agent is more environmentally protective without using induced by alkyl hydroxybenzene surfactant；Methyl oleate content of the present invention is high, has preferable profit
The performances such as slip, convergence, antistatic property, easy cleaning, environmental protection.
Specific embodiment
With reference to specific embodiment, the present invention is further explained.It is to be understood that these embodiments are merely to illustrate the present invention
Rather than it limits the scope of the invention.In addition, it should also be understood that, after present disclosure has been read, those skilled in the art can
To be made various changes or modifications to the present invention, such equivalent forms equally fall within limited range of the present invention.
Embodiment 1
A kind of easily emulsification and crude oil, each component and its content are：Methyl oleate：55%；Cocinic acid：4%, sub- oil
Acid：1%；AEO-3：3%, 1307：10%；1309：5%, isooctanol polyethoxylate (EO=9)：12%；Laruyl alcohol 0.1%；
Water 9.9%.The quick emulsification under the conditions of 0 DEG C, without stirring, the emulsion-stabilizing after emulsification, can keep 48 it is small when it is not stratified；Profit
The performances such as slip, convergence, antistatic property are good, easy cleaning.
Embodiment 2
A kind of easily emulsification and crude oil, each component and its content are：Methyl oleate：65%；Palmitoleic acid oleic acid：1%, the moon
Cinnamic acid：1%；1303：4%, 1007：8%；1312：5%, isooctanol polyethoxylate (EO=7)：8%；It is isooctanol 1%, different
Ten alcohol 1% of structure, isomerous tridecanol 1%；Water 5%.The quick emulsification under the conditions of 0 DEG C, without stirring, the emulsion-stabilizing after emulsification,
Can keep 48 it is small when it is not stratified；The performances such as lubricity, convergence, antistatic property are good, easy cleaning.
Embodiment 3
A kind of easily emulsification and crude oil, each component and its content are：Methyl oleate：60%；Myristic acid：2%, sub- oil
Acid：1%；1003：2%, 1303: 2%；AEO-7：10%, 1307：5%, 1009：5%, isooctanol polyethoxylate (EO=
9)：5%；Octanol 1.5%, laruyl alcohol 0.5%；Water 6%.The quick emulsification under the conditions of 0 DEG C, without stirring, the lotion after emulsification
Stablize, can keep 48 it is small when it is not stratified；The performances such as lubricity, convergence, antistatic property are good, easy cleaning.
The easy emulsification of the present invention and crude oil have good application performance, be suitble to it is a variety of under the conditions of wool processing.Processing
It in the process without stirring, will directly be added in crude oil in cylinder, water filling, that is, emulsifiable, and reduce time process and cost；Emulsifiability
It is good, stablize not stratified；It is more environmentally-friendly using polyethers emulsifier；Methyl oleate content is high, has preferable lubricity, boundling
The performances such as property, antistatic property, easy cleaning, environmental protection.
Than the above described, the present invention can also have other modes realization, not depart from the premise of present invention
Under, any obvious replacement is within protection scope of the present invention.
Claims (8)
1. a kind of easily emulsification and crude oil, which is characterized in that according to mass percent, the component and content of the easy emulsification and crude oil
For：
2. easy emulsification according to claim 1 and crude oil, which is characterized in that the vegetable fatty acid is selected from coconut oil
One or more in acid, palmitoleic acid, myristic acid, lauric acid, linoleic acid, leukotrienes.
3. easy emulsification according to claim 1 and crude oil, which is characterized in that the polyethers emulsifier is selected from AEO, different pungent
At least two in alcohol polyoxyethylene ether, heterogeneous ten alcohol polyoxyethylene ether, isomerous tridecanol polyoxyethylene ether.
4. easy emulsification according to claim 3 and crude oil, which is characterized in that EO value=7~9 of the AEO；It is described different pungent
EO value=5~9 of alcohol polyoxyethylene ether；EO=3~9 of the heterogeneous ten alcohol polyoxyethylene ether；The isomerous tridecanol polyoxy
EO=3~12 of vinethene.
5. easy emulsification according to claim 3 and crude oil, which is characterized in that the polyethers emulsifier be selected from AEO-3,
The isooctanol polyoxyethylene of AEO-7, E-1003, E-1307, E-1309, E-1007, E-1312, E-1303, E-1009, EO=9
Ether, EO=7 isooctanol polyethoxylate at least two.
6. easy emulsification according to claim 1 and crude oil, which is characterized in that the emulsion stabilizer is selected from octanol, different
One or more in octanol, laruyl alcohol, ten alcohol of isomery, isomerous tridecanol.
7. easy emulsification according to claim 1 and crude oil, which is characterized in that the methyl oleate contains with polyethers emulsifier
Amount is than being at least 1.5: 1.
8. a kind of easy emulsification and the preparation method of crude oil, which is characterized in that the preparation method comprises the following steps：
(1) raw material components are prepared according to following mass percents：
(2) above-mentioned raw materials are mixed, without stirring.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711369581.6A CN108085976A (en) | 2017-12-18 | 2017-12-18 | A kind of easily emulsification and crude oil |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711369581.6A CN108085976A (en) | 2017-12-18 | 2017-12-18 | A kind of easily emulsification and crude oil |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108085976A true CN108085976A (en) | 2018-05-29 |
Family
ID=62176031
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201711369581.6A Pending CN108085976A (en) | 2017-12-18 | 2017-12-18 | A kind of easily emulsification and crude oil |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN108085976A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108589285A (en) * | 2018-06-19 | 2018-09-28 | 浙江永金生物科技有限公司 | A kind of biology and crude oil and preparation method thereof |
| CN108677527A (en) * | 2018-06-07 | 2018-10-19 | 江苏斯尔邦石化有限公司 | A kind of weaving wax disk(-sc) and preparation method thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1558019A (en) * | 2004-01-13 | 2004-12-29 | 徐维青 | Slivering and crude oil |
| CN102071571A (en) * | 2011-01-27 | 2011-05-25 | 天津博莱恩科技发展有限公司 | Wool lubricant |
-
2017
- 2017-12-18 CN CN201711369581.6A patent/CN108085976A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1558019A (en) * | 2004-01-13 | 2004-12-29 | 徐维青 | Slivering and crude oil |
| CN102071571A (en) * | 2011-01-27 | 2011-05-25 | 天津博莱恩科技发展有限公司 | Wool lubricant |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108677527A (en) * | 2018-06-07 | 2018-10-19 | 江苏斯尔邦石化有限公司 | A kind of weaving wax disk(-sc) and preparation method thereof |
| CN108589285A (en) * | 2018-06-19 | 2018-09-28 | 浙江永金生物科技有限公司 | A kind of biology and crude oil and preparation method thereof |
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| PB01 | Publication | ||
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| RJ01 | Rejection of invention patent application after publication | ||
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Application publication date: 20180529 |