The content of the invention
For above-mentioned technical problem, the object of the present invention is to provide kind of melt-spinning apparatus and technique, especially a kind of magnetic
Property melt spinning fibers device and technique.
A kind of melt spinning process, the melt spinning process are in drawing process, and melt is applied parallel to ground
The magneticaction in direction, the melt are made as follows:
Step 1, at 30 ~ 80 DEG C, by a-Al2O3Nano particle is placed in the inorganic aluminum salting liquid that concentration is 0.5 ~ 1mol/L, is obtained
Dispersion liquid is obtained, adjusts pH value of solution to 6 ~ 7;Magnetic material particle is added in into dispersion liquid, adds and backward concentration is added dropwise in it
For the ammonium bicarbonate soln of 1 ~ 2mol/L, the volume of aluminum salt solution and ammonium bicarbonate soln is 1:0.5~2;Then gained is mixed
Liquid is spray-dried, and gained particle after drying is roasted, 400 ~ 550 DEG C of calcination temperature obtains a-Al2O3Coated magnetic material
Expect particle, wherein, a-Al2O3Nano particle and the ratio of inorganic aluminum salting liquid are 1g:100~1000mL;
Step 2, by a-Al obtained by step 12O3Coated magnetic material granule is mixed with other fibrous raw materials, and fusing both obtained.
In melt spinning process of the present invention, make a-Al preferably by the method for ultrasonic disperse2O3Nano particle is uniform
Disperse in the solution;And under preferred ultrasound condition, magnetic material particle is added in into dispersion liquid.
In fiber fabrication process of the present invention, the a-Al2O3The particle mean size of nano particle is 20 ~ 200nm, into one
Step is preferably 50 ~ 100nm.
In fiber fabrication process of the present invention, gained a-Al2O3In coated magnetic material granule, a-Al2O3Clad
Thickness is 0.2 ~ 1 micron, further preferably 0.2 ~ 0.5 micron.
In melt spinning process of the present invention, for adjusting the solution of solution ph as inorganic acid or aqueous slkali, such as lemon
Lemon acid, sodium hydroxide etc..
In melt spinning process of the present invention, " spray drying " carries out in the spray dryer of commercialization.
In melt spinning process of the present invention, the step 2, other fibrous raw materials refer to can use disclosed in the prior art
The raw material involved by melt in melt mode, such as polymer fiber raw material, glass fibre raw material, ceramic fibre raw material.Into one
Step ground, polymer fiber raw material such as polyphenylene sulfide, polypropylene, nylon, PVA, PVB etc.;It is based on the glass fibre raw material
SiO2Glass fibre raw material.
In melt spinning process of the present invention, the step 2 makes melting sources by heating, and heating temperature is higher than
Raw materials used fusing point or melting temperature are simultaneously less than a-Al2O3Fusing point, preferably above 5 ~ 10 DEG C of fusing point or melting temperature.
Melt spinning process of the present invention is preferred, and the inorganic aluminate is aluminium chloride, aluminum nitrate, aluminum sulfate.
Melt spinning process of the present invention is preferred, the a-Al2O3Nano particle and the ratio of inorganic aluminum salting liquid are 1g:
200~500mL。
Melt spinning process of the present invention is preferred, and the magnetic material is Fe, Co, Ni or two of which composition described above
Alloy, magnetic ferrites.The ferrite is ferrite disclosed in the prior art.
Melt spinning process of the present invention is preferred, and the grain size of the magnetic material particle is 1 ~ 5 micron.
Melt spinning process of the present invention is preferred, and the step 2 is:By a- obtained by polyphenylene sulfide powder, step 1
Al2O3After coated magnetic material granule and neopelex powder mixing, fusing both obtained, wherein, polyphenylene sulfide powder,
a-Al2O3The mass ratio of coated magnetic material granule and neopelex is 100:0.5~5:0~0.05(Containing 0).
Melt spinning process of the present invention is preferred, and the magnetic field intensity is 1.5 ~ 5T.
It is a further object of the present invention to provide a kind of melt-spinning apparatus that above-mentioned technique can be achieved.
A kind of melt-spinning apparatus, described device include funnel-form material placing device, and the material placing device is by charge portion and fibre
Forming part composition is tieed up, magnetic direction can be generated by being equipped in the outside of the material placing device fills parallel to the magnetic field on ground
Put, magnetic fields caused by the field generator for magnetic in entire fiberizing portion and charge portion close to charge portion and fiber into
The part of type portion junction.
Field generator for magnetic of the present invention, it is available commercially for the magnetic field device parallel to ground direction can be generated
It obtains or is made by method disclosed in the prior art.
Material placing device of the present invention is used to hold spinning melt feed.
Further, the charge portion has the housing of funnel structure.
Further, the fiberizing portion is hollow tubular, and the diameter that internal diameter prepares fiber needed for determines.
Further, magnetic fields caused by the field generator for magnetic are in entire fiberizing portion and higher than charge portion
At fiberizing portion 1 ~ 20cm of junction.
Further, magnetic fields caused by the field generator for magnetic are in entire fiberizing portion and higher than charge portion
At fiberizing portion 5 ~ 10cm of junction.
Melt-spinning apparatus of the present invention, is equipped with field generator for magnetic, and the field generator for magnetic is that can generate
Parallel to the magnetic field device in ground direction.Field generator for magnetic is flowed through when it includes the melt feed of magnetic material particle,
Can be arranged according to the direction of the magnetic line of force, the magnetic-particle to a certain degree according to identical magnetic domain orientations, with
The fiber formed afterwards then has the uniformity of magnetic orientation.
Melt-spinning apparatus of the present invention, preferably described funnel-form material placing device top are equipped with supercharging device, the supercharging dress
It puts to regulate and control the pressure inside the material device of city, the raw material contained in charge portion is made to enter fiberizing portion.
Further, the supercharging device includes pressuring plate, and the pressuring plate forms enclosure space with charge portion housing, increases
Connection connecting rod at the top of pressing plate, the connecting rod connecting power device are fixed for measuring in material placing device on the pressuring plate
The pressure measuring unit of portion's pressure, the pressure measuring unit ventilating controller connecting power device.
In above-mentioned technical proposal, the controller receives the material placing device internal pressure number from pressure measuring unit measurement gained
According to, control power set, and then keep material placing device internal pressure that slurry is made to enter fiberizing portion enough.The power dress
It puts, such as motor.
The hull outside in melt-spinning apparatus of the present invention, preferably described material placing device charge portion and fiberizing portion is equipped with
Heating layer.
Further, since the temperature requirements to charge portion and fiberizing portion are identical or different, charge portion housing
The heating layer in outside is each independent with the heating layer of fiberizing portion hull outside.
Melt-spinning apparatus of the present invention, preferably described fiberizing portion discharge port are arranged on true below fiberizing portion
The inside of empty room, the vacuum chamber is the housing for having certain length in vertical direction, equipped with vaccum-pumping equipment and for adjusting
The cooling device of whole internal vacuum chamber temperature.
Melt-spinning apparatus of the present invention, the lower section of preferably described vacuum chamber are equipped with material receiving roller.
Compared with prior art, the beneficial effects of the invention are as follows:
Magnetic-particle is contained in melt prepared by technique of the present invention, which is a-Al2O3Coated magnetic material
Particle is expected, by the a-Al with high intensity2O3It is wrapped in outside magnetic material, on the one hand can improve the gained intensity of fiber and tough
Property;Preparing a-Al2O3During coated magnetic material granule, a-Al has been used2O3Nano particle is as crystal seed, inductive formation a-
Al2O3The clad of phase crystal structure.On the other hand, a-Al2O3Fusing point it is high, magnetic material is wrapped in it, can be to avoid
Magnetisable material in it due to having an effect for other fibers and magnetic lose.It is above-mentioned molten invention also provides can be achieved
The device of body spinning technique.Melt-spinning apparatus of the present invention, is equipped with field generator for magnetic, and the field generator for magnetic is
The magnetic field device parallel to ground direction can be generated.Magnetic field is flowed through when it includes the melt feed of magnetic material particle
Device can be arranged according to the direction of the magnetic line of force, the magnetic-particle to a certain degree according to identical magnetic domain orientations,
It then has the uniformity of magnetic orientation in the fiber subsequently formed.The device structure is simple, easily operated, and spinning efficiency is high.