CN108084917A - For the adhesive waterproof coil and its manufacturing method of metal Roof - Google Patents

For the adhesive waterproof coil and its manufacturing method of metal Roof Download PDF

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Publication number
CN108084917A
CN108084917A CN201711260764.4A CN201711260764A CN108084917A CN 108084917 A CN108084917 A CN 108084917A CN 201711260764 A CN201711260764 A CN 201711260764A CN 108084917 A CN108084917 A CN 108084917A
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China
Prior art keywords
parts
butyl rubber
adhesive
sensitive adhesive
metal roof
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Pending
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CN201711260764.4A
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Chinese (zh)
Inventor
刘华静
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Dandong Sanguan Waterproof Material Co Ltd
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Dandong Sanguan Waterproof Material Co Ltd
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Priority to CN201711260764.4A priority Critical patent/CN108084917A/en
Publication of CN108084917A publication Critical patent/CN108084917A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J123/00Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers
    • C09J123/26Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers modified by chemical after-treatment
    • C09J123/28Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers modified by chemical after-treatment by reaction with halogens or compounds containing halogen
    • C09J123/283Halogenated homo- or copolymers of iso-olefines
    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04DROOF COVERINGS; SKY-LIGHTS; GUTTERS; ROOF-WORKING TOOLS
    • E04D5/00Roof covering by making use of flexible material, e.g. supplied in roll form
    • E04D5/10Roof covering by making use of flexible material, e.g. supplied in roll form by making use of compounded or laminated materials, e.g. metal foils or plastic films coated with bitumen
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24Acids; Salts thereof
    • C08K3/26Carbonates; Bicarbonates
    • C08K2003/265Calcium, strontium or barium carbonate
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2301/00Additional features of adhesives in the form of films or foils
    • C09J2301/30Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier
    • C09J2301/312Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier parameters being the characterizing feature
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2400/00Presence of inorganic and organic materials
    • C09J2400/10Presence of inorganic materials
    • C09J2400/14Glass
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2423/00Presence of polyolefin
    • C09J2423/006Presence of polyolefin in the substrate
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2423/00Presence of polyolefin
    • C09J2423/16Presence of ethen-propene or ethene-propene-diene copolymers
    • C09J2423/166Presence of ethen-propene or ethene-propene-diene copolymers in the substrate

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Architecture (AREA)
  • Civil Engineering (AREA)
  • Structural Engineering (AREA)
  • Adhesives Or Adhesive Processes (AREA)

Abstract

The present invention provides a kind of adhesive waterproof coil for metal Roof, including base, Butyl Rubber Pressure-Sensitive Adhesive self-adhesive layer and the antiadhesion barrier set gradually;Wherein, Butyl Rubber Pressure-Sensitive Adhesive self-adhesive layer includes the component of following parts by weight:35 parts of the polyisobutene that molecular weight is 10,000 100,000,24 parts of ethylene propylene diene rubber, 16 20 parts of butyl rubber, 18 23 parts of precipitated calcium carbonate, 46 parts of white carbon, molecular weight be 1,000 3500 24 28 parts of polyisobutene, 18 22 parts of Petropols C5,13 parts of polyethylene wax, 13 parts of white cement, 0.5 1 parts of antiaging agent, 12 parts of coupling agent, 12 parts of other auxiliary agents.The Butyl Rubber Pressure-Sensitive Adhesive of the present invention is permanent not solid type stabilizing material, with creep properties and self-healing property, be not in seam alice phenomenon, and color steel can be resisted and expand with heat and contract with cold the fasteners such as displacement caused by with external shock and metal Roof nail through leaking vapour seepage problem caused by waterproof layer.

Description

For the adhesive waterproof coil and its manufacturing method of metal Roof
Technical field
The present invention relates to a kind of adhesive waterproof coils and its manufacturing method for metal Roof.
Background technology
Steel construction metal Roof large area Seepage caused by expanding with heat and contract with cold with various corrosions has caused society The attention of all circles.《Structural metal containment system engineering standard》By examining, which, which determines metal Roof, to reach To level-one waterproof, it is necessary to increase waterproof layer.
The TPO waterproof rolls being currently mainly used, seam need thermal weld, and basal plane needs Mechanical Method to fix, expensive, Construction requirement technology is high.Because being empty paving, a little miss, big area roof system corrosion and leakage can be caused.
Also useful self-adhesive construction in recent years, but self-adhesive uses not ageing-resistant hot melt adhesive, only play bonding and make With;And the thickness of hot melt adhesive is usually 0.5mm or so, seam alice phenomenon often occurs.It can not support in actual use Destruction of the displacement to waterproof layer caused by imperial metal Roof expands with heat and contract with cold.
The content of the invention
To solve the problems, such as that metal Roof is gone along with sb. to guard him, the present invention provides a kind of adhesive waterproof coil for metal Roof, with Butyl Rubber Pressure-Sensitive Adhesive made of the blends such as polyisobutene (PIB), ethylene propylene diene rubber (EPDM), butyl rubber (BUTYL), It is coated on using advanced technologies on TPO/TPV films, and stabilized zone is done being sandwiched between grid cloth, lower surface is anti-sticking with that can take off Film forms the superpower ageing-resistant adhesive waterproof coil for being mainly used for metal Roof containment system.
The Butyl Rubber Pressure-Sensitive Adhesive of the present invention is permanent not solid type stabilizing material, has creep properties and self-healing property, will not There is seam alice phenomenon, and color steel can be resisted and expanded with heat and contract with cold displacement caused by with external shock and metal Roof nail Fasteners is waited to pass through, vapour seepage problem is leaked caused by waterproof layer.
The present invention provide a kind of adhesive waterproof coil for metal Roof, including set gradually base, butyl rubber Pressure sensitive adhesive self-adhesive layer and antiadhesion barrier;
Wherein, Butyl Rubber Pressure-Sensitive Adhesive self-adhesive layer includes the component of following parts by weight:Molecular weight is 10,000-100,000 3-5 parts of polyisobutene, 2-4 parts of ethylene propylene diene rubber, 16-20 parts of butyl rubber, 18-23 parts of precipitated calcium carbonate, white carbon 4-6 Part, molecular weight be 1000-3500 24-28 parts of polyisobutene, 18-22 parts of Petropols C5,1-3 parts of polyethylene wax, white cement 1-3 parts, 0.5-1 parts of antiaging agent, 1-2 parts of coupling agent, 1-2 parts of other auxiliary agents.
Preferably, Butyl Rubber Pressure-Sensitive Adhesive self-adhesive layer includes the component of following parts by weight:Molecular weight is different for 40,000 gather 4 parts of butylene, 3 parts of ethylene propylene diene rubber, 18 parts of butyl rubber, 20 parts of precipitated calcium carbonate, 5 parts of white carbon, molecular weight are 2400 26 parts of polyisobutene, 20 parts of Petropols C5,2 parts of polyethylene wax, 2 parts of white cement, 0.5 part of antiaging agent, 1 part of coupling agent, His 1 part of auxiliary agent.
Wherein, glass fiber reticular cloth is added among Butyl Rubber Pressure-Sensitive Adhesive self-adhesive layer as stabilized zone.
Base can be TPO films or TPV films, preferably TPV films.
The TPO films are the film that thermoplastic polyolefin is formed.The TPV films are thermoplasticity EPDM dynamic vulcanization bullet The film of property body extrusion calendaring.
Antioxidant 2246 can be used in the antiaging agent, there is fabulous protective action to heat, oxygen, aging cracking.
The coupling agent can be silane coupling agent, silane coupling agent can improve rubber adhesive strength, it is water-fast, The performances such as weatherability.
Other described auxiliary agents are paraffin oil, for improving rubber ageing resistance and increasing flexibility etc..
Polyethylene silicon oil film can be used in antiadhesion barrier.
The thickness of base can be 0.3-0.6mm.The thickness of Butyl Rubber Pressure-Sensitive Adhesive self-adhesive layer can be 0.9-1.5mm.This hair The thickness of bright Butyl Rubber Pressure-Sensitive Adhesive is more than skin covering of the surface more than twice, is not in seam alice phenomenon.
White cement can use No. 425 white cements or No. 325 white cements.
White cement is added in Butyl Rubber Pressure-Sensitive Adhesive self-adhesive layer in the present invention, this is because self-adhesive layer prepared by the present invention For never solid type pressure sensitive adhesive, pressure sensitive adhesive is very soft, and balanced rigidity can be played the role of by adding in white cement.
The waterproof roll of the present invention can be not only affixed directly to above the thermal insulation board of metal Roof system or on color steel Face, but also can be overlay on cement sand pulp, wet-laying, the white cement in Butyl Rubber Pressure-Sensitive Adhesive can rise with cement mortar to be changed Reaction is learned, is securely pasted onto on cement sand bed.
The present invention also provides a kind of manufacturing methods of the adhesive waterproof coil for metal Roof, comprise the following steps:
A, Butyl Rubber Pressure-Sensitive Adhesive is prepared:
(1) following raw material is prepared
3-5 parts of the polyisobutene that molecular weight is 10,000-100,000,2-4 parts of ethylene propylene diene rubber, butyl rubber 16-20 Part, 18-23 part of precipitated calcium carbonate, 4-6 parts of white carbon, molecular weight be 1000-3500 24-28 parts of polyisobutene, Petropols 18-22 parts of C5,1-3 parts of polyethylene wax, 1-3 parts of white cement, 0.5-1 parts of antiaging agent, 1-2 parts of coupling agent, other auxiliary agents 1-2 Part;
(2) it is polyisobutene, ethylene propylene diene rubber, butyl rubber, the half component of 10,000-100,000 by molecular weight Precipitated calcium carbonate, white carbon be added to pressure initial refining machine and be kneaded uniform, be then refined into film on a mill.
(3) film for preparing step (2) puts into kneader, is warming up to 135-145 DEG C, then adds in molecular weight and is Polyisobutene, Petropols C5, polyethylene wax, the precipitated calcium carbonate of residual components, the white cement of 1000-3500, antiaging agent, Coupling agent, other auxiliary agents are uniformly mixed, Butyl Rubber Pressure-Sensitive Adhesive are made;
B, it is compound
Butyl Rubber Pressure-Sensitive Adhesive prepared by step A puts into Rubber Extruder, is applied on basement membrane, forms butyl rubber pressure Quick glue self-adhesive layer, and by the use of glass fiber reticular cloth among pressure sensitive adhesive as stabilized zone;In the another of Butyl Rubber Pressure-Sensitive Adhesive self-adhesive layer Surface is isolated with can take off antiadhesion barrier and do, once-combined to form superpower ageing-resistant adhesive waterproof coil.
Superpower ageing-resistant adhesive waterproof coil according to the present invention is with ageing-resistant superior polyisobutene (PIB), ternary EP rubbers (EPDM), butyl rubber (BUTYL) are primary raw material, add never solid type pressure sensitive adhesive made of other auxiliary materials, It is coated on extrusion molding on TPV films, and pressure sensitive adhesive intermediate stable layer is done with glass fiber reticular cloth, another surface is made of that can take off antiadhesion barrier Isolation, using the once-combined superpower ageing-resistant adhesive waterproof coil of the feature of environmental protection of new generation formed of advanced technologies.
Pressure sensitive adhesive and TPV films are realized " similar compatibility " all with EPDM material.
Main body waterproof layer is made with never dry and solid characterisc material in the present invention, has creep properties and self-healing property, and exposed parts use Ageing-resistant superior TPV films completely using the thermal insulation board of steel structural roof or color steel surface is placed directly against from bonding, rise anti- Water, anticorrosion, damping, heat-blocking action, can exposed use for a long time, substantially prolong service life of steel structural roof.Product valency Lattice are less than TPO waterproof rolls, and construction cost is low and environmentally friendly simple.
The adhesive waterproof coil for metal Roof of the present invention has the following advantages:
1st, there is butyl rubber, ethylene propylene diene rubber and the superior superpower resistances to ag(e)ing of TPV, chemical resistance, heat-insulated Sound-proofing, -40 DEG C -100 DEG C of temperature in use belong to " combination among the strong ones " of waterproof material.
2nd, can be affixed directly to above the insulating layer of metal Roof system or above color steel.The excellent gas of butyl rubber Close property and watertightness can effectively stop from the corrosion of indoor and outdoor rainwater and steam to color steel.Extending metal Roof system makes Use the service life.
3rd, the thickness of Butyl Rubber Pressure-Sensitive Adhesive is more than skin covering of the surface more than twice, for permanent not solid type stabilizing material, has Creep properties and self-healing property are not in seam alice phenomenon, and can resist color steel and expand with heat and contract with cold and cause with external shock Displacement and the fasteners such as metal Roof nail through leaking vapour seepage problem caused by waterproof layer.
4th, white cement is added in Butyl Rubber Pressure-Sensitive Adhesive self-adhesive layer in the present invention, plays the work of balance self-adhesive layer hardness With;When overlay on cement sand pulp, wet-laying when, white cement in Butyl Rubber Pressure-Sensitive Adhesive can and cement mortar to play chemistry anti- Should, securely it is pasted onto on cement sand bed.
5th, fixed without Mechanical Method, cold construction, technically simple, Environmental Safety, it can be with exposed long-time service.For cement bonded sand Slurry base can overlay, the construction of wet-laying and dry-laid.
Specific embodiment
The manufacturer of the adhesive waterproof coil according to the present invention for metal Roof is described in detail below by embodiment Method.
Embodiment 1
A, Butyl Rubber Pressure-Sensitive Adhesive is prepared:
1st, by the polyisobutene 4kg of molecular weight 40000, EPDM 3kg, halogenated butyl rubber 18kg, precipitated calcium carbonate 10kg, white carbon 5kg add in pressure initial refining machine and are kneaded uniformly, are refined into film on a mill.
2nd, it will be mixed in the film input kneader of above-mentioned preparation, be warming up to 140 DEG C, and sequentially add molecular weight 2400 Polyisobutene 26kg, Petropols C5 20kg, polyethylene wax 2kg, precipitated calcium carbonate 10kg, No. 425 white cement 2kg, antioxygen Butyl Rubber Pressure-Sensitive Adhesive is made in agent 2246 0.5kg, silane coupling agent 1kg, paraffin oil 1kg.
B, it is compound
The Butyl Rubber Pressure-Sensitive Adhesive prepared input Rubber Extruder is applied on TPV films, forms Butyl rubber pressure sensitive Glue self-adhesive layer, and pressure sensitive adhesive intermediate stable layer is done with glass fiber reticular cloth, it is used on another surface of Butyl Rubber Pressure-Sensitive Adhesive self-adhesive layer Antiadhesion barrier can be taken off and done and isolated, it is once-combined to form Butyl Rubber Pressure-Sensitive Adhesive adhesive waterproof coil.
Embodiment 2
A, Butyl Rubber Pressure-Sensitive Adhesive is prepared:
1st, by the polyisobutene 5kg of molecular weight 50000, EPDM 4kg, halogenated butyl rubber 19kg, precipitated calcium carbonate 9kg, white carbon 6kg add in pressure initial refining machine and are kneaded uniformly, are refined into film on a mill.
2nd, it will be mixed in the film input kneader of above-mentioned preparation, be warming up to 140 DEG C, and sequentially add molecular weight 2500 Polyisobutene 25kg, Petropols C5 21kg, polyethylene wax 2kg, precipitated calcium carbonate 10kg, No. 325 white cement 2kg, antioxygen Butyl Rubber Pressure-Sensitive Adhesive is made in agent 2246 0.5kg, silane coupling agent 1kg, paraffin oil 1kg.
B, it is compound
The Butyl Rubber Pressure-Sensitive Adhesive prepared input Rubber Extruder is applied on TPV films, forms Butyl rubber pressure sensitive Glue self-adhesive layer, and pressure sensitive adhesive intermediate stable layer is done with glass fiber reticular cloth, it is used on another surface of Butyl Rubber Pressure-Sensitive Adhesive self-adhesive layer Antiadhesion barrier can be taken off and done and isolated, it is once-combined to form Butyl Rubber Pressure-Sensitive Adhesive adhesive waterproof coil.
Butyl Rubber Pressure-Sensitive Adhesive physical and chemical index according to the present invention meets JC/T942-2004 standards.
The waterproof roll of the present invention has butyl rubber, ethylene propylene diene rubber and the superior superpower resistances to ag(e)ing of TPV, resistance toization Learn corrosivity, sound deadener/insulator.
The waterproof roll of the present invention can be affixed directly to above the insulating layer of metal Roof system or above color steel, fourth Base rubber pressure sensitive glue is permanent not solid type stabilizing material, has creep properties and self-healing property, and the thickness of Butyl Rubber Pressure-Sensitive Adhesive Degree is more than skin covering of the surface more than twice, is not in seam alice phenomenon;The excellent air-tightness of butyl rubber and watertightness can have Effect stops from indoor and outdoor rainwater and steam to the corrosion of color steel and resists color steel and expand with heat and contract with cold and cause with external shock Displacement and the fasteners such as metal Roof nail through leaking vapour seepage problem caused by waterproof layer.
The waterproof roll of the present invention can also be overlay on cement sand pulp, wet-laying, the plain boiled water in Butyl Rubber Pressure-Sensitive Adhesive Mud can be securely pasted onto on cement sand bed with cement mortar chemically reactive.
The adhesive waterproof coil self-adhesive coiled material for metal Roof of the present invention is primarily adapted for use in the exposed room such as metal Roof Face waterproof and underground waterproof, subway waterproof-ing, underground pipe gallery waterproof, high ferro waterproof etc..

Claims (9)

1. a kind of adhesive waterproof coil for metal Roof, including set gradually base, Butyl Rubber Pressure-Sensitive Adhesive self-adhesive layer And antiadhesion barrier;
Wherein, Butyl Rubber Pressure-Sensitive Adhesive self-adhesive layer includes the component of following parts by weight:Molecular weight is the poly- of 10,000-100,000 3-5 parts of isobutene, 2-4 parts of ethylene propylene diene rubber, 16-20 parts of butyl rubber, 18-23 parts of precipitated calcium carbonate, 4-6 parts of white carbon, Molecular weight be 1000-3500 24-28 parts of polyisobutene, 18-22 parts of Petropols C5,1-3 parts of polyethylene wax, white cement 1-3 Part, 0.5-1 parts of antiaging agent, 1-2 parts of coupling agent, 1-2 parts of other auxiliary agents.
2. the adhesive waterproof coil according to claim 1 for metal Roof, wherein, Butyl Rubber Pressure-Sensitive Adhesive self-adhesive layer Include the component of following parts by weight:
4 parts of the polyisobutene that molecular weight is 40,000,3 parts of ethylene propylene diene rubber, 18 parts of butyl rubber, 20 parts of precipitated calcium carbonate, 5 parts of white carbon, molecular weight be 2400 26 parts of polyisobutene, 20 parts of Petropols C5,2 parts of polyethylene wax, 2 parts of white cement, prevent 0.5 part of aging agent, 1 part of coupling agent, 1 part of other auxiliary agents.
3. the adhesive waterproof coil according to claim 1 or 2 for metal Roof, wherein, in Butyl Rubber Pressure-Sensitive Adhesive Glass fiber reticular cloth is added among self-adhesive layer as stabilized zone.
4. the adhesive waterproof coil according to claim 1 or 2 for metal Roof, wherein, base is TPO films or TPV Film, preferably TPV films.
5. the adhesive waterproof coil according to claim 1 or 2 for metal Roof, wherein, antiadhesion barrier is polyethylene silicon Oil film.
6. the adhesive waterproof coil according to claim 1 or 2 for metal Roof, wherein, the coupling agent is silane Coupling agent.
7. the adhesive waterproof coil according to claim 1 or 2 for metal Roof, wherein, other described auxiliary agents are stone Wax oil.
8. the adhesive waterproof coil for metal Roof according to foregoing any claim, wherein, the thickness of base is 0.3-0.6mm, the thickness of Butyl Rubber Pressure-Sensitive Adhesive self-adhesive layer is 0.9-1.5mm.
9. a kind of preparation method of the adhesive waterproof coil described in claim 1 for metal Roof, including:
A, Butyl Rubber Pressure-Sensitive Adhesive is prepared:
(1) by molecular weight be the polyisobutene of 10,000-100,000, ethylene propylene diene rubber, butyl rubber, half component it is light Matter calcium carbonate, white carbon are added to pressure initial refining machine and are kneaded uniformly, are then refined into film on a mill;
(2) film for preparing step (2) puts into kneader, is warming up to 135-145 DEG C, and it is 1000- then to add in molecular weight 3500 polyisobutene, Petropols C5, polyethylene wax, the precipitated calcium carbonate of residual components, white cement, antiaging agent, coupling Agent, other auxiliary agents are uniformly mixed, Butyl Rubber Pressure-Sensitive Adhesive are made;
B, it is compound
Butyl Rubber Pressure-Sensitive Adhesive prepared by step A puts into Rubber Extruder, is applied in base, forms Butyl Rubber Pressure-Sensitive Adhesive Self-adhesive layer, and by the use of glass fiber reticular cloth among pressure sensitive adhesive as stabilized zone;On another surface of Butyl Rubber Pressure-Sensitive Adhesive self-adhesive layer Isolated with that can take off antiadhesion barrier and do, the once-combined adhesive waterproof coil formed for metal Roof.
CN201711260764.4A 2017-12-04 2017-12-04 For the adhesive waterproof coil and its manufacturing method of metal Roof Pending CN108084917A (en)

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Cited By (10)

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CN108977124A (en) * 2018-06-29 2018-12-11 烟台智本知识产权运营管理有限公司 A kind of preparation method of butyl pressure sensitive
CN109401346A (en) * 2018-10-24 2019-03-01 辽宁女娲防水建材科技集团有限公司 A kind of cold roofing reflection and heat insulation adhesive waterproof coil and preparation method, application
CN110387197A (en) * 2019-08-07 2019-10-29 常熟市三恒建材有限责任公司 A kind of self adhesive water-proof coiled material
CN111421922A (en) * 2020-04-15 2020-07-17 江苏屋堡建材科技有限公司 High-stability coated composite polymer self-adhesive waterproof coiled material and processing technology
CN112280493A (en) * 2020-11-09 2021-01-29 河南蓝翎环科防水材料有限公司 High-molecular butyl rubber waterproof coiled material and production process thereof
CN112375512A (en) * 2020-11-03 2021-02-19 广东能辉新材料科技有限公司 Non-vulcanized butyl pressure-sensitive adhesive, preparation method and application thereof, and waterproof roll
CN112852315A (en) * 2021-03-11 2021-05-28 广州天骄建筑有限公司 Production method of high-molecular waterproof coiled material
CN113372851A (en) * 2021-07-20 2021-09-10 安徽省奥佳建材有限公司 Self-adhesive rubber waterproof coiled material and preparation method thereof
CN113652182A (en) * 2021-08-19 2021-11-16 重庆新天地华宇新材料集团有限公司 Macromolecule butyl self-adhesive waterproof coiled material and preparation method thereof
CN114940879A (en) * 2021-06-04 2022-08-26 上海亥博胶粘材料有限公司 Butyl sealing adhesive tape for solar photovoltaic module and preparation method thereof

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CN108977124A (en) * 2018-06-29 2018-12-11 烟台智本知识产权运营管理有限公司 A kind of preparation method of butyl pressure sensitive
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CN111421922A (en) * 2020-04-15 2020-07-17 江苏屋堡建材科技有限公司 High-stability coated composite polymer self-adhesive waterproof coiled material and processing technology
CN112375512A (en) * 2020-11-03 2021-02-19 广东能辉新材料科技有限公司 Non-vulcanized butyl pressure-sensitive adhesive, preparation method and application thereof, and waterproof roll
CN112280493A (en) * 2020-11-09 2021-01-29 河南蓝翎环科防水材料有限公司 High-molecular butyl rubber waterproof coiled material and production process thereof
CN112280493B (en) * 2020-11-09 2022-04-26 河南蓝翎环科防水材料有限公司 High-molecular butyl rubber waterproof coiled material and production process thereof
CN112852315A (en) * 2021-03-11 2021-05-28 广州天骄建筑有限公司 Production method of high-molecular waterproof coiled material
CN114940879A (en) * 2021-06-04 2022-08-26 上海亥博胶粘材料有限公司 Butyl sealing adhesive tape for solar photovoltaic module and preparation method thereof
CN113372851A (en) * 2021-07-20 2021-09-10 安徽省奥佳建材有限公司 Self-adhesive rubber waterproof coiled material and preparation method thereof
CN113652182A (en) * 2021-08-19 2021-11-16 重庆新天地华宇新材料集团有限公司 Macromolecule butyl self-adhesive waterproof coiled material and preparation method thereof

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