CN108084815A - A kind of alternating flashing light inner wall decorative coating and preparation method thereof - Google Patents

A kind of alternating flashing light inner wall decorative coating and preparation method thereof Download PDF

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Publication number
CN108084815A
CN108084815A CN201711378205.3A CN201711378205A CN108084815A CN 108084815 A CN108084815 A CN 108084815A CN 201711378205 A CN201711378205 A CN 201711378205A CN 108084815 A CN108084815 A CN 108084815A
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parts
powder
flashing light
decorative coating
wall decorative
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张浩杰
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Ningbo Aike Chuangwei New Mstar Technology Ltd
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Ningbo Aike Chuangwei New Mstar Technology Ltd
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D125/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Coating compositions based on derivatives of such polymers
    • C09D125/02Homopolymers or copolymers of hydrocarbons
    • C09D125/04Homopolymers or copolymers of styrene
    • C09D125/08Copolymers of styrene
    • C09D125/14Copolymers of styrene with unsaturated esters
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/22Luminous paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/29Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for multicolour effects
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K13/00Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
    • C08K13/04Ingredients characterised by their shape and organic or inorganic ingredients
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/221Oxides; Hydroxides of metals of rare earth metal
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2237Oxides; Hydroxides of metals of titanium
    • C08K2003/2241Titanium dioxide
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24Acids; Salts thereof
    • C08K3/26Carbonates; Bicarbonates
    • C08K2003/262Alkali metal carbonates
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/38Boron-containing compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K7/00Use of ingredients characterised by shape

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Paints Or Removers (AREA)

Abstract

The present invention provides a kind of alternating flashing light inner wall decorative coating, and component and mass fraction proportioning are:30 50 parts of styrene-acrylic emulsion, 25 parts of coalescents, 0.1 0.5 parts of antifoaming agent, 0.5 1 parts of thickener, 58 parts of nano-titanium dioxide, 35 parts of photochromic fluorescent pigment, 23 parts of flashlight powder, 12 parts of dispersant, 12 parts of levelling agent, 12 parts of wetting agent, 58 parts of nano-scaled electric mountain flour, 5 15 parts of water.The photochromic fluorescent pigment is obtained by calcining the mixture of rare earth oxide, boric acid and lithium carbonate, and the grain size of photochromic fluorescent pigment is 50 100nm.The present invention in coating by adding in nanocomposite, discoloration filler and flash of light filler so that paint coatings are environmentally protective, and different colors can be shown under different illumination conditions.

Description

A kind of alternating flashing light inner wall decorative coating and preparation method thereof
Technical field
The invention belongs to building coating technical fields, and in particular to a kind of alternating flashing light inner wall decorative coating and its preparation side Method.
Background technology
The ornament materials of building and ornament materials particularly house inner wall at present primarily serves the effect of beautification interior wall.It is existing The decorative paint of technology is usually that the raw materials such as kaolin, silica ashes, talcum powder, mica powder, titanium dioxide add in dispersant, wetting Agent, propylene glycol, lotion, water reconcile, and play the role of landscaping effect and protection wall.But people apply decoration now The requirement of material is higher and higher, on the one hand needs coating environment-protecting and non-poisonous, ageing-resistant, on the other hand wish decorative paint have discoloration, The functions such as flash of light, give ornament materials more possibilities, can show different colors in different environments, enrich people Life.But decorative paint function is relatively simple on the market, does not possess the functions such as discoloration or flash of light.
The content of the invention
Be based on the more than prior art, it is an object of the invention to provide a kind of alternating flashing light inner wall decorative coating, by Nanocomposite, discoloration filler and flash of light filler etc. are added in coating so that coating is environmentally protective, and can be in different illumination Different colors is shown under environment.
In order to achieve the goal above, the technical solution adopted by the present invention is:A kind of alternating flashing light inner wall decorative coating, group Divide and mass fraction proportioning is:30-50 parts of styrene-acrylic emulsion, 2-5 parts of coalescents, 0.1-0.5 parts of antifoaming agent, thickener 0.5-1 Part, 5-8 parts of nano-titanium dioxide, 3-5 parts of photochromic fluorescent pigment, 2-3 parts of flashlight powder, 1-2 parts of dispersant, levelling agent 1-2 Part, 1-2 parts of wetting agent, 5-8 parts of nano-scaled electric mountain flour, 5-15 parts of water.The photochromic fluorescent pigment is by calcining rare earth The mixture of oxide, boric acid and lithium carbonate obtains, and the grain size of photochromic fluorescent pigment is 50-100nm.
Preferably, the rare earth oxide is neodymia or holimium oxide.
Preferably, the quality parts ratio (30-50) of the rare earth oxide, boric acid and lithium carbonate:(20-30):(30- 40)。
Preferably, the flashlight powder includes pearl powder and glitter powder, and the quality parts ratio of pearl powder and glitter powder is 1:1.
Preferably, the glitter powder be gold plaque, silver strip and assorted plastics and the color pieces of radium-shine flash of light seven, shape for quadrangle or Hexagon powder particle, particle size are 0.01-0.05 microns.
Preferably, the grain size of the nano-titanium dioxide is 10-100nm.
Preferably, the grain size of the nano-scaled electric mountain flour is 50-100nm.
The component mechanism of action of alternating flashing light inner wall decorative coating of the present invention is:
Using styrene-acrylic emulsion as base-material, nonhazardous gas generate the alternating flashing light inner wall decorative coating of the present invention, will not be to ring Border pollutes;Nano-titanium dioxide in component has the transparency in itself, and has to a degree of covering of visible ray, When being that flashlight powder mixes, mirror-reflection occurs on flashlight powder surface for an incident light part, and another part penetrates nanometer two It after dispersion occurs for titanium oxide, is reflected in nano-titanium dioxide and flashlight powder interface, polychromatic finish is formed, so that coating has Unique colour effect, and add in the flashlight powder of different colours, can be formed it is different face color and side view color so that Coating can show different colors in different directions;The characteristic realization that the present invention selects rare earth ion to absorb is photochromic, Select different rare earth ions that can realize the transformation of different colours, the boron lithium hydrochlorate containing Ho is under sunlight as photosensitizer Pink is presented in yellow under energy-saving lamp;Boron lithium hydrochlorate containing Nd, in purple, is presented greyish white under sunlight under energy-saving lamp Color, this photochromism processes are reversible in real time, and the photochromic characteristic is permanently effective, so that coating is different Different colors is shown under illumination, adds the variability of coating;Nanometer electricity mineral powder in component can discharge negative for a long time Ion so as to alleviate the fatigue of people, makes people happy, and can help to drive away indoor various peculiar smell, purification air;This Dispersant has been additionally added in the component of invention, nanometer titanium dioxide in paints, photochromic fluorescent pigment, flashlight powder can be improved With the dispersiveness of nano-tourmaline powder;Wetting agent in the component of the present invention, can enhance adhesive force of the coating to wall, so as to Enhance the durability of coating.
The present invention also provides the preparation methods of above-mentioned alternating flashing light inner wall decorative coating, comprise the following steps:
Step 1):According to mass fraction proportioning by rare earth oxide, boric acid and lithium carbonate mix and grind 1-2 it is small when, obtain To mixed powder;Mixed powder obtained is calcined at 700-1000 DEG C 4-8 it is small when after natural cooling, be cooled to room temperature postposition Extra-fine grinding is carried out in high energy nanometer impact grinding, until grain size reaches 50-100nm, photochromic fluorescent pigment is made;
Step 2):It is matched according to mass fraction and coalescents, dispersant is sequentially added into styrene-acrylic emulsion, thickener, is received Rice titanium dioxide, photochromic fluorescent pigment, water, nano-scaled electric mountain flour, flashlight powder, levelling agent, wetting agent, antifoaming agent, add It is kept stirring during entering, until being uniformly mixed, obtains alternating flashing light inner wall decorative coating.
Compared with prior art, the device have the advantages that being:
1. the coating of the present invention is environment-protecting and non-poisonous, and paint coatings have the performance of permanent release anion, so as to help people Fatigue-relieving, it is happy, drive away various peculiar smell, purification air;
2. paint coatings of the present invention can change colour under different illumination, and color changeable effect is apparent, and photochromism processes are real-time Reversible, photochromic characteristic is permanently effective, so as to impart the more possibilities of coating so that interior decoration is rich and varied.This The paint coatings of invention also have the characteristics that flash of light, and add in the flashlight powder of different colours, can be formed and different face color With side view color so that coating can show different colors in different directions.
3. the pigment coated wearability of the present invention is strong, resistance to ag(e)ing is strong, strong with the bonding force of metope, the service life of paint coatings It is long.
Specific embodiment
The present invention is described in further detail with reference to specific embodiment.
Embodiment 1
A kind of alternating flashing light inner wall decorative coating, component and mass fraction proportioning are:40 parts of styrene-acrylic emulsion, coalescents 3 parts, 0.2 part of antifoaming agent, 0.6 part of thickener, 6 parts of nano-titanium dioxide, 4 parts of photochromic fluorescent pigment, 1.2 parts of pearl powder, 1.2 parts of glitter powder, 1.5 parts of dispersant, 1.5 parts of levelling agent, 1.5 parts of wetting agent, 6 parts of nano-scaled electric mountain flour, 10 parts of water.It is described Photochromic fluorescent pigment is obtained by the mixture of calcined oxide neodymium, boric acid and lithium carbonate, the grain of photochromic fluorescent pigment Footpath is 50-100nm.The quality parts ratio 40 of the rare earth oxide, boric acid and lithium carbonate:25:35.The glitter powder is gold Piece, silver strip and assorted plastics and the color piece of radium-shine flash of light seven, shape are tetragonal powder particle, and particle size is micro- for 0.01-0.05 Rice.The grain size of the nano-titanium dioxide is 10-100nm.The grain size of the nano-scaled electric mountain flour is 50-100nm.
The preparation method of above-mentioned alternating flashing light inner wall decorative coating, comprises the following steps:
Step 1):According to mass fraction proportioning by neodymia, boric acid and lithium carbonate mix and grind 1.5 it is small when, mixed Close powder;Mixed powder obtained is calcined at 800 DEG C 5 it is small when after natural cooling, be cooled to room temperature and be placed on high energy nanometer When progress extra-fine grinding 5 is small in impact grinding, until grain size reaches 50-100nm, photochromic fluorescent pigment is obtained;
Step 2):It is matched according to mass fraction and coalescents, dispersant is sequentially added into styrene-acrylic emulsion, thickener, is received Rice titanium dioxide, photochromic fluorescent pigment, water, nano-scaled electric mountain flour, flashlight powder, levelling agent, wetting agent, antifoaming agent, add It is kept stirring during entering, until being uniformly mixed, obtains alternating flashing light inner wall decorative coating.
Embodiment 2
A kind of alternating flashing light inner wall decorative coating, component and mass fraction proportioning are:30 parts of styrene-acrylic emulsion, coalescents 2 parts, 0.1 part of antifoaming agent, 0.5 part of thickener, 5 parts of nano-titanium dioxide, 3 parts of photochromic fluorescent pigment, 1 part of pearl powder, gold 1 part of green onion powder, 1 part of dispersant, 1 part of levelling agent, 1 part of wetting agent, 5 parts of nano-scaled electric mountain flour, 5 parts of water.It is described photochromic glimmering Delustering pigment is obtained by the mixture of calcined oxide holmium, boric acid and lithium carbonate, and the grain size of photochromic fluorescent pigment is 50- 100nm.The quality parts ratio 30 of the rare earth oxide, boric acid and lithium carbonate:20:30.The glitter powder for gold plaque, silver strip and Assorted plastics and the color piece of radium-shine flash of light seven, shape are hexagon powder particle, and particle size is 0.01-0.05 microns.It is described to receive The grain size of rice titanium dioxide is 10-100nm.The grain size of the nano-scaled electric mountain flour is 50-100nm.
The preparation method of above-mentioned alternating flashing light inner wall decorative coating, comprises the following steps:
Step 1):According to mass fraction proportioning by holimium oxide, boric acid and lithium carbonate mix and grind 1.5 it is small when, mixed Close powder;Mixed powder obtained is calcined at 700 DEG C 8 it is small when after natural cooling, be cooled to room temperature and be placed on high energy nanometer When progress extra-fine grinding 6 is small in impact grinding, until grain size reaches 50-100nm, photochromic fluorescent pigment is obtained;
Step 2):It is matched according to mass fraction and coalescents, dispersant is sequentially added into styrene-acrylic emulsion, thickener, is received Rice titanium dioxide, photochromic fluorescent pigment, water, nano-scaled electric mountain flour, flashlight powder, levelling agent, wetting agent, antifoaming agent, add It is kept stirring during entering, until being uniformly mixed, obtains alternating flashing light inner wall decorative coating.
Embodiment 3
A kind of alternating flashing light inner wall decorative coating, component and mass fraction proportioning are:50 parts of styrene-acrylic emulsion, coalescents 5 parts, 0.5 part of antifoaming agent, 1 part of thickener, 8 parts of nano-titanium dioxide, 5 parts of photochromic fluorescent pigment, 1.5 parts of pearl powder, gold 1.5 parts of green onion powder, 2 parts of dispersant, 2 parts of levelling agent, 2 parts of wetting agent, 8 parts of nano-scaled electric mountain flour, 15 parts of water.It is described photochromic Fluorescent pigment is obtained by the mixture of calcined oxide holmium, boric acid and lithium carbonate, and the grain size of photochromic fluorescent pigment is 50- 100nm.The quality parts ratio 50 of the holimium oxide, boric acid and lithium carbonate:30:40.The glitter powder is gold plaque, silver strip and colors Plastics and the color piece of radium-shine flash of light seven, shape are tetragonal powder particle, and particle size is 0.01-0.05 microns.The nanometer two The grain size of titanium oxide is 10-100nm.The grain size of the nano-scaled electric mountain flour is 50-100nm.
The preparation method of above-mentioned alternating flashing light inner wall decorative coating, comprises the following steps:
Step 1):According to mass fraction proportioning by holimium oxide, boric acid and lithium carbonate mix and grind 1.5 it is small when, mixed Close powder;Mixed powder obtained is calcined at 1000 DEG C 4 it is small when after natural cooling, be cooled to room temperature and be placed on high energy nanometer When progress extra-fine grinding 5 is small in impact grinding, until grain size reaches 50-100nm, photochromic fluorescent pigment is obtained;
Step 2):It is matched according to mass fraction and coalescents, dispersant is sequentially added into styrene-acrylic emulsion, thickener, is received Rice titanium dioxide, photochromic fluorescent pigment, water, nano-scaled electric mountain flour, flashlight powder, levelling agent, wetting agent, antifoaming agent, add It is kept stirring during entering, until being uniformly mixed, obtains alternating flashing light inner wall decorative coating.
To the colour rendering after decorative paint application made from above-described embodiment 1 to 3 under different illumination and angle and bear Ion release is tested, coating layer thickness 0.2mm, and test result is as shown in table 1 below.
1 paint coatings test result of table
Embodiment 1 Embodiment 2 Embodiment 3
Coating faces color under sunlight Khaki Khaki Purple
Coated side regards color under sunlight Glassy yellow Glassy yellow Lavender
Coating faces color under energy saving light It is red It is red Canescence
Coated side regards color under energy saving light Pink Pink Brilliant white
Anion number in environment 1200/cm3 1100/cm3 1150/cm3
Anion number in environment after 30 days 1000/cm3 950/cm3 980/cm3
From above-mentioned test result, paint coatings made from the embodiment of the present invention 1 to 3 in different illumination conditions and Different colors is shown under angle, it was demonstrated that decorative paint of the invention has the effect of alternating flashing light, solves in the prior art The problem of decorative paint color is single.And the pigment of the embodiment of the present invention 1 to 3 all has long-acting negative ion releasing function, Air can be purified, improves indoor environment, solves the problems, such as that interior wall coating is without air purification effect in the prior art.
Finally it should be noted that:The foregoing is only a preferred embodiment of the present invention, is not intended to limit the invention, Although the present invention is described in detail with reference to the foregoing embodiments, for those skilled in the art, still may be used To modify to the technical solution recorded in foregoing embodiments or carry out equivalent substitution to which part technical characteristic. Within the spirit and principles of the invention, any modifications, equivalent replacements and improvements are made should be included in the present invention's Within protection domain.

Claims (8)

1. a kind of alternating flashing light inner wall decorative coating, component and mass fraction proportioning are:30-50 parts of styrene-acrylic emulsion, film forming help 2-5 parts of agent, 0.1-0.5 parts of antifoaming agent, 0.5-1 parts of thickener, 5-8 parts of nano-titanium dioxide, photochromic fluorescent pigment 3-5 Part, 2-3 parts of flashlight powder, 1-2 parts of dispersant, 1-2 parts of levelling agent, 1-2 parts of wetting agent, 5-8 parts of nano-scaled electric mountain flour, water 5-15 Part;
The photochromic fluorescent pigment is obtained by calcining the mixture of rare earth oxide, boric acid and lithium carbonate, photochromic The grain size of fluorescent pigment is 50-100nm.
2. alternating flashing light inner wall decorative coating according to claim 1, which is characterized in that the rare earth oxide is oxidation Neodymium or holimium oxide.
3. alternating flashing light inner wall decorative coating according to claim 1 or 2, which is characterized in that the rare earth oxide, boron The quality parts ratio (30-50) of acid and lithium carbonate:(20-30):(30-40).
4. alternating flashing light inner wall decorative coating according to claim 1, which is characterized in that the flashlight powder includes pearl powder And glitter powder, the quality parts ratio of pearl powder and glitter powder is 1:1.
5. alternating flashing light inner wall decorative coating according to claim 4, which is characterized in that the glitter powder is gold plaque, silver Piece and assorted plastics and the color pieces of radium-shine flash of light seven, shape are quadrangle or hexagon powder particle, particle size 0.01-0.05 Micron.
6. alternating flashing light inner wall decorative coating according to claim 1, which is characterized in that the grain of the nano-titanium dioxide Footpath is 10-100nm.
7. alternating flashing light inner wall decorative coating according to claim 1, which is characterized in that the nano-scaled electric mountain flour Grain size is 50-100nm.
8. a kind of preparation method of alternating flashing light inner wall decorative coating described in claim 1, which is characterized in that including following step Suddenly:
Step 1):According to mass fraction proportioning by rare earth oxide, boric acid and lithium carbonate mix and grind 1-2 it is small when, mixed Close powder;Mixed powder obtained is calcined at 700~1000 DEG C 4-8 it is small when after natural cooling, be cooled to room temperature and be placed on Extra-fine grinding is carried out in high energy nanometer impact grinding, until grain size reaches 50-100nm;
Step 2):It is matched according to mass fraction and coalescents, dispersant, thickener, nanometer two is sequentially added into styrene-acrylic emulsion Titanium oxide, photochromic fluorescent pigment, water, nano-scaled electric mountain flour, flashlight powder, levelling agent, wetting agent, antifoaming agent, addition It keeps stirring in the process, until being uniformly mixed, obtains alternating flashing light inner wall decorative coating.
CN201711378205.3A 2017-12-19 2017-12-19 A kind of alternating flashing light inner wall decorative coating and preparation method thereof Pending CN108084815A (en)

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CN109808399A (en) * 2019-03-07 2019-05-28 海南必凯水性新材料有限公司 A kind of bi-component clay inlayed for craftwork
CN110564223A (en) * 2019-09-04 2019-12-13 广东涂乐师新材料科技有限公司 Water-based interior wall decorative artistic coating and preparation method thereof
CN114479609A (en) * 2022-01-12 2022-05-13 弘润清源(北京)科技有限责任公司 Colored nano semitransparent heat-insulating coating and preparation method thereof

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CN104559499A (en) * 2013-10-22 2015-04-29 青岛德固建筑材料有限公司 Environment-friendly fluorescent interior wall coating
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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109808399A (en) * 2019-03-07 2019-05-28 海南必凯水性新材料有限公司 A kind of bi-component clay inlayed for craftwork
CN110564223A (en) * 2019-09-04 2019-12-13 广东涂乐师新材料科技有限公司 Water-based interior wall decorative artistic coating and preparation method thereof
CN114479609A (en) * 2022-01-12 2022-05-13 弘润清源(北京)科技有限责任公司 Colored nano semitransparent heat-insulating coating and preparation method thereof

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Application publication date: 20180529