CN108084537A - A kind of protection against rodents environmental cable for preventing white ant material and preparation method thereof - Google Patents

A kind of protection against rodents environmental cable for preventing white ant material and preparation method thereof Download PDF

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Publication number
CN108084537A
CN108084537A CN201711210373.1A CN201711210373A CN108084537A CN 108084537 A CN108084537 A CN 108084537A CN 201711210373 A CN201711210373 A CN 201711210373A CN 108084537 A CN108084537 A CN 108084537A
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parts
protection against
against rodents
hdpe
preventing white
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CN201711210373.1A
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Chinese (zh)
Inventor
叶明江
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ANHUI ZHUOYUE CABLE Co Ltd
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ANHUI ZHUOYUE CABLE Co Ltd
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Priority to CN201711210373.1A priority Critical patent/CN108084537A/en
Publication of CN108084537A publication Critical patent/CN108084537A/en
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24Acids; Salts thereof
    • C08K3/26Carbonates; Bicarbonates
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K13/00Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
    • C08K13/02Organic and inorganic ingredients
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/34Silicon-containing compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/04Oxygen-containing compounds
    • C08K5/07Aldehydes; Ketones
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/04Oxygen-containing compounds
    • C08K5/09Carboxylic acids; Metal salts thereof; Anhydrides thereof
    • C08K5/098Metal salts of carboxylic acids
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/04Oxygen-containing compounds
    • C08K5/10Esters; Ether-esters
    • C08K5/101Esters; Ether-esters of monocarboxylic acids
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/16Nitrogen-containing compounds
    • C08K5/205Compounds containing groups, e.g. carbamates
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B3/00Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
    • H01B3/18Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
    • H01B3/30Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
    • H01B3/44Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins
    • H01B3/441Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins from alkenes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24Acids; Salts thereof
    • C08K3/26Carbonates; Bicarbonates
    • C08K2003/265Calcium, strontium or barium carbonate
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00Applications
    • C08L2203/20Applications use in electrical or conductive gadgets
    • C08L2203/202Applications use in electrical or conductive gadgets use in electrical wires or wirecoating
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2207/00Properties characterising the ingredient of the composition
    • C08L2207/06Properties of polyethylene
    • C08L2207/062HDPE

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Insulated Conductors (AREA)

Abstract

The invention discloses a kind of protection against rodents environmental cable for preventing white ant material, which is characterized in that by following parts by weight into being grouped into:80 100 parts of high density polyethylene (HDPE), environmentally friendly 5 10 parts of calcium zinc heat stabilizer, 15 20 parts of fire retardant, 10 20 parts of plasticizer, 5 10 parts of calcium carbonate, 0.5 1.5 parts of zinc stearate, 0.4 1 parts of antioxidant, 10 20 parts of talcum powder, 10 15 parts of camphor, 10 20 parts of pyrethroid, 48 parts of carbamate.The present invention has selected pyrethroid, carbamate, and confrontation protection against rodents is termite-proof especially effectively.To human body without " three cause "(Carcinogenic, teratogenesis, mutagenesis), it is a kind of environmentally friendly, efficient, permanent new additive agent.With stronger action of contace poison, knock down that power is strong, and drug effect is rapid, to positive light and thermally stable.It can hardly gasify below 200 DEG C, not decompose, processing stability is excellent.And high density polyethylene (HDPE) is used as basis material, such material hardness is high, and add termite bites difficulty.

Description

A kind of protection against rodents environmental cable for preventing white ant material and preparation method thereof
Technical field
The present invention relates to a kind of field of cables more particularly to a kind of protection against rodents environmental cable for preventing white ant material and preparation method thereof.
Background technology
At present, with the rapid development of China's modernization construction, the usage amount of cable increasingly increases, and cable is by mouse ant The problem of infringement, also becomes increasingly conspicuous, they can gnaw through cable sheath, and cable run short circuit is caused the failures such as to set off an explosion, makes electricity Power and Office of the Telecommunications Authority are damaged occurs permanent fault with cable run, this problem, which also seems, to become increasingly conspicuous.It is previous to use Toxic additive is added in cable jacket material(Such as Niran, heptachlor, dieldrite, drinox)Method, but these toxic add Add agent that can pollute and endanger environment and the person.
Therefore the cable that manufacture can overcome mouse ant to encroach on is very important for the development of China's cable industry it.
The content of the invention
The defects of in order to overcome the above-mentioned prior art, the object of the present invention is to provide a kind of protection against rodents environmental cable for preventing white ant material And preparation method thereof.
The present invention takes following technical scheme to realize:A kind of protection against rodents environmental cable for preventing white ant material, by following weight Part into being grouped into:80-100 parts of high density polyethylene (HDPE), environmentally friendly 5-10 parts of calcium zinc heat stabilizer, 15-20 parts of fire retardant, plasticizer 10-20 parts, 5-10 parts of calcium carbonate, 0.5-1.5 parts of zinc stearate, 0.4-1 parts of antioxidant, 10-20 parts of talcum powder, camphor 10-15 Part, 10-20 parts of pyrethroid, 4-8 parts of carbamate.
Above-mentioned a kind of protection against rodents environmental cable for preventing white ant material, by following parts by weight into being grouped into:High density polyethylene (HDPE) 80- 90 parts, environmentally friendly 5-8 parts of calcium zinc heat stabilizer, 15-18 parts of fire retardant, 10-17 parts of plasticizer, 5-9 parts of calcium carbonate, zinc stearate 0.5-1.3 parts, 0.4-0.8 parts of antioxidant, 10-15 parts of talcum powder, 10-13 parts of camphor, 10-18 parts of pyrethroid, amino first 4-7 parts of acid esters.
Above-mentioned a kind of protection against rodents environmental cable for preventing white ant material, by following parts by weight into being grouped into:High density polyethylene (HDPE) 85 Part, environmentally friendly 6 parts of calcium zinc heat stabilizer, 17 parts of fire retardant, 15 parts of plasticizer, 7 parts of calcium carbonate, 1 part of zinc stearate, antioxidant 0.6 Part, 13 parts of talcum powder, 12 parts of camphor, 15 parts of pyrethroid, 6 parts of carbamate.
A kind of preparation method of above-mentioned protection against rodents environmental cable for preventing white ant material, comprises the steps of:
(1)By high density polyethylene (HDPE), environmentally friendly calcium zinc heat stabilizer, fire retardant, plasticizer, calcium carbonate, zinc stearate, antioxidant, It is uniformly mixed, obtains mixture A;
(2)Camphor, pyrethroid, carbamate, talcum powder are uniformly mixed, obtain mixture B;
(3)By step(1)Mixture A obtained and step(2)Mixture B obtained is added in together carries out mixing in mixer, Temperature is set to 170 DEG C -180 DEG C, and mixing 10-15min obtains blend;
(4)By step(3)Blend obtained, which is put into open mill, carries out mill, and material temperature is set to 160 DEG C -- 180 DEG C, prevented Mouse environmental cable for preventing white ant material.
In summary the invention has the advantages that:
The present invention overcomes conventional protection against rodents anti-termite cable it is toxic the defects of, selected pyrethroid, carbamate, resist Protection against rodents is termite-proof especially effectively.To human body without " three cause "(Carcinogenic, teratogenesis, mutagenesis), be a kind of environmental protection, efficiently, it is permanent new Type additive.With stronger action of contace poison, knock down that power is strong, and drug effect is rapid, to positive light and thermally stable.It can be several below 200 DEG C Do not gasify, do not decompose, and have preferable intermiscibility with resin, plasticizer etc., processing stability is excellent.And using highly dense Degree polyethylene is basis material, and such material hardness is high, and add termite bites difficulty.
Specific embodiment
Specific embodiment 1:
A kind of protection against rodents environmental cable for preventing white ant material, by following parts by weight into being grouped into:80 parts of high density polyethylene (HDPE), environmentally friendly calcium zinc 5 parts of heat stabilizer, 15 parts of fire retardant, 10 parts of plasticizer, 5 parts of calcium carbonate, 0.5 part of zinc stearate, 0.4 part of antioxidant, talcum powder 10 parts, 10 parts of camphor, 10 parts of pyrethroid, 4 parts of carbamate.
Specific embodiment 2:
A kind of protection against rodents environmental cable for preventing white ant material, by following parts by weight into being grouped into:85 parts of high density polyethylene (HDPE), environmentally friendly calcium zinc 6 parts of heat stabilizer, 17 parts of fire retardant, 15 parts of plasticizer, 7 parts of calcium carbonate, 1 part of zinc stearate, 0.6 part of antioxidant, talcum powder 13 Part, 12 parts of camphor, 15 parts of pyrethroid, 6 parts of carbamate.
Specific embodiment 3:
A kind of protection against rodents environmental cable for preventing white ant material, by following parts by weight into being grouped into:90 parts of high density polyethylene (HDPE), environmentally friendly calcium zinc 8 parts of heat stabilizer, 18 parts of fire retardant, 17 parts of plasticizer, 9 parts of calcium carbonate, 1.3 parts of zinc stearate, 0.8 part of antioxidant, talcum powder 15 parts, 13 parts of camphor, 18 parts of pyrethroid, 7 parts of carbamate.
A kind of preparation method of protection against rodents environmental cable for preventing white ant material, comprises the steps of:
(1)By high density polyethylene (HDPE), environmentally friendly calcium zinc heat stabilizer, fire retardant, plasticizer, calcium carbonate, zinc stearate, antioxidant, It is uniformly mixed, obtains mixture A;
(2)Camphor, pyrethroid, carbamate, talcum powder are uniformly mixed, obtain mixture B;
(3)By step(1)Mixture A obtained and step(2)Mixture B obtained is added in together carries out mixing in mixer, Temperature is set to 180 DEG C, and mixing 15min obtains blend;
(4)By step(3)Blend obtained, which is put into open mill, carries out mill, and material temperature is set to 180 DEG C, and it is termite-proof to obtain protection against rodents Environment-friendly cable material.
Embodiment provided above is the better embodiment of the present invention, only is used for facilitating illustrating the present invention, not to this hair The limitation of bright work in any form, any those of ordinary skill in the art, if putting forward skill not departing from the present invention In the range of art feature, using the equivalent embodiment for locally changing or modifying made by disclosed technology contents, and Without departing from the technical feature content of the present invention, in the range of still falling within the technology of the present invention feature.

Claims (4)

1. a kind of protection against rodents environmental cable for preventing white ant material, which is characterized in that by following parts by weight into being grouped into:High density polyethylene (HDPE) 80-100 parts, environmentally friendly 5-10 part of calcium zinc heat stabilizer, 15-20 parts of fire retardant, 10-20 parts of plasticizer, 5-10 parts of calcium carbonate, tristearin Sour zinc 0.5-1.5 parts, 0.4-1 parts of antioxidant, 10-20 parts of talcum powder, 10-15 parts of camphor, 10-20 parts of pyrethroid, amino 4-8 parts of formic acid esters.
2. a kind of protection against rodents environmental cable for preventing white ant material according to claim 1, which is characterized in that by following parts by weight into It is grouped into:80-90 parts of high density polyethylene (HDPE), environmentally friendly 5-8 parts of calcium zinc heat stabilizer, 15-18 parts of fire retardant, 10-17 parts of plasticizer, 5-9 parts of calcium carbonate, 0.5-1.3 parts of zinc stearate, 0.4-0.8 parts of antioxidant, 10-15 parts of talcum powder, 10-13 parts of camphor, plan are removed 10-18 parts of worm chrysanthemum ester, 4-7 parts of carbamate.
3. a kind of protection against rodents environmental cable for preventing white ant material according to claim 1, which is characterized in that by following parts by weight into It is grouped into:85 parts of high density polyethylene (HDPE), environmentally friendly 6 parts of calcium zinc heat stabilizer, 17 parts of fire retardant, 15 parts of plasticizer, 7 parts of calcium carbonate, 1 part of zinc stearate, 0.6 part of antioxidant, 13 parts of talcum powder, 12 parts of camphor, 15 parts of pyrethroid, 6 parts of carbamate.
4. according to a kind of preparation method of any protection against rodents environmental cable for preventing white ant material of claim 1-3, which is characterized in that It comprises the steps of:
(1)By high density polyethylene (HDPE), environmentally friendly calcium zinc heat stabilizer, fire retardant, plasticizer, calcium carbonate, zinc stearate, antioxidant, It is uniformly mixed, obtains mixture A;
(2)Camphor, pyrethroid, carbamate, talcum powder are uniformly mixed, obtain mixture B;
(3)By step(1)Mixture A obtained and step(2)Mixture B obtained is added in together carries out mixing in mixer, Temperature is set to 170 DEG C -180 DEG C, and mixing 10-15min obtains blend;
(4)By step(3)Blend obtained, which is put into open mill, carries out mill, and material temperature is set to 160 DEG C -- 180 DEG C, prevented Mouse environmental cable for preventing white ant material.
CN201711210373.1A 2017-11-28 2017-11-28 A kind of protection against rodents environmental cable for preventing white ant material and preparation method thereof Withdrawn CN108084537A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113683828A (en) * 2021-08-03 2021-11-23 浙江三科线缆股份有限公司 Antibacterial rat and ant prevention magnetic polyethylene material and preparation method thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1528144A (en) * 2003-10-15 2004-09-15 王卫东 Long-acting disinsection spray agent and preparing method thereof
CN103059445A (en) * 2011-10-20 2013-04-24 常熟市筑紫机械有限公司 Flame-retardant polyvinyl chloride wire and cable material capable of preventing termites
CN105504459A (en) * 2016-02-29 2016-04-20 萧县明智电子有限公司 Anti-termite environment-friendly cable material and preparation method thereof
CN106633298A (en) * 2016-12-19 2017-05-10 钦州市科学技术开发中心 Termite-resistant environment-friendly cable material and preparation method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1528144A (en) * 2003-10-15 2004-09-15 王卫东 Long-acting disinsection spray agent and preparing method thereof
CN103059445A (en) * 2011-10-20 2013-04-24 常熟市筑紫机械有限公司 Flame-retardant polyvinyl chloride wire and cable material capable of preventing termites
CN105504459A (en) * 2016-02-29 2016-04-20 萧县明智电子有限公司 Anti-termite environment-friendly cable material and preparation method thereof
CN106633298A (en) * 2016-12-19 2017-05-10 钦州市科学技术开发中心 Termite-resistant environment-friendly cable material and preparation method thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113683828A (en) * 2021-08-03 2021-11-23 浙江三科线缆股份有限公司 Antibacterial rat and ant prevention magnetic polyethylene material and preparation method thereof

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Application publication date: 20180529

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