CN107474355A - A kind of protection against rodents environmental cable for preventing white ant material and preparation method thereof - Google Patents

A kind of protection against rodents environmental cable for preventing white ant material and preparation method thereof Download PDF

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Publication number
CN107474355A
CN107474355A CN201710661439.2A CN201710661439A CN107474355A CN 107474355 A CN107474355 A CN 107474355A CN 201710661439 A CN201710661439 A CN 201710661439A CN 107474355 A CN107474355 A CN 107474355A
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Prior art keywords
parts
protection against
against rodents
hdpe
pyrethroid
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CN201710661439.2A
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Chinese (zh)
Inventor
李宁
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ANHUI YUANZHENG CABLE TECHNOLOGY Co Ltd
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ANHUI YUANZHENG CABLE TECHNOLOGY Co Ltd
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Priority to CN201710661439.2A priority Critical patent/CN107474355A/en
Publication of CN107474355A publication Critical patent/CN107474355A/en
Withdrawn legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
    • C08K13/02—Organic and inorganic ingredients
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24—Acids; Salts thereof
    • C08K3/26—Carbonates; Bicarbonates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/34—Silicon-containing compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/09—Carboxylic acids; Metal salts thereof; Anhydrides thereof
    • C08K5/098—Metal salts of carboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/16—Nitrogen-containing compounds
    • C08K5/205—Compounds containing groups, e.g. carbamates
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
    • H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
    • H01B3/30—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
    • H01B3/44—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins
    • H01B3/441—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins from alkenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24—Acids; Salts thereof
    • C08K3/26—Carbonates; Bicarbonates
    • C08K2003/265—Calcium, strontium or barium carbonate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/08—Stabilised against heat, light or radiation or oxydation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00—Applications
    • C08L2203/20—Applications use in electrical or conductive gadgets
    • C08L2203/202—Applications use in electrical or conductive gadgets use in electrical wires or wirecoating
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2207/00—Properties characterising the ingredient of the composition
    • C08L2207/06—Properties of polyethylene
    • C08L2207/062—HDPE

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Insulated Conductors (AREA)

Abstract

The invention discloses a kind of protection against rodents environmental cable for preventing white ant material, it is characterised in that is made up of the composition of following parts by weight：80 100 parts of high density polyethylene (HDPE), environmentally friendly 57 parts of calcium zinc heat stabilizer, 15 20 parts of fire retardant, 10 20 parts of plasticizer, 5 10 parts of calcium carbonate, 0.5 1.5 parts of zinc stearate, 0.4 1 parts of antioxidant, 10 20 parts of talcum powder, 10 15 parts of camphor, 10 20 parts of pyrethroid, 48 parts of carbamate.The present invention has selected pyrethroid, carbamate, and it is termite-proof especially effective to resist protection against rodents.To human body without " three cause "（Carcinogenic, teratogenesis, mutagenesis）, it is a kind of environmentally friendly, efficient, permanent new additive agent.With stronger action of contace poison, knock down that power is strong, and drug effect is rapid, to positive light and thermally stable.It can hardly gasify below 200 DEG C, not decompose, processing stability is excellent.And high density polyethylene (HDPE) is used as matrix material, such a material hardness is high, and add termite stings food difficulty.

Description

A kind of protection against rodents environmental cable for preventing white ant material and preparation method thereof
Technical field
The present invention relates to a kind of field of cables, more particularly to a kind of protection against rodents environmental cable for preventing white ant material and preparation method thereof.
Background technology
At present, with the rapid development of China's modernization construction, the usage amount of cable increasingly increases, and cable is by mouse ant The problem of infringement, also becomes increasingly conspicuous, and they can gnaw through cable sheath, causes cable run short circuit the failure such as to set off an explosion, makes electricity Power and Office of the Telecommunications Authority suffer damage occurs permanent fault with cable run, and this problem, which also seems, to become increasingly conspicuous.Used in the past Poisonous additive is added in cable jacket material（Such as Niran, heptachlor, dieldrite, drinox）Method, but these poisonous add Agent is added to pollute and endanger environment and the person.
Therefore it is very important that manufacture, which can overcome development of the cable that mouse ant encroaches on for China's cable industry it,.
The content of the invention
The defects of in order to overcome above-mentioned prior art, it is an object of the invention to provide a kind of protection against rodents environmental cable for preventing white ant material And preparation method thereof.
The present invention takes following technical scheme to realize：A kind of protection against rodents environmental cable for preventing white ant material, by following weight The composition composition of part：High density polyethylene (HDPE) 80-100 parts, environmentally friendly calcium zinc heat stabilizer 5-7 parts, fire retardant 15-20 parts, plasticizer 10-20 parts, calcium carbonate 5-10 parts, zinc stearate 0.5-1.5 parts, antioxidant 0.4-1 parts, talcum powder 10-20 parts, camphor 10-15 Part, pyrethroid 10-20 parts, carbamate 4-8 parts.
A kind of described protection against rodents environmental cable for preventing white ant material, is made up of the composition of following parts by weight：High density polyethylene (HDPE) 90 Part, environmentally friendly 6 parts of calcium zinc heat stabilizer, 18 parts of fire retardant, 17 parts of plasticizer, 8 parts of calcium carbonate, 1.2 parts of zinc stearate, antioxidant 0.6 part, 13 parts of talcum powder, 12 parts of camphor, 15 parts of pyrethroid, 7 parts of carbamate.
A kind of described protection against rodents environmental cable for preventing white ant material, is made up of the composition of following parts by weight：High density polyethylene (HDPE) 95 Part, environmentally friendly 5 parts of calcium zinc heat stabilizer, 13 parts of fire retardant, 20 parts of plasticizer, 7 parts of calcium carbonate, 1 part of zinc stearate, antioxidant 0.8 Part, 16 parts of talcum powder, 15 parts of camphor, 17 parts of pyrethroid, 8 parts of carbamate.
A kind of preparation method of described protection against rodents environmental cable for preventing white ant material, is comprised the steps of：
（1）By high density polyethylene (HDPE), environmentally friendly calcium zinc heat stabilizer, fire retardant, plasticizer, calcium carbonate, zinc stearate, antioxidant, It is well mixed, obtain mixture A；
（2）Camphor, pyrethroid, carbamate, talcum powder are well mixed, obtain mixture B；
（3）By step（1）Obtained mixture A and step（2）Obtained mixture B is added together carries out banburying in banbury, Material temperature is set to 170 DEG C -180 DEG C, banburying 10-15min, obtains blend；
（4）By step（3）Obtained blend, which is put into mill, carries out mill, and material temperature is set to 160 DEG C -- 180 DEG C, prevented Mouse environmental cable for preventing white ant material.
In summary the invention has the advantages that：
Instant invention overcomes conventional protection against rodents anti-termite cable it is poisonous the defects of, selected pyrethroid, carbamate, resist Protection against rodents is termite-proof especially effective.To human body without " three cause "（Carcinogenic, teratogenesis, mutagenesis）, be a kind of environmental protection, efficiently, it is permanent new Type additive.With stronger action of contace poison, knock down that power is strong, and drug effect is rapid, to positive light and thermally stable.Can be several below 200 DEG C Do not gasify, do not decompose, and have a preferable intermiscibility with resin, plasticizer etc., processing stability is excellent.And using highly dense Degree polyethylene is matrix material, and such a material hardness is high, and add termite stings food difficulty.
Embodiment
A kind of protection against rodents environmental cable for preventing white ant material, is made up of the composition of following parts by weight：High density polyethylene (HDPE) 80-100 parts, Environmentally friendly calcium zinc heat stabilizer 5-7 parts, fire retardant 15-20 parts, plasticizer 10-20 parts, calcium carbonate 5-10 parts, zinc stearate 0.5- 1.5 parts, antioxidant 0.4-1 parts, talcum powder 10-20 parts, camphor 10-15 parts, pyrethroid 10-20 parts, carbamate 4-8 Part.
A kind of described protection against rodents environmental cable for preventing white ant material, is made up of the composition of following parts by weight：High density polyethylene (HDPE) 90 Part, environmentally friendly 6 parts of calcium zinc heat stabilizer, 18 parts of fire retardant, 17 parts of plasticizer, 8 parts of calcium carbonate, 1.2 parts of zinc stearate, antioxidant 0.6 part, 13 parts of talcum powder, 12 parts of camphor, 15 parts of pyrethroid, 7 parts of carbamate.
A kind of described protection against rodents environmental cable for preventing white ant material, is made up of the composition of following parts by weight：High density polyethylene (HDPE) 95 Part, environmentally friendly 5 parts of calcium zinc heat stabilizer, 13 parts of fire retardant, 20 parts of plasticizer, 7 parts of calcium carbonate, 1 part of zinc stearate, antioxidant 0.8 Part, 16 parts of talcum powder, 15 parts of camphor, 17 parts of pyrethroid, 8 parts of carbamate.
A kind of preparation method of described protection against rodents environmental cable for preventing white ant material, is comprised the steps of：
（1）By high density polyethylene (HDPE), environmentally friendly calcium zinc heat stabilizer, fire retardant, plasticizer, calcium carbonate, zinc stearate, antioxidant, It is well mixed, obtain mixture A；
（2）Camphor, pyrethroid, carbamate, talcum powder are well mixed, obtain mixture B；
（3）By step（1）Obtained mixture A and step（2）Obtained mixture B is added together carries out banburying in banbury, Material temperature is set to 180 DEG C, banburying 15min, obtains blend；
（4）By step（3）Obtained blend, which is put into mill, carries out mill, and material temperature is set to 180 DEG C, and it is termite-proof to obtain protection against rodents Environment-friendly cable material.
The present invention has selected pyrethroid, carbamate, and it is termite-proof especially effective to resist protection against rodents.To human body without " three Cause "（Carcinogenic, teratogenesis, mutagenesis）, it is a kind of environmentally friendly, efficient, permanent new additive agent.With stronger action of contace poison, hit Power is strong, and drug effect is rapid, to positive light and thermally stable.It can hardly gasify below 200 DEG C, not decompose, processing stability is excellent It is good.And high density polyethylene (HDPE) is used as matrix material, such a material hardness is high, and add termite stings food difficulty.
Described above is the embodiment of the present invention, therefore all construction, feature and principles according to described in the present patent application scope are done Equivalent change or modification, be included in the range of present patent application.

Claims (4)

1. a kind of protection against rodents environmental cable for preventing white ant material, it is characterised in that be made up of the composition of following parts by weight：High density polyethylene (HDPE) 80-100 parts, environmentally friendly calcium zinc heat stabilizer 5-7 parts, fire retardant 15-20 parts, plasticizer 10-20 parts, calcium carbonate 5-10 parts are stearic Sour zinc 0.5-1.5 parts, antioxidant 0.4-1 parts, talcum powder 10-20 parts, camphor 10-15 parts, pyrethroid 10-20 parts, amino Formic acid esters 4-8 parts.
A kind of 2. protection against rodents environmental cable for preventing white ant material according to claim 1, it is characterised in that by following parts by weight into It is grouped into：90 parts of high density polyethylene (HDPE), environmentally friendly 6 parts of calcium zinc heat stabilizer, 18 parts of fire retardant, 17 parts of plasticizer, 8 parts of calcium carbonate, 1.2 parts of zinc stearate, 0.6 part of antioxidant, 13 parts of talcum powder, 12 parts of camphor, 15 parts of pyrethroid, 7 parts of carbamate.
A kind of 3. protection against rodents environmental cable for preventing white ant material according to claim 1, it is characterised in that by following parts by weight into It is grouped into：95 parts of high density polyethylene (HDPE), environmentally friendly 5 parts of calcium zinc heat stabilizer, 13 parts of fire retardant, 20 parts of plasticizer, 7 parts of calcium carbonate, 1 part of zinc stearate, 0.8 part of antioxidant, 16 parts of talcum powder, 15 parts of camphor, 17 parts of pyrethroid, 8 parts of carbamate.
4. according to a kind of preparation method of any described protection against rodents environmental cable for preventing white ant material of claim 1-3, it is characterised in that Comprise the steps of：
（1）By high density polyethylene (HDPE), environmentally friendly calcium zinc heat stabilizer, fire retardant, plasticizer, calcium carbonate, zinc stearate, antioxidant, It is well mixed, obtain mixture A；
（2）Camphor, pyrethroid, carbamate, talcum powder are well mixed, obtain mixture B；
（3）By step（1）Obtained mixture A and step（2）Obtained mixture B is added together carries out banburying in banbury, Material temperature is set to 170 DEG C -180 DEG C, banburying 10-15min, obtains blend；
（4）By step（3）Obtained blend, which is put into mill, carries out mill, and material temperature is set to 160 DEG C -- 180 DEG C, prevented Mouse environmental cable for preventing white ant material.
CN201710661439.2A 2017-08-04 2017-08-04 A kind of protection against rodents environmental cable for preventing white ant material and preparation method thereof Withdrawn CN107474355A (en)

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108752701A (en) * 2018-06-13 2018-11-06 浙江威思康塑胶有限公司 A kind of preparation method of protection against rodents anti-termite cable material
CN108752700A (en) * 2018-06-13 2018-11-06 浙江威思康塑胶有限公司 A kind of protection against rodents anti-termite cable material
CN109294119A (en) * 2018-09-30 2019-02-01 康泰塑胶科技集团有限公司 Anti- mouse and termite sting bad sheath tubing and preparation method thereof
CN113683828A (en) * 2021-08-03 2021-11-23 浙江三科线缆股份有限公司 Antibacterial rat and ant prevention magnetic polyethylene material and preparation method thereof
CN117170054A (en) * 2023-11-01 2023-12-05 江苏中天科技股份有限公司 Rat-proof optical cable with multilayer rat-proof structure

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101492554A (en) * 2009-01-23 2009-07-29 同济大学 Environment friendly ant-proof mouse-proof cable sheath material and preparation method thereof
CN102977466A (en) * 2012-11-05 2013-03-20 安徽金桥电缆有限公司 Flame-retardant, environmentally-friendly and safe polyolefin sheath material and its preparation method
CN104650439A (en) * 2015-01-09 2015-05-27 长园长通新材料有限公司 Anti-termite adhesive tape substrate of polyethylene pipeline and preparation method of substrate
CN105037893A (en) * 2015-08-21 2015-11-11 安徽吉安特种线缆制造有限公司 Anticorrosion termite-insect-resistant power cable material and preparation method thereof
CN105504460A (en) * 2016-02-29 2016-04-20 萧县明智电子有限公司 Moisture-resistant and termite-resistant buried-cable materials and preparation method thereof
CN106633489A (en) * 2016-11-07 2017-05-10 贵州固达电缆有限公司 Rat-proof and termite-resistant cable material and preparation method thereof
CN106633298A (en) * 2016-12-19 2017-05-10 钦州市科学技术开发中心 Termite-resistant environment-friendly cable material and preparation method thereof

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101492554A (en) * 2009-01-23 2009-07-29 同济大学 Environment friendly ant-proof mouse-proof cable sheath material and preparation method thereof
CN102977466A (en) * 2012-11-05 2013-03-20 安徽金桥电缆有限公司 Flame-retardant, environmentally-friendly and safe polyolefin sheath material and its preparation method
CN104650439A (en) * 2015-01-09 2015-05-27 长园长通新材料有限公司 Anti-termite adhesive tape substrate of polyethylene pipeline and preparation method of substrate
CN105037893A (en) * 2015-08-21 2015-11-11 安徽吉安特种线缆制造有限公司 Anticorrosion termite-insect-resistant power cable material and preparation method thereof
CN105504460A (en) * 2016-02-29 2016-04-20 萧县明智电子有限公司 Moisture-resistant and termite-resistant buried-cable materials and preparation method thereof
CN106633489A (en) * 2016-11-07 2017-05-10 贵州固达电缆有限公司 Rat-proof and termite-resistant cable material and preparation method thereof
CN106633298A (en) * 2016-12-19 2017-05-10 钦州市科学技术开发中心 Termite-resistant environment-friendly cable material and preparation method thereof

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108752701A (en) * 2018-06-13 2018-11-06 浙江威思康塑胶有限公司 A kind of preparation method of protection against rodents anti-termite cable material
CN108752700A (en) * 2018-06-13 2018-11-06 浙江威思康塑胶有限公司 A kind of protection against rodents anti-termite cable material
CN109294119A (en) * 2018-09-30 2019-02-01 康泰塑胶科技集团有限公司 Anti- mouse and termite sting bad sheath tubing and preparation method thereof
CN113683828A (en) * 2021-08-03 2021-11-23 浙江三科线缆股份有限公司 Antibacterial rat and ant prevention magnetic polyethylene material and preparation method thereof
CN117170054A (en) * 2023-11-01 2023-12-05 江苏中天科技股份有限公司 Rat-proof optical cable with multilayer rat-proof structure

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