CN108071028A - A kind of cationic low-temperature dyeing method of ENCDP fabric linings - Google Patents

A kind of cationic low-temperature dyeing method of ENCDP fabric linings Download PDF

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Publication number
CN108071028A
CN108071028A CN201711343638.5A CN201711343638A CN108071028A CN 108071028 A CN108071028 A CN 108071028A CN 201711343638 A CN201711343638 A CN 201711343638A CN 108071028 A CN108071028 A CN 108071028A
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Prior art keywords
encdp
fabric
temperature
dyeing
drying
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CN201711343638.5A
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Inventor
毛永强
钟国能
司冠锋
刘琼
王健刚
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Ningbo Daqian Textile Co Ltd
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Ningbo Daqian Textile Co Ltd
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Priority to CN201711343638.5A priority Critical patent/CN108071028A/en
Publication of CN108071028A publication Critical patent/CN108071028A/en
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    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P3/00Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
    • D06P3/34Material containing ester groups
    • D06P3/52Polyesters
    • D06P3/522Polyesters using basic dyes
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/41General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using basic dyes
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/653Nitrogen-free carboxylic acids or their salts
    • D06P1/6533Aliphatic, araliphatic or cycloaliphatic
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/673Inorganic compounds
    • D06P1/67333Salts or hydroxides
    • D06P1/6735Salts or hydroxides of alkaline or alkaline-earth metals with anions different from those provided for in D06P1/67341
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P5/00Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
    • D06P5/20Physical treatments affecting dyeing, e.g. ultrasonic or electric

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Coloring (AREA)

Abstract

A kind of cationic low-temperature dyeing method of ENCDP fabric linings, is related to a kind of dyeing of modified dacron, including following steps, step A:ENCDP fabrics fabric is subjected to pre-setting;Step B:Pre-treatment is carried out to ENCDP fabrics fabric;Step C:Overflow dyeing is carried out to ENCDP fabrics fabric by cationic colourant;Step D:Opposite material base cloth is washed;Step E:Opposite material base cloth is dehydrated;Step F:Opposite material base cloth is dried, and vibration drying or oven for drying can be used in drying.Compared with prior art, this method uses cation stain method, considerably reduces pre-treatment temperature, dyeing temperature and pre-setting temperature and water consumption before dyeing, in dyeing and after dyeing, the loss of the energy is greatly reduced, reduces the use condition and dyeing cost of dyeing installation.

Description

A kind of cationic low-temperature dyeing method of ENCDP fabric linings
Technical field
The present invention relates to a kind of dyeing of modified dacron, more particularly to a kind of dyeing of ENCDP modified fibres.
Background technology
Polyester fiber (polyester fibre), is commonly called as " terylene ".It is formed by organic dibasic acid and dihydric alcohol polycondensation For polyester through the synthetic fibers obtained by spinning, terylene compares that there are moisture content is low, poor air permeability, dyeability is poor, holds with natural fiber Easy pilling fluffing, easy the shortcomings of staiing.The characteristics of ordinary polyester fiber is due in structure, can only be under high temperature, high pressure with scattered Dyeing, thus equipment and technological requirement harshness to dyeing, cost are also higher.In order to improve these shortcomings, taking It learns modified and physical deformation method to be modified terylene, there is a kind of dye of positive ion normal pressure dyeable polyester fibre on the market at present It ties up (ENCDP), this fiber improves the dyeability of terylene, can just be dyed without disperse dyes, the application is exactly to cation The application of dyestuff normal pressure dyeable dacron (ENCDP) colouring method.
The content of the invention
The present invention provides a kind of cationic low temperature dyeing side of ENCDP fabric linings for deficiency of the prior art Method, this method use cation stain method, considerably reduce pre-treatment temperature, dye before dyeing, in dyeing and after dyeing Color temperature and pre-setting temperature, greatly reduce the loss of the energy, reduce the use condition and dyeing cost of dyeing installation.
In order to solve the above-mentioned technical problem, a kind of cationic low-temperature dyeing method of ENCDP fabric linings, it is characterized in that bag Include following steps, step A:ENCDP fabrics fabric is subjected to pre-setting, at 170 DEG C ~ 200 DEG C, speed exists pre-setting temperature 15m/min~25 m/min.;Step B:Pre-treatment is carried out to ENCDP fabrics fabric, ENCDP fabric fabrics are immersed in pre-treatment In liquid, the bath raio 1 of fabric fabric and pretreatment liquid:8 ~ 12, pre-treatment temperature is 80 DEG C ~ 110 DEG C, and processing time is 15min ~ 25 Min,;Step C:Overflow dyeing, ENCDP fabrics fabric and dyeing liquor are carried out to ENCDP fabrics fabric by cationic colourant Bath raio 1:5 ~ 8, dyeing temperature is 80 DEG C ~ 110 DEG C, and processing time is the min of 30min ~ 60;Step D:Opposite material base cloth carries out Washing;Step E:Opposite material base cloth is dehydrated;Step F:Opposite material base cloth is dried, and vibration drying or baking can be used in drying Case is dried.
In above-mentioned technical proposal, it is preferred that in step, the pre-setting temperature is at 180 DEG C ~ 190 DEG C.
In above-mentioned technical proposal, it is preferred that further include the defoaming of 0.1g/L ~ 1g/L non-silicon in stepb, in pretreatment liquid Agent, 1g/L ~ 2g/L refining dyes one-bath deoiling agent, 0.1g/L ~ 1g/L glacial acetic acid, 0.1g/L ~ 1g/L piece alkali.
In above-mentioned technical proposal, it is preferred that further included in step C, in dyeing 0.1g/L ~ 1g/L glacial acetic acid, 0.1g/L ~ 1g/L sodium acetates, 1g/L ~ 2g/L chelating agents, 1g/L ~ 4g/L anhydrous sodium sulphate, 1g/L ~ 3g/L Disperse Levelers.
In above-mentioned technical proposal, it is preferred that in step C, in terms of percentage, the dye of positive ion accounts for 1% (owf) ~ 7% (owf)。
In above-mentioned technical proposal, it is preferred that in step F, during using oven for drying, oven temperature at 100 DEG C ~ 120 DEG C, Drying time is in 30min ~ 50min.
In above-mentioned technical proposal, it is preferred that in step F, during using vibration drying, drying temperature at 100 DEG C ~ 120 DEG C, 15 m/min -20m/min of speed.
In above-mentioned technical proposal, it is preferred that in step D, soaping agent is added with during washing.
Cationic-dyeable polyester fibers (CDP) are to introduce Third monomer in the macromolecular chain of PET to be allowed to and its shape Into block copolymer (also known as copolyesters), this Third monomer contains the sodium group-SO of highly acid3Na can be with cation Dyestuff chemically reacts, and dyestuff is made to be easily fastened on fiber.Although the introducing of Third monomer SIPE improves the dyeing of CDP Performance, but since its Tg is still higher, dyed under the conditions of boiling dyeing at normal pressure, dye-uptake is still relatively low, in order to overcome this shortcoming, is drawing The 4th monomer polyethylene glycol (PEG) is introduced while entering SIPE again, due to the compliance of PEG strands, is further destroyed The regularity and crystal property of strand, increase amorphous area, improve the activity performance of amorphous area macromolecular, obtain sun from The effect of sub- dyestuff boiling dyeing at normal pressure, so dyeing cost can be reduced.The application is according to the property of ENCDP fibers, in low temperature environment Under ENCDP fabric linings are dyed, thermal energy can not only be greatly reduced, simultaneously because the suction crystalline substance rate of the dye of positive ion Higher than disperse dyes, dyeing, quantity of wastewater effluent when handling is few more than existing disperse dyes, the usage amount of water purification also far fewer than Existing colouring method.Simultaneously because temperature reduces, the dyeing installation without high temperature and pressure is with regard to that can be dyed, suitable for major part Dyeing installation.
Compared with prior art, this method use cation stain method, considerably reduce dyeing before, dyeing in and contaminate Pre-treatment temperature, dyeing temperature and pre-setting temperature and water consumption after color, greatly reduce the loss of the energy, reduce The use condition and dyeing cost of dyeing installation.
Specific embodiment
The present invention is described in further detail With reference to embodiment.
Embodiment 1, a kind of cationic low-temperature dyeing method of ENCDP fabric linings, including following steps, step A: ENCDP fabrics fabric is subjected to pre-setting, pre-setting temperature is at 170 DEG C, and speed is in 15m/min.Step B:To ENCDP fabric bases Cloth carries out pre-treatment, ENCDP fabric fabrics is immersed in pretreatment liquid, the bath raio 1 of fabric fabric and pretreatment liquid:5, preceding place It is 80 DEG C to manage temperature, processing time 15min;0.1g/ non-silicon defoaming agents are further included in pretreatment liquid, 1g/L refining dyes are removed with bath Finish, 0.1g/L glacial acetic acid, 0.1g/ piece alkali.Step C:Overflow dye is carried out to ENCDP fabrics fabric by cationic colourant The bath raio 1 of color, ENCDP fabrics fabric and dyeing liquor:8, dyeing temperature is 80 DEG C, processing time 30min;It is further included in dyeing 0.1g/L glacial acetic acid, 0.1g/L sodium acetates, 1g/L chelating agents, 1g/L anhydrous sodium sulphate, 1g/L Disperse Levelers.With percentage Meter, the dye of positive ion account for 1% (owf).Step D:Opposite material base cloth is washed;Soaping agent is added with during washing.Step E:Opposite Material base cloth is dehydrated.Step F:Opposite material base cloth is dried, and vibration drying or oven for drying can be used in drying.In step F In, during using oven for drying, oven temperature is at 100 DEG C, and drying time is in 30min.
Embodiment 2, a kind of cationic low-temperature dyeing method of ENCDP fabric linings, including following steps, step A: ENCDP fabrics fabric is subjected to pre-setting, pre-setting temperature is at 200 DEG C, and speed is in 25 m/min.Step B:To ENCDP fabrics Fabric carries out pre-treatment, ENCDP fabric fabrics is immersed in pretreatment liquid, the bath raio 1 of fabric fabric and pretreatment liquid:8, Pre-treatment temperature is 110 DEG C, and processing time is 25 min;It is same that 1g/L non-silicon defoaming agents, 2g/L refining dyes are further included in pretreatment liquid Bathe degreaser, 1g/L glacial acetic acid, 1g/L piece alkali.Step C:Overflow is carried out to ENCDP fabrics fabric by cationic colourant The bath raio 1 of dyeing, ENCDP fabrics fabric and dyeing liquor:12, dyeing temperature is 110 DEG C, and processing time is 60 min;In step 1g/L glacial acetic acid, 1g/L sodium acetates, 2g/L chelating agents, 4g/L anhydrous sodium sulphate, 3g/L Disperse Levelers are further included in C, in dyeing. In terms of percentage, the dye of positive ion accounts for 7% (owf).Step D:Opposite material base cloth is washed;It is added with and soaps during washing Agent.Step E:Opposite material base cloth is dehydrated.Step F:Opposite material base cloth is dried, and vibration drying or baking oven can be used in drying Drying.During using vibration drying, drying temperature is at 100 DEG C, 15 m/min of speed.
Embodiment 3, a kind of cationic low-temperature dyeing method of ENCDP fabric linings, including following steps, step A: ENCDP fabrics fabric is subjected to pre-setting, pre-setting temperature is at 180 DEG C, and speed is in 20m/min.Step B:To ENCDP fabric bases Cloth carries out pre-treatment, ENCDP fabric fabrics is immersed in pretreatment liquid, the bath raio 1 of fabric fabric and pretreatment liquid:6, preceding place It is 90 DEG C to manage temperature, processing time 20min;0.5g/ non-silicon defoaming agents, 0.5g/L refining dyes are further included in pretreatment liquid with bath Degreaser, 0.5g/L glacial acetic acid, 0.5g/ piece alkali.Step C:Overflow is carried out to ENCDP fabrics fabric by cationic colourant The bath raio 1 of dyeing, ENCDP fabrics fabric and dyeing liquor:10, dyeing temperature is 85 DEG C, processing time 35min;In dyeing also Including 0.5g/L glacial acetic acid, 0.5g/L sodium acetates, 5g/L chelating agents, 5g/L anhydrous sodium sulphate, 5g/L Disperse Levelers.With concentration hundred Divide than meter, the dye of positive ion accounts for 4% (owf).Step D:Opposite material base cloth is washed;Soaping agent is added with during washing.Step E: Opposite material base cloth is dehydrated.Step F:Opposite material base cloth is dried, and vibration drying or oven for drying can be used in drying.In step In rapid F, during using oven for drying, oven temperature is at 120 DEG C, and drying time is in 50min.
Embodiment 4, a kind of cationic low-temperature dyeing method of ENCDP fabric linings, including following steps, step A: ENCDP fabrics fabric is subjected to pre-setting, pre-setting temperature is at 190 DEG C, and speed is in 18m/min.Step B:To ENCDP fabric bases Cloth carries out pre-treatment, ENCDP fabric fabrics is immersed in pretreatment liquid, the bath raio 1 of fabric fabric and pretreatment liquid:7, preceding place It is 100 DEG C to manage temperature, processing time 22min;It is same that 0.45g/ non-silicon defoaming agents, 0.55g/L refining dyes are further included in pretreatment liquid Bathe degreaser, 0.6g/L glacial acetic acid, 0.4g/ piece alkali.Step C:It is overflow by cationic colourant to ENCDP fabric fabrics The bath raio 1 of stream dyeing, ENCDP fabrics fabric and dyeing liquor:10, dyeing temperature is 100 DEG C, processing time 50min;In dyeing Further include 0.6g/L glacial acetic acid, 0.5g/L sodium acetates, 7.5g/L chelating agents, 6.7g/L anhydrous sodium sulphate, 3.2g/L Disperse Levelers. In terms of percentage, the dye of positive ion accounts for 4.4% (owf).Step D:Opposite material base cloth is washed;Soap is added with during washing Lotion.Step E:Opposite material base cloth is dehydrated.Step F:Opposite material base cloth is dried, and vibration drying or baking can be used in drying Case is dried.In step F, during using vibration drying, drying temperature is at 120 DEG C, 25 m/min of speed.
Embodiment 5, a kind of cationic low-temperature dyeing method of ENCDP fabric linings, including following steps, step A: ENCDP fabrics fabric is subjected to pre-setting, pre-setting temperature is at 185 DEG C, and speed is in 21m/min.Step B:To ENCDP fabric bases Cloth carries out pre-treatment, ENCDP fabric fabrics is immersed in pretreatment liquid, the bath raio 1 of fabric fabric and pretreatment liquid:6.5, it is preceding Treatment temperature is 95 DEG C, processing time 21min;0.23g/ non-silicon defoaming agents, 0.65g/L refining dyes are further included in pretreatment liquid One-bath deoiling agent, 0.43g/L glacial acetic acid, 0.21g/ piece alkali.Step C:By cationic colourant to ENCDP fabrics fabric into The bath raio 1 of row overflow dyeing, ENCDP fabrics fabric and dyeing liquor:10, dyeing temperature is 92.5 DEG C, processing time 40min; 0.55g/L glacial acetic acid, 0.45g/L sodium acetates, 5.5g/L chelating agents, 4.9g/L anhydrous sodium sulphate, 4.2g/L is further included in dyeing to disperse Levelling agent.In terms of percentage, the dye of positive ion accounts for 5% (owf).Step D:Opposite material base cloth is washed;Add during washing Added with soaping agent.Step E:Opposite material base cloth is dehydrated.Step F:Opposite material base cloth is dried, and drying can be used vibration and dry Dry or oven for drying.In step F, during using vibration drying, drying temperature is at 110 DEG C, 20 m/min of speed.

Claims (8)

1. a kind of cationic low-temperature dyeing method of ENCDP fabric linings, it is characterized in that including following steps,
Step A:ENCDP fabrics fabric is subjected to pre-setting, pre-setting temperature is at 170 DEG C ~ 200 DEG C, and speed is in 15m/min ~ 25 m/min;
Step B:Pre-treatment is carried out to ENCDP fabrics fabric, ENCDP fabric fabrics are immersed in pretreatment liquid, fabric fabric With the bath raio 1 of pretreatment liquid:5 ~ 8, pre-treatment temperature is 80 DEG C ~ 110 DEG C, and processing time is the min of 15min ~ 25;
Step C:Overflow dyeing is carried out to ENCDP fabrics fabric by cationic colourant, ENCDP fabrics fabric and dyeing liquor Bath raio 1:8 ~ 12, dyeing temperature is 80 DEG C ~ 110 DEG C, and processing time is the min of 30min ~ 60;
Step D:Opposite material base cloth is washed;
Step E:Opposite material base cloth is dehydrated;
Step F:Opposite material base cloth is dried, and vibration drying or oven for drying can be used in drying.
2. a kind of cationic low-temperature dyeing method of ENCDP fabric linings according to claim 1, it is characterized in that, in step In rapid A, the pre-setting temperature is at 180 DEG C ~ 190 DEG C.
3. a kind of cationic low-temperature dyeing method of ENCDP fabric linings according to claim 1, it is characterized in that, in step In rapid B, further included in pretreatment liquid 0.1g/L ~ 1g/L non-silicon defoaming agents, 1g/L ~ 2g/L refining dyes one-bath deoiling agent, 0.1g/L ~ 1g/L glacial acetic acid, 0.1g/L ~ 1g/L piece alkali.
4. a kind of cationic low-temperature dyeing method of ENCDP fabric linings according to claim 1, it is characterized in that, in step In rapid C, further included in dyeing 0.1g/L ~ 1g/L glacial acetic acid, 0.1g/L ~ 1g/L sodium acetates, 1g/L ~ 2g/L chelating agents, 1g/L ~ 4g/L anhydrous sodium sulphate, 1g/L ~ 3g/L Disperse Levelers.
5. a kind of cationic low-temperature dyeing method of ENCDP fabric linings according to claim 1, it is characterized in that, in step In rapid C, in terms of percentage, the dye of positive ion accounts for 1% (owf) ~ 7% (owf).
6. a kind of cationic low-temperature dyeing method of ENCDP fabric linings according to claim 1, it is characterized in that, in step In rapid F, during using oven for drying, oven temperature is at 100 DEG C ~ 120 DEG C, and drying time is in 30min ~ 50min.
7. a kind of cationic low-temperature dyeing method of ENCDP fabric linings according to claim 1, it is characterized in that, in step In rapid F, during using vibration drying, drying temperature is at 100 DEG C ~ 120 DEG C, 15 m/min -20m/min of speed.
8. a kind of cationic low-temperature dyeing method of ENCDP fabric linings according to claim 1, it is characterized in that, in step In rapid D, when washing, is added with soaping agent.
CN201711343638.5A 2017-12-15 2017-12-15 A kind of cationic low-temperature dyeing method of ENCDP fabric linings Pending CN108071028A (en)

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5225185A (en) * 1975-08-20 1977-02-24 Unitika Ltd Method of dyeing cation dyeable polyester fiber textile
CN103422237A (en) * 2012-05-25 2013-12-04 常州老三集团有限公司 Fabric and dyeing and finishing process thereof
CN105803816A (en) * 2016-05-25 2016-07-27 山东同大海岛新材料股份有限公司 Preparation method of easy-dyeing microfiber leather
CN107354728A (en) * 2017-08-24 2017-11-17 宁波大千纺织品有限公司 A kind of preparation method of modified poly ester fancy style knitting fabric

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5225185A (en) * 1975-08-20 1977-02-24 Unitika Ltd Method of dyeing cation dyeable polyester fiber textile
CN103422237A (en) * 2012-05-25 2013-12-04 常州老三集团有限公司 Fabric and dyeing and finishing process thereof
CN105803816A (en) * 2016-05-25 2016-07-27 山东同大海岛新材料股份有限公司 Preparation method of easy-dyeing microfiber leather
CN107354728A (en) * 2017-08-24 2017-11-17 宁波大千纺织品有限公司 A kind of preparation method of modified poly ester fancy style knitting fabric

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
沈新元: "《化学纤维手册》", 30 September 2008, 中国纺织出版社 *

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Application publication date: 20180525