CN108069681A - soil stabilizer - Google Patents

soil stabilizer Download PDF

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Publication number
CN108069681A
CN108069681A CN201711198750.4A CN201711198750A CN108069681A CN 108069681 A CN108069681 A CN 108069681A CN 201711198750 A CN201711198750 A CN 201711198750A CN 108069681 A CN108069681 A CN 108069681A
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Prior art keywords
acetic acid
soil
polycarboxylate
parts
methyl cellulose
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不公告发明人
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Changsha Road Industrial Design Co
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Changsha Road Industrial Design Co
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/14Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing calcium sulfate cements
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00474Uses not provided for elsewhere in C04B2111/00
    • C04B2111/00732Uses not provided for elsewhere in C04B2111/00 for soil stabilisation
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2201/00Mortars, concrete or artificial stone characterised by specific physical values
    • C04B2201/50Mortars, concrete or artificial stone characterised by specific physical values for the mechanical strength

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Soil Conditioners And Soil-Stabilizing Materials (AREA)

Abstract

The invention discloses a kind of soil stabilizers, belong to land technical field.The soil stabilizer, including following raw material:Modification infusorial earth, flyash, cement, land plaster, crushed crude pearlite, titanium oxide, surfactant, tetramethylammonium hydroxide, polyacrylamide, hydroxypropyl methyl cellulose, polycarboxylate, polyoxyethylene octane alkylphenol ether, acetic acid isopropyl alkene ethyl acetic acid propylene ester copolymer.The soil stabilizer of the present invention can significantly improve intensity unconfined compressive strength, water stability and the scour resistance of soil.

Description

Soil stabilizer
Technical field
The invention belongs to land technical fields, and in particular to a kind of soil stabilizer.
Background technology
Soil stabilizer is a kind of new soil curing material, it by changing the permutation and combination of soil molecule, point The intransitable nethike embrane of water is formed between son, the viscosity of soil itself is recycled to reach stable soil, bearing capacity of soil is improved, prevents Water penetration accelerates the purpose of soil natural petrochemical industry.Therefore the use of soil stabilizer is to ecologies such as soil erosion, desertifications The solution of environmental problem can act as good effect.To in the 1980s, people have synthesized class high score to existing Sub- soil texture stabilizer has sufficient understanding.By 1996, polyacrylamide as soil stabilization water-retaining agent in the U.S. Substantial amounts of popularization and application are obtained.At the same time, for the considerations of reducing cost and the friendly property of environment etc., people are also to day The soil stabilization effect of right macromolecule modified product is studied;And by the application study of polymeric soil structural stabilizing agent by Step expands to Desert Control, exposed soil is fixed, engineering construction etc..
Domestic polymeric soil stabilizer products many at present are all that two kinds or several chemical materials are carried out simply Mixing is so difficult that stabilizer is targetedly improved according to the improved effect of Modified soil.And to the soil of different soil properties The research of earth stabilizer also lacks specific aim, deep not enough to the research of its mechanism of improvement.
A kind of Chinese patent literature " efficient soil stabilizer (Authorization Notice No.:CN103864391B) " disclose a kind of high Soil stabilizer is imitated, the stabilizer is in terms of parts by weight, including following material:10-70 parts of flyash, 10-50 parts of cement, gypsum 10-30 parts of powder, 1-20 parts of aluminum sulfate, 1-5 parts of SILICA FUME, 1-10 parts of modification infusorial earth, 1-10 parts of crushed crude pearlite, titanium oxide 1-10 Part.The soil stabilizer can be widely used for riverbed sludge dredging, and the laying of park stroll road and rural area dirt road improves soil Deng having superpower foul smell adsorption capacity, excellent water-retaining property and water penetration, however there is unconfined compressive strength, water are steady The problems such as qualitative and scour resistance is relatively low.
The content of the invention
It is an object of the invention to provide a kind of soil stabilizer, to solve in a kind of Chinese patent literature " efficient soil Stabilizer (Authorization Notice No.:CN103864391B on the basis of soil stabilizer disclosed in) ", how to optimize component, dosage etc., carry Unconfined compressive strength, water stability and the scour resistance in high soil.
For solution more than technical problem, the present invention uses following technical scheme:
A kind of soil stabilizer, in units of parts by weight, including following raw material:Modification infusorial earth, flyash, cement, stone It is cream powder, crushed crude pearlite, titanium oxide, surfactant, tetramethylammonium hydroxide, polyacrylamide, hydroxypropyl methyl cellulose, poly- Carboxylate, polyoxyethylene octane alkylphenol ether, acetic acid isopropyl alkene-ethyl acetic acid propylene ester copolymer;
The hydroxypropyl methyl cellulose, polycarboxylate, polyoxyethylene octane alkylphenol ether, acetic acid isopropyl alkene-ethyl Propylene acetate copolymer weight ratio is (1.2-2.5):(0.9-1.4):(0.5-1.2):(0.6-1.3).
Preferably, the surfactant is sodium metasilicate, aluminum sulfate is with the mixture of arbitrary proportion.
Preferably, the glass fibre, polycarboxylate, polyoxyethylene octane alkylphenol ether, acetic acid isopropyl alkene-ethyl second Acid propylene ester copolymer weight ratio is 1.8:1.1:0.9:1.
The present invention also provides a kind of preparation methods of soil stabilizer, comprise the following steps:
S1:Diatomite is toasted into 4-5h under 500-520 DEG C of temperature temperature, fast quickly cooling in a low temperature of being subsequently placed in 5-10 DEG C But, the distilled water stirring of 2 times of amounts is added, 100-120 DEG C is raised the temperature to, adds in the sulfuric acid of 20%-30% while stirring, It after when reaction 3-5 is small, is washed with water, filters, you can obtain modification infusorial earth.
S2:By modification infusorial earth, flyash, cement, land plaster, crushed crude pearlite, titanium oxide, surfactant, tetramethyl Ammonium hydroxide, polyacrylamide, hydroxypropyl methyl cellulose, polycarboxylate, polyoxyethylene octane alkylphenol ether, acetic acid isopropyl Alkene-ethyl acetic acid propylene ester copolymer mixed dissolution, stirs evenly, is fully reacted under conditions of 50-80 DEG C, and the reaction time is 4-6h。
The invention has the advantages that:
(1) by the data of embodiment 1-4 and comparative example 6 as it can be seen that using the soil of embodiment 1-4 soils stabilizer without lateral spacing Compression strength, water stability and scour resistance significantly improve;Simultaneously by the data of embodiment 1-4 as it can be seen that embodiment 4 is optimal reality Apply example.
(2) by embodiment 4 and the data of comparative example 1-6 as it can be seen that hydroxypropyl methyl cellulose, polycarboxylate, polyoxyethylene Octane alkylphenol ether, acetic acid isopropyl alkene-ethyl acetic acid propylene ester copolymer play synergistic effect in soil stabilizer, collaboration Soil unconfined compressive strength, water stability and scour resistance are improved, this may be:
1) hydroxypropyl methyl cellulose can improve the gelling property of stabilizer, and hydroxypropyl methyl cellulose, polyoxyethylene are pungent Alkylbenzene phenolic ether generates electrochemical reaction with grogs surface ionization, can form the corpus fibrosum with good gelatification, this Neighboring soil particle can be together in series by kind of corpus fibrosum, so as to improve the tensile capacity of soil, even at dampness, It can make soil that there is good tensile capacity, so as to improve the unconfined compressive strength of soil, water stability and scour resistance, this There is very important effect to soil stability.
2) polycarboxylate has good hydrophobic performance, can tightly hold hydrone when meeting water, form good absorption Water layer promotes soil particle to uphold and increases the distance between grogs, as adsorbed water layer is constantly thickening, can improve soil Stability changes the hydrophily of grogs, soil is made to have better hydrophobicity, therefore polycarboxylate can enhance between soil particle Water stability and scour resistance.
3) be used in combination can be in soil for polyoxyethylene octane alkylphenol ether and hydroxypropyl methyl cellulose, polycarboxylate Intergranular forms certain netted membrane structure, enhances the binding strength between soil particle, so as to improve the unconfined compressive strength of soil, Water stability and scour resistance.
4) acetic acid isopropyl alkene-ethyl acetic acid acrylic ester and hydroxypropyl methyl cellulose, polycarboxylate, polyoxyethylene octyl Phenol ether copolymer acts on soil particle so that power, the intermembranous viscous force of aquation and capillary water are acted between soil particle Surface tension synergy and cause to produce cohesive force between particle, the contact force between soil particle is increased, between soil particle The surface tension of capillary water is also remarkably reinforced, so as to improve the intensity unconfined compressive strength of soil, water stability and resist Erosion.
(3) hydroxypropyl methyl cellulose, polycarboxylate, polyoxyethylene octane alkylphenol ether, acetic acid isopropyl alkene-ethyl acetic acid Propylene ester copolymer is as reinforcement system, by controlling hydroxypropyl methyl cellulose, polycarboxylate, polyoxyethylene octyl phenol Ether, acetic acid isopropyl alkene-ethyl acetic acid acrylic ester copolymer weight ratio are (1.2-2.5):(0.9-1.4):(0.5-1.2):(0.6- 1.3), realize and made in reinforcement system with polyoxyethylene octane alkylphenol ether, acetic acid isopropyl alkene-ethyl acetic acid propylene ester copolymer For the raw material of the leading role of reinforcement system, using the gelling property of hydroxypropyl methyl cellulose and polycarboxylate hydrophobic performance, So that reinforcement system, which is applied in the soil stabilizer of the present invention, can effectively improve soil unconfined compressive strength, water stability And scour resistance.
Specific embodiment
It for ease of more fully understanding the present invention, is illustrated by following instance, these examples belong to the protection of the present invention Scope, but do not limit the scope of the invention.
In embodiment, the soil stabilizer, in units of parts by weight, including following raw material:Modification infusorial earth 12- 18 parts, 4-10 parts of flyash, 2-5 parts of cement, 3-6 parts of land plaster, 1.6-2.5 parts of crushed crude pearlite, 1-2 parts of titanium oxide, surface live 1.5-3.2 parts of agent of property, 2.4-3.8 parts of tetramethylammonium hydroxide, 2.2-3.5 parts of polyacrylamide, hydroxypropyl methyl cellulose 1.2-2.5 parts, 0.9-1.4 parts of polycarboxylate, 0.5-1.2 parts of polyoxyethylene octane alkylphenol ether, acetic acid isopropyl alkene-ethyl acetic acid 0.6-1.3 parts of propylene ester copolymer;
The surfactant is sodium metasilicate, aluminum sulfate is with the mixture of arbitrary proportion.
The preparation method of the soil stabilizer, comprises the following steps:
S1:Diatomite is toasted into 4-5h under 500-520 DEG C of temperature temperature, fast quickly cooling in a low temperature of being subsequently placed in 5-10 DEG C But, the distilled water stirring of 2 times of amounts is added, 100-120 DEG C is raised the temperature to, adds in the sulfuric acid of 20%-30% while stirring, It after when reaction 3-5 is small, is washed with water, filters, you can obtain modification infusorial earth.
S2:By modification infusorial earth, flyash, cement, land plaster, crushed crude pearlite, titanium oxide, surfactant, tetramethyl Ammonium hydroxide, polyacrylamide, hydroxypropyl methyl cellulose, polycarboxylate, polyoxyethylene octane alkylphenol ether, acetic acid isopropyl Alkene-ethyl acetic acid propylene ester copolymer mixed dissolution, stirs evenly, is fully reacted under conditions of 50-80 DEG C, and the reaction time is 4-6h。
Below by more specific embodiment, the present invention will be described.
Embodiment 1
A kind of soil stabilizer, in units of parts by weight, including following raw material:12 parts of modification infusorial earth, 4 parts of flyash, 2 parts of cement, 3 parts of land plaster, 1.6 parts of crushed crude pearlite, 1 part of titanium oxide, 2.5 parts of surfactant, tetramethylammonium hydroxide 3.8 Part, 2.2 parts of polyacrylamide, 1.2 parts of hydroxypropyl methyl cellulose, 1.2 parts of polycarboxylate, polyoxyethylene octane alkylphenol ether 0.5 part, acetic acid isopropyl alkene-.3 parts of ethyl acetic acid acrylic ester copolymer 1;
The surfactant is sodium metasilicate, aluminum sulfate is with the mixture of arbitrary proportion.
The preparation method of the soil stabilizer, comprises the following steps:
S1:Diatomite is toasted into 4.5h under 500 DEG C of temperature temperature, is quickly cooled down in a low temperature of being subsequently placed in 8 DEG C, then is added Enter 2 times amount distilled water stirring, raise the temperature to 120 DEG C, while stirring add in 25% sulfuric acid, reaction 3 it is small when after, use water Washing, filtering, you can obtain modification infusorial earth.
S2:By modification infusorial earth, flyash, cement, land plaster, crushed crude pearlite, titanium oxide, surfactant, tetramethyl Ammonium hydroxide, polyacrylamide, hydroxypropyl methyl cellulose, polycarboxylate, polyoxyethylene octane alkylphenol ether, acetic acid isopropyl Alkene-ethyl acetic acid propylene ester copolymer mixed dissolution, stirs evenly, is fully reacted under conditions of 65 DEG C, reaction time 6h.
Embodiment 2
A kind of soil stabilizer, in units of parts by weight, including following raw material:15 parts of modification infusorial earth, 6 parts of flyash, 3 parts of cement, 4 parts of land plaster, 1.8 parts of crushed crude pearlite, 1.2 parts of titanium oxide, 3.2 parts of surfactant, tetramethylammonium hydroxide 2.4 Part, 3 parts of polyacrylamide, 1.6 parts of hydroxypropyl methyl cellulose, 1.4 parts of polycarboxylate, polyoxyethylene octane alkylphenol ether 0.6 Part, acetic acid isopropyl alkene -0.6 part of ethyl acetic acid propylene ester copolymer;
The surfactant is sodium metasilicate, aluminum sulfate is with the mixture of arbitrary proportion.
The preparation method of the soil stabilizer, comprises the following steps:
S1:Diatomite is toasted into 5h under 510 DEG C of temperature temperature, is quickly cooled down in a low temperature of being subsequently placed in 10 DEG C, then is added Enter 2 times amount distilled water stirring, raise the temperature to 100 DEG C, while stirring add in 30% sulfuric acid, reaction 4 it is small when after, use water Washing, filtering, you can obtain modification infusorial earth.
S2:By modification infusorial earth, flyash, cement, land plaster, crushed crude pearlite, titanium oxide, surfactant, tetramethyl Ammonium hydroxide, polyacrylamide, hydroxypropyl methyl cellulose, polycarboxylate, polyoxyethylene octane alkylphenol ether, acetic acid isopropyl Alkene-ethyl acetic acid propylene ester copolymer mixed dissolution, stirs evenly, is fully reacted under conditions of 80 DEG C, reaction time 4h.
Embodiment 3
A kind of soil stabilizer, in units of parts by weight, including following raw material:18 parts of modification infusorial earth, 8 parts of flyash, 4 parts of cement, 5 parts of land plaster, 2 parts of crushed crude pearlite, 1.5 parts of titanium oxide, 1.5 parts of surfactant, tetramethylammonium hydroxide 3.4 Part, 3.5 parts of polyacrylamide, 2.5 parts of hydroxypropyl methyl cellulose, 0.9 part of polycarboxylate, polyoxyethylene octane alkylphenol ether 1.2 parts, acetic acid isopropyl alkene -0.8 part of ethyl acetic acid propylene ester copolymer;
The surfactant is sodium metasilicate, aluminum sulfate is with the mixture of arbitrary proportion.
The preparation method of the soil stabilizer, comprises the following steps:
S1:Diatomite is toasted into 4h under 520 DEG C of temperature temperature, is quickly cooled down, adds in a low temperature of being subsequently placed in 5 DEG C 2 times amount distilled water stirring, raise the temperature to 110 DEG C, while stirring add in 20% sulfuric acid, reaction 5 it is small when after, be washed with water It washs, filters, you can obtain modification infusorial earth.
S2:By modification infusorial earth, flyash, cement, land plaster, crushed crude pearlite, titanium oxide, surfactant, tetramethyl Ammonium hydroxide, polyacrylamide, hydroxypropyl methyl cellulose, polycarboxylate, polyoxyethylene octane alkylphenol ether, acetic acid isopropyl Alkene-ethyl acetic acid propylene ester copolymer mixed dissolution, stirs evenly, is fully reacted under conditions of 50 DEG C, reaction time 5h.
Embodiment 4
A kind of soil stabilizer, in units of parts by weight, including following raw material:17 parts of modification infusorial earth, 9 parts of flyash, 4 parts of cement, 5 parts of land plaster, 2.2 parts of crushed crude pearlite, 1.8 parts of titanium oxide, 2 parts of surfactant, tetramethylammonium hydroxide 3.3 Part, 3 parts of polyacrylamide, 1.8 parts of hydroxypropyl methyl cellulose, 1.1 parts of polycarboxylate, polyoxyethylene octane alkylphenol ether 0.9 Part, acetic acid isopropyl alkene-ethyl acetic acid acrylic ester copolymer 1 part;
The surfactant is sodium metasilicate, aluminum sulfate is with the mixture of arbitrary proportion.
The preparation method of the soil stabilizer, comprises the following steps:
S1:Diatomite is toasted into 5h under 520 DEG C of temperature temperature, is quickly cooled down, adds in a low temperature of being subsequently placed in 5 DEG C 2 times amount distilled water stirring, raise the temperature to 120 DEG C, while stirring add in 30% sulfuric acid, reaction 3 it is small when after, be washed with water It washs, filters, you can obtain modification infusorial earth.
S2:By modification infusorial earth, flyash, cement, land plaster, crushed crude pearlite, titanium oxide, surfactant, tetramethyl Ammonium hydroxide, polyacrylamide, hydroxypropyl methyl cellulose, polycarboxylate, polyoxyethylene octane alkylphenol ether, acetic acid isopropyl Alkene-ethyl acetic acid propylene ester copolymer mixed dissolution, stirs evenly, is fully reacted under conditions of 50 DEG C, reaction time 4h.
Comparative example 1
It is essentially identical with the preparation process of embodiment 4, have only unlike prepare in the raw material of soil stabilizer and lack hydroxyl Propyl methocel, polycarboxylate, polyoxyethylene octane alkylphenol ether, acetic acid isopropyl alkene-ethyl acetic acid propylene ester copolymer.
Comparative example 2
It is essentially identical with the preparation process of embodiment 4, have only unlike prepare in the raw material of soil stabilizer and lack hydroxyl Propyl methocel.
Comparative example 3
It is essentially identical with the preparation process of embodiment 4, have only unlike prepare lack in the raw material of soil stabilizer it is poly- Carboxylate.
Comparative example 4
It is essentially identical with the preparation process of embodiment 4, have only unlike prepare lack in the raw material of soil stabilizer it is poly- Ethylene oxide octane alkylphenol ether.
Comparative example 5
It is essentially identical with the preparation process of embodiment 4, have only unlike prepare in the raw material of soil stabilizer and lack vinegar Sour isopropyl alkene-ethyl acetic acid propylene ester copolymer.
Comparative example 6
Using a kind of Chinese patent literature " efficient soil stabilizer (Authorization Notice No.:CN103864391B) " embodiment 1- 14 technique prepares stabilizer.
The soil of the same area is taken, is air-dried after crushing, is separately added into the stabilizer for implementing 1-4 and comparative example 1-6, according to 《Standard for test methods of earthworks》(GB/T50123-1999) carried out using Static compaction method, each group soil is measured after conserving 72h Unconfined compressive strength;The above-mentioned soil of same particle size is taken, its stability is measured using hydrostatic method;Take the same area Soil is air-dried after crushing, and the stabilizer for implementing 1-4 and comparative example 1-6 is separately added into, after compacting, using the method for simulated rainfall Progress scour resistance research, rainfall intensity 3.2L/min, rain time 1h, testing result are as shown in the table.
As seen from the above table:(1) by the data of embodiment 1-4 and comparative example 6 as it can be seen that using embodiment 1-4 soils stabilizer Soil unconfined compressive strength, water stability and scour resistance significantly improve;Simultaneously by the data of embodiment 1-4 as it can be seen that reality Example 4 is applied as optimum embodiment.
(2) by embodiment 4 and the data of comparative example 1-6 as it can be seen that hydroxypropyl methyl cellulose, polycarboxylate, polyoxyethylene Octane alkylphenol ether, acetic acid isopropyl alkene-ethyl acetic acid propylene ester copolymer play synergistic effect in soil stabilizer, collaboration Soil unconfined compressive strength, water stability and scour resistance are improved, this may be:
1) hydroxypropyl methyl cellulose can improve the gelling property of stabilizer, and hydroxypropyl methyl cellulose, polyoxyethylene are pungent Alkylbenzene phenolic ether generates electrochemical reaction with grogs surface ionization, can form the corpus fibrosum with good gelatification, this Neighboring soil particle can be together in series by kind of corpus fibrosum, so as to improve the tensile capacity of soil, even at dampness, It can make soil that there is good tensile capacity, so as to improve the unconfined compressive strength of soil, water stability and scour resistance, this There is very important effect to soil stability.
2) polycarboxylate has good hydrophobic performance, can tightly hold hydrone when meeting water, form good absorption Water layer promotes soil particle to uphold and increases the distance between grogs, as adsorbed water layer is constantly thickening, can improve soil Stability changes the hydrophily of grogs, soil is made to have better hydrophobicity, therefore polycarboxylate can enhance between soil particle Water stability and scour resistance.
3) be used in combination can be in soil for polyoxyethylene octane alkylphenol ether and hydroxypropyl methyl cellulose, polycarboxylate Intergranular forms certain netted membrane structure, enhances the binding strength between soil particle, so as to improve the unconfined compressive strength of soil, Water stability and scour resistance.
4) acetic acid isopropyl alkene-ethyl acetic acid acrylic ester and hydroxypropyl methyl cellulose, polycarboxylate, polyoxyethylene octyl Phenol ether copolymer acts on soil particle so that power, the intermembranous viscous force of aquation and capillary water are acted between soil particle Surface tension synergy and cause to produce cohesive force between particle, the contact force between soil particle is increased, between soil particle The surface tension of capillary water is also remarkably reinforced, so as to improve the intensity unconfined compressive strength of soil, water stability and resist Erosion.
(3) hydroxypropyl methyl cellulose, polycarboxylate, polyoxyethylene octane alkylphenol ether, acetic acid isopropyl alkene-ethyl acetic acid Propylene ester copolymer is as reinforcement system, by controlling hydroxypropyl methyl cellulose, polycarboxylate, polyoxyethylene octyl phenol Ether, acetic acid isopropyl alkene-ethyl acetic acid acrylic ester copolymer weight ratio are (1.2-2.5):(0.9-1.4):(0.5-1.2):(0.6- 1.3), realize and made in reinforcement system with polyoxyethylene octane alkylphenol ether, acetic acid isopropyl alkene-ethyl acetic acid propylene ester copolymer For the raw material of the leading role of reinforcement system, using the gelling property of hydroxypropyl methyl cellulose and polycarboxylate hydrophobic performance, So that reinforcement system, which is applied in the soil stabilizer of the present invention, can effectively improve soil unconfined compressive strength, water stability And scour resistance.
More than content is it cannot be assumed that present invention specific implementation is confined to these explanations, for the technical field of the invention Those of ordinary skill for, under the premise of present inventive concept is not departed from, several simple deduction or replace can also be made, all should When being considered as belonging to present invention scope of patent protection determined by the appended claims.

Claims (4)

1. a kind of soil stabilizer, which is characterized in that including following raw material:Modification infusorial earth, flyash, cement, land plaster, treasure Pearl rock powder, titanium oxide, surfactant, tetramethylammonium hydroxide, polyacrylamide, hydroxypropyl methyl cellulose, polycarboxylate, Polyoxyethylene octane alkylphenol ether, acetic acid isopropyl alkene-ethyl acetic acid propylene ester copolymer;
The hydroxypropyl methyl cellulose, polycarboxylate, polyoxyethylene octane alkylphenol ether, acetic acid isopropyl alkene-ethyl acetic acid Acrylic ester copolymer weight ratio is (1.2-2.5):(0.9-1.4):(0.5-1.2):(0.6-1.3).
2. soil stabilizer according to claim 1, which is characterized in that the surfactant is sodium metasilicate, sulfuric acid Aluminium is with the mixture of arbitrary proportion.
3. soil stabilizer according to claim 1, which is characterized in that the glass fibre, polycarboxylate, polyoxy second Alkene octane alkylphenol ether, acetic acid isopropyl alkene-ethyl acetic acid acrylic ester copolymer weight ratio are 1.8:1.1:0.9:1.
4. according to claim 1-3 any one of them soil stabilizer, which is characterized in that its preparation method includes following step Suddenly:
S1:Diatomite is toasted into 4-5h under 500-520 DEG C of temperature temperature, is quickly cooled down in a low temperature of being subsequently placed in 5-10 DEG C, The distilled water stirring of 2 times of amounts is added, 100-120 DEG C is raised the temperature to, adds in the sulfuric acid of 20%-30% while stirring, instead It after when answering 3-5 small, is washed with water, filters, you can obtain modification infusorial earth.
S2:By modification infusorial earth, flyash, cement, land plaster, crushed crude pearlite, titanium oxide, surfactant, tetramethyl hydrogen-oxygen Change ammonium, polyacrylamide, hydroxypropyl methyl cellulose, polycarboxylate, polyoxyethylene octane alkylphenol ether, acetic acid isopropyl alkene-second Ethyl acrylates copolymer mixed dissolution, stirs evenly, is fully reacted under conditions of 50-80 DEG C, reaction time 4-6h.
CN201711198750.4A 2017-11-26 2017-11-26 soil stabilizer Pending CN108069681A (en)

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CN103864391A (en) * 2014-01-16 2014-06-18 刘洪军 Efficient soil stabilizer
CN104004525A (en) * 2014-06-09 2014-08-27 包宗义 Soil body stabilizer
CN104556812A (en) * 2015-01-06 2015-04-29 江苏中凯新材料有限公司 Plastic stabilizer for wet-mixed mortar
CN106459762A (en) * 2014-03-31 2017-02-22 索理思科技公司 Low degree of substitution sodium carboxymethylcellulose for soil stabilized and water retardant film

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Publication number Priority date Publication date Assignee Title
JPS5814477B2 (en) * 1978-10-04 1983-03-19 三菱鉱業セメント株式会社 Setting-retarded soil stabilizer
BR8307461A (en) * 1982-07-30 1984-07-17 Miseal Inc SOIL STABILIZATION COMPOSITION AND SOIL STABILIZATION PROCESS
CN1726270A (en) * 2002-10-15 2006-01-25 恩卡普有限责任公司 Soil stabilizer carrier
CN101805615A (en) * 2010-03-16 2010-08-18 江汉大学 Vegetation soil stabilizer for soil slope and preparation method thereof
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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112916609A (en) * 2021-03-03 2021-06-08 重庆桂溪生态环境科技有限公司 Method for blocking and burying polluted soil

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Application publication date: 20180525