CN108069511A - A kind of solar anaerobic reactor assembly applied in processing unit and its application method - Google Patents

A kind of solar anaerobic reactor assembly applied in processing unit and its application method Download PDF

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CN108069511A
CN108069511A CN201611032696.1A CN201611032696A CN108069511A CN 108069511 A CN108069511 A CN 108069511A CN 201611032696 A CN201611032696 A CN 201611032696A CN 108069511 A CN108069511 A CN 108069511A
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reaction kettle
water
anaerobic reactor
denitrifying bacteria
solar
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毛国柱
王帅
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Tianjin University
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Tianjin University
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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/28Anaerobic digestion processes
    • C02F3/2866Particular arrangements for anaerobic reactors
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/30Aerobic and anaerobic processes
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/34Biological treatment of water, waste water, or sewage characterised by the microorganisms used
    • HELECTRICITY
    • H02GENERATION; CONVERSION OR DISTRIBUTION OF ELECTRIC POWER
    • H02JCIRCUIT ARRANGEMENTS OR SYSTEMS FOR SUPPLYING OR DISTRIBUTING ELECTRIC POWER; SYSTEMS FOR STORING ELECTRIC ENERGY
    • H02J7/00Circuit arrangements for charging or depolarising batteries or for supplying loads from batteries
    • H02J7/34Parallel operation in networks using both storage and other dc sources, e.g. providing buffering
    • H02J7/35Parallel operation in networks using both storage and other dc sources, e.g. providing buffering with light sensitive cells
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00Nature of the contaminant
    • C02F2101/10Inorganic compounds
    • C02F2101/16Nitrogen compounds, e.g. ammonia
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00Nature of the contaminant
    • C02F2101/10Inorganic compounds
    • C02F2101/20Heavy metals or heavy metal compounds
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E10/00Energy generation through renewable energy sources
    • Y02E10/50Photovoltaic [PV] energy
    • Y02E10/56Power conversion systems, e.g. maximum power point trackers

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  • Life Sciences & Earth Sciences (AREA)
  • Microbiology (AREA)
  • Engineering & Computer Science (AREA)
  • Biodiversity & Conservation Biology (AREA)
  • Hydrology & Water Resources (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Power Engineering (AREA)
  • Purification Treatments By Anaerobic Or Anaerobic And Aerobic Bacteria Or Animals (AREA)

Abstract

The invention discloses a kind of solar anaerobic reactor assembly applied in processing unit and its application method, the device include anaerobic reactor, into water conduit tube, go out water conduit tube, interior return duct, pump, accumulator, photoelectric controller, inverter and generator;Anaerobic reactor includes reaction kettle, electric heating assembly and solar photovoltaic assembly, reaction kettle is divided into reaction kettle top, reaction kettle middle part and reaction kettle lower part, reaction kettle top is connected with going out water conduit tube, in in the middle part of reaction kettle filler material is activated full of denitrifying bacteria, water distributor in reaction kettle lower part is connected by pumping with into water conduit tube, is intake, is gone out between water conduit tube equipped with interior return duct;Electric heating assembly is set in anaerobic reactor side wall;Solar photovoltaic assembly, accumulator, photoelectric controller, inverter, the control system of generator are sequentially connected, and generator is connected with electric heating assembly and pump.The present invention is without energy consumption, pollution-free, versatility is good, environmentally protective.

Description

A kind of solar anaerobic reactor assembly applied in processing unit and its use Method
Technical field
The present invention relates to anaerobic reactor devices, and in particular to removes eutrophic water using water body original inhabitants denitrifying bacteria A kind of solar anaerobic reactor assembly applied in processing unit and its application method of heavy metal and nitrate nitrogen in body.
Background technology
Eutrophication of natural water and heavy metal pollution are always current most common combined pollution.Eutrophication is current Important behaviour in conventional pollution, as the mankind increasingly increase environmental resource utilization activity, particularly industrial and agricultural production Extensive development, largely the sewage containing compound fertilizer be discharged into neighbouring natural water body, add the battalion of these water bodys Substance load is supported, essential problem is the multifarious destruction of aqueous bio, and the system that thereby results in is lost self―sustaining, self adjusted The ability of section and system balancing unstability accelerate the speed of body eutrophication.And in the discharge process of sewage, pollutant Heavy metal retaining in water body water body is also increasing, and heavy metal retaining in water body accumulates and the features such as migration increases The difficulty that heavy metal in water has been added to purify.Simultaneously as heavy metal has, source is wide, the residence time is long, has accumulation property, can not drop Solution can not only endanger Fishery Water Environment and aquatile, also endanger human health along the features such as food chain transport.Therefore compel Being essential will be administered and be repaired to the water body water body of nitrate nitrogen and heavy-metal composite pollution.
The existing administering method for polluted water body can be divided into Physical, chemical method, bioanalysis, restoration of the ecosystem Four major classes, and many method for treating water technological processes are very ripe, but deposited for the improvement of the open water body such as water body, river In significant limitation.Therefore, from financial cost and recycling angularly, economical and efficient, energy-saving and environment-friendly water are explored Weight metal purification method and device is the difficult point that current heavy metal pollution of water body is administered.
The content of the invention
Present invention aims to overcome that the deficiencies in the prior art, provide a kind of solar anaerobic applied in processing unit Reactor assembly and its application method.
A kind of solar anaerobic reactor assembly applied in processing unit, including into water conduit tube, go out water conduit tube, interior time Flow tube, pump, accumulator, photoelectric controller, inverter and generator;The anaerobic reactor includes reaction kettle, electrical heating group Part and solar photovoltaic assembly, anaerobic reactor top are provided with one-way exhaust valve;The reaction kettle is vertically arranged closed Tank body, reaction kettle are divided into reaction kettle top, reaction kettle middle part and reaction kettle lower part, three phase separator are set in reaction kettle top, Reaction kettle top is provided with water outlet, and the water outlet is connected with the water conduit tube that goes out;It is set in the middle part of the reaction kettle There is spacer-frame, spacer-frame activates filler material full of denitrifying bacteria, and the denitrifying bacteria activates filler material with inorganic carrying Body, inorganic flocculate, inorganic metal salt, activated carbon are prepared for raw material, and the mass ratio of four kinds of raw materials is followed successively by (1~8):(0 ~0.5):(0~0.5):(2~4), wherein the quality of inorganic flocculate and inorganic metal salt ratio value range be more than 0 and Less than or equal to 0.5, the four kind raw material is sufficiently mixed and is dispersed in 60~80 DEG C of water, and denitrifying bacteria is added in after cooling and is swashed Agent living, the organic high molecular polymer being then dissolved in the water in the case where being sufficiently stirred with the speed instillation of 3~4ml/min are organic High molecular polymer is used to denitrifying bacteria activator being fixed on inorganic carrying body surface, after cooling precipitates, lower part deposit As denitrifying bacteria activation filler material, the inorganic carrying body are one kind in silica gel, montmorillonite or diatomite, institute Inorganic flocculate is stated as aluminium polychloride (PAC), polyaluminium sulfate (PAS), bodied ferric sulfate (PFS) or poly-ferric chloride (PFC) one kind in, the one kind of the inorganic metal salt for sodium chloride, in potassium chloride, the denitrifying bacteria activator into It is divided into frerrous chloride, sodium acetate, peptone, yeast extract, glucose, sodium chloride, agar, potassium nitrate, mass ratio is successively during addition For (1~1.5):(2~2.5):(15~16):(3~3.5):(1~1.5):(6~6.5):(12~13):(2~2.5);Instead It answers and water distributor is provided in kettle lower part, water distributor is connected by the pump with described into water conduit tube, described into water conduit tube The interior return duct is provided with going out between water conduit tube;Hollow interlayer is provided in the anaerobic reactor side wall, it is described Electric heating assembly be arranged in hollow interlayer and be evenly distributed on anaerobic reactor side wall;The solar photovoltaic assembly with Described accumulator connection, accumulator are connected with the photoelectric controller, and photoelectric controller is connected with inverter, inverter and The control system connection of the generator, generator are connected with electric heating assembly and pump.
Moreover, system must be cooled to 30~40 DEG C when adding in the denitrifying bacteria activator, and control itself and nothing The ratio of machine carrying body is (0.3~8):1, preferably (3~5):1;The organic high molecular polymer is polyvinyl alcohol, poly- second One kind in alkene, polypropylene, polystyrene or cellulose, the organic high molecular polymer are dispersed in 95~97 DEG C In water, the final mass ratio of the organic high molecular polymer and inorganic carrying body is (0.5~0.6):(7~8).
Moreover, described going out on water conduit tube is provided with out water regulating valve, advanced treating is treated in the other end connection for going out water conduit tube Pond entrance;It is described into inlet regulating valve is provided on water conduit tube, the other end connection into water conduit tube treats that aerobic tank exports;It is described Interior return duct on be provided with return valve.
Moreover, the reaction kettle top and the outer surface of reaction kettle lower part are arc-shaped, reaction kettle top and reaction kettle High 0.2~the 0.4m in lower part, the high 0.2~0.4m in bottom;It is cylinder, a diameter of 0.5~1m, high 1~3m in the middle part of reaction kettle.
Moreover, the denitrifying bacteria activation filler material is filled in using the method for lattice filling in reaction kettle middle part, It is close fill out that total height is reaction kettle total height 75%~90%, the distance at the top of denitrifying bacteria Activation filling and reaction kettle is anti- Answer the 10%~25% of kettle total height, the disposable 1000~4000mg/L of dosage of technique initial period..
Moreover, the electric heating assembly is made of the heating wire of n groups parallel connection, 10≤n≤40, heating wire is in vertical direction It is upper S-type, and heating wire is integrally along reaction kettle axial rings around annular in shape.
A kind of application method for the solar anaerobic reactor assembly applied in processing unit, comprises the following steps:
Step 1, it is connected described by the anaerobic reactor device of Driven by Solar Energy with aerobic tank and advanced treating pond, profit The quantity of indigenous denitrifying bacteria is measured with the method for quantitative fluorescent PCR;
Step 2, the equipment is run, inlet regulating valve and return valve is opened, closes out water regulating valve, utilize solar energy The energy hole pump that photovoltaic module generates is introduced from aerobic tank intakes, and realizes the self-loopa of technique initial period internal system, This stage denitrifying bacteria microorganism carry out biofilm culture, by the method for quantitative fluorescent PCR measure add in water body after denitrification Denitrifying bacteria quantity in bacterium activation filler material realizes that the multiple that the quantity of indigenous denitrifying bacteria increases is more than or equal to 10;
Step 3, inlet regulating valve and return valve is kept to open, then opens out water regulating valve, when controlling normal operation Flow of inlet water, control hydraulic detention time, by adjust inlet regulating valve, go out water regulating valve and return valve control Inlet and outlet water Ratio and nitrate recirculation ratio;
Step 4, the water outlet in anaerobic reactor device flows into advanced treating pond by self gravitation;
In step 2 and step 3, solar photovoltaic assembly, which converts solar energy into electrical energy, is stored in solar storage battery It is interior, then direct current energy signal is converted by photoelectric control prop, DC signal enters inverter and is being converted into AC load Ac electric apparatus is supplied, then electric energy is provided for the electric heating assembly of solar photovoltaic assembly lower floor by generator control system, electricity Heating component converts electrical energy into thermal energy, and electric heating assembly is all covered in tank surface, effectively accomplished in anaerobic reactor Heated liquid is uniform;Meanwhile generator control system provides electric energy for pump, during realizing the self-loopa of the device and normal operation Stable state.
Moreover, in above-mentioned application method, the technique initial period internal system self-loopa time is 24~26h, 0.1~0.9m of flow of inlet water during normal operation3/ h, described controls hydraulic detention time as 6~10h, the nitrate recirculation ratio Example is 400%~500%.
Beneficial effects of the present invention:
(1) a kind of solar anaerobic reactor assembly applied in processing unit is net using the ecology of eutrophication water Change method, by the denitrifying bacteria for activating water body native country so that denitrifying bacteria quantity is rised in value in geometric progression, and uses water Body replaces traditional limited bioreactor in itself, releases denitrifying bacteria growing space significantly, it is thin to give full play to denitrification The powerful capacity of decomposition generated during bacterium amount reproduction to nitrate nitrogen improves the effective biomass and function of denitrifying bacteria Property, restructuring is improved and optimizes Water microbial ecology system, and then strengthens microorganism central hub effect of establishing, and promotes water body Recover capacity of self-regulation, so as to which efficiently N, P of removal induction algal blooms etc. are contaminants associated, effectively reduce in water body Suspended alga, suspended particulate content, reduce turbidity, increase transparency, it is horizontal to promote Dissolved Oxygen in Water, fundamentally improves water The material balance state of matter and water ecosystem is finally reached and keeps the restoration of the ecosystem purpose of the self-purification of water.
(2) present invention process is simple, and floor space is small, and operational management is convenient, invests, condition of compatibility model low with operating cost It encloses extensively, it can the extensive use in various the natural water bodies even restoration of the ecosystem of artificial water.
(3) a kind of solar anaerobic reactor assembly applied in processing unit involved in this technology, outermost layer are Solar photovoltaic assembly, is mainly used for converting solar energy into electrical energy and is stored in solar storage battery, then passes through photoelectric control branch Device is converted into direct current energy signal, and DC signal can directly be used in DC electric apparatus, can also be converted into inverter AC load removes supply ac electric apparatus, then is carried by generator control system for the electric heating assembly of solar photovoltaic assembly lower floor For electric energy, electric heating assembly converts electrical energy into thermal energy, and electric heating assembly is all covered in tank surface, can effectively accomplished Heated liquid is uniform in anaerobic reactor, and suitable temperature is provided for microorganism, convenient for the growth of microorganism, the activity of microorganism It is protected with flora number, the in vivo biological activated sludge of tank is with regard to that can have the work that preferable phagocytosis Organic substance in water is decomposed With, stable anaerobism purification is carried out to water body, meanwhile, generator control system provides electric energy for pump, with realize the device oneself Stable state when Xun Huan and normal operation.For the heat preserving method of now existing other forms, the photovoltaic installed Component and electric heating assembly have apparent advantage, without energy consumption, pollution-free, good without operating cost, versatility, not only green ring It protects, and does not destroy the landscape function that some water bodys have.Therefore, the device use condition is very wide, throughout the year except cold zone not Seeing the place of sunlight cannot use, and secondary pollution is not caused after non-maintaining use, be real clean energy resource, and energy quality is high, The time for obtaining the energy is short.System one-time investment can keep continuously power supply 20 years.
(4) during denitrifying bacteria multiplication, Fe2+While playing the role of being obviously promoted in the process, aoxidized The ferric oxide of generation has heavy metal that can largely in adsorbed water body, effectively removes the heavy metal in water body.
Description of the drawings
Fig. 1 is the schematic diagram of the present invention.
Wherein:1 is anaerobic reactor, and 2 be water outlet, and 3 be water conduit tube, and 4 be reaction kettle top, and 5 be reaction kettle middle part, 6 be reaction kettle lower part, and 7 be water regulating valve, and 8 be advanced treating pond, and 8-1 is advanced treating pond entrance, and 9 be aerobic tank, and 9-1 is Aerobic tank exports, and 10 be inlet regulating valve, and 11 be into water conduit tube, and 12 be return valve, and 13 be interior return duct, and 14 is pump, and 15 It is water distributor for spacer-frame, 16,17 be ferric oxide and heavy metal outlet, and 18 be accumulator, and 19 be photoelectric controller, 20 be generator, and 21 be inverter, and 22 be reaction kettle, and 23 be solar photovoltaic assembly, and 24 be hollow interlayer, and 25 be reaction kettle, 26 be three phase separator, and 27 be one-way exhaust mouth.
Specific embodiment
The present invention is further illustrated with reference to the accompanying drawings and examples, but should not be construed as the limit to the present invention System.
A kind of solar anaerobic reactor assembly applied in processing unit, including anaerobic reactor 1, into water conduit tube 11st, water conduit tube 3, interior return duct 13, pump 14, accumulator 18, photoelectric controller 19, inverter 21 and generator 20 are gone out;Described Anaerobic reactor includes reaction kettle 25, electric heating assembly 23 and solar photovoltaic assembly 22, and list is provided at the top of anaerobic reactor To air bleeding valve 27;The closed tank body that the reaction kettle is vertically arranged, reaction kettle are divided into reaction kettle top 4,5 and of reaction kettle middle part Reaction kettle lower part 6 sets three phase separator 26 in reaction kettle top, and reaction kettle top is provided with water outlet 2, the water outlet It is connected with the water conduit tube 3 that goes out, interior in the middle part of the reaction kettle to be equipped with spacer-frame 15, spacer-frame is activated full of denitrifying bacteria Filler material is provided with water distributor 16 in reaction kettle lower part, and water distributor is connected by the pump 14 with described into water conduit tube 11, It is described into water conduit tube and to go out between water conduit tube to be provided with the interior return duct 13;It is set in the anaerobic reactor side wall There is hollow interlayer 24, the electric heating assembly is arranged in hollow interlayer 24 and is evenly distributed on anaerobic reactor side wall; The solar photovoltaic assembly is connected with the accumulator 18, and accumulator is connected with the photoelectric controller 19, photoelectric control Device processed is connected with inverter 21, and inverter is connected with the control system of the generator 20, generator and electric heating assembly and Pump connection.
Moreover, described going out on water conduit tube is provided with out water regulating valve 7, go out the other end connection advanced treating pond of water conduit tube Entrance 8-1;It is described into inlet regulating valve 10 is provided on water conduit tube, into the other end connection aerobic tank outlet 9-1 of water conduit tube; Return valve 12 is provided on the interior return duct.
Moreover, the reaction kettle top and the outer surface of reaction kettle lower part are arc-shaped, reaction kettle top and reaction kettle The high 0.2m in lower part, the high 0.2m in bottom;It is cylinder, a diameter of 0.8m, high 3m in the middle part of reaction kettle.
Moreover, the denitrifying bacteria activation filler material is filled in using the method for lattice filling in reaction kettle middle part, It is close fill out that total height is reaction unit total height 85%, the distance at the top of denitrifying bacteria Activation filling and reaction kettle fills for reaction Put the 15% of total height, the disposable dosage 3000mg/L of technique initial period.
Moreover, the electric heating assembly is made of 35 groups of heating wire in parallel, heating wire is S-type in the vertical direction, And heating wire entirety is along reaction kettle axial rings around annular in shape.
The denitrifying bacteria prepared according to following preparation method activation filler material is filled in a kind of above-mentioned apply to handle In solar anaerobic reactor assembly in unit:It is 3 by mass ratio:0.5:0.5:4 inorganic carrying body silica gel, inorganic flocculation Object polymer alumina, inorganic metal salt sodium chloride, activated carbon are sufficiently mixed and are scattered in 70 DEG C of water, treat above-mentioned suspension Be cooled to 40 DEG C, add in denitrifying bacteria activator (activator by frerrous chloride, sodium acetate, peptone, yeast extract, glucose, Sodium chloride, agar, potassium nitrate composition, mass ratio is followed successively by 1 when each ingredient adds:2:15:3:1:6:12:2;It is anti-described in adding in System must be cooled to 30 DEG C during nitrobacteria activator), the ratio for controlling itself and inorganic carrying body is 3, is then being sufficiently stirred While organic high molecular polymer polyvinyl alcohol in 95 DEG C of water is dissolved in the instillation of the speed of 3ml/min, for fixed anti- Nitrobacteria activator is final to realize that organic high molecular polymer and the mass ratio of inorganic carrying body are in inorganic carrying body surface 0.5:8, after liquid to be mixed is cooled to room temperature precipitation, abandoning supernatant, specific denitrifying bacteria made from the deposit of lower part lives Change filler material;Filler material load after, which with aerobic tank and advanced treating pond is connected, runs the device, open into Water regulating valve and return valve, close out water regulating valve, and introducing water inlet from aerobic tank using the power that solar energy generates (utilizes The quantity that the method for quantitative fluorescent PCR measures indigenous denitrifying bacteria in aerobic tank water inlet is 106-107Copies/L), work is realized When the time is 24 small, biofilm culture is carried out in this stage denitrifying bacteria microorganism for the self-loopa of skill initial period internal system, Control the water conservancy residence time for 8 it is small when, by the method for quantitative fluorescent PCR, obtain adding in anti-nitre after aerobic tank water inlet reaction for 24 hours The denitrifying bacteria quantity changed in bacterium activation filler material is about 107-108(quantity of i.e. indigenous denitrifying bacteria is real by copies/g Existing 10 times of growths);Finally, inlet regulating valve and return valve is kept to open, then opens out water regulating valve, controls normal operation When flow of inlet water 0.9m3/ h, control hydraulic detention time for 9 it is small when, by adjusting inlet regulating valve, going out water regulating valve and reflux It is 400% that regulating valve, which controls Inlet and outlet water ratio and nitrate recirculation ratio example,.Denitrifying bacteria constantly removes aerobic tank in this process Nitrate nitrogen in water inlet, and Oxidation of Fe2+Form Fe3+With amorphous Fe3+Based on mineral, in thalline deposit it is inorganic composition with Based on Fe, contain a small amount of heavy metal As5+, in Fe2+NO in the case of oxidation totally3 -Average removal rate up to 40~60%, As Average removal rate up to 40~70%.
The denitrifying bacteria prepared according to following preparation method activation filler material is filled in a kind of above-mentioned apply to handle In solar anaerobic reactor assembly in unit:It is 4 by mass ratio:0.5:0.5:4 inorganic carrying body montmorillonite, inorganic wadding Condensate poly-ferric chloride, inorganic metal salt sodium chloride, activated carbon are sufficiently mixed and are scattered in 70 DEG C of water, are treated above-mentioned suspended Liquid is cooled to 40 DEG C, and adding in denitrifying bacteria activator, (activator is by frerrous chloride, sodium acetate, peptone, yeast extract, grape Sugar, sodium chloride, agar, potassium nitrate composition, mass ratio is followed successively by 1.2 when each ingredient adds:2:16:3:1.5:6:13:2;It adds in System must be cooled to 35 DEG C during described denitrifying bacteria activator), the ratio for controlling itself and inorganic carrying body is 4, Ran Hou The organic high molecular polymer polyvinyl alcohol being dissolved in 95 DEG C of water is instilled with the speed of 3ml/min while being sufficiently stirred, is used It is final to realize organic high molecular polymer and inorganic carrying body in fixed denitrifying bacteria activator in inorganic carrying body surface Mass ratio is 0.6:7, after liquid to be mixed is cooled to room temperature precipitation, abandoning supernatant, the anti-nitre of specificity made from the deposit of lower part Change bacterium activation filler material;After filler material loads, which with aerobic tank and advanced treating pond is connected, runs the dress It puts, opens inlet regulating valve and return valve, close out water regulating valve, introduced using the power that solar energy generates from aerobic tank (quantity that indigenous denitrifying bacteria in aerobic tank water inlet is measured using the method for quantitative fluorescent PCR is 10 for water inlet5-106copies/ L), realize the self-loopa of technique initial period internal system, when the time is 24 small, carried out in this stage denitrifying bacteria microorganism Biofilm culture, control the water conservancy residence time for 8 it is small when, by the method for quantitative fluorescent PCR, obtain adding in aerobic tank water inlet reaction Denitrifying bacteria quantity after for 24 hours in denitrifying bacteria activation filler material is about 106-107(i.e. indigenous denitrification is thin by copies/g The quantity of bacterium realizes 10 times of growths);Finally, inlet regulating valve and return valve is kept to open, then opens out water regulating valve, is controlled Flow of inlet water 0.9m during normal operation processed3/ h, control hydraulic detention time for 9 it is small when, by adjusting inlet regulating valve, water outlet tune It is 400% that section valve and return valve, which control Inlet and outlet water ratio and nitrate recirculation ratio example,.Denitrifying bacteria is continuous in this process Remove the nitrate nitrogen in aerobic tank water inlet, and Oxidation of Fe2+Form Fe3+With amorphous Fe3+Based on mineral, in thalline deposit Inorganic composition contains a small amount of heavy metal As based on Fe5+, in Fe2+NO in the case of oxidation totally3 -Removal rate up to 30~ The removal rate of 40%, As are up to 30~40%.
The denitrifying bacteria prepared according to following preparation method activation filler material is filled in a kind of above-mentioned apply to handle In solar anaerobic reactor assembly in unit:It is 3 by mass ratio:0.5:0.5:3 inorganic carrying body silica gel, inorganic flocculation Object bodied ferric sulfate, inorganic metal salt potassium chloride, activated carbon are sufficiently mixed and are scattered in 80 DEG C of water, treat above-mentioned suspension Be cooled to 40 DEG C, add in denitrifying bacteria activator (activator by frerrous chloride, sodium acetate, peptone, yeast extract, glucose, Sodium chloride, agar, potassium nitrate composition, mass ratio is followed successively by 1.2 when each ingredient adds:2.5:16:3.5:1.5:6:13:2;It adds in System must be cooled to 40 DEG C during described denitrifying bacteria activator), the ratio for controlling itself and inorganic carrying body is 1, Ran Hou The organic high molecular polymer polyvinyl alcohol being dissolved in 95 DEG C of water is instilled with the speed of 3ml/min while being sufficiently stirred, is used It is final to realize organic high molecular polymer and inorganic carrying body in fixed denitrifying bacteria activator in inorganic carrying body surface Mass ratio is 0.5:8, after liquid to be mixed is cooled to room temperature precipitation, abandoning supernatant, the anti-nitre of specificity made from the deposit of lower part Change bacterium activation filler material;After filler material loads, which with aerobic tank and advanced treating pond is connected, runs the dress It puts, opens inlet regulating valve and return valve, close out water regulating valve, introduced using the power that solar energy generates from aerobic tank (quantity that indigenous denitrifying bacteria in aerobic tank water inlet is measured using the method for quantitative fluorescent PCR is 10 for water inlet6-107copies/ L), realize the self-loopa of technique initial period internal system, when the time is 24 small, carried out in this stage denitrifying bacteria microorganism Biofilm culture, control the water conservancy residence time for 8 it is small when, by the method for quantitative fluorescent PCR, obtain after adding in water body reaction for 24 hours Denitrifying bacteria quantity in denitrifying bacteria activation filler material is about 107-108Copies/g (the numbers of i.e. indigenous denitrifying bacteria Amount realizes 10 times of growths);Finally, inlet regulating valve and return valve is kept to open, then opens out water regulating valve, control is normal Flow of inlet water 0.9m during operation3/ h, control hydraulic detention time for 9 it is small when, by adjust inlet regulating valve, go out water regulating valve and It is 400% that return valve, which controls Inlet and outlet water ratio and nitrate recirculation ratio example,.Denitrifying bacteria constantly removes in this process Nitrate nitrogen in the water inlet of oxygen pond, and Oxidation of Fe2+Form Fe3+With amorphous Fe3+Based on mineral, without unit in thalline deposit Into based on Fe, contain a small amount of heavy metal Pb5+, in Fe2+NO in the case of oxidation totally3 -Removal rate up to 50~60%, Pb's Removal rate is up to 40~50%.
It is adjusted using technical solution disclosed in present invention and prepares different filler materials, when carrying out sewage disposal Show the property basically identical with embodiment.Illustrative description is done to the present invention above, it should which explanation is not taking off In the case of core from the present invention, any simple deformation, modification or other skilled in the art can not spend wound The equivalent substitution of the property made work each falls within protection scope of the present invention.

Claims (8)

1. a kind of solar anaerobic reactor assembly applied in processing unit, it is characterised in that:Including into water conduit tube, water outlet Main pipe, interior return duct, pump, accumulator, photoelectric controller, inverter and generator;The anaerobic reactor include reaction kettle, Electric heating assembly and solar photovoltaic assembly, anaerobic reactor top are provided with one-way exhaust valve;The reaction kettle is to set vertically The closed tank body put, reaction kettle are divided into reaction kettle top, reaction kettle middle part and reaction kettle lower part, three-phase are set in reaction kettle top Separator, reaction kettle top are provided with water outlet, and the water outlet is connected with the water conduit tube that goes out;In the reaction kettle Spacer-frame is equipped in portion, spacer-frame activates filler material full of denitrifying bacteria, and the denitrifying bacteria activates filler material with nothing Machine carrying body, inorganic flocculate, inorganic metal salt, activated carbon are prepared for raw material, and the mass ratio of four kinds of raw materials is followed successively by (1 ~8):(0~0.5):(0~0.5):(2~4), wherein the quality of inorganic flocculate and inorganic metal salt ratio value range is big In 0 and less than or equal to 0.5, four kinds of raw materials, which are sufficiently mixed, to be dispersed in 60~80 DEG C of water, and anti-nitre is added in after cooling Change bacterium activator, the organic polymer being then dissolved in the water in the case where being sufficiently stirred with the speed instillation of 3~4ml/min polymerize Object, organic high molecular polymer is used to denitrifying bacteria activator being fixed on inorganic carrying body surface, after cooling precipitates, lower part Deposit is the denitrifying bacteria activation filler material, and the inorganic carrying body is in silica gel, montmorillonite or diatomite One kind, the inorganic flocculate are aluminium polychloride (PAC), polyaluminium sulfate (PAS), bodied ferric sulfate (PFS) or polymerization One kind in iron chloride (PFC), the inorganic metal salt is sodium chloride, one kind in potassium chloride, and the denitrifying bacteria swashs Agent ingredient living is frerrous chloride, sodium acetate, peptone, yeast extract, glucose, sodium chloride, agar, potassium nitrate, quality during addition Than being followed successively by (1~1.5):(2~2.5):(15~16):(3~3.5):(1~1.5):(6~6.5):(12~13):(2~ 2.5);Water distributor is provided in reaction kettle lower part, water distributor is connected by the pump with described into water conduit tube, it is described into Water conduit tube and go out between water conduit tube to be provided with the interior return duct;Hollow folder is provided in the anaerobic reactor side wall Layer, the electric heating assembly are arranged in hollow interlayer and are evenly distributed on anaerobic reactor side wall;The solar energy Volt component is connected with the accumulator, and accumulator is connected with the photoelectric controller, and photoelectric controller is connected with inverter, Inverter is connected with the control system of the generator, and generator is connected with electric heating assembly and pump.
2. a kind of solar anaerobic reactor assembly applied in natural water according to claim 1, feature exist In:System must be cooled to 30~40 DEG C when adding in the denitrifying bacteria activator, and control itself and inorganic carrying body Ratio is (0.3~8):1, preferably (3~5):1;The organic high molecular polymer is polyvinyl alcohol, polyethylene, polypropylene, poly- One kind in styrene or cellulose, the organic high molecular polymer is dispersed in 95~97 DEG C of water, described Organic high molecular polymer and the final mass ratio of inorganic carrying body are (0.5~0.6):(7~8).
3. a kind of solar anaerobic reactor assembly applied in natural water according to claim 1, feature exist In:Described going out on water conduit tube is provided with out water regulating valve, and advanced treating pond entrance is treated in the other end connection for going out water conduit tube;It is described Into inlet regulating valve is provided on water conduit tube, the other end connection into water conduit tube treats that aerobic tank exports;The interior return duct On be provided with return valve.
4. a kind of solar anaerobic reactor assembly applied in natural water according to claim 1, feature exist In:The reaction kettle top and the outer surface of reaction kettle lower part be it is arc-shaped, reaction kettle top and reaction kettle lower part it is high by 0.2~ 0.4m, the high 0.2~0.4m in bottom;It is cylinder, a diameter of 0.5~1m, high 1~3m in the middle part of reaction kettle.
5. a kind of solar anaerobic reactor assembly applied in natural water according to claim 1, feature exist In:The denitrifying bacteria activation filler material is filled in using the method for lattice filling in reaction kettle middle part, close to fill out total height For the 75%~90% of reaction kettle total height, denitrifying bacteria Activation filling is reaction kettle total height with the distance at the top of reaction kettle 10%~25%, the disposable 1000~4000mg/L of dosage of technique initial period.
6. a kind of solar anaerobic reactor assembly applied in natural water according to claim 1, feature exist In:Moreover, the electric heating assembly is made of the heating wire of n groups parallel connection, 10≤n≤40, heating wire is in S in the vertical direction Type, and heating wire is integrally along reaction kettle axial rings around annular in shape.
7. a kind of user of solar anaerobic reactor assembly applied in processing unit according to claim 1 Method comprises the following steps:
Step 1, it is connected described by the anaerobic reactor device of Driven by Solar Energy with aerobic tank and advanced treating pond, utilization is glimmering The method of Fluorescent Quantitative PCR measures the quantity of indigenous denitrifying bacteria;
Step 2, the equipment is run, inlet regulating valve and return valve is opened, closes out water regulating valve, utilize photovoltaic The energy hole pump that component generates is introduced from aerobic tank intakes, and the self-loopa of technique initial period internal system is realized, in this rank Section denitrifying bacteria microorganism carries out biofilm culture, is measured by the method for quantitative fluorescent PCR and adds in denitrifying bacteria after water body The denitrifying bacteria quantity in filler material is activated, realizes that the multiple that the quantity of indigenous denitrifying bacteria increases is more than or equal to 10;
Step 3, inlet regulating valve and return valve is kept to open, then opens out water regulating valve, is intake when controlling normal operation Flow, control hydraulic detention time, by adjust inlet regulating valve, go out water regulating valve and return valve control Inlet and outlet water ratio And nitrate recirculation ratio;
Step 4, the water outlet in anaerobic reactor device flows into advanced treating pond by self gravitation;
In step 2 and step 3, solar photovoltaic assembly, which converts solar energy into electrical energy, to be stored in solar storage battery, then Direct current energy signal is converted by photoelectric control prop, DC signal enters inverter and supply gone to hand over being converted into AC load Galvanic electricity device, then by generator control system electric energy, electrical heating group are provided for the electric heating assembly of solar photovoltaic assembly lower floor Part converts electrical energy into thermal energy, and electric heating assembly is all covered in tank surface, effectively accomplish in anaerobic reactor liquid by It is hot uniform;Meanwhile generator control system provides electric energy for pump, to realize the stabilization when self-loopa of the device and normal operation State.
8. a kind of user of solar anaerobic reactor assembly applied in processing unit according to claim 7 Method, it is characterised in that:The technique initial period internal system self-loopa time is 24~26h, feed water flow during normal operation Measure 0.1~0.9m3/ h, described controls hydraulic detention time as 6~10h, and the nitrate recirculation ratio example is 400%~500%.
CN201611032696.1A 2016-11-15 2016-11-15 A kind of solar anaerobic reactor assembly applied in processing unit and its application method Pending CN108069511A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109734256A (en) * 2019-03-11 2019-05-10 苏州科技大学 A kind of energy-saving denitrification dephosphorization apparatus

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101844830A (en) * 2009-03-25 2010-09-29 株式会社日立工业设备技术 Method of wastewater treatment
CN202285903U (en) * 2011-10-20 2012-07-04 莱州明波水产有限公司 Circulating water culture system biofilter self-maintaining non-inoculation special device
CN102701442A (en) * 2012-05-22 2012-10-03 青岛理工大学 Quick start method of source water biological denitrification system
CN204848436U (en) * 2015-08-12 2015-12-09 甘肃新天亿环保工程有限公司 Solar energy anaerobic reactor device
CN105712497A (en) * 2016-01-18 2016-06-29 同济大学 Microbial activation method and system for eutrophicated water body ecological restoration
CN105948241A (en) * 2016-06-03 2016-09-21 湖南恒凯环保科技投资有限公司 Packed EGSB reactor

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101844830A (en) * 2009-03-25 2010-09-29 株式会社日立工业设备技术 Method of wastewater treatment
CN202285903U (en) * 2011-10-20 2012-07-04 莱州明波水产有限公司 Circulating water culture system biofilter self-maintaining non-inoculation special device
CN102701442A (en) * 2012-05-22 2012-10-03 青岛理工大学 Quick start method of source water biological denitrification system
CN204848436U (en) * 2015-08-12 2015-12-09 甘肃新天亿环保工程有限公司 Solar energy anaerobic reactor device
CN105712497A (en) * 2016-01-18 2016-06-29 同济大学 Microbial activation method and system for eutrophicated water body ecological restoration
CN105948241A (en) * 2016-06-03 2016-09-21 湖南恒凯环保科技投资有限公司 Packed EGSB reactor

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109734256A (en) * 2019-03-11 2019-05-10 苏州科技大学 A kind of energy-saving denitrification dephosphorization apparatus

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Application publication date: 20180525