CN1080622A - Produce road cement with the coal gangue substitute for clay - Google Patents

Produce road cement with the coal gangue substitute for clay Download PDF

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Publication number
CN1080622A
CN1080622A CN92106592A CN92106592A CN1080622A CN 1080622 A CN1080622 A CN 1080622A CN 92106592 A CN92106592 A CN 92106592A CN 92106592 A CN92106592 A CN 92106592A CN 1080622 A CN1080622 A CN 1080622A
Authority
CN
China
Prior art keywords
road cement
cement
coal gangue
road
substitute
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN92106592A
Other languages
Chinese (zh)
Inventor
师允政
侯昭让
田家宽
尹旭
王昌明
王善军
时学祥
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Zaozhuang zhang zhuang cement factory
BUILDING MATERIAL INST ZAOZHUANG CITY
Original Assignee
Zaozhuang zhang zhuang cement factory
BUILDING MATERIAL INST ZAOZHUANG CITY
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Zaozhuang zhang zhuang cement factory, BUILDING MATERIAL INST ZAOZHUANG CITY filed Critical Zaozhuang zhang zhuang cement factory
Priority to CN92106592A priority Critical patent/CN1080622A/en
Publication of CN1080622A publication Critical patent/CN1080622A/en
Pending legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/02Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
    • C04B28/08Slag cements
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B7/00Hydraulic cements
    • C04B7/14Cements containing slag
    • C04B7/147Metallurgical slag
    • C04B7/153Mixtures thereof with other inorganic cementitious materials or other activators
    • C04B7/17Mixtures thereof with other inorganic cementitious materials or other activators with calcium oxide containing activators
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00474Uses not provided for elsewhere in C04B2111/00
    • C04B2111/0075Uses not provided for elsewhere in C04B2111/00 for road construction
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/76Use at unusual temperatures, e.g. sub-zero
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P40/00Technologies relating to the processing of minerals
    • Y02P40/10Production of cement, e.g. improving or optimising the production methods; Cement grinding
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/91Use of waste materials as fillers for mortars or concrete

Abstract

With coal gangue substitute for clay production road cement, coal gangue is one of main food ingredient of road cement, by Wingdale, coal gangue, sandstone, iron powder, hard coal, fluorite, after fragmentation, fit in raw material, after grinding, calcining, become the road cement grog again, the active addition and the gypsum that add appropriate amount again are behind grinding and become the gelling material with hydraulicity---road cement.Advantages such as this cement has the label height, sclerosis is fast, abrasion resistance is good, contract with dry rate is little, folding strength and anti-freezing property are good, therefore it is highly suitable for the construction of motorway, common road, airstrip, but also be applicable to Highrise buildings, of many uses.

Description

Produce road cement with the coal gangue substitute for clay
The present invention relates to a kind of prescription of producing silicate road cement or normal silicate road cement with the coal gangue substitute for clay.
Silicate road cement or normal silicate road cement, it has good wear resistance, frost resistance, less contract with dry rate and shock resistance.At present, obtained in the expressway construction at home and abroad using widely.But, in the batching of producing the silicate road cement, all add the silicate component of the clay of significant proportion, and the use clay has constituted the destruction to the soil as the silicate road cement, produce totally unfavorable to developing agricultural.
The purpose of this invention is to provide a kind of prescription with coal gangue substitute for clay production road cement, the protection good farmland alleviates the pollution of industrial residue to environment.Increase economic benefit of enterprises.
The coal gangue substitute for clay is produced road cement, be as one of main food ingredient of road cement raw material with the waste residue-coal gangue of coal-mining industry, add an amount of siliceous correction material simultaneously, be made into the raw material of proper composition, in mechanized cement shaft kiln, form silicate road cement grog through high-temperature calcination.The active addition and the gypsum that add appropriate amount again are behind grinding and become gelling material-silicate road cement or the normal silicate road cement (abbreviation road cement) with hydraulicity.
The prescription of road cement:
A raw mix formula (weight percent)
Wingdale 60~80%, coal gangue 5~20%, sandstone 0~7%, iron powder 1~8%, hard coal 6~15%, fluorite 0~5%.
In the above-mentioned prescription, Wingdale, coal gangue, sandstone, hard coal, fluorite mix with iron powder after fragmentation, through grinding, the calcining after silicate road cement grog.The requirement of grog mineral composition: wherein tricalcium aluminate 1~6%, tetracalcium aluminoferrite 15~22%, tricalcium silicate 50~68%.Burning till back cement clinker label reaches 425~No. 725.
The prescription of B road cement (weight percent)
Silicate road cement grog 85~95%, gypsum 1~5%, active addition (anthracite spoil or flyash or granulated blast-furnace slag) 0~13%.
Grog in the above-mentioned prescription, gypsum and active addition promptly become road cement behind grinding.Cement mark reaches 425~No. 725.Below by embodiment in detail the present invention is described in detail.
Embodiment 1
The raw mix formula of road cement (weight percent)
Wingdale 60~66%, coal gangue 14~20%, sandstone 1~2%, iron powder 1~2%, hard coal 13~14%, fluorite 1~2%.Wingdale in the above-mentioned prescription, coal gangue, sandstone, hard coal, fluorite mix with iron powder after fragmentation, then through grinding, the calcining after silicate road cement grog.Cement clinker after burning till, label reach 425~No. 525.
The product formula of road cement (weight percent)
Label is 425~No. 525 a silicate road cement grog 96~98%, adds 2~4% gypsum, is mixed with 425~No. 525 road cement, behind grinding the road cement finished product.
Embodiment 2
The raw mix formula of road cement (weight percent)
Wingdale 73~76%, coal gangue 4~7%, sandstone 5~6%, iron powder 2~4%, hard coal 11~14%, fluorite 2~3%.Wingdale in the above-mentioned prescription, coal gangue, sandstone, hard coal, fluorite mix with iron powder after fragmentation, become the road cement grog after grinding, calcining, and the cement clinker label after burning till reaches 425~No. 525.
The product formula of road cement (weight percent)
Label is 425~No. 525 a road cement grog 96~98%, adds 2~4% gypsum, is mixed with 425~No. 525 road cement, behind grinding the road cement finished product.
Embodiment 3
The raw mix formula of road cement (weight percent)
Wingdale 77~80%, coal gangue 3~4%, sandstone 6~7%, iron powder 3~7%, hard coal 12~15%, fluorite 3~5%.Wingdale, coal gangue, sandstone, hard coal, fluorite mix with iron powder after fragmentation in the above-mentioned batching, become the road cement grog after grinding, calcining, and the cement clinker label after burning till reaches 425~No. 525.
The product formula of road cement (weight percent)
Label is 425~No. 525 a road cement grog 96~98%, adds 2~4% gypsum, is mixed with 425~No. 525 road cement, behind grinding the road cement finished product.
Embodiment 4(most preferred embodiment)
The raw mix formula of road cement (weight percent)
Wingdale 67~72%, coal gangue 8~13%, sandstone 2~5%, iron powder 2~3%, hard coal 9~13%, fluorite 2~3%, Wingdale in the above-mentioned batching, coal gangue, sandstone, hard coal, fluorite mix with iron powder after fragmentation, become the road cement grog after grinding, calcining.The label that burns till the back cement clinker reaches 525~No. 725.
The product formula of coal gangue road cement (weight percent)
Prescription 1
The road cement grog 85~88% that No. 525~725, label, anthracite spoil or flyash or granulated blast-furnace slag 10~13%, gypsum 1~4% promptly becomes the road cement finished product behind grinding.Cement mark reaches 425~No. 625.
Prescription 2
The road cement grog 89~92% that No. 525~725, label, anthracite spoil or flyash or granulated blast-furnace slag 5~8%, gypsum 2~4% becomes the road cement finished product behind grinding.Cement mark reaches 425~No. 625.
Prescription 3
The coal gangue road cement grog 93~95% that No. 525~725, label, anthracite spoil or flyash or granulation slag 3~5%, gypsum 2~5% becomes the road cement finished product behind grinding.Cement mark reaches 525~No. 725.
When preparation road cement finished product, its grog label all should be not less than the label of the finished product.During concrete the preparation, according to cement clinker, press the definite label of desired product, distribution is prepared routinely.
The physicochemical characteristic of road cement
Label: 425 525 625 725
The mortar wear rate: 28 days less than 0.5g/cm 2
The mortar shrinking percentage: 28 days less than 0.08%
Freeze proof label: greater than 50 times
Advantage and effect
Produce road cement with the process of Si Al Fe clay, one ton of road cement of every production can utilize 0.16~0.22 ton of industrial residue gangue, has reduced because waste residue is piled up the good farmland that takies, and has alleviated simultaneously the pollution to environment. Utilize the process of Si Al Fe clay to produce road cement, a cement plant of producing 100000 tons per year can obtain net income 200~3,000,000 yuan, economic benefits every year. Utilize the road cement of gangue production not only to be applicable to the construction of highway, common road, runway, but also be applicable to skyscraper, of many uses.

Claims (4)

1, a kind of road cement of producing with the coal gangue substitute for clay, comprise 60~80% Wingdale, 1~8% iron powder, 6~15% hard coal, 2~5% fluorite, 1~7% sandstone in its raw mix formula, it is characterized in that: added the coal gangue of substitute for clay in the raw mix formula, after grinding, calcining, become the road cement grog.
2, a kind of road cement of producing with the coal gangue substitute for clay according to claim 1, the add-on that it is characterized in that coal gangue is 5~20%.
3, a kind of road cement of producing with the coal gangue substitute for clay is characterized in that: road cement is that road cement grog, anthracite spoil or flyash or granulated blast-furnace slag, 2~5% gypsum cooperate and form.
4, a kind of road cement with the production of coal gangue substitute for clay according to claim 3 is characterized in that: the road cement grog is 85~95%, and anthracite spoil or fine coal soot particle or granulated blast-furnace slag are 3~13%.
CN92106592A 1992-07-02 1992-07-02 Produce road cement with the coal gangue substitute for clay Pending CN1080622A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN92106592A CN1080622A (en) 1992-07-02 1992-07-02 Produce road cement with the coal gangue substitute for clay

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN92106592A CN1080622A (en) 1992-07-02 1992-07-02 Produce road cement with the coal gangue substitute for clay

Publications (1)

Publication Number Publication Date
CN1080622A true CN1080622A (en) 1994-01-12

Family

ID=4942249

Family Applications (1)

Application Number Title Priority Date Filing Date
CN92106592A Pending CN1080622A (en) 1992-07-02 1992-07-02 Produce road cement with the coal gangue substitute for clay

Country Status (1)

Country Link
CN (1) CN1080622A (en)

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN100334027C (en) * 2006-01-18 2007-08-29 内蒙古西水创业股份有限公司 Freeze-thaw resisting cement and its production process
CN102718419A (en) * 2012-06-29 2012-10-10 酒钢(集团)宏达建材有限责任公司 Method for producing portland cement for road by blending iron ore beneficiation tailings in cement
CN104386930A (en) * 2014-09-27 2015-03-04 安徽海螺建材设计研究院 Application method of coal gangue to dry-process cement clinker production
CN104446036A (en) * 2014-11-25 2015-03-25 广西鱼峰水泥股份有限公司 Method for improving cement and mineral powder mixing amount for road
CN104773977A (en) * 2014-10-17 2015-07-15 韩先福 Road paving material prepared by compounding residue soil with cola gangue powder and preparation method thereof
CN104926163B (en) * 2015-06-15 2016-09-28 中国葛洲坝集团水泥有限公司 A kind of Portland clinker and preparation method thereof
CN111253095A (en) * 2020-03-14 2020-06-09 天瑞集团汝州水泥有限公司 Special road retarding cement
CN115321850A (en) * 2022-09-05 2022-11-11 富源县宏发恒际水泥有限公司 Raw material, clinker and cement formula and preparation method

Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN100334027C (en) * 2006-01-18 2007-08-29 内蒙古西水创业股份有限公司 Freeze-thaw resisting cement and its production process
CN102718419A (en) * 2012-06-29 2012-10-10 酒钢(集团)宏达建材有限责任公司 Method for producing portland cement for road by blending iron ore beneficiation tailings in cement
CN104386930A (en) * 2014-09-27 2015-03-04 安徽海螺建材设计研究院 Application method of coal gangue to dry-process cement clinker production
CN104386930B (en) * 2014-09-27 2016-08-31 安徽海螺建材设计研究院 Gangue application process in dry-process cement clinker produces
CN104773977A (en) * 2014-10-17 2015-07-15 韩先福 Road paving material prepared by compounding residue soil with cola gangue powder and preparation method thereof
CN104773977B (en) * 2014-10-17 2016-11-09 韩先福 A kind of dregs road pavements being combined colliery powder and preparation method thereof
CN104446036A (en) * 2014-11-25 2015-03-25 广西鱼峰水泥股份有限公司 Method for improving cement and mineral powder mixing amount for road
CN104926163B (en) * 2015-06-15 2016-09-28 中国葛洲坝集团水泥有限公司 A kind of Portland clinker and preparation method thereof
CN106277865A (en) * 2015-06-15 2017-01-04 中国葛洲坝集团水泥有限公司 A kind of preparation method of Portland clinker
CN106277865B (en) * 2015-06-15 2018-04-10 中国葛洲坝集团水泥有限公司 A kind of preparation method of Portland clinker
CN111253095A (en) * 2020-03-14 2020-06-09 天瑞集团汝州水泥有限公司 Special road retarding cement
CN115321850A (en) * 2022-09-05 2022-11-11 富源县宏发恒际水泥有限公司 Raw material, clinker and cement formula and preparation method

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