CN108060037B - Soap powder composition of sodium oleate and its preparation method - Google Patents

Soap powder composition of sodium oleate and its preparation method Download PDF

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CN108060037B
CN108060037B CN201711415616.5A CN201711415616A CN108060037B CN 108060037 B CN108060037 B CN 108060037B CN 201711415616 A CN201711415616 A CN 201711415616A CN 108060037 B CN108060037 B CN 108060037B
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sodium
oleic acid
soap powder
sodium oleate
powder composition
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杨庆香
石荣莹
贺波
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Shanghai Hutchison Whitecat Co ltd
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    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D10/00Compositions of detergents, not provided for by one single preceding group
    • C11D10/04Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap
    • C11D10/045Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap based on non-ionic surface-active compounds and soap

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Abstract

The invention relates to the field of detergent compositions mainly using soap as a base material, in particular to a sodium oleate soap powder composition and a preparation method thereof. A sodium oleate soap powder composition is characterized in that: the composition is prepared by uniformly mixing the following components: the components are 1-5% of a non-ionic surfactant, 10-25% of sodium oleate, 25-60% of a solid alkaline material, 10-20% of sodium aluminosilicate, 0.5-2% of an organic phosphonate, 0-2.0% of a decolorizing agent and the balance of a solid filler is 100. The invention has simple production process, flexible formula adjustment, no generation of peculiar smell, low energy consumption and low cost.

Description

Soap powder composition of sodium oleate and its preparation method
Technical Field
The invention relates to the field of detergent compositions mainly using soap as a base material, in particular to a sodium oleate soap powder composition and a preparation method thereof.
Background
In recent years, laundry soap powders containing partial fatty acid salts (soap bases) are becoming more and more popular among consumers due to their natural, green, low-foaming, easy rinsing, and other characteristics. In the current standard of China light industry QB/T2387-2008 laundry soap powder, the content of dry sodium soap (fatty acid sodium) is required to be more than or equal to 7%, most of the currently marketed laundry soap powder executes the light industry standard QB/T2387-2008 and contains 7% -10% of fatty acid sodium. At present, soap powder is produced by adopting the following three modes:
the fatty acid and liquid alkali sodium hydroxide are neutralized into sodium fatty acid, and the common raw materials in the washing powder comprise anionic surfactant (alkyl benzene sulfonate or alkenyl sulfonate), solid raw material soda, anhydrous sodium sulphate and the like to prepare slurry with total solid of 60-70%, and then the slurry is sprayed and dried by a high tower to prepare the washing soap powder. In general, the temperature of hot air in the high tower spray drying process is above 300 ℃, and the fatty acid sodium is decomposed at high temperature to generate unpleasant smell. Because of the environmental protection problem, the peculiar smell gas is not allowed to be discharged in most areas at present, so the production of the laundry soap powder is limited; in addition, because the viscosity of the slurry added with the sodium aliphatate is higher than that of the slurry of the common washing powder, the total solid of the slurry for producing the soap powder is lower than that of the slurry of the common washing powder, and the heat energy consumption required during spray drying is higher; still another biggest problem is that the sodium aliphatate is decomposed at high temperature, so that part of the sodium aliphatate is lost due to decomposition and volatilization, and great waste is caused. Therefore, the production of laundry soap powder by the high tower spray drying process should be gradually eliminated in the future.
The second production mode is that firstly, the grease and the liquid alkali are used for saponification reaction to produce high-content soap base, then the high-content soap base is dried and crushed into soap powder with the content of more than 80%, and more than 80% of soap powder raw materials are directly mixed with washing powder to prepare the washing soap powder. The method solves the problems of decomposition, volatilization loss and generation of peculiar smell of the sodium aliphatate in the high-tower spray-dried soap powder, but has a great problem of poor solubility; the critical micelle temperature (critical solution temperature) of the sodium fatty acid is higher than that of a common anionic surfactant, the solubility of the sodium fatty acid is very low at low temperature, the sodium fatty acid is easy to float on water surface or adhere to clothes during washing, consumer complaints are caused, and the active ingredient sodium fatty acid can not play a role completely. Even if the soap powder is smashed into very fine soap powder, the addition amount of the soap powder cannot be very high directly, if 7-10% of sodium fatty acid is directly mixed into the washing powder by using the soap powder raw material, the problem of floating of the soap powder can be caused during use, and the cost for producing the washing soap powder by the method is higher than that of the first method because the price of the high-content soap powder and the fine powder is high, so the method is not a very reasonable production method of the washing soap powder.
The third method is to overcome the defects of the two methods, and part of the soap powder raw material with the content of 80 percent in the second process is added into the slurry to be dissolved, and part of the soap powder raw material is directly mixed into the washing powder in a dry mode after the auxiliary materials are added, so that the method reduces the floating problem during washing, but still has the problems of poor soap powder solubility, high slurry consistency, high production energy consumption and peculiar smell during production. Such formulations are also more expensive to produce than processes 1 and 2, and are not optimal production processes.
Disclosure of Invention
In order to overcome the defects of the prior art, the invention provides soap powder which has the advantages of simple process, low equipment requirement, flexible formula adjustment, no peculiar smell, low energy consumption and low cost, and discloses a sodium oleate soap powder composition and a preparation method thereof.
The invention achieves the purpose by the following technical scheme:
a sodium oleate soap powder composition is characterized in that: the composition is prepared by uniformly mixing the following components:
Figure GDA0001617258550000021
wherein: the nonionic surfactant has a carbon chain length of C10-C18The average addition number of the ethylene oxide is 7 to10 fatty alcohol polyoxyethylene ethers;
the sodium oleate is formed by neutralizing oleic acid and solid alkaline materials, wherein C in the oleic acid18-1 acid and C18-2 the proportion of the sum of the acid mass to the total mass of oleic acid is not less than 85%;
the solid alkaline material is at least one of powdery or fine granular sodium carbonate, sodium bicarbonate and sodium metasilicate;
sodium aluminosilicate, i.e., zeolite 4A;
the organic phosphonate is selected from at least one of hydroxyl ethylidene diphosphonate, nitrilo trimethylene triphosphonate and ethylene diamine tetramethylene phosphonate, and is generated by the reaction of organic phosphonic acid and solid alkaline materials;
the decolorizing agent is hydrogen peroxide solution with the mass percent concentration of 15-50%, and the decolorizing agent reacts with solid alkaline materials to generate peroxide, and 30% of hydrogen peroxide is preferred in view of the easy availability and safety of raw materials. If the used oleic acid is light in color and the neutralized product is white in color, a decolorizing agent can not be added;
the solid filler is anhydrous sodium sulphate or sodium chloride.
The preparation method of the sodium oleate soap powder composition is characterized by comprising the following steps: the method is implemented in sequence according to the following steps:
the oleic acid and the nonionic surfactant are uniformly premixed in a premixing tank, if the oleic acid and the nonionic surfactant are solidified at a low temperature, the oleic acid and the nonionic surfactant are heated and melted into transparent liquid for use before use, and the heating temperature is not more than 50 ℃;
adding a solid alkaline material and a solid filler into a vertical double-helix dry mixing tank, and stirring for 1-3 min to mix uniformly;
the vertical double-helix dry mixing tank is always kept in a stirring and opening state, and the mixture of liquid oleic acid and nonionic surfactant is directly added into the vertical double-helix dry mixing tank to react for 5min +/-1 min; then adding organic phosphonic acid, and continuing stirring for 5-8 min until all acidic components are completely neutralized and react, and the appearance is in a white flowable powder state; adding sodium aluminosilicate, stirring and mixing uniformly;
and (3) inputting the white product in a flowable powder state into a 5-8-mesh vibrating screen through a discharge port of a vertical double-helix dry mixing tank, and sieving to remove large particles, wherein the rest is the sodium oleate soap powder composition.
The preparation method of the sodium oleate soap powder composition is characterized by comprising the following steps: the method is implemented in sequence according to the following steps:
the oleic acid and the nonionic surfactant are uniformly premixed in a premixing tank, if the oleic acid and the nonionic surfactant are solidified at a low temperature, the oleic acid and the nonionic surfactant are heated and melted into transparent liquid for use before use, and the heating temperature is not more than 50 ℃;
adding a solid alkaline material and a solid filler into a vertical double-helix dry mixing tank, and stirring for 1-3 min to mix uniformly;
the vertical double-helix dry mixing tank is always kept in a stirring and opening state, and the mixture of liquid oleic acid and nonionic surfactant is directly added into the vertical double-helix dry mixing tank to react for 5min +/-1 min; adding a decolorizing agent and organic phosphonic acid, and continuously stirring for 5-8 min until all acidic components are completely neutralized and react, wherein the appearance of the acidic components is in a white flowable powder state; adding sodium aluminosilicate, stirring and mixing uniformly;
and (3) inputting the white product in a flowable powder state into a 5-8-mesh vibrating screen through a discharge port of a vertical double-helix dry mixing tank, and sieving to remove large particles, wherein the rest is the sodium oleate soap powder composition.
The composition can be used as a soap-base-containing component to be directly matched with one or more of other common washing powder raw materials, such as powdery sodium alkyl benzene sulfonate, alpha-alkenyl sodium sulfonate and fatty acid methyl ester sodium sulfonate, or washing powder base powder produced by a spray drying process of the anionic surfactants, a fluorescent whitening agent, biological enzyme, essence and the like to prepare a finished product of the washing soap powder. Thus, the problems of decomposition, peculiar smell and loss of the sodium aliphatate in the existing production process are solved, and the problems of poor solubility, high production energy consumption and high cost are also solved.
The invention has another innovation that oleic acid and nonionic surfactant are adopted to be premixed and neutralized, so that the fatty acid sodium soap is very easy to combine with calcium and magnesium ions in hard water to generate insoluble calcium soap precipitate, the detergency of the soap is reduced, and the soap is easy to deposit on clothes to harden the clothes. The nonionic surfactant is a very good lime soap dispersant, and is mixed with oleic acid in advance to generate a mixture of sodium oleate and the nonionic surfactant, when the soap powder is used, the mixture of the nonionic surfactant and the sodium oleate is dissolved simultaneously, and mixed micelles are quickly formed in hard water, so that lime soap precipitation is avoided, the solubility of sodium fatty acid in the soap powder at low temperature can be effectively improved, and the decontamination effect is improved; the nonionic is added to form an isolating membrane between the neutralized soap powder fine particles, so that the neutralized soap powder composition can be prevented from being bonded, large particles after neutralization are reduced, and the qualification rate of finished products is improved.
The invention has simple production process, low equipment requirement, flexibly adjustable formula, low production energy consumption and low production cost, avoids the decomposition of sodium oleate and the generation of peculiar smell in the spray drying process of a high tower and has very high popularization value.
Detailed Description
The invention is further illustrated by the following specific examples.
Example 1
The sodium oleate soap powder composition is prepared by uniformly mixing the following components:
Figure GDA0001617258550000041
the preparation steps of this example are as follows:
the batch of the composite material is 1 ton, 10kg of nonionic AEO7 and 14kg of oleic acid (1kg of oleic acid can produce 1.08kg of sodium oleate) are mixed into a uniform mixture in advance, 350kg of light sodium carbonate and 370kg of anhydrous sodium carbonate are weighed and placed into a vertical double-helix dry mixing tank, stirring is started for 1-2 min to make the mixture uniform, then premixed nonionic AEO7 and oleic acid are slowly added onto solid materials under the stirring starting state to react for 3min, then hydrogen peroxide solution and organic phosphonic acid are added, stirring is continued for 5-8 min until all acidic materials are completely neutralized, and large particles are removed through a vibrating screen with 8-10 meshes to obtain a finished product.
Example 2
The sodium oleate soap powder composition is prepared by uniformly mixing the following components:
Figure GDA0001617258550000051
the preparation steps of this example are as follows:
the batch weight is 1 ton, 30kg of nonionic AEO9 and 18.51kg of oleic acid (1kg of oleic acid can produce 1.08kg of sodium oleate) are mixed into a uniform mixture in advance, 300kg of light sodium carbonate, 50kg of sodium metasilicate, 100kg of sodium bicarbonate and 180kg of sodium chloride are weighed and placed into a vertical double-spiral dry mixing tank, stirring is started for 2-3 min to make the mixture uniform, then the premixed nonionic AEO9 and the oleic acid are slowly added onto the solid material in the state of stirring start to react for 5min, then hydrogen peroxide solution and organic phosphonic acid are added, stirring is continued for 5-8 min until all the acidic materials are completely neutralized and reacted. And (5) removing large particles through a vibrating screen with 8-10 meshes to obtain a finished product.
Example 3
The sodium oleate soap powder composition is prepared by uniformly mixing the following components:
Figure GDA0001617258550000052
Figure GDA0001617258550000061
the preparation steps of this example are as follows:
the batch weight is 1 ton, 50kg of nonionic AEO9 and 23.15kg of oleic acid (1kg of oleic acid can produce 1.08kg of sodium oleate) are mixed into a uniform mixture in advance, 400kg of light sodium carbonate, 50kg of sodium metasilicate and 100kg of sodium bicarbonate are weighed and placed into a vertical double-spiral dry mixing tank, stirring is started for 2-3 min to make the mixture uniform, then the premixed nonionic AEO9 and the oleic acid are slowly added to the solid material under the stirring starting state to react for 5min, then hydrogen peroxide and organic phosphonic acid are added, stirring is continued for 5-8 min until all acidic materials are completely neutralized and reacted. And (5) removing large particles through a vibrating screen with 8-10 meshes to obtain a finished product.
Example 4
The sodium oleate soap powder composition is prepared by uniformly mixing the following components:
Figure GDA0001617258550000062
wherein: the nonionic surfactant has a carbon chain length of C10-C18Fatty alcohol-polyoxyethylene ethers with the average addition number of ethylene oxide being 7-10;
the sodium oleate is formed by neutralizing oleic acid and solid alkaline materials, wherein C in the oleic acid18-1 acid and C18-2 the proportion of the sum of the acid mass to the total mass of oleic acid is not less than 85%;
the solid alkaline material sequentially selects powdery or fine granular sodium carbonate, sodium bicarbonate and sodium metasilicate;
the organic phosphonate is selected from hydroxy ethylidene diphosphonate, nitrilo trimethylene triphosphonate and ethylene diamine tetramethylene phosphonate in sequence, and the organic phosphonate is generated by reacting organic phosphonic acid with solid alkaline materials;
the decolorizing agent is hydrogen peroxide solution with the mass percentage concentration of 15-50%;
the solid filler is anhydrous sodium sulphate or sodium chloride.
See example 1 for the preparation method.
Example 5
The sodium oleate soap powder composition is prepared by uniformly mixing the following components:
Figure GDA0001617258550000071
the ingredients were selected as in example 4 and prepared as described in example 1.
Example 6
The sodium oleate soap powder composition is prepared by uniformly mixing the following components:
Figure GDA0001617258550000072
the ingredients were selected as in example 4 and prepared as described in example 1.
Example 7
The sodium oleate soap powder composition is prepared by uniformly mixing the following components:
Figure GDA0001617258550000073
Figure GDA0001617258550000081
the ingredients were selected as in example 4 and prepared as described in example 1.
Example 8
The sodium oleate soap powder composition is prepared by uniformly mixing the following components:
Figure GDA0001617258550000082
the ingredients were selected as in example 4 and prepared as described in example 1.
Example 9
The sodium oleate soap powder composition is prepared by uniformly mixing the following components:
Figure GDA0001617258550000083
the ingredients were selected as in example 4 and prepared as described in example 1.
Example 10
The sodium oleate soap powder composition is prepared by uniformly mixing the following components:
Figure GDA0001617258550000084
Figure GDA0001617258550000091
the ingredients were selected as in example 4 and prepared as described in example 1.
Example 11
The sodium oleate soap powder composition is prepared by uniformly mixing the following components:
Figure GDA0001617258550000092
the ingredients were selected as in example 4 and prepared as described in example 1.
Example 12
The sodium oleate soap powder composition is prepared by uniformly mixing the following components:
Figure GDA0001617258550000093
the ingredients were selected as in example 4 and prepared as described in example 1.
Example 13
The sodium oleate soap powder composition is prepared by uniformly mixing the following components:
Figure GDA0001617258550000101
the ingredients were selected as in example 4 and prepared as described in example 1.
Example 14
The sodium oleate soap powder composition is prepared by uniformly mixing the following components:
Figure GDA0001617258550000102
the ingredients were selected as in example 4 and prepared as described in example 1.
Example 15
The sodium oleate soap powder composition is prepared by uniformly mixing the following components:
Figure GDA0001617258550000103
Figure GDA0001617258550000111
the ingredients were selected as in example 4 and prepared as described in example 1.
Example 16
The sodium oleate soap powder composition is prepared by uniformly mixing the following components:
Figure GDA0001617258550000112
the ingredients were selected as in example 4 and the preparation was as described in example 4.
Example 17
The sodium oleate soap powder composition is prepared by uniformly mixing the following components:
Figure GDA0001617258550000113
the ingredients were selected as in example 5 and the preparation was as described in example 5.
Example 18
The sodium oleate soap powder composition is prepared by uniformly mixing the following components:
Figure GDA0001617258550000114
Figure GDA0001617258550000121
the ingredients were selected as in example 6 and the preparation was as described in example 6.
Example 19
The sodium oleate soap powder composition is prepared by uniformly mixing the following components:
Figure GDA0001617258550000122
the ingredients were selected as in example 7 and prepared as described in example 7.
Example 20
The sodium oleate soap powder composition is prepared by uniformly mixing the following components:
Figure GDA0001617258550000123
the ingredients were selected as in example 8 and the preparation was as described in example 8.
Example 21
The sodium oleate soap powder composition is prepared by uniformly mixing the following components:
Figure GDA0001617258550000124
Figure GDA0001617258550000131
the ingredients were selected as in example 9 and the preparation was as described in example 9.

Claims (2)

1. A sodium oleate soap powder composition is characterized in that: the composition is prepared by uniformly mixing the following components:
Figure FDA0002303213810000011
wherein: is notThe ionic surfactant adopts a carbon chain with the length of C10-C18Fatty alcohol-polyoxyethylene ethers with the average addition number of ethylene oxide being 7-10;
the sodium oleate is formed by neutralizing oleic acid and solid alkaline materials, wherein C in the oleic acid18-1Acid and C18-2The mass sum of the acids accounts for not less than 85% of the total mass of the oleic acid;
the solid alkaline material is at least one of powdery or fine granular sodium carbonate, sodium bicarbonate and sodium metasilicate;
the organic phosphonate is selected from at least one of hydroxyl ethylidene diphosphonate, nitrilo trimethylene triphosphonate and ethylene diamine tetramethylene phosphonate, and is generated by the reaction of organic phosphonic acid and solid alkaline materials;
the decolorizing agent is hydrogen peroxide solution with the mass percentage concentration of 15-50%;
the solid filler is anhydrous sodium sulphate or sodium chloride.
2. The method of making a sodium oleate soap powder composition as claimed in claim 1, which is characterized by: the method is implemented in sequence according to the following steps:
the oleic acid and the nonionic surfactant are uniformly premixed in a premixing tank, if the oleic acid and the nonionic surfactant are solidified at a low temperature, the oleic acid and the nonionic surfactant are heated and melted into transparent liquid for use before use, and the heating temperature is not more than 50 ℃;
adding a solid alkaline material and a solid filler into a vertical double-helix dry mixing tank, and stirring for 1-3 min to mix uniformly;
the vertical double-helix dry mixing tank is always kept in a stirring and opening state, and the mixture of liquid oleic acid and nonionic surfactant is directly added into the vertical double-helix dry mixing tank to react for 5min +/-1 min; adding a decolorizing agent and organic phosphonic acid, and continuously stirring for 5-8 min until all acidic components are completely neutralized and react, wherein the appearance of the acidic components is in a white flowable powder state; adding sodium aluminosilicate, stirring and mixing uniformly;
and (3) inputting the white product in a flowable powder state into a 5-8-mesh vibrating screen through a discharge port of a vertical double-helix dry mixing tank, and sieving to remove large particles, wherein the rest is the sodium oleate soap powder composition.
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Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1152024A (en) * 1995-10-23 1997-06-18 尤尼利弗公司 Method of manufacturing detergent bar containing soap
CN1188794A (en) * 1997-01-22 1998-07-29 何选明 Phosphorus free and aluminium free soap powder
CN1234433A (en) * 1999-04-26 1999-11-10 杨鹄昉 Cold preparation process for natural soap powder without environmental pollution and products thereof
CN1260385A (en) * 2000-01-28 2000-07-19 杜倩 Phosphorusfree and aluminium-free washing powder and its manufacture technology
CN1388235A (en) * 2001-05-29 2003-01-01 杨解定 Phosphate-free and benzene-free soap powder and its production process
CN1608125A (en) * 2001-10-25 2005-04-20 荷兰联合利华有限公司 Process for the production of detergent granules
CN104726215A (en) * 2015-03-31 2015-06-24 谢松芬 Preparation method of sphorus laundry powder

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1152024A (en) * 1995-10-23 1997-06-18 尤尼利弗公司 Method of manufacturing detergent bar containing soap
CN1188794A (en) * 1997-01-22 1998-07-29 何选明 Phosphorus free and aluminium free soap powder
CN1234433A (en) * 1999-04-26 1999-11-10 杨鹄昉 Cold preparation process for natural soap powder without environmental pollution and products thereof
CN1260385A (en) * 2000-01-28 2000-07-19 杜倩 Phosphorusfree and aluminium-free washing powder and its manufacture technology
CN1388235A (en) * 2001-05-29 2003-01-01 杨解定 Phosphate-free and benzene-free soap powder and its production process
CN1608125A (en) * 2001-10-25 2005-04-20 荷兰联合利华有限公司 Process for the production of detergent granules
CN104726215A (en) * 2015-03-31 2015-06-24 谢松芬 Preparation method of sphorus laundry powder

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