CN108048254B - 一种洗涤剂及其制备方法 - Google Patents
一种洗涤剂及其制备方法 Download PDFInfo
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- CN108048254B CN108048254B CN201711298964.9A CN201711298964A CN108048254B CN 108048254 B CN108048254 B CN 108048254B CN 201711298964 A CN201711298964 A CN 201711298964A CN 108048254 B CN108048254 B CN 108048254B
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- 239000003599 detergent Substances 0.000 title claims abstract description 59
- 238000002360 preparation method Methods 0.000 title claims abstract description 14
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 claims abstract description 45
- -1 methyl hydroxypropyl Chemical group 0.000 claims abstract description 20
- 229940105902 mint extract Drugs 0.000 claims abstract description 20
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 20
- 239000008367 deionised water Substances 0.000 claims abstract description 17
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 17
- MRUAUOIMASANKQ-UHFFFAOYSA-N cocamidopropyl betaine Chemical compound CCCCCCCCCCCC(=O)NCCC[N+](C)(C)CC([O-])=O MRUAUOIMASANKQ-UHFFFAOYSA-N 0.000 claims abstract description 16
- 229940073507 cocamidopropyl betaine Drugs 0.000 claims abstract description 15
- 235000006408 oxalic acid Nutrition 0.000 claims abstract description 15
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- QELSKZZBTMNZEB-UHFFFAOYSA-N propylparaben Chemical compound CCCOC(=O)C1=CC=C(O)C=C1 QELSKZZBTMNZEB-UHFFFAOYSA-N 0.000 claims abstract description 13
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- ILRSCQWREDREME-UHFFFAOYSA-N dodecanamide Chemical compound CCCCCCCCCCCC(N)=O ILRSCQWREDREME-UHFFFAOYSA-N 0.000 claims abstract description 8
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- JMGZBMRVDHKMKB-UHFFFAOYSA-L disodium;2-sulfobutanedioate Chemical compound [Na+].[Na+].OS(=O)(=O)C(C([O-])=O)CC([O-])=O JMGZBMRVDHKMKB-UHFFFAOYSA-L 0.000 claims abstract description 5
- 229940116335 lauramide Drugs 0.000 claims abstract description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 70
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims description 28
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- JNGWKQJZIUZUPR-UHFFFAOYSA-N [3-(dodecanoylamino)propyl](hydroxy)dimethylammonium Chemical compound CCCCCCCCCCCC(=O)NCCC[N+](C)(C)[O-] JNGWKQJZIUZUPR-UHFFFAOYSA-N 0.000 claims description 10
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- 229940076988 freshmint Drugs 0.000 description 6
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- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 description 1
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- ZDQYSKICYIVCPN-UHFFFAOYSA-L sodium succinate (anhydrous) Chemical compound [Na+].[Na+].[O-]C(=O)CCC([O-])=O ZDQYSKICYIVCPN-UHFFFAOYSA-L 0.000 description 1
- SXHLENDCVBIJFO-UHFFFAOYSA-M sodium;2-[2-(2-dodecoxyethoxy)ethoxy]ethyl sulfate Chemical compound [Na+].CCCCCCCCCCCCOCCOCCOCCOS([O-])(=O)=O SXHLENDCVBIJFO-UHFFFAOYSA-M 0.000 description 1
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Abstract
本发明涉及一种洗涤剂及其制备方法，其中洗涤剂包括以下以重量份数表示的组分：月桂酰胺丙基氧化胺10‑12份；椰油酰胺丙基甜菜碱5‑8份；脂肪醇聚氧乙烯醚琥珀酸酯磺酸钠5‑8份；甲基羟丙基纤维素0.1‑3份；草酸1‑3份；聚乙二醇3‑6份；卡松0.5‑2份；对羟基苯甲酸丙酯0.5‑1份；香精0.1‑0.5份；去离子水35‑58份；还包括薄荷提取物1‑3份；艾蒿提取物3‑5份；石榴皮提取物3‑5份。采用以上配比制得的洗涤剂具有温和、去污能力强、抑菌时间长久、抑制污垢颗粒再沉积到织物上的优点。
Description
技术领域
本发明涉及织物洗涤领域，更具体的说，它涉及一种洗涤剂及其制备方法。
背景技术
大型酒店或宾馆需要接待大量流动人员，每天需要换洗大量的公用床单、被罩或者餐布。由于这些物件属于公共用品，为避免残留细菌或者病毒，酒店或者宾馆通常使用大量漂白剂或者碳酸盐等碱性物质，使床单、被罩或者餐布看起来干净整洁。但是由于碳酸盐和硬水反应容易产生不溶于水的碳酸钙结晶，使用时间较久之后，容易使衣物变硬。
申请公布号为CN103215142A的中国专利公开了一种集洗涤柔软二合一的洗衣液，提高洗涤衣物的柔顺性。其中，该洗衣液主要包括月桂醇聚醚硫酸酯钠、柠檬酸钠、椰子油二乙醇酰胺、磺酸、脂肪酸甲酯乙氧化物、氢氧化钠，并且辅助加入有机硅柔软剂减少洗衣液中的泡沫，此外还辅助加入增稠剂、防霉剂等。该洗衣液减少了碳酸盐和氢氧化钠的使用量，但是在洗涤过程中产生的一些颗粒物质有可能再沉积在衣物上，造成衣物二次污染。
发明内容
本发明的目的在于提供一种洗涤剂，其具有温和、去污能力强、抑菌时间长久、抑制污垢颗粒再沉积到织物上的优点。
本发明的上述技术目的是通过以下技术方案得以实现的：一种洗涤剂，包括以下以重量份数表示的组分：月桂酰胺丙基氧化胺10-12份；椰油酰胺丙基甜菜碱5-8份；脂肪醇聚氧乙烯醚琥珀酸酯磺酸钠5-8份；甲基羟丙基纤维素0.1-3份；草酸1-3份；聚乙二醇3-6份；卡松0.5-2份；对羟基苯甲酸丙酯0.5-1份；香精0.1-0.5份；去离子水35-58份；还包括薄荷提取物1-3份；艾蒿提取物3-5份；石榴皮提取物3-5份。
采用以上技术方案，月桂酰胺丙基氧化胺为非离子表面活性剂，其具有一定的乳化、渗透和抗硬水作用。椰油酰胺丙基甜菜碱具有丰富的泡沫，便于将污垢与织物分离，织物表面不容易沉积污垢，不会发硬。脂肪醇聚氧乙烯醚琥珀酸酯磺酸钠具有降低表面张力的作用，其与椰油酰胺丙基甜菜碱和月桂酰胺丙基氧化胺混合，既可以适当减少洗涤剂的泡沫，同时还具有易漂洗的作用，容易带走分离的污垢，以免造成二次污染。
甲基羟丙基纤维素具有较佳的增稠效果，草酸具有一定的抗菌作用，并且还可以适当调节pH值，使脂肪醇聚氧乙烯醚琥珀酸酯磺酸钠稳定存在于洗涤剂中。此外，草酸还可以与洗涤剂中的金属离子发生螯合作用，调节水的硬度，并且促进污垢与织物分离。聚乙二醇与椰油酰胺丙基甜菜碱协同，提高洗涤剂的抗静电性能。聚乙二醇还具有较佳的增溶性能，促进洗涤剂分散均匀，软化织物的作用。
卡松和对羟基苯甲酸丙酯结合，提高洗涤剂的杀菌、防腐作用，提高洗涤剂的存放时间，并且具有长久保持洗涤剂有效成分的作用。
香精、薄荷提取物、艾蒿提取物和石榴皮提取物均可以提高洗涤剂的香味。此外，薄荷提取物还可以起到杀菌和长久抑菌的作用。艾蒿提取物可去除大肠杆菌、金黄色葡萄球菌，避免皮肤瘙痒。石榴皮提取物与薄荷提取物和艾蒿提取物协同，提高洗涤剂的杀菌作用，并且对肉汁、牛奶、血等污渍具有持续的分解效力。
优选地，薄荷提取物按照以下方法制得：新鲜薄荷叶剪碎，并与乙醇以质量比为1:3的比例混合，采用超临界二氧化碳进行萃取，萃取压力为8-10MPa，萃取温度为40-50℃，二氧化碳流量为20-25L/h。
采用以上技术方案，直接对新鲜薄荷叶进行超临界二氧化碳提取，保留薄荷叶中的大量薄荷醇有效组分，使其具有较佳的抗菌效果；并且还可以保留薄荷本身具备的香味。
优选地，艾蒿提取物按照以下方法制得：新鲜艾蒿剪碎，与乙醇以质量比为1:2的比例混合，采用超临界二氧化碳进行萃取，萃取压力为25-32MPa，萃取温度为40-45℃，二氧化碳的流量为20-25L/h。
在该条件下制得的艾蒿提取物可保留更多有效成分，具有较佳的杀菌作用，并且保留艾蒿本身的香气。
优选地，石榴皮提取物按照以下方法制得：新鲜石榴皮剪碎，与体积百分数为85％的乙醇以质量比为1:1的比例混合，并且在60-75℃下微波20min制得石榴皮溶出物；石榴皮溶出物减压蒸馏进行浓缩制得石榴皮浓缩物；石榴皮浓缩物采用大孔树脂填充物进行洗脱，洗脱剂依次为体积百分数为75-85％的乙醇、体积百分数为50-60％的乙醇进行洗脱。
优选地，微波功率为100-150W。
采用以上技术方案，石榴皮预先使用微波浸提，提高石榴皮中有效成分的浸出。之后经过洗脱，可去除石榴皮中的色素，还可有效分离石榴皮中的有效成分。
进一步地，聚乙二醇的平均分子量为200-600。
在该条件下，聚乙二醇具有较佳的抗静电作用，并且具有较好的润湿作用，提高洗涤剂的去污效果。
本发明的另一目的在于提供一种洗涤剂的制备方法，其具有混料均匀，保持洗涤剂有效成分的优点。
本发明的上述目的通过以下技术方案得以实现：一种洗涤剂的制备方法，包括以下步骤：草酸、聚乙二醇、卡松和对羟基苯甲酸丙酯分散于1/2体积去离子水中，加热至30-35℃混合均匀；将温度升高至45-50℃搅拌加入香精制得第一混合液；月桂酰胺丙基氧化胺、椰油酰胺丙基甜菜碱、脂肪醇聚氧乙烯醚琥珀酸酯磺酸钠、甲基羟丙基纤维素加入剩余去离子水中，升高温度至35-40℃搅拌均匀；之后降至室温加入薄荷提取物、艾蒿提取物和石榴皮提取物混合均匀，并加入第一混合液制得洗涤剂。
采用以上技术方案，预先将草酸溶解于水中，调整溶液的pH，并且促进香精、卡松和对羟基苯甲酸丙酯的溶解度。月桂酰胺丙基氧化胺、椰油酰胺丙基甜菜碱、脂肪醇聚氧乙烯醚琥珀酸酯磺酸钠预先低温混合，最后再加入第一混合液，提高洗涤剂的稳定性，避免分层。
综上所述，本发明具有以下有益效果：
1、本发明制得的洗涤剂具有较佳的去污效果，月桂酰胺丙基氧化胺、椰油酰胺丙基甜菜碱、脂肪醇聚氧乙烯醚琥珀酸酯磺酸钠和草酸协同，移除污垢，并且可避免污垢再次沉降至织物表面；此外，洗涤剂的泡沫适当，满足去除污垢的同时，还方便漂洗，减少残留；
2、本发明制得的洗涤剂具有较好的抗静电性能，椰油酰胺丙基甜菜碱和聚乙二醇协同，使织物柔软，更加亲肤；
3、本发明制得的洗涤剂具有较佳的杀菌性能，草酸、卡松、对羟基苯甲酸丙酯与薄荷提取物、艾蒿提取物和石榴皮提取物混合，提高洗涤剂对织物的抗菌、长久抑菌的效果，还可以避免洗涤剂长期放置被氧化；
4、本发明制得的洗涤剂具有宜人香气，添加少量香精，并且配合薄荷提取物和艾蒿提取物，增加洗涤剂的天然香气，提高舒适度。
具体实施方式
以下结合实施例对本发明作进一步详细说明。应该理解的是，本发明实施例所述制备方法仅仅是用于说明本发明，而不是对本发明的限制，在本发明的构思前提下对本发明制备方法的简单改进都属于本发明要求保护的范围。
本发明涉及的原料规格如表1所示。
表1本发明涉及的原料
实施例一：一种洗涤剂的制备方法，包括如下步骤：
1、薄荷提取物的制备：取新鲜薄荷嫩叶100g，清洗干净后剪碎，并且与300g体积百分数为85％的乙醇混合，进行超临界二氧化碳萃取，萃取压力为8MPa，萃取温度为40℃，并调节二氧化碳流量为20L/h，萃取1.5h；之后，采用活性炭吸附脱色制得薄荷提取物；
2、艾蒿提取物的制备：取新鲜艾蒿叶100g，清洗干净后剪碎，并且与200g体积百分数为95％的乙醇混合，进行超临界二氧化碳萃取，萃取压力为25MPa，萃取温度为40℃，调节二氧化碳的流量为25L/h，萃取2h；之后，采用活性炭吸附脱色制得艾蒿提取物；
3、石榴皮提取物的制备：新鲜石榴皮100g洗净烘干剪碎，加入1g维生素C粉末进行护色，并与100g体积百分数为85％的乙醇搅拌混合，在60℃下微波20min(微波功率为100W)制得石榴皮溶出物；石榴皮溶出物经过减压蒸馏去除乙醇得到石榴皮浓缩物；石榴皮浓缩物采用D-101-1型大孔吸附树脂进行洗脱，洗脱剂依次采用体积百分数为75％和60％的乙醇进行洗脱。
4、1kg草酸、3kg聚乙二醇-200、0.5kg卡松、0.5kg对羟基苯甲酸丙酯分散于17.5kg去离子水中，加热至30℃混合均匀；之后升温至45℃并加入0.1kg水溶性玫瑰香精制得第一混合液；
10kg月桂酰胺丙基氧化胺、5kg椰油酰胺丙基甜菜碱、5kg脂肪醇聚氧乙烯醚琥珀酸酯磺酸钠、0.1kg甲基羟丙基纤维素加入剩余的17.5kg去离子水中，升温至35℃搅拌均匀；降至室温后加入1kg薄荷提取物、3kg艾蒿提取物和3kg石榴皮提取物搅拌均匀，并在搅拌的情况下加入第一混合液制得洗涤剂。
实施例二：一种洗涤剂的制备方法，包括如下步骤：
1、薄荷提取物的制备：取新鲜薄荷嫩叶100g，清洗干净后剪碎，并且与300g体积百分数为90％的乙醇混合，进行超临界二氧化碳萃取，萃取压力为10MPa，萃取温度为50℃，并调节二氧化碳流量为25L/h，萃取1.5h；之后，采用活性炭吸附脱色制得薄荷提取物；
2、艾蒿提取物的制备：取新鲜艾蒿叶100g，清洗干净后剪碎，并且与200g体积百分数为95％的乙醇混合，进行超临界二氧化碳萃取，萃取压力为32MPa，萃取温度为45℃，调节二氧化碳的流量为20L/h，萃取2h；之后，采用活性炭吸附脱色制得艾蒿提取物；
3、石榴皮提取物的制备：新鲜石榴皮100g洗净烘干剪碎，加入1g维生素C粉末进行护色，并与100g体积百分数为85％的乙醇搅拌混合，在75℃下微波20min(微波功率为150W)制得石榴皮溶出物；石榴皮溶出物经过减压蒸馏去除乙醇得到石榴皮浓缩物；石榴皮浓缩物采用DM-301型大孔吸附树脂进行洗脱，洗脱剂依次采用体积百分数为85％和60％的乙醇进行洗脱。
4、2kg草酸、6kg聚乙二醇-400、1kg卡松、0.8kg对羟基苯甲酸丙酯分散于26.5kg去离子水中，加热至35℃混合均匀；之后升温至50℃并加入0.5kg水溶性兰花香精制得第一混合液；
12kg月桂酰胺丙基氧化胺、8kg椰油酰胺丙基甜菜碱、6kg脂肪醇聚氧乙烯醚琥珀酸酯磺酸钠、1kg甲基羟丙基纤维素加入剩余的26.5kg去离子水中，升温至40℃搅拌均匀；降至室温后加入2kg薄荷提取物、4kg艾蒿提取物和4kg石榴皮提取物搅拌均匀，并在搅拌的情况下加入第一混合液制得洗涤剂。
实施例三：一种洗涤剂的制备方法，包括如下步骤：
1、薄荷提取物的制备：取新鲜薄荷嫩叶100g，清洗干净后剪碎，并且与300g体积百分数为95％的乙醇混合，进行超临界二氧化碳萃取，萃取压力为10MPa，萃取温度为45℃，并调节二氧化碳流量为25L/h，萃取1.5h；之后，采用活性炭吸附脱色制得薄荷提取物；
2、艾蒿提取物的制备：取新鲜艾蒿叶100g，清洗干净后剪碎，并且与200g体积百分数为90％的乙醇混合，进行超临界二氧化碳萃取，萃取压力为28MPa，萃取温度为43℃，调节二氧化碳的流量为25L/h，萃取2h；之后，采用活性炭吸附脱色制得艾蒿提取物；
3、石榴皮提取物的制备：新鲜石榴皮100g洗净烘干剪碎，加入1g维生素C粉末进行护色，并与100g体积百分数为85％的乙醇搅拌混合，在70℃下微波20min(微波功率为150W)制得石榴皮溶出物；石榴皮溶出物经过减压蒸馏去除乙醇得到石榴皮浓缩物；石榴皮浓缩物采用DM-301型大孔吸附树脂进行洗脱，洗脱剂依次采用体积百分数为80％和55％的乙醇进行洗脱。
4、3kg草酸、6kg聚乙二醇-600、1kg卡松、1kg对羟基苯甲酸丙酯分散于26.5kg去离子水中，加热至35℃混合均匀；之后升温至45℃并加入0.3kg水溶性兰花香精制得第一混合液；
10kg月桂酰胺丙基氧化胺、6kg椰油酰胺丙基甜菜碱、8kg脂肪醇聚氧乙烯醚琥珀酸酯磺酸钠、2kg甲基羟丙基纤维素加入剩余的26.5kg去离子水中，升温至40℃搅拌均匀；降至室温后加入2kg薄荷提取物、4kg艾蒿提取物和3kg石榴皮提取物搅拌均匀，并在搅拌的情况下加入第一混合液制得洗涤剂。
实施例四：一种洗涤剂的制备方法，包括如下步骤：
1、薄荷提取物的制备：取新鲜薄荷嫩叶100g，清洗干净后剪碎，并且与300g体积百分数为95％的乙醇混合，进行超临界二氧化碳萃取，萃取压力为10MPa，萃取温度为50℃，并调节二氧化碳流量为25L/h，萃取1.5h；之后，采用活性炭吸附脱色制得薄荷提取物；
2、艾蒿提取物的制备：取新鲜艾蒿叶100g，清洗干净后剪碎，并且与200g体积百分数为90％的乙醇混合，进行超临界二氧化碳萃取，萃取压力为30MPa，萃取温度为45℃，调节二氧化碳的流量为25L/h，萃取2h；之后，采用活性炭吸附脱色制得艾蒿提取物；
3、石榴皮提取物的制备：新鲜石榴皮100g洗净烘干剪碎，加入1g维生素C粉末进行护色，并与100g体积百分数为85％的乙醇搅拌混合，在75℃下微波20min(微波功率为100W)制得石榴皮溶出物；石榴皮溶出物经过减压蒸馏去除乙醇得到石榴皮浓缩物；石榴皮浓缩物采用DM-301型大孔吸附树脂进行洗脱，洗脱剂依次采用体积百分数为80％和50％的乙醇进行洗脱。
4、2kg草酸、4kg聚乙二醇-400、1kg卡松、1kg对羟基苯甲酸丙酯分散于28.5kg去离子水中，加热至35℃混合均匀；之后升温至45℃并加入0.3kg水溶性兰花香精制得第一混合液；
12kg月桂酰胺丙基氧化胺、6kg椰油酰胺丙基甜菜碱、8kg脂肪醇聚氧乙烯醚琥珀酸酯磺酸钠、3kg甲基羟丙基纤维素加入剩余的26.5kg去离子水中，升温至40℃搅拌均匀；降至室温后加入2kg薄荷提取物、4kg艾蒿提取物和5kg石榴皮提取物搅拌均匀，并在搅拌的情况下加入第一混合液制得洗涤剂。
实施例五：一种洗涤剂的制备方法，包括如下步骤：
1、薄荷提取物的制备：取新鲜薄荷嫩叶100g，清洗干净后剪碎，并且与300g体积百分数为95％的乙醇混合，进行超临界二氧化碳萃取，萃取压力为10MPa，萃取温度为50℃，并调节二氧化碳流量为25L/h，萃取1.5h；之后，采用活性炭吸附脱色制得薄荷提取物；
2、艾蒿提取物的制备：取新鲜艾蒿叶100g，清洗干净后剪碎，并且与200g体积百分数为90％的乙醇混合，进行超临界二氧化碳萃取，萃取压力为30MPa，萃取温度为45℃，调节二氧化碳的流量为25L/h，萃取2h；之后，采用活性炭吸附脱色制得艾蒿提取物；
3、石榴皮提取物的制备：新鲜石榴皮100g洗净烘干剪碎，加入1g维生素C粉末进行护色，并与100g体积百分数为85％的乙醇搅拌混合，在75℃下微波20min(微波功率为100W)制得石榴皮溶出物；石榴皮溶出物经过减压蒸馏去除乙醇得到石榴皮浓缩物；石榴皮浓缩物采用DM-301型大孔吸附树脂进行洗脱，洗脱剂依次采用体积百分数为75％和50％的乙醇进行洗脱。
4、3kg草酸、5kg聚乙二醇-600、2kg卡松、0.8kg对羟基苯甲酸丙酯分散于29kg去离子水中，加热至35℃混合均匀；之后升温至50℃并加入0.3kg水溶性兰花香精制得第一混合液；
10kg月桂酰胺丙基氧化胺、6kg椰油酰胺丙基甜菜碱、8kg脂肪醇聚氧乙烯醚琥珀酸酯磺酸钠、3kg甲基羟丙基纤维素加入剩余的29kg去离子水中，升温至40℃搅拌均匀；降至室温后加入3kg薄荷提取物、5kg艾蒿提取物和3kg石榴皮提取物搅拌均匀，并在搅拌的情况下加入第一混合液制得洗涤剂。
对实施例一至实施例五制得的洗涤剂进行性能测试，其中采用GB/T13174-2003对洗涤剂的去污力以及抗污渍再沉积能力进行测定；依据QB-T2850-2007对洗涤剂的抗菌性能进行测定；感官测试洗涤后织物的柔韧性；采用FZ/T01060-1999测试漂洗后织物的抗静电性能。具体测试结果如表2所示。
表2实施例一至实施例五制得的洗涤剂性能测试结果
根据以上数据可看出，实施例一至实施例五制得的洗涤剂对蛋白污布、皮脂污布和粘土污布均具有较佳的去污能力，经过多次反复漂洗之后，织物仍可保持鲜亮、并且不会发硬。漂洗后的织物表面电阻均小于1011Ω，具有较佳的抗静电性能。此外，使用洗涤剂漂洗后的织物细菌几乎无残留，可避免交叉感染。
Claims (4)
1.一种洗涤剂，其特征在于，包括以下以重量份数表示的组分：月桂酰胺丙基氧化胺10-12份；椰油酰胺丙基甜菜碱5-8份；脂肪醇聚氧乙烯醚琥珀酸酯磺酸钠5-8份；甲基羟丙基纤维素0.1-3份；草酸1-3份；聚乙二醇3-6份；卡松0.5-2份；对羟基苯甲酸丙酯0.5-1份；香精0.1-0.5份；去离子水35-58份；还包括薄荷提取物1-3份；艾蒿提取物3-5份；石榴皮提取物3-5份，
薄荷提取物按照以下方法制得：新鲜薄荷叶剪碎，并与乙醇以质量比为1:3的比例混合，采用超临界二氧化碳进行萃取，萃取压力为8-10MPa，萃取温度为40-50℃，二氧化碳流量为20-25L/h，
艾蒿提取物按照以下方法制得：新鲜艾蒿剪碎，与乙醇以质量比为1:2的比例混合，采用超临界二氧化碳进行萃取，萃取压力为25-32MPa，萃取温度为40-45℃，二氧化碳的流量为20-25L/h，
石榴皮提取物按照以下方法制得：新鲜石榴皮剪碎，与体积百分数为85％的乙醇以质量比为1:1的比例混合，并且在60-75℃下微波20min制得石榴皮溶出物；石榴皮溶出物减压蒸馏进行浓缩制得石榴皮浓缩物；石榴皮浓缩物采用大孔树脂填充物进行洗脱，洗脱剂依次为体积百分数为75-85％的乙醇、体积百分数为50-60％的乙醇进行洗脱。
2.根据权利要求1所述的洗涤剂，其特征在于，微波功率为100-150W。
3.根据权利要求1或2所述的洗涤剂，其特征在于：聚乙二醇的平均分子量为200-600。
4.一种如权利要求1-3任一项所述洗涤剂的制备方法，其特征在于，包括以下步骤：草酸、聚乙二醇、卡松和对羟基苯甲酸丙酯分散于1/2体积去离子水中，加热至30-35℃混合均匀；将温度升高至45-50℃搅拌加入香精制得第一混合液；
月桂酰胺丙基氧化胺、椰油酰胺丙基甜菜碱、脂肪醇聚氧乙烯醚琥珀酸酯磺酸钠、甲基羟丙基纤维素加入剩余去离子水中，升高温度至35-40℃搅拌均匀；之后降至室温加入薄荷提取物、艾蒿提取物和石榴皮提取物混合均匀，并加入第一混合液制得洗涤剂。
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