A kind of Multi-function dry washing material and preparation method thereof
Technical field
The present invention relates to dry cleaning agent, in particular to a kind of Multi-function dry washing material and preparation method thereof.
Background technology
Tetrachloro-ethylene (Perchloroethylene) is most common dry-cleaning material, it has many advantages, such as:(1) to oil
Dirty cleaning performance is preferable, cleanliness factor is higher;(2) clothes is expected and organic glass button zero damage, do not fade, colour contamination, change
Shape;(3) it is nonflammable, non-explosive;(4) it is relatively preferable to textile material compatibility;(5) it is cheap;(6) there is good change
Learn stability.Therefore, tetrachloro-ethylene is widely used in dry-cleaning in industry, and the proportion in global dry cleaning agent is about more than 80%,
Proportion in domestic DC naphtha is about 85-90%.
But study for a long period of time and show, Long Term Contact tetrachloro-ethylene produces harm to animals and humans, and tetrachloro-ethylene is to human body
Toxic action be mainly reflected in the suppression of Central nervous and the infringement to liver, kidney, it to human toxicity first to maincenter god
The anesthetic effect of warp, shows as headache, dizziness, vomits and illness, the severe one such as lose consciousness may cause death.At present, tetrachloro
Ethene is be evaluated as the volatile organic matter for having destruction to earth's ozone layer, and the U.S., Germany, Canada and Japan are
Tetrachloro-ethylene dry-cleaning material is included in the item controlled of ecological textile.
The content of the invention
First purpose of the present invention be to provide it is a kind of safely and effectively, greasy dirt solvability it is strong, it is harmless, to ring
Border is friendly, a kind of dry-cleaning material simply used, to solve the problems mentioned in the above background technology:
To achieve the above object, the present invention provides following technical solution:
A kind of Multi-function dry washing material, by weight including following components:
Oil dry-cleans 80 ~ 90 parts of material;
1 ~ 10 part of ether compound;
0.1 ~ 5 part of surfactant;
0.1 ~ 5 part of softener;
0.1 ~ 5 part of fungicide.
As the further scheme of the present invention:The oil dry-cleaning material includes n-undecane, 2- methyldecanes, 3- methyl
Decane, 4- methyldecanes, 5- methyldecanes, 2,2- dimethylnonanes, 2,3- dimethylnonanes, 2,4- dimethylnonanes, 2,5-
Dimethylnonane, 2,6- dimethylnonanes, 5-methyl-3-ethyl octane, 3- ethyls decane, n-dodecane, 2-methyl ten
One alkane, 3-methylundecane, 4-methylundecane, 5-methylundecane, 6-methylundecane, 3-ethyl decane, 4-
Ethyl decane, 5-ethyl decane, 2,2-dimethyl decane, 2,3-dimethyl decane, 2,4-dimethyl decane, 2,5-two
Methyldecane, 2,6-dimethyl decane, 3-methyl-3-ethyl nonane, 2,2,3-trimethyl nonane it is therein a kind of or
It is a variety of.
As the further scheme of the present invention:The ether compound includes diethylene glycol monomethyl ether, triethylene glycol list
Methyl ether, diethylene glycol monobutyl ether, triethylene glycol butyl ether, dipropylene glycol monomethyl ether, dipropylene glycol monopropyl ether, three glycerine lists third
Ether, dipropylene and tripropylene glycol butyl ether one or more therein.
As the further scheme of the present invention:The surfactant includes alkane polyoxyethylene alkyl ether ester, isomery alcohol
Polyoxyethylene ether, fatty acid methyl ester APEO, glycerine mono-acid stearate, aliphatic acid polyethenoxy acid esters, polyglycerol ester
Fat acid esters and methyl glycol fatty acid ester one of which or a variety of.
As the further scheme of the present invention:The softener includes poly- methylhydrogen silicone, polyether-modified poly- silicon
One or more in oxygen alkane, amino modified polysiloxane, long chain alkyl modified polysiloxanes;
As the further scheme of the present invention:The fungicide include ethylene glycol phenyl ether, dimethyl fumarate, sodium Diacetate,
2-(4- thiazolyls)One or more in-benzimidazole.
It is another object of the present invention to provide it is a kind of safely and effectively, greasy dirt solvability it is strong, it is harmless, to ring
Border is friendly, the preparation method of the dry-cleaning material simply used, to solve the problems mentioned in the above background technology.
To achieve the above object, the present invention provides following technical solution:
A kind of preparation method of Multi-function dry washing material, comprises the following steps:
A. 1 ~ 10 part of ether compound is dissolved in 80 ~ 90 parts of oil dry-cleaning material, and be evenly stirred until transparent;
B. 0.1 ~ 5 surfactant is added thereto and is uniformly mixed;
C. 0.1 ~ 5 part of softener is added thereto uniformly mixed;
D. 0.1 ~ 5 part of fungicide is added thereto to be uniformly mixed and filters to obtain finished product.
The advantage of the invention is that:
1st, use environment friendly oil dry-cleaning material of the present invention, is halogen-free solvent and aromatic solvent, does not have in wash clean process
Polluted gas and exhaust gas discharge, do not destroy ozone layer, the fabric after cleaning does not have pollution residue, to the nontoxic nothing of human body
Evil, it is environmentally protective.
2nd, the present invention improves clean ability of the oil dry-cleaning material to water-soluble greasy dirt using alcohol ether auxiliary agent, to fruit juice, sweat
The stains such as stain, lipstick, nail polish, ink, tea, coating have very strong cleaning ability, clean long lifespan, can be used as and pass
Tetrachloro-ethylene of uniting dry-cleans the ideal substitute of material.
3rd, dry-cleaning material of the invention has fabric the multi-function actions such as submissive, sterilization, disinfection, can carry greatly improve it is dry
Wash the application range of material.
Embodiment
Embodiment one,
In the present embodiment, a kind of Multi-function dry washing material, by weight including following components:
Oil dry-cleans 80 parts of material;
1 part of ether compound;
0.1 part of surfactant;
0.1 part of softener;
0.1 part of fungicide.
Its petrochina dry-cleaning material includes 13 parts of n-undecanes, 5 parts of 4- methyldecanes, 7 parts of 5- methyldecanes, 3 parts of 2,2-
Dimethylnonane, 9 parts of 2,3- dimethylnonanes, 2 parts of 5-methyl-3-ethyl octane, 6 parts of 3- ethyls decane, 4 parts of 6-methyl
Hendecane, 12 parts of 3-ethyl decane, 3 parts of 4-ethyl decane, 8 parts of 3-methyl-3-ethyl nonane, 8 part 2,2,3-front three
Base nonane.
Wherein ether compound includes 1 part of diethylene glycol monomethyl ether.
Wherein surfactant includes 0.1 part of isomeric alcohol polyethenoxy ether.
Wherein softener includes 0.1 part of poly- methylhydrogen silicone.
Wherein fungicide includes 0.1 part of ethylene glycol phenyl ether.
The preparation method of above-mentioned dry-cleaning material comprises the following steps,
A. by 13 parts of n-undecanes, 5 parts of 4- methyldecanes, 7 parts of 5- methyldecanes, 3 parts of 2,2- dimethylnonanes, 9 parts of 2,3- bis-
Methylnonane, 2 parts of 5-methyl-3-ethyl octane, 6 parts of 3- ethyls decane, 4 parts of 6-methylundecanes, 12 parts of 3-ethyl last of the ten Heavenly stems
Alkane, 3 parts of 4-ethyl decane, 8 parts of 3-methyl-3-ethyl nonane, 8 part 2,2,3-trimethyl nonane is put into reaction kettle,
Then 1 part of good diethylene glycol monomethyl ether of pre-coordination is added into reaction kettle, it is dissolved in oil dry-cleaning material, it is then right
Mixed material in reaction kettle stirs evenly until its transparent state.
B. 0.1 part of isomeric alcohol polyethenoxy ether is added in reaction kettle and is uniformly mixed material;
C. 0.1 part of poly- methylhydrogen silicone is added thereto uniformly mixed;
D. 0.1 part of ethylene glycol phenyl ether is added thereto to be uniformly mixed and filters to obtain finished product.
Embodiment two,
In the present embodiment, a kind of Multi-function dry washing material, by weight including following components:
Oil dry-cleans 85 parts of material;
5 parts of ether compound;
2.5 parts of surfactant;
2.5 parts of softener;
2.5 parts of fungicide.
Its petrochina dry-cleaning material includes 8 parts of 3- methyldecanes, 6 parts of 4- methyldecanes, 5 parts of 5- methyldecanes, 5 parts of 2,2-
Dimethylnonane, 4 parts of 2,3- dimethylnonanes, 3 parts of 2,4- dimethylnonanes, 2 parts of 2,5- dimethylnonanes, 3 parts of 2,6- diformazans
Base nonane, 4 parts of 5-methyl-3-ethyl octane, 2 parts of 3- ethyls decane, 2 parts of n-dodecanes, 6 parts of 2-methylundecanes, 2 parts
3-methylundecane, 3 parts of 4-methylundecanes, 7 parts of 5-methylundecanes, 6 parts of 3-ethyl decane, 2 parts of 4-ethyl last of the ten Heavenly stems
Alkane, 3 parts of 5-ethyl decane, 3 part 2,2-dimethyl decane, 3 part 2,3-dimethyl decane, 2 part 2,4-dimethyl decane, 2
Parts 2,5-dimethyl decane and 2 part 2,6-dimethyl decane.
Wherein ether compound includes 0.3 part of diethylene glycol monomethyl ether, 1.5 parts of triethylene glycol monomethyl ethers, 1 part of triethylene glycol
Monobutyl ether, 1.5 parts of dipropylene glycol monomethyl ethers and 0.7 part of three glycerine list propyl ether.
Wherein surfactant include 0.4 part of alkane polyoxyethylene alkyl ether ester, 0.7 part of glycerine mono-acid stearate, 0.3 part
Aliphatic acid polyethenoxy acid esters, 0.5 part of polyglyceryl fatty acid ester and 0.6 part of methyl glycol fatty acid ester.
Wherein softener includes 1 part of Siloxane-Oxyalkylene Copolymers, 1 part of amino modified polysiloxane and 0.5 part of chain alkyl
Modified polyorganosiloxane;
The fungicide includes 1 part of dimethyl fumarate, 1 part of sodium Diacetate and 0.5 part of 2-(4- thiazolyls)- benzimidazole.
The preparation method of above-mentioned dry-cleaning material comprises the following steps,
A. by 8 parts of 3- methyldecanes, 6 parts of 4- methyldecanes, 5 parts of 5- methyldecanes, 5 parts of 2,2- dimethylnonanes, 4 parts of 2,3-
Dimethylnonane, 3 parts of 2,4- dimethylnonanes, 2 parts of 2,5- dimethylnonanes, 3 parts of 2,6- dimethylnonanes, 4 parts of 5-methyl-
3-ethyl octane, 2 parts of 3- ethyls decane, 2 parts of n-dodecanes, 6 parts of 2-methylundecanes, 2 parts of 3-methylundecanes, 3 parts
4-methylundecane, 7 parts of 5-methylundecanes, 6 parts of 3-ethyl decane, 2 parts of 4-ethyl decane, 3 parts of 5-ethyl decane, 3
Parts 2,2-dimethyl decane, 3 part 2,3-dimethyl decane, 2 part 2,4-dimethyl decane, 2 part 2,5-dimethyl decane and 2
Parts 2,6-dimethyl decane is put into reaction kettle, then by 0.3 part of good diethylene glycol monomethyl ether of pre-coordination, 1.5 part three
Glycol monoethyl ether, 1 part of triethylene glycol butyl ether, 1.5 parts of dipropylene glycol monomethyl ethers and 0.7 part of three glycerine list propyl ether add to
It is dissolved in oil dry-cleaning material in reaction kettle, then the mixed material in reaction kettle is stirred evenly until it is transparent
State.
B. by 0.4 part of alkane polyoxyethylene alkyl ether ester, 0.7 part of glycerine mono-acid stearate, 0.3 part of aliphatic acid polyethenoxy
Acid esters, 0.5 part of polyglyceryl fatty acid ester and 0.6 part of methyl glycol fatty acid ester are added in reaction kettle and are uniformly mixed material;
C. 1 part of Siloxane-Oxyalkylene Copolymers, 1 part of amino modified polysiloxane and 0.5 part of long chain alkyl modified polysiloxanes are added
Enter and be wherein uniformly mixed;
D. by 1 part of dimethyl fumarate, 1 part of sodium Diacetate and 0.5 part of 2-(4- thiazolyls)It is equal that-benzimidazole is added thereto mixing
It is even to filter to obtain finished product.
Embodiment three,
In the present embodiment, a kind of Multi-function dry washing material, by weight including following components:
Oil dry-cleans 90 parts of material;
10 parts of ether compound;
5 parts of surfactant;
5 parts of softener;
5 parts of fungicide.
Its petrochina dry-cleaning material includes 10 parts of n-undecanes, 10 parts of 2- methyldecanes, 10 parts of 3- methyldecanes, 3 parts of 4-
Methyldecane, 3 parts of 5- methyldecanes, 2 parts of 2,2- dimethylnonanes, 1 part of 2,3- dimethylnonane, 1 part of 2,4- dimethylnonane,
2 parts of 2,5- dimethylnonanes, 2 parts of 2,6- dimethylnonanes, 1 part of 5-methyl-3-ethyl octane, 3 parts of 3- ethyls decane, 4 parts
N-dodecane, 2 parts of 2-methylundecanes, 3 parts of 3-methylundecanes, 3 parts of 4-methylundecanes, 2 parts of 5-methylundecanes,
1 part of 6-methylundecane, 1 part of 3-ethyl decane, 6 parts of 4-ethyl decane, 3 parts of 5-ethyl decane, 2 part 2,2-dimethyl
Decane, 2 part 2,3-dimethyl decane, 3 part 2,4-dimethyl decane, 4 part 2,5-dimethyl decane, 2 part 2,6-dimethyl
Decane, 2 parts of 3-methyl-3-ethyl nonane, 1 part 2,2,3-trimethyl nonane.
Wherein ether compound includes 1.5 parts of diethylene glycol monomethyl ethers, 1.5 parts of triethylene glycol monomethyl ethers, 1.6 parts of diethyls two
Alcohol monobutyl ether, 1.8 parts of triethylene glycol butyl ethers, 1.3 parts of dipropylene glycol monomethyl ethers, 0.4 part of dipropylene glycol monopropyl ether, 0.7 part three
Glycerine list propyl ether, 0.5 part of dipropylene and 0.7 part of tripropylene glycol butyl ether.
Wherein surfactant include 0.6 part of alkane polyoxyethylene alkyl ether ester, 0.5 part of isomeric alcohol polyethenoxy ether, 0.7 part
Fatty acid methyl ester APEO, 1 part of glycerine mono-acid stearate, 0.2 part of aliphatic acid polyethenoxy acid esters, 1 part of polyglycerol ester
Fat acid esters and 1 part of methyl glycol fatty acid ester.
Wherein softener include 1.5 parts of poly- methylhydrogen silicones, 1.5 parts of Siloxane-Oxyalkylene Copolymers, 1 part it is amino modified
Polysiloxanes, 1 part of long chain alkyl modified polysiloxanes;
Wherein fungicide includes 1 part of ethylene glycol phenyl ether, 2 parts of dimethyl fumarates, 1 part of sodium Diacetate and 1 part of 2-(4- thiazolyls)-
Benzimidazole.
A. by 10 parts of n-undecanes, 10 parts of 2- methyldecanes, 10 parts of 3- methyldecanes, 3 parts of 4- methyldecanes, 3 parts of 5- first
Base decane, 2 parts of 2,2- dimethylnonanes, 1 part of 2,3- dimethylnonane, 1 part of 2,4- dimethylnonane, 2 parts of 2,5- dimethyl nonyls
Alkane, 2 parts of 2,6- dimethylnonanes, 1 part of 5-methyl-3-ethyl octane, 3 parts of 3- ethyls decane, 4 parts of n-dodecanes, 2 part 2-
Methylundecane, 3 parts of 3-methylundecanes, 3 parts of 4-methylundecanes, 2 parts of 5-methylundecanes, 1 part of 6-methyl 11
Alkane, 1 part of 3-ethyl decane, 6 parts of 4-ethyl decane, 3 parts of 5-ethyl decane, 2 part 2,2-dimethyl decane, 2 part 2,3-two
Methyldecane, 3 part 2,4-dimethyl decane, 4 part 2,5-dimethyl decane, 2 part 2,6-dimethyl decane, 2 parts of 3-first
Base-3-ethyl nonane, 1 part 2,2,3-trimethyl nonane is put into reaction kettle, then by good 1.5 part two of pre-coordination
Glycol monoethyl ether, 1.5 parts of triethylene glycol monomethyl ethers, 1.6 parts of diethylene glycol monobutyl ethers, 1.8 parts of triethylene glycol butyl ethers, 1.3
Part dipropylene glycol monomethyl ether, 0.4 part of dipropylene glycol monopropyl ether, 0.7 part of three glycerine list propyl ether, 0.5 part of dipropylene and
0.7 part of tripropylene glycol butyl ether is added makes it be dissolved in oil dry-cleaning material into reaction kettle, then to the mixed material in reaction kettle
Stir evenly until its transparent state.
B. by 0.6 part of alkane polyoxyethylene alkyl ether ester, 0.5 part of isomeric alcohol polyethenoxy ether, 0.7 part of fatty acid methyl ester polyoxy
Vinethene, 1 part of glycerine mono-acid stearate, 0.2 part of aliphatic acid polyethenoxy acid esters, 1 part of polyglyceryl fatty acid ester and 1 part the third two
Alcohol fatty acid ester is added in reaction kettle and is uniformly mixed material;
C. by 1.5 parts of poly- methylhydrogen silicones, 1.5 parts of Siloxane-Oxyalkylene Copolymers, 1 part of amino modified polysiloxane, 1 part long
Alkyl group modified polyorganosiloxane is added thereto uniformly mixed;
D. by 1 part of ethylene glycol phenyl ether, 2 parts of dimethyl fumarates, 1 part of sodium Diacetate and 1 part of 2-(4- thiazolyls)- benzimidazole adds
Enter wherein to be uniformly mixed and filter to obtain finished product.
The above is not intended to limit the scope of the present invention, and all foundation the technology of the present invention are substantially to the above
Any modification, equivalent variations and the modification that embodiment is made, in the range of still falling within technical scheme.