CN108029691A - Environmentally friendly powder granule of high osmosis and preparation method thereof - Google Patents
Environmentally friendly powder granule of high osmosis and preparation method thereof Download PDFInfo
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- CN108029691A CN108029691A CN201711160538.9A CN201711160538A CN108029691A CN 108029691 A CN108029691 A CN 108029691A CN 201711160538 A CN201711160538 A CN 201711160538A CN 108029691 A CN108029691 A CN 108029691A
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/50—1,3-Diazoles; Hydrogenated 1,3-diazoles
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/08—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing solids as carriers or diluents
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/12—Powders or granules
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/36—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids
- A01N37/38—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids having at least one oxygen or sulfur atom attached to an aromatic ring system
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- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Dentistry (AREA)
- Plant Pathology (AREA)
- Engineering & Computer Science (AREA)
- Pest Control & Pesticides (AREA)
- Agronomy & Crop Science (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Toxicology (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Medicinal Preparation (AREA)
Abstract
The present invention relates to a kind of pesticidal preparations, more particularly to environmentally friendly powder granule of a kind of high osmosis and preparation method thereof.The preparation method of powder granule includes the following steps：Intercalation modifying is carried out by organic solvent to flyash；Each raw material components are weighed in dosage bunker by proportioning, are mixed and are stirred evenly；Water is added in dosage bunker, is uniformly mixed, forms formulation material；Formulation material is subjected to coarse crushing with high-speed shearing machine, enters back into two-stage sand mill fine grinding, forms suspending agent；Suspending agent is pumped into pressure spray drying tower to be dried, be granulated；The particle of pressure spray drying tower bottom output is detected, is sieved, measure after packaging and storage.The features such as dry suspension granula has good dispersion, and wetability is good, suspensibility is high, penetration is strong.
Description
Technical field
The present invention relates to a kind of pesticidal preparations, more particularly to a kind of environmentally friendly powder granule of high osmosis and its preparation
Method.
Background technology
At present, commonly using the formulations of pesticide in it is relatively conventional with missible oil, aqua, pulvis etc., these formulations are specific
Environment, under the conditions of, preferable effect can be played.But as the mankind are to the pay attention to day by day of environmental protection, to there has also been more using pesticide
High requirement, thus these formulations have its corresponding limitation again.For this reason, higher is constantly pursued and explored to pesticide brainstrust
Effect, safer, more environmentally friendly pesticides new formulation, wherein, dry suspending agent (DF) is the one kind succeeded in developing.At present at some
Western developed country, dry suspending agent have developed more mature.
China is a big coal country, using coal as power generation substantially fuel.The energy industry stable development in China, power generation
Ability annual growth is 7.3%, and power industry develops rapidly, sharply increasing for flyash discharge capacity is brought, to China
The development of the national economy and ecological environment cause huge pressure.If can be using industrial waste flyash as pesticide dry suspending agent
Carrier filler, turn waste into wealth, it will produce larger economic benefit and the value of environmental protection.
The content of the invention
It is an object of the present invention to overcome above-mentioned deficiency, there is provided one kind can make full use of production waste material as carrier
The pesticide dry suspending agent that the drug effect of filler is high, penetration is strong.
The second object of the present invention is to provide a kind of preparation method of pesticide dry suspending agent.
The object of the present invention is achieved like this：
A kind of environmentally friendly powder granule of high osmosis, includes the raw material components of following parts by weight：5~45 parts of alkene
Morpholide, 5~45 parts of cyazofamid, 2~20 parts of dispersant, 1~8 part of wetting agent, 5~25 parts of disintegrant, 0.2~3
The defoamer, 0.1~3 part of binding agent, 0.5~8 part of bleeding agent and 20~200 parts of carrier of part, the carrier is fine coal
Ash, the flyash pass through organic solvent intercalation modifying.
Further, the environmentally friendly powder granule of the application high osmosis includes the raw material components of following parts by weight：
20~30 parts of dimethomorph, 20~30 parts of cyazofamid, 8~15 parts of dispersant, 3~6 parts of wetting agent, 10~17 parts
Disintegrant, 0.5~2 part of defoamer, 0.5~2 part of binding agent, 2~6 parts of bleeding agent and 80~160 parts of flyash.
Further, the environmentally friendly powder granule of the application high osmosis includes the raw material components of following parts by weight：
25 parts of dimethomorph, 25 parts of cyazofamid, 10 parts of dispersant, 5 parts of wetting agent, 13 parts of disintegrant, 1 part of defoaming
Agent, 1 part of binding agent, 3 parts of bleeding agent and 120 parts of flyash.
Further, the bleeding agent is polyether modified siloxane, the poly- trisiloxanes of ethyoxyl modification, sulfosuccinate two
At least one of Zhong Xin ester sodium salts and nonylphenol polyoxyethylene ether；
The dispersant is lignosulfonates, phenethyl phenol polyethenoxy ether, N methyl taurine sodium salt, castor oil gather
At least one of ethylene oxide ether, vinylpyrrolidone and carboxymethyl cellulose；
The wetting agent is dehydration mountain alcohol fatty acid ester, alkyl amine group taurate, sulfated lauryl alcohol and di-2-ethylhexylphosphine oxide
At least one of sodium naphthalene sulfonate；
The disintegrant is at least one of magnesium chloride, urea, sodium sulphate and carboxy-propyl cellulose；
The binding agent is at least one of polyvinyl alcohol, macrogol, sodium metasilicate and gelatin；
The defoamer is at least one of fatty alcohol of organic silicone and C8-10.
Correspondingly, present invention also offers the preparation method of the environmentally friendly powder granule of above-mentioned high osmosis, the system
Preparation Method includes the following steps：
S1, intercalation modifying is carried out to flyash by organic solvent；
S2, weighs each raw material components in dosage bunker by proportioning, mixes and stir evenly；
S3, adds water in dosage bunker, is uniformly mixed, and forms formulation material；
S4, coarse crushing is carried out by formulation material with high-speed shearing machine, enters back into two-stage sand mill fine grinding, forms suspending agent；
S5, is pumped into pressure spray drying tower by suspending agent and is dried, is granulated；
S6, the particle of pressure spray drying tower bottom output is detected, is sieved, measure after packaging and storage.
Further, intercalation modifying is carried out by organic solvent to flyash to include the following steps：
S101, by dimethyl sulfoxide (DMSO) with water in mass ratio (7~11):1 is mixed, and carries out mechanical agitation at room temperature
Obtain dimethyl sulphoxide aqueous solution；
S102, in mass ratio (1~10):1 mixes flyash with dimethyl sulphoxide aqueous solution, carries out ultrasonic disperse, so
Mixed system is formed by mechanical agitation afterwards, it is 12~50h to control mixing time, and it is 35~80 DEG C to control whipping temp；
S103, by mixed system by centrifuging, dry 7~15h, obtains flyash-dimethyl at 55~120 DEG C
Sulfoxide compound；
S104, roasts 1.5~2.5h by flyash-dimethylsulfide complex at 700~1350 DEG C, obtains through intercalation
Modified flyash.
Compared with prior art, the beneficial effects of the invention are as follows：
The powder granule of the present invention is substantially a kind of dry suspending agent, and multiple milled processed is used in technique, makes dry suspension grain
The features such as agent has good dispersion, and wetability is good, suspensibility is high, penetration is strong；It is also good with easy to package, easy storage, stability
The features such as；It is carrier filler that flyash, which can be made full use of, is turned waste into wealth, it will produces larger economic benefit and environmentally friendly valency
Value.
Embodiment
Embodiment 1
A kind of environmentally friendly powder granule of high osmosis, includes the raw material components of following parts by weight：5 parts of alkene acyl
Quinoline, 5 parts of cyazofamid, 2 parts of phenethyl phenol polyethenoxy ether, 1 part of dehydration mountain alcohol fatty acid ester, 5 parts of magnesium chloride, 0.2
The organic silicone, 0.1 part of polyvinyl alcohol, 0.5 part of polyether modified siloxane and 20 parts of flyash of part, the flyash warp
Cross organic solvent intercalation modifying.
Preparation method includes the following steps：
S1, intercalation modifying is carried out to flyash by organic solvent；
S2, weighs each raw material components in dosage bunker by proportioning, mixes and stir evenly；
S3, adds water in dosage bunker, is uniformly mixed, and forms formulation material；
S4, coarse crushing is carried out by formulation material with high-speed shearing machine, enters back into two-stage sand mill fine grinding, forms suspending agent；
S5, is pumped into pressure spray drying tower by suspending agent and is dried, is granulated；
S6, the particle of pressure spray drying tower bottom output is detected, is sieved, measure after packaging and storage.
Wherein, intercalation modifying is carried out by organic solvent to flyash to include the following steps：
S101, by dimethyl sulfoxide (DMSO) and water in mass ratio 7:1 is mixed, and is carried out mechanical agitation at room temperature and is obtained diformazan
Base sulfoxide aqueous solution；
S102, in mass ratio 1:1 mixes flyash with dimethyl sulphoxide aqueous solution, carries out ultrasonic disperse, then passes through
Mechanical agitation forms mixed system, and it is 12h to control mixing time, and it is 80 DEG C to control whipping temp；
S103, by mixed system by centrifuging, dry 15h, it is compound to obtain flyash-dimethyl sulfoxide (DMSO) at 55 DEG C
Thing；
S104, roasts 2.5h at 700 DEG C by flyash-dimethylsulfide complex, obtains the fine coal through intercalation modifying
Ash.
Through examining, moisture≤1.0%, fineness (passing through 1um) >=96%, suspensibility >=94%, persistent foamability (1min)
≤ 10ml, wetting time≤40s, substantially without dust, accelerated storage qualified stability.
Embodiment 2
A kind of environmentally friendly powder granule of high osmosis, includes the raw material components of following parts by weight：45 parts of alkene acyl
Morpholine, 45 parts of cyazofamid, 20 parts of dispersant, 8 parts of wetting agent, 25 parts of disintegrant, 3 parts of defoamer, 3 parts of bonding
Agent, 8 parts of bleeding agent and 200 parts of flyash, the flyash pass through organic solvent intercalation modifying.
Preparation method includes the following steps：
S1, intercalation modifying is carried out to flyash by organic solvent；
S2, weighs each raw material components in dosage bunker by proportioning, mixes and stir evenly；
S3, adds water in dosage bunker, is uniformly mixed, and forms formulation material；
S4, coarse crushing is carried out by formulation material with high-speed shearing machine, enters back into two-stage sand mill fine grinding, forms suspending agent；
S5, is pumped into pressure spray drying tower by suspending agent and is dried, is granulated；
S6, the particle of pressure spray drying tower bottom output is detected, is sieved, measure after packaging and storage.
Wherein, intercalation modifying is carried out by organic solvent to flyash to include the following steps：
S101, by dimethyl sulfoxide (DMSO) and water in mass ratio 11:1 is mixed, and is carried out mechanical agitation at room temperature and is obtained two
Methyl sulfoxide aqueous solution；
S102, in mass ratio 10:1 mixes flyash with dimethyl sulphoxide aqueous solution, carries out ultrasonic disperse, then passes through
Mechanical agitation forms mixed system, and it is 50h to control mixing time, and it is 35 DEG C to control whipping temp；
S103, by mixed system by centrifuging, dry 7h, it is compound to obtain flyash-dimethyl sulfoxide (DMSO) at 120 DEG C
Thing；
S104, roasts 2.5h at 1350 DEG C by flyash-dimethylsulfide complex, obtains the fine coal through intercalation modifying
Ash.
Through examining, moisture≤1.0%, fineness (passing through 1um) >=97%, suspensibility >=93%, persistent foamability (1min)
≤ 10ml, wetting time≤45s, substantially without dust, accelerated storage qualified stability.
Embodiment 3
The environmentally friendly powder granule of high osmosis, includes the raw material components of following parts by weight：20 parts of dimethomorph,
20 parts of cyazofamid, 8 parts of dispersant, 3 parts of wetting agent, 10 parts of disintegrant, 0.5 part of defoamer, 0.5 part of bonding
Agent, 2 parts of bleeding agent and 80 parts of flyash.
Preparation method includes the following steps：
S1, intercalation modifying is carried out to flyash by organic solvent；
S2, weighs each raw material components in dosage bunker by proportioning, mixes and stir evenly；
S3, adds water in dosage bunker, is uniformly mixed, and forms formulation material；
S4, coarse crushing is carried out by formulation material with high-speed shearing machine, enters back into two-stage sand mill fine grinding, forms suspending agent；
S5, is pumped into pressure spray drying tower by suspending agent and is dried, is granulated；
S6, the particle of pressure spray drying tower bottom output is detected, is sieved, measure after packaging and storage.
Wherein, intercalation modifying is carried out by organic solvent to flyash to include the following steps：
S101, by dimethyl sulfoxide (DMSO) and water in mass ratio 8:1 is mixed, and is carried out mechanical agitation at room temperature and is obtained diformazan
Base sulfoxide aqueous solution；
S102, in mass ratio 3:1 mixes flyash with dimethyl sulphoxide aqueous solution, carries out ultrasonic disperse, then passes through
Mechanical agitation forms mixed system, and it is 18h to control mixing time, and it is 65 DEG C to control whipping temp；
S103, by mixed system by centrifuging, dry 11h, it is compound to obtain flyash-dimethyl sulfoxide (DMSO) at 70 DEG C
Thing；
S104, roasts 2.1h at 900 DEG C by flyash-dimethylsulfide complex, obtains changing through intercalation
The flyash of property.
Through examining, moisture≤1.0%, fineness (passing through 1um) >=96%, suspensibility >=91%, persistent foamability (1min)
≤ 10ml, wetting time≤50s, substantially without dust, accelerated storage qualified stability.
Embodiment 4
The environmentally friendly powder granule of high osmosis, includes the raw material components of following parts by weight：30 parts of dimethomorph,
30 parts of cyazofamid, 15 parts of dispersant, 6 parts of wetting agent, 17 parts of disintegrant, 2 parts of defoamer, 2 parts of binding agent, 6
The bleeding agent and 160 parts of flyash of part.
Preparation method includes the following steps：
S1, intercalation modifying is carried out to flyash by organic solvent；
S2, weighs each raw material components in dosage bunker by proportioning, mixes and stir evenly；
S3, adds water in dosage bunker, is uniformly mixed, and forms formulation material；
S4, coarse crushing is carried out by formulation material with high-speed shearing machine, enters back into two-stage sand mill fine grinding, forms suspending agent；
S5, is pumped into pressure spray drying tower by suspending agent and is dried, is granulated；
S6, the particle of pressure spray drying tower bottom output is detected, is sieved, measure after packaging and storage.
Wherein, intercalation modifying is carried out by organic solvent to flyash to include the following steps：
S101, by dimethyl sulfoxide (DMSO) and water in mass ratio 10:1 is mixed, and is carried out mechanical agitation at room temperature and is obtained two
Methyl sulfoxide aqueous solution；
S102, in mass ratio 8:1 mixes flyash with dimethyl sulphoxide aqueous solution, carries out ultrasonic disperse, then passes through
Mechanical agitation forms mixed system, and it is 44h to control mixing time, and it is 40 DEG C to control whipping temp；
S103, by mixed system by centrifuging, dry 9h, it is compound to obtain flyash-dimethyl sulfoxide (DMSO) at 100 DEG C
Thing；
S104, roasts 1.8h at 1200 DEG C by flyash-dimethylsulfide complex, obtains the fine coal through intercalation modifying
Ash.
Through examining, moisture≤1.0%, fineness (passing through 1um) >=97%, suspensibility >=92%, persistent foamability (1min)
≤ 10ml, wetting time≤50s, substantially without dust, accelerated storage qualified stability.
Embodiment 5
The environmentally friendly powder granule of high osmosis, includes the raw material components of following parts by weight：25 parts of dimethomorph,
25 parts of cyazofamid, 10 parts of dispersant, 5 parts of wetting agent, 13 parts of disintegrant, 1 part of defoamer, 1 part of binding agent, 3
The bleeding agent and 120 parts of flyash of part.
Preparation method includes the following steps：
S1, intercalation modifying is carried out to flyash by organic solvent；
S2, weighs each raw material components in dosage bunker by proportioning, mixes and stir evenly；
S3, adds water in dosage bunker, is uniformly mixed, and forms formulation material；
S4, coarse crushing is carried out by formulation material with high-speed shearing machine, enters back into two-stage sand mill fine grinding, forms suspending agent；
S5, is pumped into pressure spray drying tower by suspending agent and is dried, is granulated；
S6, the particle of pressure spray drying tower bottom output is detected, is sieved, measure after packaging and storage.
Wherein, intercalation modifying is carried out by organic solvent to flyash to include the following steps：
S101, by dimethyl sulfoxide (DMSO) and water in mass ratio 9:1 is mixed, and is carried out mechanical agitation at room temperature and is obtained diformazan
Base sulfoxide aqueous solution；
S102, in mass ratio 6:1 mixes flyash with dimethyl sulphoxide aqueous solution, carries out ultrasonic disperse, then passes through
Mechanical agitation forms mixed system, and it is 30h to control mixing time, and it is 60 DEG C to control whipping temp；
S103, by mixed system by centrifuging, dry 11h, it is compound to obtain flyash-dimethyl sulfoxide (DMSO) at 85 DEG C
Thing；
S104, roasts 2h at 1000 DEG C by flyash-dimethylsulfide complex, obtains the fine coal through intercalation modifying
Ash.
Through examining, moisture≤1.0%, fineness (passing through 1um) >=97%, suspensibility >=92%, persistent foamability (1min)
≤ 10ml, wetting time≤40s, substantially without dust, accelerated storage qualified stability.
Test example 1：Permeability test
The present invention has found after measured using the compounding of dimethomorph and cyazofamid as active ingredient, adds after bleeding agent, oozes
Saturating power is remarkably reinforced, and the application is specifically illustrated using cabbage leaves epidermic method measure penetration example.
1st, test medicine：The dry suspending agent that embodiment 1~5 is prepared.
2nd, test method：Cabbage leaves epidermic method --- wild cabbage leaf epidermis separation is with reference to Walker methods, penetration measure ginseng
According to Zeng Xinnian methods.Using clear water as control.
3rd, test results and analysis
Result of the test is referring to table 1
1 cabbage leaves epidermic method of table measures the relation of time of penetration and concentration
In table numerical value represent penetrate the required time of penetration of leaf table (unit s), numerical value is smaller, represent penetration it is stronger.
From the results, it was seen that the penetration of various embodiments of the present invention is significantly stronger than control group.
In addition, field control effectiveness test shows, the environmentally friendly powder granule of high osmosis of the present invention is to the late blight of potato
There is good preventive effect with grape phytophthora root rot, prevention effect is substantially better than the dimethomorph of other forms and the compounding system of cyazofamid
Agent, is also significantly better than the effect that dimethomorph and cyazofamid are used alone.
The foregoing is only a preferred embodiment of the present invention, is not intended to limit the invention, for the skill of this area
For art personnel, the invention may be variously modified and varied.Within the spirit and principles of the invention, that is made any repaiies
Change, equivalent substitution, improvement etc., should all be included in the protection scope of the present invention.
Claims (6)
1. a kind of environmentally friendly powder granule of high osmosis, it is characterised in that include the raw material components of following parts by weight：5
~45 parts of dimethomorph, 5~45 parts of cyazofamid, 2~20 parts of dispersant, 1~8 part of wetting agent, 5~25 parts of disintegration
Agent, 0.2~3 part of defoamer, 0.1~3 part of binding agent, 0.5~8 part of bleeding agent and 20~200 parts of carrier, the load
Body is flyash, and the flyash passes through organic solvent intercalation modifying.
2. the environmentally friendly powder granule of high osmosis according to claim 1, it is characterised in that including following parts by weight
Several raw material components：20~30 parts of dimethomorph, 20~30 parts of cyazofamid, 8~15 parts of dispersant, 3~6 parts of wetting
Agent, 10~17 parts of disintegrant, 0.5~2 part of defoamer, 0.5~2 part of binding agent, 2~6 parts of bleeding agent and 80~160
The flyash of part.
3. the environmentally friendly powder granule of high osmosis according to claim 1, it is characterised in that including following parts by weight
Several raw material components：25 parts of dimethomorph, 25 parts of cyazofamid, 10 parts of dispersant, 5 parts of wetting agent, 13 parts of disintegration
Agent, 1 part of defoamer, 1 part of binding agent, 3 parts of bleeding agent and 120 parts of flyash.
4. according to the environmentally friendly powder granule of claims 1 to 3 any one of them high osmosis, it is characterised in that
The bleeding agent is polyether modified siloxane, ethyoxyl is modified poly- trisiloxanes, sulfosuccinate di-sec-octyl sodium salt and
At least one of nonylphenol polyoxyethylene ether；
The dispersant is lignosulfonates, phenethyl phenol polyethenoxy ether, N methyl taurine sodium salt, castor oil polyoxy second
At least one of alkene ether, vinylpyrrolidone and carboxymethyl cellulose；
The wetting agent is dehydration mountain alcohol fatty acid ester, alkyl amine group taurate, sulfated lauryl alcohol and di-2-ethylhexylphosphine oxide naphthalene sulphur
At least one of sour sodium；
The disintegrant is at least one of magnesium chloride, urea, sodium sulphate and carboxy-propyl cellulose；
The binding agent is at least one of polyvinyl alcohol, macrogol, sodium metasilicate and gelatin；
The defoamer is at least one of fatty alcohol of organic silicone and C8-10.
5. the preparation method of the environmentally friendly powder granule of Claims 1 to 4 any one of them high osmosis, its feature exist
In the preparation method includes the following steps：
S1, intercalation modifying is carried out to flyash by organic solvent；
S2, weighs each raw material components in dosage bunker by proportioning, mixes and stir evenly；
S3, adds water in dosage bunker, is uniformly mixed, and forms formulation material；
S4, coarse crushing is carried out by formulation material with high-speed shearing machine, enters back into two-stage sand mill fine grinding, forms suspending agent；
S5, is pumped into pressure spray drying tower by suspending agent and is dried, is granulated；
S6, the particle of pressure spray drying tower bottom output is detected, is sieved, measure after packaging and storage.
6. the preparation method of the environmentally friendly powder granule of high osmosis according to claim 5, it is characterised in that to powder
Coal ash carries out intercalation modifying by organic solvent and includes the following steps：
S101, by dimethyl sulfoxide (DMSO) with water in mass ratio (7~11):1 is mixed, and is carried out mechanical agitation at room temperature and is obtained two
Methyl sulfoxide aqueous solution；
S102, in mass ratio (1~10):1 mixes flyash with dimethyl sulphoxide aqueous solution, carries out ultrasonic disperse, Ran Houtong
Cross mechanical agitation and form mixed system, it is 12~50h to control mixing time, and it is 35~80 DEG C to control whipping temp；
S103, by mixed system by centrifuging, dry 7~15h, obtains flyash-dimethyl sulfoxide (DMSO) at 55~120 DEG C
Compound；
S104, roasts 1.5~2.5h by flyash-dimethylsulfide complex at 700~1350 DEG C, obtains through intercalation modifying
Flyash.
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| CN101647447A (en) * | 2009-07-06 | 2010-02-17 | 东莞市瑞德丰生物科技有限公司 | Sterilizing composition |
| CN101690484A (en) * | 2009-08-24 | 2010-04-07 | 陕西标正作物科学有限公司 | Suspending agent compounded by dimethomorph and cyazofamid as well as preparation method thereof |
| CN101984815A (en) * | 2010-07-15 | 2011-03-16 | 江阴苏利科技有限公司 | Fluazinam dry suspending agent and preparation method thereof |
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2017
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