CN108026450B - 将生物质转化成液态烃物质 - Google Patents

将生物质转化成液态烃物质 Download PDF

Info

Publication number
CN108026450B
CN108026450B CN201680051445.XA CN201680051445A CN108026450B CN 108026450 B CN108026450 B CN 108026450B CN 201680051445 A CN201680051445 A CN 201680051445A CN 108026450 B CN108026450 B CN 108026450B
Authority
CN
China
Prior art keywords
biomass
catalyst
product
hydropyrolysis
hydroconversion
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CN201680051445.XA
Other languages
English (en)
Chinese (zh)
Other versions
CN108026450A (zh
Inventor
V·N·乌拉德
L·N·奇尔克桑达拉拉詹
A·A·德尔帕乔
M·R·潘查格努拉
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shell Internationale Research Maatschappij BV
Original Assignee
Shell Internationale Research Maatschappij BV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shell Internationale Research Maatschappij BV filed Critical Shell Internationale Research Maatschappij BV
Publication of CN108026450A publication Critical patent/CN108026450A/zh
Application granted granted Critical
Publication of CN108026450B publication Critical patent/CN108026450B/zh
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Images

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G1/00—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
    • C10G1/06—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal by destructive hydrogenation
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G1/00—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
    • C10G1/08—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal with moving catalysts
    • C10G1/086—Characterised by the catalyst used
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G3/00—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
    • C10G3/50—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids in the presence of hydrogen, hydrogen donors or hydrogen generating compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
    • C10K1/00—Purifying combustible gases containing carbon monoxide
    • C10K1/002—Removal of contaminants
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
    • C10K1/00—Purifying combustible gases containing carbon monoxide
    • C10K1/002—Removal of contaminants
    • C10K1/003—Removal of contaminants of acid contaminants, e.g. acid gas removal
    • C10K1/004—Sulfur containing contaminants, e.g. hydrogen sulfide
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
    • C10K3/00—Modifying the chemical composition of combustible gases containing carbon monoxide to produce an improved fuel, e.g. one of different calorific value, which may be free from carbon monoxide
    • C10K3/02—Modifying the chemical composition of combustible gases containing carbon monoxide to produce an improved fuel, e.g. one of different calorific value, which may be free from carbon monoxide by catalytic treatment
    • C10K3/04—Modifying the chemical composition of combustible gases containing carbon monoxide to produce an improved fuel, e.g. one of different calorific value, which may be free from carbon monoxide by catalytic treatment reducing the carbon monoxide content, e.g. water-gas shift [WGS]
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1011—Biomass
    • C10G2300/1014—Biomass of vegetal origin
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/20—Characteristics of the feedstock or the products
    • C10G2300/201—Impurities
    • C10G2300/202—Heteroatoms content, i.e. S, N, O, P
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/20—Characteristics of the feedstock or the products
    • C10G2300/201—Impurities
    • C10G2300/207—Acid gases, e.g. H2S, COS, SO2, HCN
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/70—Catalyst aspects
    • C10G2300/703—Activation
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/70—Catalyst aspects
    • C10G2300/708—Coking aspect, coke content and composition of deposits
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/02—Gasoline
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P30/00—Technologies relating to oil refining and petrochemical industry
    • Y02P30/20—Technologies relating to oil refining and petrochemical industry using bio-feedstock

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Combustion & Propulsion (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
CN201680051445.XA 2015-09-07 2016-09-05 将生物质转化成液态烃物质 Active CN108026450B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
IN4737CH2015 2015-09-07
IN4737/CHE/2015 2015-09-07
PCT/EP2016/070872 WO2017042129A1 (en) 2015-09-07 2016-09-05 Conversion of biomass into a liquid hydrocarbon material

Publications (2)

Publication Number Publication Date
CN108026450A CN108026450A (zh) 2018-05-11
CN108026450B true CN108026450B (zh) 2020-11-27

Family

ID=56853656

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201680051445.XA Active CN108026450B (zh) 2015-09-07 2016-09-05 将生物质转化成液态烃物质

Country Status (9)

Country Link
US (1) US11174438B2 (https=)
EP (1) EP3347438B1 (https=)
CN (1) CN108026450B (https=)
AU (1) AU2016320326B2 (https=)
BR (1) BR112018004517B1 (https=)
CA (1) CA2995649C (https=)
DK (1) DK3347438T5 (https=)
MY (1) MY189091A (https=)
WO (1) WO2017042129A1 (https=)

Families Citing this family (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DK3198075T3 (en) * 2014-09-22 2019-04-01 Huntsman Int Llc PROCEDURE FOR TREATING BLACK BLOOD
MY196728A (en) 2015-11-23 2023-05-03 Shell Int Research Conversion of biomass into a liquid hydrocarbon material
MY189381A (en) 2015-11-23 2022-02-08 Shell Int Research Conversion of biomass into a liquid hydrocarbon material
WO2017202837A1 (en) 2016-05-25 2017-11-30 Shell Internationale Research Maatschappij B.V. Conversion of biomass into a liquid hydrocarbon material
US10647924B2 (en) 2016-08-04 2020-05-12 Shell Oil Company Biomass conversion process
CN109913256B (zh) * 2019-02-01 2021-07-02 易高环保能源研究院有限公司 利用高酸值生物性油脂制备燃料的方法及系统
CN110330996B (zh) * 2019-07-19 2021-10-29 华东理工大学 矿化垃圾裂解油加氢裂化的方法及装置
US11639472B2 (en) 2020-04-22 2023-05-02 Chevron U.S.A. Inc. Circular economy for plastic waste to polyethylene via oil refinery with filtering and metal oxide treatment of pyrolysis oil
CN115427536A (zh) 2020-04-22 2022-12-02 雪佛龙美国公司 经由炼油厂通过过滤和金属氧化物处理热解油来将废塑料转化成聚丙烯的循环经济
US11590485B2 (en) * 2021-01-13 2023-02-28 Saudi Arabian Oil Company Process for modifying a hydroprocessing catalyst
EP4277965A1 (en) 2021-01-18 2023-11-22 Topsoe A/S <sup2/>? <sub2/>?2?process and plant for producing hydrocarbons from a solid renewable feedstock with reduced co-footprint
CN115491235B (zh) * 2022-09-15 2024-10-18 东南大学 一种生物质水相制航油有机废液的能量利用方法
WO2024151690A2 (en) 2023-01-13 2024-07-18 Shell Usa, Inc. Catalyst preparation
WO2025136847A1 (en) * 2023-12-18 2025-06-26 Shell Usa, Inc. Renewable naphthenic base oil
US20260062622A1 (en) * 2024-08-28 2026-03-05 Chevron U.S.A. Inc. Method for hydrodeoxygenation of feedstocks of biological origin

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1339986A (zh) * 1999-02-15 2002-03-13 国际壳牌研究有限公司 加氢处理催化剂的制备
CN103038321A (zh) * 2010-06-15 2013-04-10 瓦斯技术研究所 由生物质制备甲烷的方法
CN103930524A (zh) * 2011-11-14 2014-07-16 国际壳牌研究有限公司 制备烃的方法
WO2015114008A1 (en) * 2014-01-28 2015-08-06 Shell Internationale Research Maatschappij B.V. Conversion of biomass or residual waste material to biofuels

Family Cites Families (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA1283880C (en) 1987-05-07 1991-05-07 Dave A. Berg Method and apparatus for rapid thermal processing
US5961786A (en) 1990-01-31 1999-10-05 Ensyn Technologies Inc. Apparatus for a circulating bed transport fast pyrolysis reactor system
US5215954A (en) 1991-07-30 1993-06-01 Cri International, Inc. Method of presulfurizing a hydrotreating, hydrocracking or tail gas treating catalyst
US6281158B1 (en) 1999-02-15 2001-08-28 Shell Oil Company Preparation of a co-containing hydrotreating catalyst precursor and catalyst
US8084655B2 (en) * 2007-06-15 2011-12-27 E. I. Du Pont De Nemours And Company Catalytic process for converting renewable resources into paraffins for use as diesel blending stocks
AU2010230279B2 (en) * 2009-03-30 2013-10-10 Shell Internationale Research Maatschappij B.V. Process for producing purified synthesis gas
US8492600B2 (en) 2009-04-07 2013-07-23 Gas Technology Institute Hydropyrolysis of biomass for producing high quality fuels
US9447328B2 (en) * 2009-04-07 2016-09-20 Gas Technology Institute Hydropyrolysis of biomass for producing high quality liquid fuels
AU2012258767B2 (en) * 2011-05-23 2017-01-05 Virent, Inc. Production of chemicals and fuels from biomass
BR112014008917B1 (pt) 2011-10-12 2024-02-27 Basf Corporation Catalisador, gotícula, processo para preparação de um catalisador, processo para a hidrogenação de um material graxo insaturado e uso de um catalisador
WO2013064539A1 (en) 2011-11-01 2013-05-10 Shell Internationale Research Maatschappij B.V. Paraffin wax
PH12014500895A1 (en) 2011-11-11 2014-02-06 Basf Se Thickener containing at least one cationic polymer
US20140230317A1 (en) * 2013-02-21 2014-08-21 Chevron U.S.A. Inc. In-Situ Upgrading Of Biomass Pyrolysis Vapor Using Water-Gas Shift And Hydroprocessing
AU2015282725B2 (en) * 2014-07-01 2017-11-30 Shell Internationale Research Maatschappij B.V. Conversion of solid biomass into a liquid hydrocarbon material

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1339986A (zh) * 1999-02-15 2002-03-13 国际壳牌研究有限公司 加氢处理催化剂的制备
CN103038321A (zh) * 2010-06-15 2013-04-10 瓦斯技术研究所 由生物质制备甲烷的方法
CN103930524A (zh) * 2011-11-14 2014-07-16 国际壳牌研究有限公司 制备烃的方法
WO2015114008A1 (en) * 2014-01-28 2015-08-06 Shell Internationale Research Maatschappij B.V. Conversion of biomass or residual waste material to biofuels

Also Published As

Publication number Publication date
CN108026450A (zh) 2018-05-11
CA2995649C (en) 2023-12-19
BR112018004517B1 (pt) 2022-06-14
MY189091A (en) 2022-01-25
US20180245000A1 (en) 2018-08-30
CA2995649A1 (en) 2017-03-16
BR112018004517A2 (https=) 2018-10-02
EP3347438A1 (en) 2018-07-18
EP3347438B1 (en) 2020-02-12
DK3347438T5 (da) 2020-06-02
US11174438B2 (en) 2021-11-16
WO2017042129A1 (en) 2017-03-16
AU2016320326B2 (en) 2019-05-02
AU2016320326A1 (en) 2018-03-08
DK3347438T3 (da) 2020-03-30

Similar Documents

Publication Publication Date Title
CN108026450B (zh) 将生物质转化成液态烃物质
AU2016325487B2 (en) Conversion of biomass into methane
CN108291152B (zh) 生物质向液态烃物质的转化
CN109153920B (zh) 生物质向液体烃材料的转化
CN108350365B (zh) 生物质向液态烃材料的转化
CN106471099A (zh) 固体生物质到液体烃材料的转化
CA3004679C (en) Conversion of biomass into a liquid hydrocarbon material

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant