CN108018737A - A kind of fireproof flame-retardation wallpaper - Google Patents

A kind of fireproof flame-retardation wallpaper Download PDF

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Publication number
CN108018737A
CN108018737A CN201711298869.9A CN201711298869A CN108018737A CN 108018737 A CN108018737 A CN 108018737A CN 201711298869 A CN201711298869 A CN 201711298869A CN 108018737 A CN108018737 A CN 108018737A
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China
Prior art keywords
present
wallpaper
following parts
fiber
basalt fibre
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CN201711298869.9A
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Chinese (zh)
Inventor
姚景城
陈松
周振威
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Individual
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Priority to CN201711298869.9A priority Critical patent/CN108018737A/en
Publication of CN108018737A publication Critical patent/CN108018737A/en
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    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H13/00—Pulp or paper, comprising synthetic cellulose or non-cellulose fibres or web-forming material
    • D21H13/10—Organic non-cellulose fibres
    • D21H13/20—Organic non-cellulose fibres from macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D21H13/24—Polyesters
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H13/00—Pulp or paper, comprising synthetic cellulose or non-cellulose fibres or web-forming material
    • D21H13/36—Inorganic fibres or flakes
    • D21H13/38—Inorganic fibres or flakes siliceous
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/03—Non-macromolecular organic compounds
    • D21H17/05—Non-macromolecular organic compounds containing elements other than carbon and hydrogen only
    • D21H17/06—Alcohols; Phenols; Ethers; Aldehydes; Ketones; Acetals; Ketals
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/03—Non-macromolecular organic compounds
    • D21H17/05—Non-macromolecular organic compounds containing elements other than carbon and hydrogen only
    • D21H17/14—Carboxylic acids; Derivatives thereof
    • D21H17/15—Polycarboxylic acids, e.g. maleic acid
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/20—Macromolecular organic compounds
    • D21H17/21—Macromolecular organic compounds of natural origin; Derivatives thereof
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/20—Macromolecular organic compounds
    • D21H17/21—Macromolecular organic compounds of natural origin; Derivatives thereof
    • D21H17/22—Proteins
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/20—Macromolecular organic compounds
    • D21H17/21—Macromolecular organic compounds of natural origin; Derivatives thereof
    • D21H17/24—Polysaccharides
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/20—Macromolecular organic compounds
    • D21H17/33—Synthetic macromolecular compounds
    • D21H17/34—Synthetic macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D21H17/36—Polyalkenyalcohols; Polyalkenylethers; Polyalkenylesters
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/63—Inorganic compounds
    • D21H17/66—Salts, e.g. alums
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
    • D21H21/34—Ignifugeants
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
    • D21H21/38—Corrosion-inhibiting agents or anti-oxidants
    • E—FIXED CONSTRUCTIONS
    • E04—BUILDING
    • E04F—FINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
    • E04F13/00—Coverings or linings, e.g. for walls or ceilings
    • E04F13/002—Coverings or linings, e.g. for walls or ceilings made of webs, e.g. of fabrics, or wallpaper, used as coverings or linings

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Architecture (AREA)
  • Civil Engineering (AREA)
  • Structural Engineering (AREA)
  • Synthetic Leather, Interior Materials Or Flexible Sheet Materials (AREA)
  • Paper (AREA)

Abstract

The present invention provides a kind of fireproof flame-retardation wallpaper, includes the component of following parts by weight：Polyvinyl acetate powder 11 17, D-lactic acid caprolactone nanofiber 23 34, antioxidant 6 11, compatilizer 27, fire retardant 0.8 3.4, reed fiber 15 24, zein fiber 23 39, basalt fibre 14 29, Chinese yam slurry 57 169；The soluble solid content of the Chinese yam slurry is 39% 48%；The filament diameter of the basalt fibre is 0.25 0.45um, and the filament length of the basalt fibre is 6 12mm.Functionalization is dissolved into wallpaper by the present invention, meets the requirement of application and development of the wallpaper in modern house.

Description

A kind of fireproof flame-retardation wallpaper
Technical field
The present invention relates to decorative materials technology, and in particular to a kind of fireproof flame-retardation wallpaper.
Background technology
Ornament materials is the material base of building decoration engineering, is the actual effect of decorative engineering and the color of ornament materials Color, texture and the specific of texture show, and decorative material for internal wall is as part important in modern house decorations, Account for the largest percentage in overall house ornamentation.Wall decorative material currently on the market include coating, wallpaper, ceramics, glass, minute surface, Diatom ooze etc., species is enriched, and advantage is different, can flexibly be selected according to each room function and environment, numerous materials wherein more than wallpaper With the surface lining that most wide, kind are most in material, be widely used in restaurant in room interior wall and public place, market, On the wall in hotel.
Wallpaper is increasingly becoming decorate home material since the 1980s, is the quite extensive indoor dress of current application Exterior material.Initially originating from drawing on the paper Tang Dynasty, the rear wallpaper for just evolving into Modern Significance through Britain's production printing again, it develops Process successively experienced paper, scribble on paper, blistering paper, calico paper, the process to version cruddy paper, special process paper.It is but existing Wallpaper normally only there is single dicoration, mostly using artificial chemical materials, lack other comprehensive performances, it is difficult to meet Requirement of the people for wallpaper higher.
The content of the invention
In view of this, the present invention provides a kind of fireproof flame-retardation wallpaper, and the present invention is upgraded wallpaper from rudimentary to advanced, Comprehensive comprehensive performance is expanded to from single dicoration, material will also become from artificial chemical materials turns to new type natural environmental protection section Energy material, and functionalization is dissolved into wallpaper, meet the requirement of application and development of the wallpaper in modern house.
The technical scheme is that：A kind of fireproof flame-retardation wallpaper, it is characterised in that include the group of following parts by weight Point：Polyvinyl acetate powder 11-17, D-lactic acid-caprolactone nanofiber 23-34, antioxidant 6-11, compatilizer 2-7, Fire retardant 0.8-3.4, reed fiber 15-24, zein fiber 23-39, basalt fibre 14-29, Chinese yam slurry 57-169； The soluble solid content of the Chinese yam slurry is 39%-48%；The filament diameter of the basalt fibre is 0.25- 0.45um, the filament length of the basalt fibre is 6-12mm..
Polyvinyl acetate powder of the present invention, D-lactic acid-caprolactone nanofiber, reed fiber, zein fiber, Basalt fibre, Chinese yam slurry can be prepared by any prior art.
Further, the compatilizer includes the component of following parts by weight：Chitin fiber element 7-16, mannitol 0.2- 0.7th, potassium chlorate 0.03-0.09, sodium potassium tartrate tetrahydrate 1-6, gelatin 4-11, polyvinyl alcohol 0.8-2.2；The compatilizer can be notable The compatibility between inorfil and organic fiber in the present invention is improved, while effectively reduces distributing for raw material components of the present invention Property, make still to be able to be stabilized under the action of light and heat in existing wallpaper preparation process without easily distributing, keep this hair The bright performance of itself.
Further, the fire retardant includes the component of following parts by weight：Cr2AlC ceramic powders 13-24, nanometer SAPO-31 molecular sieves 7-12.The average particle size of the fire retardant is 310-400um.
The Cr2AlC ceramic powders can be compounded with nano SAPO-31 molecular sieve synergistic, significantly improve the fire-retardant fireproof of wallpaper Performance.The Cr2AlC ceramic powders can be prepared with nano SAPO-31 molecular sieve by any prior art.
Further, the antioxidant includes the component of following parts by weight：Rosmarinus officinalis extract 1.3-3.9, the leaf of bamboo Extract 1.8-4.7, myricetin 3.7-5.1.The antioxidant of the invention for using plant component, safety and environmental protection, and can The compatibility with other components of the present invention is improved, improves the service life of the present invention.
In the present invention, it is combined using plant fiber with organic fiber, wallpaper can be assigned by compounding the other components of the present invention New performance；Vegetalitas antioxidant is added in the present invention, be ensure that anti-aging property, is significantly improved service life；Make With fire retardant, greatly improve the fire retardant performance of the wallpaper of preparation；Inventive formulation is simple, and raw material are chosen conveniently, Use cost is low, and the wall paper products performance produced is stablized, and fire retardant performance is good；The present invention has excellent comprehensive performance, It can be made by the preparation process of this area any prior art, meet wanting for application and development of the wallpaper in modern house Ask.
Embodiment
With reference to embodiment, the present invention is described in further detail, but the implementation of the present invention is not limited to this.
Embodiment 1
A kind of fireproof flame-retardation wallpaper, it is characterised in that include the component of following parts by weight：It is polyvinyl acetate powder 11, left-handed Lactic acid-caprol acton nanofiber 23, antioxidant 6, compatilizer 2, fire retardant 0.8, reed fiber 15, zein fiber 23, the Black Warrior Rock fiber 14, Chinese yam slurry 57；The soluble solid content of the Chinese yam slurry is 39%；The list of the basalt fibre The a diameter of 0.25um of silk, the filament length of the basalt fibre is 6mm.
Polyvinyl acetate powder of the present invention, D-lactic acid-caprolactone nanofiber, reed fiber, zein fiber, Basalt fibre, Chinese yam slurry can be prepared by any prior art.
Further, the compatilizer includes the component of following parts by weight：Chitin fiber element 7, mannitol 0.2, chlorine Sour potassium 0.03, sodium potassium tartrate tetrahydrate 1, gelatin 4, polyvinyl alcohol 0.8；The compatilizer can significantly improve inorfil in the present invention Compatibility between organic fiber, while the sporadic of raw material components of the present invention is effectively reduced, make to prepare in existing wallpaper It still is able to be stabilized without easily distributing under the action of light and heat in technique, keeps the performance of itself of the invention.
Further, the fire retardant includes the component of following parts by weight：Cr2AlC ceramic powders 13, nanometer SAPO-31 Molecular sieve 7.The average particle size of the fire retardant is 310um.
The Cr2AlC ceramic powders can be compounded with nano SAPO-31 molecular sieve synergistic, significantly improve the fire-retardant fireproof of wallpaper Performance.The Cr2AlC ceramic powders can be prepared with nano SAPO-31 molecular sieve by any prior art.
Further, the antioxidant includes the component of following parts by weight：Rosmarinus officinalis extract 1.3, leaf of bamboo extraction Thing 1.8, myricetin 3.7.The present invention uses the antioxidant of plant component, safety and environmental protection, and can improve and the present invention Other components compatibility, improve the present invention service life.
In the present invention, it is combined using plant fiber with organic fiber, wallpaper can be assigned by compounding the other components of the present invention New performance；Vegetalitas antioxidant is added in the present invention, be ensure that anti-aging property, is significantly improved service life；Make With fire retardant, greatly improve the fire retardant performance of the wallpaper of preparation；Inventive formulation is simple, and raw material are chosen conveniently, Use cost is low, and the wall paper products performance produced is stablized, and fire retardant performance is good；The present invention has excellent comprehensive performance, It can be made by the preparation process of this area any prior art, meet wanting for application and development of the wallpaper in modern house Ask.
The preferable preparation process of the present embodiment is：By polyvinyl acetate powder, D-lactic acid-caprolactone nanofiber, reed Reed fiber, zein fiber, basalt fibre, Chinese yam slurry parts by weights number after mixing and being beaten to 40-55 ° of SR than sending to mixing Stock tank, adds antioxidant, compatilizer, fire retardant, is uniformly mixing to obtain slurry by ratio of weight and the number of copies；Into closed paper injection Cylinder mould machine carries out dehydration forming, and speed 65m/min, forms the l Water Paper page containing wallpaper line skin texture；The slurry enters paper machine Online concentration be 0.22%；On its cylindrical type skeleton, circumferential uniform welding is arranged with not rotary screen cage in the cylinder mould machine Become rusty steel steel wire, and stainless steel gauge of wire is 0.2mm, and spacing is 1.2mm between steel wire；Circle between rotary screen cage and outer arcuate plate The dimensional parameters in net groove ox horn road are：Rotary screen cage import and the spacing of outer arcuate plate are 55mm, rotary screen cage bottom and arc panel Between spacing be 42mm, rotary screen cage outlet and the spacing between arc panel are 32mm；By above-mentioned l Water Paper page through press dewatering and drying cylinder It is dry, obtain finished product.
Embodiment 2
A kind of fireproof flame-retardation wallpaper, it is characterised in that include the component of following parts by weight：It is polyvinyl acetate powder 17, left-handed Lactic acid-caprol acton nanofiber 34, antioxidant 11, compatilizer 7, fire retardant 3.4, reed fiber 24, zein fiber 39, the Black Warrior Rock fiber 29, Chinese yam slurry 169；The soluble solid content of the Chinese yam slurry is 48%；The list of the basalt fibre The a diameter of 0.45um of silk, the filament length of the basalt fibre is 12mm..
Polyvinyl acetate powder of the present invention, D-lactic acid-caprolactone nanofiber, reed fiber, zein fiber, Basalt fibre, Chinese yam slurry can be prepared by any prior art.
Further, the compatilizer includes the component of following parts by weight：Chitin fiber element 16, mannitol 0.7, chlorine Sour potassium 0.09, sodium potassium tartrate tetrahydrate 6, gelatin 11, polyvinyl alcohol 2.2；The compatilizer can significantly improve inorganic fibre in the present invention Compatibility between dimension and organic fiber, while the sporadic of raw material components of the present invention is effectively reduced, make in existing wallpaper system It still is able to be stabilized under the action of light and heat without easily distributing in standby technique, keeps the performance of itself of the invention.
Further, the fire retardant includes the component of following parts by weight：Cr2AlC ceramic powders 24, nanometer SAPO-31 Molecular sieve 12.The average particle size of the fire retardant is 400um.
The Cr2AlC ceramic powders can be compounded with nano SAPO-31 molecular sieve synergistic, significantly improve the fire-retardant fireproof of wallpaper Performance.The Cr2AlC ceramic powders can be prepared with nano SAPO-31 molecular sieve by any prior art.
Further, the antioxidant includes the component of following parts by weight：Rosmarinus officinalis extract 3.9, leaf of bamboo extraction Thing 4.7, myricetin 5.1.The present invention uses the antioxidant of plant component, safety and environmental protection, and can improve and the present invention Other components compatibility, improve the present invention service life.
Embodiment 3
A kind of fireproof flame-retardation wallpaper, it is characterised in that include the component of following parts by weight：It is polyvinyl acetate powder 14, left-handed Lactic acid-caprol acton nanofiber 28.5, antioxidant 8.5, compatilizer 4.5, fire retardant 2.1, reed fiber 19.5, corn are fine Dimension 31, basalt fibre 21.5, Chinese yam slurry 113；The soluble solid content of the Chinese yam slurry is 43.5%；It is described profound The filament diameter of military rock fiber is 0.35um, and the filament length of the basalt fibre is 9mm..
Polyvinyl acetate powder of the present invention, D-lactic acid-caprolactone nanofiber, reed fiber, zein fiber, Basalt fibre, Chinese yam slurry can be prepared by any prior art.
Further, the compatilizer includes the component of following parts by weight：Chitin fiber element 9, mannitol 0.4, chlorine Sour potassium 0.05, sodium potassium tartrate tetrahydrate 2, gelatin 7, polyvinyl alcohol 1.8；The compatilizer can significantly improve inorfil in the present invention Compatibility between organic fiber, while the sporadic of raw material components of the present invention is effectively reduced, make to prepare in existing wallpaper It still is able to be stabilized without easily distributing under the action of light and heat in technique, keeps the performance of itself of the invention.
Further, the fire retardant includes the component of following parts by weight：Cr2AlC ceramic powders 18.5, nanometer SAPO- 31 molecular sieves 9.5.The average particle size of the fire retardant is 355um.
The Cr2AlC ceramic powders can be compounded with nano SAPO-31 molecular sieve synergistic, significantly improve the fire-retardant fireproof of wallpaper Performance.The Cr2AlC ceramic powders can be prepared with nano SAPO-31 molecular sieve by any prior art.
Further, the antioxidant includes the component of following parts by weight：Rosmarinus officinalis extract 2.6, leaf of bamboo extraction Thing 3.25, myricetin 4.4.The present invention uses the antioxidant of plant component, safety and environmental protection, and can improve and the present invention Other components compatibility, improve the present invention service life.
Embodiment 4
A kind of fireproof flame-retardation wallpaper, it is characterised in that include the component of following parts by weight：It is polyvinyl acetate powder 15, left-handed Lactic acid-caprol acton nanofiber 30, antioxidant 9, compatilizer 6, fire retardant 3.2, reed fiber 22, zein fiber 25, the Black Warrior Rock fiber 20, Chinese yam slurry 70；The soluble solid content of the Chinese yam slurry is 42%；The monofilament of the basalt fibre A diameter of 0.3um, the filament length of the basalt fibre is 10mm..
Polyvinyl acetate powder of the present invention, D-lactic acid-caprolactone nanofiber, reed fiber, zein fiber, Basalt fibre, Chinese yam slurry can be prepared by any prior art.
Further, the compatilizer includes the component of following parts by weight：Chitin fiber element 9, mannitol 0.3, chlorine Sour potassium 0.07, sodium potassium tartrate tetrahydrate 2, gelatin 6, polyvinyl alcohol 1；The compatilizer can significantly improve in the present invention inorfil with Compatibility between organic fiber, while the sporadic of raw material components of the present invention is effectively reduced, make to prepare work in existing wallpaper It still is able to be stabilized without easily distributing under the action of light and heat in skill, keeps the performance of itself of the invention.
Further, the fire retardant includes the component of following parts by weight：Cr2AlC ceramic powders 15, nanometer SAPO-31 Molecular sieve 8.The average particle size of the fire retardant is 330um.
The Cr2AlC ceramic powders can be compounded with nano SAPO-31 molecular sieve synergistic, significantly improve the fire-retardant fireproof of wallpaper Performance.The Cr2AlC ceramic powders can be prepared with nano SAPO-31 molecular sieve by any prior art.
Further, the antioxidant includes the component of following parts by weight：Rosmarinus officinalis extract 1.5, leaf of bamboo extraction Thing 3, myricetin 4.The present invention use plant component antioxidant, safety and environmental protection, and can improve with the present invention its The compatibility of its component, improves the service life of the present invention.
Embodiment 5
A kind of fireproof flame-retardation wallpaper, it is characterised in that include the component of following parts by weight：It is polyvinyl acetate powder 13, left-handed Lactic acid-caprol acton nanofiber 25, antioxidant 7, compatilizer 3, fire retardant 1, reed fiber 17, zein fiber 30, basalt Fiber 27, Chinese yam slurry 120；The soluble solid content of the Chinese yam slurry is 47%；The monofilament of the basalt fibre is straight Footpath is 0.4um, and the filament length of the basalt fibre is 8mm.
Polyvinyl acetate powder of the present invention, D-lactic acid-caprolactone nanofiber, reed fiber, zein fiber, Basalt fibre, Chinese yam slurry can be prepared by any prior art.
Further, the compatilizer includes the component of following parts by weight：Chitin fiber element 14, mannitol 0.6, chlorine Sour potassium 0.04, sodium potassium tartrate tetrahydrate 5, gelatin 9, polyvinyl alcohol 2；The compatilizer can significantly improve in the present invention inorfil with Compatibility between organic fiber, while the sporadic of raw material components of the present invention is effectively reduced, make to prepare work in existing wallpaper It still is able to be stabilized without easily distributing under the action of light and heat in skill, keeps the performance of itself of the invention.
Further, the fire retardant includes the component of following parts by weight：Cr2AlC ceramic powders 22, nanometer SAPO-31 Molecular sieve 11.The average particle size of the fire retardant is 376um.
The Cr2AlC ceramic powders can be compounded with nano SAPO-31 molecular sieve synergistic, significantly improve the fire-retardant fireproof of wallpaper Performance.The Cr2AlC ceramic powders can be prepared with nano SAPO-31 molecular sieve by any prior art.
Further, the antioxidant includes the component of following parts by weight：Rosmarinus officinalis extract 2, bamboo extractive 2nd, myricetin 4.7.The present invention use plant component antioxidant, safety and environmental protection, and can improve with the present invention its The compatibility of its component, improves the service life of the present invention.
Comparative example 1
A kind of fireproof flame-retardation wallpaper, it is characterised in that include the component of following parts by weight：It is polyvinyl acetate powder 14, left-handed Lactic acid-caprol acton nanofiber 28.5, antioxidant 8.5, compatilizer 4.5, reed fiber 19.5, zein fiber 31, basalt Fiber 21.5, Chinese yam slurry 113；The soluble solid content of the Chinese yam slurry is 43.5%；The list of the basalt fibre The a diameter of 0.35um of silk, the filament length of the basalt fibre is 9mm..
Polyvinyl acetate powder of the present invention, D-lactic acid-caprolactone nanofiber, reed fiber, zein fiber, Basalt fibre, Chinese yam slurry can be prepared by any prior art.
Further, the compatilizer includes the component of following parts by weight：Chitin fiber element 9, mannitol 0.4, chlorine Sour potassium 0.05, sodium potassium tartrate tetrahydrate 2, gelatin 7, polyvinyl alcohol 1.8；The compatilizer can significantly improve inorfil in the present invention Compatibility between organic fiber, while the sporadic of raw material components of the present invention is effectively reduced, make to prepare in existing wallpaper It still is able to be stabilized without easily distributing under the action of light and heat in technique, keeps the performance of itself of the invention.
Further, the antioxidant includes the component of following parts by weight：Rosmarinus officinalis extract 2.6, leaf of bamboo extraction Thing 3.25, myricetin 4.4.The present invention uses the antioxidant of plant component, safety and environmental protection, and can improve and the present invention Other components compatibility, improve the present invention service life.
Comparative example 2
A kind of fireproof flame-retardation wallpaper, it is characterised in that include the component of following parts by weight：It is polyvinyl acetate powder 15, left-handed Lactic acid-caprol acton nanofiber 30, compatilizer 6, fire retardant 3.2, reed fiber 22, zein fiber 25, basalt fibre 20, mountain Medicine slurry material 70；The soluble solid content of the Chinese yam slurry is 42%；The filament diameter of the basalt fibre is 0.3um, The filament length of the basalt fibre is 10mm..
Polyvinyl acetate powder of the present invention, D-lactic acid-caprolactone nanofiber, reed fiber, zein fiber, Basalt fibre, Chinese yam slurry can be prepared by any prior art.
Further, the compatilizer includes the component of following parts by weight：Chitin fiber element 9, mannitol 0.3, chlorine Sour potassium 0.07, sodium potassium tartrate tetrahydrate 2, gelatin 6, polyvinyl alcohol 1；The compatilizer can significantly improve in the present invention inorfil with Compatibility between organic fiber, while the sporadic of raw material components of the present invention is effectively reduced, make to prepare work in existing wallpaper It still is able to be stabilized without easily distributing under the action of light and heat in skill, keeps the performance of itself of the invention.
Further, the fire retardant includes the component of following parts by weight：Cr2AlC ceramic powders 15, nanometer SAPO-31 Molecular sieve 8.The average particle size of the fire retardant is 330um.
The Cr2AlC ceramic powders can be compounded with nano SAPO-31 molecular sieve synergistic, significantly improve the fire-retardant fireproof of wallpaper Performance.The Cr2AlC ceramic powders can be prepared with nano SAPO-31 molecular sieve by any prior art.
Performance test
The parameters such as all embodiments of the invention, the fire resistance of comparative example, tensile index are detected by relevant national standard method, The material specification of detection is 100g/m2, it is as a result as shown in the table.
Test event Average after flame time/s Averagely burn time/s Average char length/s Tensile index/Nmg-1 Ageing-resistant whiteness（Absolute value）Decline/%
Embodiment 1 4.5 44 105 48 4.2
Embodiment 2 4.1 40 103 50 4.1
Embodiment 3 5.2 48 107 44 3.5
Embodiment 4 5.0 53 113 46 3.7
Embodiment 5 5.3 52 110 43 3.4
Comparative example 1 1.8 26 88 57 4.6
Comparative example 2 3.2 37 100 49 6.0
It is obvious to a person skilled in the art that the invention is not restricted to the details of above-mentioned one exemplary embodiment, and do not carrying on the back In the case of spirit or essential attributes from the present invention, the present invention can be realized in other specific forms.Therefore, no matter from which From the point of view of a bit, the present embodiments are to be considered as illustrative and not restrictive, and the scope of the present invention will by appended right Ask rather than described above limits, it is intended that all changes in the implication and scope of the equivalency of claim will be fallen Include in the present invention.
Moreover, it will be appreciated that although the present specification is described in terms of embodiments, not each embodiment is only wrapped Containing an independent technical solution, this narrating mode of specification is only that those skilled in the art should for clarity Using specification as an entirety, the technical solutions in the various embodiments may also be suitably combined, forms those skilled in the art It is appreciated that other embodiment.It is noted that the technical characteristic not being described in detail in the present invention, can be by appointing One prior art is realized.

Claims (5)

1. a kind of fireproof flame-retardation wallpaper, it is characterised in that include the component of following parts by weight：Polyvinyl acetate powder 11- 17th, D-lactic acid-caprolactone nanofiber 23-34, antioxidant 6-11, compatilizer 2-7, fire retardant 0.8-3.4, reed fiber 15-24, zein fiber 23-39, basalt fibre 14-29, Chinese yam slurry 57-169；The solubility of the Chinese yam slurry is consolidated Shape thing content is 39%-48%；The filament diameter of the basalt fibre is 0.25-0.45um, the monofilament of the basalt fibre Length is 6-12mm.
2. fireproof flame-retardation wallpaper according to claim 1, it is characterised in that the compatilizer includes following parts by weight Component：It is chitin fiber element 7-16, mannitol 0.2-0.7, potassium chlorate 0.03-0.09, sodium potassium tartrate tetrahydrate 1-6, gelatin 4-11, poly- Vinyl alcohol 0.8-2.2.
3. fireproof flame-retardation wallpaper according to claim 1, it is characterised in that the fire retardant includes following parts by weight Component：Cr2AlC ceramic powders 13-24, nano SAPO-31 molecular sieve 7-12.
4. fireproof flame-retardation wallpaper according to claim 3, it is characterised in that the average particle size of the fire retardant is 310-400um。
5. fireproof flame-retardation wallpaper according to claim 1, it is characterised in that the antioxidant includes following parts by weight Component：Rosmarinus officinalis extract 1.3-3.9, bamboo extractive 1.8-4.7, myricetin 3.7-5.1.
CN201711298869.9A 2017-12-08 2017-12-08 A kind of fireproof flame-retardation wallpaper Pending CN108018737A (en)

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