CN108004831A - A kind of flame retardant type wallpaper - Google Patents

A kind of flame retardant type wallpaper Download PDF

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Publication number
CN108004831A
CN108004831A CN201711295885.2A CN201711295885A CN108004831A CN 108004831 A CN108004831 A CN 108004831A CN 201711295885 A CN201711295885 A CN 201711295885A CN 108004831 A CN108004831 A CN 108004831A
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China
Prior art keywords
alkali
free
present
fiber
short glass
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CN201711295885.2A
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Chinese (zh)
Inventor
姚景城
陈松
周振威
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Individual
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Priority to CN201711295885.2A priority Critical patent/CN108004831A/en
Publication of CN108004831A publication Critical patent/CN108004831A/en
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    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H13/00—Pulp or paper, comprising synthetic cellulose or non-cellulose fibres or web-forming material
    • D21H13/10—Organic non-cellulose fibres
    • D21H13/20—Organic non-cellulose fibres from macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D21H13/26—Polyamides; Polyimides
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H13/00—Pulp or paper, comprising synthetic cellulose or non-cellulose fibres or web-forming material
    • D21H13/10—Organic non-cellulose fibres
    • D21H13/28—Organic non-cellulose fibres from natural polymers
    • D21H13/30—Non-cellulose polysaccharides
    • D21H13/32—Alginate fibres
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H13/00—Pulp or paper, comprising synthetic cellulose or non-cellulose fibres or web-forming material
    • D21H13/36—Inorganic fibres or flakes
    • D21H13/38—Inorganic fibres or flakes siliceous
    • D21H13/40—Inorganic fibres or flakes siliceous vitreous, e.g. mineral wool, glass fibres
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H15/00—Pulp or paper, comprising fibres or web-forming material characterised by features other than their chemical constitution
    • D21H15/02—Pulp or paper, comprising fibres or web-forming material characterised by features other than their chemical constitution characterised by configuration
    • D21H15/10—Composite fibres
    • D21H15/12—Composite fibres partly organic, partly inorganic
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/02—Material of vegetable origin
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/03—Non-macromolecular organic compounds
    • D21H17/05—Non-macromolecular organic compounds containing elements other than carbon and hydrogen only
    • D21H17/06—Alcohols; Phenols; Ethers; Aldehydes; Ketones; Acetals; Ketals
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/03—Non-macromolecular organic compounds
    • D21H17/05—Non-macromolecular organic compounds containing elements other than carbon and hydrogen only
    • D21H17/14—Carboxylic acids; Derivatives thereof
    • D21H17/15—Polycarboxylic acids, e.g. maleic acid
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/20—Macromolecular organic compounds
    • D21H17/21—Macromolecular organic compounds of natural origin; Derivatives thereof
    • D21H17/22—Proteins
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/20—Macromolecular organic compounds
    • D21H17/21—Macromolecular organic compounds of natural origin; Derivatives thereof
    • D21H17/24—Polysaccharides
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/20—Macromolecular organic compounds
    • D21H17/21—Macromolecular organic compounds of natural origin; Derivatives thereof
    • D21H17/24—Polysaccharides
    • D21H17/25—Cellulose
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/20—Macromolecular organic compounds
    • D21H17/21—Macromolecular organic compounds of natural origin; Derivatives thereof
    • D21H17/24—Polysaccharides
    • D21H17/28—Starch
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/20—Macromolecular organic compounds
    • D21H17/33—Synthetic macromolecular compounds
    • D21H17/34—Synthetic macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D21H17/37—Polymers of unsaturated acids or derivatives thereof, e.g. polyacrylates
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/63—Inorganic compounds
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/63—Inorganic compounds
    • D21H17/66—Salts, e.g. alums
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/63—Inorganic compounds
    • D21H17/67—Water-insoluble compounds, e.g. fillers, pigments
    • D21H17/68—Water-insoluble compounds, e.g. fillers, pigments siliceous, e.g. clays
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
    • D21H21/34—Ignifugeants
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
    • D21H21/38—Corrosion-inhibiting agents or anti-oxidants
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
    • D21H27/18—Paper- or board-based structures for surface covering
    • D21H27/20—Flexible structures being applied by the user, e.g. wallpaper

Abstract

The present invention provides a kind of flame retardant type wallpaper, includes the component of following parts by weight：Akund 9 14, the low floating short glass fiber 14 29 of be lost synthetic fibre polyimides staple fiber 32 47, antioxidant 6 11, compatilizer 27, fire retardant 0.8 3.4, alginate fibre 27 42, wood pulp cellulose 11 24, alkali-free, cornstarch 27 41；The soluble solid content of the cornstarch is 42% 53%；The filament diameter of the low floating short glass fiber of the alkali-free is 27 38um, and the filament length of the low floating short glass fiber of the alkali-free is 3 9mm.Functionalization is dissolved into wallpaper by the present invention, meets the requirement of application and development of the wallpaper in modern house.

Description

A kind of flame retardant type wallpaper
Technical field
The present invention relates to decorative materials technology, and in particular to a kind of flame retardant type wallpaper.
Background technology
Ornament materials is the material base of building decoration engineering, is the actual effect of decorative engineering and the color of ornament materials Color, texture and the specific of texture show, and decorative material for internal wall is as part important in modern house decorations, Account for the largest percentage in overall house ornamentation.Wall decorative material currently on the market include coating, wallpaper, ceramics, glass, minute surface, Diatom ooze etc., species is enriched, and advantage is different, can flexibly be selected according to each room function and environment, numerous materials wherein more than wallpaper With the surface lining that most wide, kind are most in material, be widely used in restaurant in room interior wall and public place, market, On the wall in hotel.
Wallpaper is increasingly becoming decorate home material since the 1980s, is the quite extensive indoor dress of current application Exterior material.Initially originating from drawing on the paper Tang Dynasty, the rear wallpaper for just evolving into Modern Significance through Britain's production printing again, it develops Process successively experienced paper, scribble on paper, blistering paper, calico paper, the process to version cruddy paper, special process paper.It is but existing Wallpaper normally only there is single dicoration, mostly using artificial chemical materials, lack other comprehensive performances, it is difficult to meet Requirement of the people for wallpaper higher.
The content of the invention
In view of this, the present invention provides a kind of flame retardant type wallpaper, and the present invention is risen wallpaper from rudimentary to advanced Level, expands to comprehensive comprehensive performance, material will also become from artificial chemical materials turns to new type natural ring from single dicoration Energy-saving material is protected, and functionalization is dissolved into wallpaper, meets the requirement of application and development of the wallpaper in modern house.
The technical scheme is that：A kind of flame retardant type wallpaper, it is characterised in that include the group of following parts by weight Point：Akund 9-14, synthetic fibre polyimides staple fiber of being lost 32-47, antioxidant 6-11, compatilizer 2-7, fire retardant 0.8- 3.4th, the low floating short glass fiber 14-29 of alginate fibre 27-42, wood pulp cellulose 11-24, alkali-free, cornstarch 27-41；The corn The soluble solid content of starch is 42%-53%；The filament diameter of the low floating short glass fiber of the alkali-free is 27-38um, the nothing The filament length of the low floating short glass fiber of alkali is 3-9mm.
Wingceltis hide fiber of the present invention, be lost synthetic fibre polyimides staple fiber, alginate fibre, bamboo fibre, alkali-free are low floating short Glass, cornstarch can be prepared by any prior art.
Further, the compatilizer includes the component of following parts by weight：Chitin fiber element 2-6, mannitol 0.2- 0.7th, potassium chlorate 0.03-0.09, sodium potassium tartrate tetrahydrate 1-6, gelatin 4-11, polyacrylic acid 0.8-2.2；The compatilizer can be shown The compatibility improved in the present invention between inorfil and organic fiber is write, while effectively reduces distributing for raw material components of the present invention Property, make still to be able to be stabilized under the action of light and heat in existing wallpaper preparation process without easily distributing, keep this hair The bright performance of itself.
Further, the fire retardant includes the component of following parts by weight：Zinc hydride ferrite ceramics powder 19-34, receive Meter level MCM-49 molecular sieves 5-12.The average particle size of the fire retardant is 200-230um.
The zinc hydride ferrite ceramics powder can be compounded with nanoscale MCM-49 molecular sieves synergistic, significantly improve the resistance of wallpaper Fire fire protecting performance.The zinc hydride ferrite ceramics powder can be prepared into nanoscale MCM-49 molecular sieves by any prior art Arrive.
Further, the antioxidant includes the component of following parts by weight：Bamboo extractive 2-5, grape seed polyphenols 1.3-2.2, myricetin 3.7-5.1.The present invention use plant component antioxidant, safety and environmental protection, and can improve with The compatibility of other components of the present invention, improves the service life of the present invention.
In the present invention, it is combined using plant fiber with organic fiber, wallpaper can be assigned by compounding the other components of the present invention New performance；Vegetalitas antioxidant is added in the present invention, be ensure that anti-aging property, is significantly improved service life；Make With fire retardant, greatly improve the fire retardant performance of the wallpaper of preparation；Inventive formulation is simple, and raw material are chosen conveniently, Use cost is low, and the wall paper products performance produced is stablized, and fire resistance is good；The present invention has excellent comprehensive performance, can lead to The preparation process for crossing this area any prior art is made, and meets the requirement of application and development of the wallpaper in modern house.
Embodiment
With reference to embodiment, the present invention is described in further detail, but the implementation of the present invention is not limited to this.
Embodiment 1
A kind of flame retardant type wallpaper, it is characterised in that include the component of following parts by weight：Akund 9, synthetic fibre polyamides of being lost Imines staple fiber 32, antioxidant 6, compatilizer 2, fire retardant 0.8, alginate fibre 27, wood pulp cellulose 11, alkali-free are low to float short glass Fibre 14, cornstarch 27；The soluble solid content of the cornstarch is 42%；The monofilament of the low floating short glass fiber of the alkali-free A diameter of 27um, the filament length of the low floating short glass fiber of the alkali-free is 3mm.
Wingceltis hide fiber of the present invention, be lost synthetic fibre polyimides staple fiber, alginate fibre, bamboo fibre, alkali-free are low floating short Glass, cornstarch can be prepared by any prior art.
Further, the compatilizer includes the component of following parts by weight：Chitin fiber element 2, mannitol 0.2, chlorine Sour potassium 0.03, sodium potassium tartrate tetrahydrate 1, gelatin 4, polyacrylic acid 0.8；The compatilizer can significantly improve inorganic fibre in the present invention Compatibility between dimension and organic fiber, while the sporadic of raw material components of the present invention is effectively reduced, make in existing wallpaper system It still is able to be stabilized under the action of light and heat without easily distributing in standby technique, keeps the performance of itself of the invention.
Further, the fire retardant includes the component of following parts by weight：Zinc hydride ferrite ceramics powder 19, nanoscale MCM-49 molecular sieves 5.The average particle size of the fire retardant is 200um.
The zinc hydride ferrite ceramics powder can be compounded with nanoscale MCM-49 molecular sieves synergistic, significantly improve the resistance of wallpaper Fire fire protecting performance.The zinc hydride ferrite ceramics powder can be prepared into nanoscale MCM-49 molecular sieves by any prior art Arrive.
Further, the antioxidant includes the component of following parts by weight：Bamboo extractive 2, grape seed polyphenols 1.3rd, myricetin 3.7.The present invention uses the antioxidant of plant component, safety and environmental protection, and can improve with the present invention's The compatibility of other components, improves the service life of the present invention.
In the present invention, it is combined using plant fiber with organic fiber, wallpaper can be assigned by compounding the other components of the present invention New performance；Vegetalitas antioxidant is added in the present invention, be ensure that anti-aging property, is significantly improved service life；Make With fire retardant, greatly improve the fire retardant performance of the wallpaper of preparation；Inventive formulation is simple, and raw material are chosen conveniently, Use cost is low, and the wall paper products performance produced is stablized, and fire resistance is good；The present invention has excellent comprehensive performance, can lead to The preparation process for crossing this area any prior art is made, and meets the requirement of application and development of the wallpaper in modern house.
The preferable preparation process of the present embodiment is：By wingceltis hide fiber, be lost synthetic fibre polyimides staple fiber, alginate fibre, bamboo The low floating short glass fiber of fiber, alkali-free, cornstarch score ratio by weight are mixed and sent after being beaten to 40-55 ° of SR to blending chest, are pressed Ratio of weight and number adds antioxidant, compatilizer, fire retardant, is uniformly mixing to obtain slurry；Into the cylinder paper of closed paper injection Machine carries out dehydration forming, and speed 65m/min, forms the l Water Paper page containing wallpaper line skin texture；The slurry enters the online of paper machine Concentration is 0.22%；For rotary screen cage in the cylinder mould machine on its cylindrical type skeleton, circumferential uniform welding is arranged with stainless steel steel Silk, stainless steel gauge of wire are 0.2mm, and spacing is 1.2mm between steel wire；Cylinder vat ox between rotary screen cage and outer arcuate plate The dimensional parameters in angle road are：The spacing of rotary screen cage import and outer arcuate plate is 55mm, between rotary screen cage bottom and arc panel between Away from for 42mm, rotary screen cage outlet and the spacing between arc panel are 32mm；By above-mentioned l Water Paper page through press dewatering and cylinder dried, obtain Obtain finished product.
Embodiment 2
A kind of flame retardant type wallpaper, it is characterised in that include the component of following parts by weight：Wingceltis hide fiber 14, synthetic fibre of being lost gather Acid imide staple fiber 47, antioxidant 11, compatilizer 7, fire retardant 3.4, alginate fibre 42, wood pulp cellulose 24, alkali-free are low floating short Glass 29, cornstarch 41；The soluble solid content of the cornstarch is 53%；The list of the low floating short glass fiber of the alkali-free Silk a diameter of 38um, the filament length of the low floating short glass fiber of the alkali-free is 9mm.
Wingceltis hide fiber of the present invention, be lost synthetic fibre polyimides staple fiber, alginate fibre, bamboo fibre, alkali-free are low floating short Glass, cornstarch can be prepared by any prior art.
Further, the compatilizer includes the component of following parts by weight：Chitin fiber element 6, mannitol 0.7, chlorine Sour potassium 0.09, sodium potassium tartrate tetrahydrate 6, gelatin 11, polyacrylic acid 2.2；The compatilizer can significantly improve inorganic fibre in the present invention Compatibility between dimension and organic fiber, while the sporadic of raw material components of the present invention is effectively reduced, make in existing wallpaper system It still is able to be stabilized under the action of light and heat without easily distributing in standby technique, keeps the performance of itself of the invention.
Further, the fire retardant includes the component of following parts by weight：Zinc hydride ferrite ceramics powder 34, nanoscale MCM-49 molecular sieves 12.The average particle size of the fire retardant is 230um.
The zinc hydride ferrite ceramics powder can be compounded with nanoscale MCM-49 molecular sieves synergistic, significantly improve the resistance of wallpaper Fire fire protecting performance.The zinc hydride ferrite ceramics powder can be prepared into nanoscale MCM-49 molecular sieves by any prior art Arrive.
Further, the antioxidant includes the component of following parts by weight：Bamboo extractive 5, grape seed polyphenols 2.2nd, myricetin 5.1.The present invention uses the antioxidant of plant component, safety and environmental protection, and can improve with the present invention's The compatibility of other components, improves the service life of the present invention.
Embodiment 3
A kind of flame retardant type wallpaper, it is characterised in that include the component of following parts by weight：Wingceltis hide fiber 11.5, synthetic fibre of being lost Polyimides staple fiber 39.5, antioxidant 8.5, compatilizer 4.5, fire retardant 2.1, alginate fibre 34.5, wood pulp cellulose 17.5, The low floating short glass fiber 21.5 of alkali-free, cornstarch 34；The soluble solid content of the cornstarch is 47.5%；The alkali-free The filament diameter of low floating short glass fiber is 32.5um, and the filament length of the low floating short glass fiber of the alkali-free is 6mm.
Wingceltis hide fiber of the present invention, be lost synthetic fibre polyimides staple fiber, alginate fibre, bamboo fibre, alkali-free are low floating short Glass, cornstarch can be prepared by any prior art.
Further, the compatilizer includes the component of following parts by weight：Chitin fiber element 4, mannitol 0.45, chlorine Sour potassium 0.06, sodium potassium tartrate tetrahydrate 3.5, gelatin 7.5, polyacrylic acid 1.5；The compatilizer can significantly improve inorganic in the present invention Compatibility between fiber and organic fiber, while the sporadic of raw material components of the present invention is effectively reduced, make in existing wallpaper It still is able to be stabilized without easily distributing under the action of light and heat in preparation process, keeps the performance of itself of the invention.
Further, the fire retardant includes the component of following parts by weight：Zinc hydride ferrite ceramics powder 26.5, nanometer Level MCM-49 molecular sieves 8.5.The average particle size of the fire retardant is 215um.
The zinc hydride ferrite ceramics powder can be compounded with nanoscale MCM-49 molecular sieves synergistic, significantly improve the resistance of wallpaper Fire fire protecting performance.The zinc hydride ferrite ceramics powder can be prepared into nanoscale MCM-49 molecular sieves by any prior art Arrive.
Further, the antioxidant includes the component of following parts by weight：Bamboo extractive 3.5, grape seed polyphenols 1.75th, myricetin 4.4.The present invention uses the antioxidant of plant component, safety and environmental protection, and can improve with the present invention's The compatibility of other components, improves the service life of the present invention.
Embodiment 4
A kind of flame retardant type wallpaper, it is characterised in that include the component of following parts by weight：Wingceltis hide fiber 11, synthetic fibre of being lost gather The low floating short glass fiber of acid imide staple fiber 35, antioxidant 9, compatilizer 3, fire retardant 1, alginate fibre 30, wood pulp cellulose 13, alkali-free 16th, cornstarch 29；The soluble solid content of the cornstarch is 46%；The monofilament of the low floating short glass fiber of the alkali-free is straight Footpath is 30um, and the filament length of the low floating short glass fiber of the alkali-free is 4mm.
Wingceltis hide fiber of the present invention, be lost synthetic fibre polyimides staple fiber, alginate fibre, bamboo fibre, alkali-free are low floating short Glass, cornstarch can be prepared by any prior art.
Further, the compatilizer includes the component of following parts by weight：Chitin fiber element 5, mannitol 0.3, chlorine Sour potassium 0.08, sodium potassium tartrate tetrahydrate 2, gelatin 10, polyacrylic acid 1；The compatilizer can significantly improve inorfil in the present invention Compatibility between organic fiber, while the sporadic of raw material components of the present invention is effectively reduced, make to prepare in existing wallpaper It still is able to be stabilized without easily distributing under the action of light and heat in technique, keeps the performance of itself of the invention.
Further, the fire retardant includes the component of following parts by weight：Zinc hydride ferrite ceramics powder 22, nanoscale MCM-49 molecular sieves 10.The average particle size of the fire retardant is 210um.
The zinc hydride ferrite ceramics powder can be compounded with nanoscale MCM-49 molecular sieves synergistic, significantly improve the resistance of wallpaper Fire fire protecting performance.The zinc hydride ferrite ceramics powder can be prepared into nanoscale MCM-49 molecular sieves by any prior art Arrive.
Further, the antioxidant includes the component of following parts by weight：Bamboo extractive 3, grape seed polyphenols 2, Myricetin 4.The present invention uses the antioxidant of plant component, safety and environmental protection, and can improve other groups with the present invention The compatibility divided, improves the service life of the present invention.
Embodiment 5
A kind of flame retardant type wallpaper, it is characterised in that include the component of following parts by weight：Wingceltis hide fiber 12, synthetic fibre of being lost gather Acid imide staple fiber 45, antioxidant 7, compatilizer 6, fire retardant 2, alginate fibre 40, wood pulp cellulose 11-24, alkali-free are low floating short Glass 25, cornstarch 30；The soluble solid content of the cornstarch is 50%；The list of the low floating short glass fiber of the alkali-free Silk a diameter of 36um, the filament length of the low floating short glass fiber of the alkali-free is 8mm.
Wingceltis hide fiber of the present invention, be lost synthetic fibre polyimides staple fiber, alginate fibre, bamboo fibre, alkali-free are low floating short Glass, cornstarch can be prepared by any prior art.
Further, the compatilizer includes the component of following parts by weight：Chitin fiber element 3, mannitol 0.6, chlorine Sour potassium 0.05, sodium potassium tartrate tetrahydrate 5, gelatin 6, polyacrylic acid 2；The compatilizer can significantly improve in the present invention inorfil with Compatibility between organic fiber, while the sporadic of raw material components of the present invention is effectively reduced, make to prepare work in existing wallpaper It still is able to be stabilized without easily distributing under the action of light and heat in skill, keeps the performance of itself of the invention.
Further, the fire retardant includes the component of following parts by weight：Zinc hydride ferrite ceramics powder 30, nanoscale MCM-49 molecular sieves 6.The average particle size of the fire retardant is 228um.
The zinc hydride ferrite ceramics powder can be compounded with nanoscale MCM-49 molecular sieves synergistic, significantly improve the resistance of wallpaper Fire fire protecting performance.The zinc hydride ferrite ceramics powder can be prepared into nanoscale MCM-49 molecular sieves by any prior art Arrive.
Further, the antioxidant includes the component of following parts by weight：Bamboo extractive 4, grape seed polyphenols 1.5th, myricetin 4.5.The present invention uses the antioxidant of plant component, safety and environmental protection, and can improve with the present invention's The compatibility of other components, improves the service life of the present invention.
Comparative example 1
A kind of flame retardant type wallpaper, it is characterised in that include the component of following parts by weight：Wingceltis hide fiber 11.5, synthetic fibre of being lost Polyimides staple fiber 39.5, antioxidant 8.5, compatilizer 4.5, alginate fibre 34.5, wood pulp cellulose 17.5, alkali-free are low floating short Glass 21.5, cornstarch 34；The soluble solid content of the cornstarch is 47.5%；The low floating short glass fiber of the alkali-free Filament diameter be 32.5um, the filament length of the low floating short glass fiber of the alkali-free is 6mm.
Wingceltis hide fiber of the present invention, be lost synthetic fibre polyimides staple fiber, alginate fibre, bamboo fibre, alkali-free are low floating short Glass, cornstarch can be prepared by any prior art.
Further, the compatilizer includes the component of following parts by weight：Chitin fiber element 4, mannitol 0.45, chlorine Sour potassium 0.06, sodium potassium tartrate tetrahydrate 3.5, gelatin 7.5, polyacrylic acid 1.5；The compatilizer can significantly improve inorganic in the present invention Compatibility between fiber and organic fiber, while the sporadic of raw material components of the present invention is effectively reduced, make in existing wallpaper It still is able to be stabilized without easily distributing under the action of light and heat in preparation process, keeps the performance of itself of the invention.
Further, the antioxidant includes the component of following parts by weight：Bamboo extractive 3.5, grape seed polyphenols 1.75th, myricetin 4.4.The present invention uses the antioxidant of plant component, safety and environmental protection, and can improve with the present invention's The compatibility of other components, improves the service life of the present invention.
Comparative example 2
A kind of flame retardant type wallpaper, it is characterised in that include the component of following parts by weight：Wingceltis hide fiber 11, synthetic fibre of being lost gather The low floating short glass fiber 16 of acid imide staple fiber 35, compatilizer 3, fire retardant 1, alginate fibre 30, wood pulp cellulose 13, alkali-free, corn form sediment Powder 29；The soluble solid content of the cornstarch is 46%；The filament diameter of the low floating short glass fiber of the alkali-free is 30um, The filament length of the low floating short glass fiber of the alkali-free is 4mm.
Wingceltis hide fiber of the present invention, be lost synthetic fibre polyimides staple fiber, alginate fibre, bamboo fibre, alkali-free are low floating short Glass, cornstarch can be prepared by any prior art.
Further, the compatilizer includes the component of following parts by weight：Chitin fiber element 5, mannitol 0.3, chlorine Sour potassium 0.08, sodium potassium tartrate tetrahydrate 2, gelatin 10, polyacrylic acid 1；The compatilizer can significantly improve inorfil in the present invention Compatibility between organic fiber, while the sporadic of raw material components of the present invention is effectively reduced, make to prepare in existing wallpaper It still is able to be stabilized without easily distributing under the action of light and heat in technique, keeps the performance of itself of the invention.
Further, the fire retardant includes the component of following parts by weight：Zinc hydride ferrite ceramics powder 22, nanoscale MCM-49 molecular sieves 10.The average particle size of the fire retardant is 210um.
The zinc hydride ferrite ceramics powder can be compounded with nanoscale MCM-49 molecular sieves synergistic, significantly improve the resistance of wallpaper Fire fire protecting performance.The zinc hydride ferrite ceramics powder can be prepared into nanoscale MCM-49 molecular sieves by any prior art Arrive.
Performance test
The parameters such as all embodiments of the invention, the fire resistance of comparative example, tensile index are detected by relevant national standard method, The material specification of detection is 100g/m2, it is as a result as shown in the table.
Test event Average afterflame Time/s Averagely burn Time/s Average charing length Degree/s Tensile index/N m·g-1 Ageing-resistant whiteness（Absolute value） Decline/%
Embodiment 1 4.7 46 109 51 4.3
Embodiment 2 4.3 42 107 53 4.3
Embodiment 3 5.5 51 113 46 3.7
Embodiment 4 5.3 56 119 48 3.9
Embodiment 5 5.5 55 116 45 3.6
Comparative example 1 1.9 28 93 60 4.9
Comparative example 2 3.4 39 105 52 6.2
It is obvious to a person skilled in the art that the invention is not restricted to the details of above-mentioned one exemplary embodiment, and do not carrying on the back In the case of spirit or essential attributes from the present invention, the present invention can be realized in other specific forms.Therefore, no matter from which From the point of view of a bit, the present embodiments are to be considered as illustrative and not restrictive, and the scope of the present invention will by appended right Ask rather than described above limits, it is intended that all changes in the implication and scope of the equivalency of claim will be fallen Include in the present invention.
Moreover, it will be appreciated that although the present specification is described in terms of embodiments, not each embodiment is only wrapped Containing an independent technical solution, this narrating mode of specification is only that those skilled in the art should for clarity Using specification as an entirety, the technical solutions in the various embodiments may also be suitably combined, forms those skilled in the art It is appreciated that other embodiment.It is noted that the technical characteristic not being described in detail in the present invention, can be by appointing One prior art is realized.

Claims (5)

1. a kind of flame retardant type wallpaper, it is characterised in that include the component of following parts by weight：Akund 9-14, be lost Synthetic fibre polyimides staple fiber 32-47, antioxidant 6-11, compatilizer 2-7, fire retardant 0.8-3.4, alginate fibre 27-42, wood The low floating short glass fiber 14-29 of pulp fibres 11-24, alkali-free, cornstarch 27-41；The soluble solid content of the cornstarch For 42%-53%；The filament diameter of the low floating short glass fiber of the alkali-free is 27-38um, the filament length of the low floating short glass fiber of the alkali-free For 3-9mm.
2. flame retardant type wallpaper according to claim 1, it is characterised in that the compatilizer includes following parts by weight Component：Chitin fiber element 2-6, mannitol 0.2-0.7, potassium chlorate 0.03-0.09, sodium potassium tartrate tetrahydrate 1-6, gelatin 4-11, Polyacrylic acid 0.8-2.2.
3. flame retardant type wallpaper according to claim 1, it is characterised in that the fire retardant includes following parts by weight Component：Zinc hydride ferrite ceramics powder 19-34, nanoscale MCM-49 molecular sieves 5-12.
4. flame retardant type wallpaper according to claim 3, it is characterised in that the average particle size of the fire retardant is 200-230um。
5. flame retardant type wallpaper according to claim 1, it is characterised in that the antioxidant includes following parts by weight Several components：Bamboo extractive 2-5, grape seed polyphenols 1.3-2.2, myricetin 3.7-5.1.
CN201711295885.2A 2017-12-08 2017-12-08 A kind of flame retardant type wallpaper Pending CN108004831A (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108755272A (en) * 2018-05-25 2018-11-06 安徽银兔装饰材料有限公司 Flame wallpaper base material and preparation method thereof
CN108755273A (en) * 2018-05-25 2018-11-06 安徽银兔装饰材料有限公司 Wallpaper base material and preparation method thereof
CN109811468A (en) * 2019-03-01 2019-05-28 杭州鹏图化纤有限公司 A kind of compound type non-woven fabric and preparation method thereof
CN111851145A (en) * 2020-06-28 2020-10-30 杭州壹澍美生态科技发展有限公司 Antibacterial and mothproof Wula sedge wallpaper and processing technology thereof

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108755272A (en) * 2018-05-25 2018-11-06 安徽银兔装饰材料有限公司 Flame wallpaper base material and preparation method thereof
CN108755273A (en) * 2018-05-25 2018-11-06 安徽银兔装饰材料有限公司 Wallpaper base material and preparation method thereof
CN109811468A (en) * 2019-03-01 2019-05-28 杭州鹏图化纤有限公司 A kind of compound type non-woven fabric and preparation method thereof
CN111851145A (en) * 2020-06-28 2020-10-30 杭州壹澍美生态科技发展有限公司 Antibacterial and mothproof Wula sedge wallpaper and processing technology thereof

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