CN108004836A - A kind of antibacterial green wallpaper - Google Patents

A kind of antibacterial green wallpaper Download PDF

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Publication number
CN108004836A
CN108004836A CN201711298872.0A CN201711298872A CN108004836A CN 108004836 A CN108004836 A CN 108004836A CN 201711298872 A CN201711298872 A CN 201711298872A CN 108004836 A CN108004836 A CN 108004836A
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CN
China
Prior art keywords
fiber
alkali
free
following parts
short glass
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Pending
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CN201711298872.0A
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Chinese (zh)
Inventor
姚景城
陈松
周振威
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Individual
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Individual
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Priority to CN201711298872.0A priority Critical patent/CN108004836A/en
Publication of CN108004836A publication Critical patent/CN108004836A/en
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    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H11/00—Pulp or paper, comprising cellulose or lignocellulose fibres of natural origin only
    • D21H11/12—Pulp from non-woody plants or crops, e.g. cotton, flax, straw, bagasse
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H13/00—Pulp or paper, comprising synthetic cellulose or non-cellulose fibres or web-forming material
    • D21H13/10—Organic non-cellulose fibres
    • D21H13/20—Organic non-cellulose fibres from macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D21H13/24—Polyesters
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H13/00—Pulp or paper, comprising synthetic cellulose or non-cellulose fibres or web-forming material
    • D21H13/10—Organic non-cellulose fibres
    • D21H13/28—Organic non-cellulose fibres from natural polymers
    • D21H13/30—Non-cellulose polysaccharides
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H13/00—Pulp or paper, comprising synthetic cellulose or non-cellulose fibres or web-forming material
    • D21H13/10—Organic non-cellulose fibres
    • D21H13/28—Organic non-cellulose fibres from natural polymers
    • D21H13/30—Non-cellulose polysaccharides
    • D21H13/32—Alginate fibres
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H13/00—Pulp or paper, comprising synthetic cellulose or non-cellulose fibres or web-forming material
    • D21H13/10—Organic non-cellulose fibres
    • D21H13/28—Organic non-cellulose fibres from natural polymers
    • D21H13/34—Protein fibres
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H13/00—Pulp or paper, comprising synthetic cellulose or non-cellulose fibres or web-forming material
    • D21H13/36—Inorganic fibres or flakes
    • D21H13/38—Inorganic fibres or flakes siliceous
    • D21H13/40—Inorganic fibres or flakes siliceous vitreous, e.g. mineral wool, glass fibres
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H15/00—Pulp or paper, comprising fibres or web-forming material characterised by features other than their chemical constitution
    • D21H15/02—Pulp or paper, comprising fibres or web-forming material characterised by features other than their chemical constitution characterised by configuration
    • D21H15/10—Composite fibres
    • D21H15/12—Composite fibres partly organic, partly inorganic
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/02—Material of vegetable origin
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/03—Non-macromolecular organic compounds
    • D21H17/05—Non-macromolecular organic compounds containing elements other than carbon and hydrogen only
    • D21H17/06—Alcohols; Phenols; Ethers; Aldehydes; Ketones; Acetals; Ketals
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/03—Non-macromolecular organic compounds
    • D21H17/05—Non-macromolecular organic compounds containing elements other than carbon and hydrogen only
    • D21H17/14—Carboxylic acids; Derivatives thereof
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/20—Macromolecular organic compounds
    • D21H17/21—Macromolecular organic compounds of natural origin; Derivatives thereof
    • D21H17/24—Polysaccharides
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/20—Macromolecular organic compounds
    • D21H17/33—Synthetic macromolecular compounds
    • D21H17/46—Synthetic macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D21H17/53—Polyethers; Polyesters
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/63—Inorganic compounds
    • D21H17/66—Salts, e.g. alums
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/63—Inorganic compounds
    • D21H17/67—Water-insoluble compounds, e.g. fillers, pigments
    • D21H17/68—Water-insoluble compounds, e.g. fillers, pigments siliceous, e.g. clays
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
    • D21H21/143—Agents preventing ageing of paper, e.g. radiation absorbing substances
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
    • D21H21/34—Ignifugeants
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
    • D21H21/36—Biocidal agents, e.g. fungicidal, bactericidal, insecticidal agents
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
    • D21H21/38—Corrosion-inhibiting agents or anti-oxidants
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
    • D21H27/18—Paper- or board-based structures for surface covering
    • D21H27/20—Flexible structures being applied by the user, e.g. wallpaper
    • E—FIXED CONSTRUCTIONS
    • E04—BUILDING
    • E04F—FINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
    • E04F13/00—Coverings or linings, e.g. for walls or ceilings
    • E04F13/002—Coverings or linings, e.g. for walls or ceilings made of webs, e.g. of fabrics, or wallpaper, used as coverings or linings
    • E—FIXED CONSTRUCTIONS
    • E04—BUILDING
    • E04F—FINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
    • E04F2290/00—Specially adapted covering, lining or flooring elements not otherwise provided for
    • E04F2290/04—Specially adapted covering, lining or flooring elements not otherwise provided for for insulation or surface protection, e.g. against noise, impact or fire
    • E—FIXED CONSTRUCTIONS
    • E04—BUILDING
    • E04F—FINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
    • E04F2290/00—Specially adapted covering, lining or flooring elements not otherwise provided for
    • E04F2290/04—Specially adapted covering, lining or flooring elements not otherwise provided for for insulation or surface protection, e.g. against noise, impact or fire
    • E04F2290/045—Specially adapted covering, lining or flooring elements not otherwise provided for for insulation or surface protection, e.g. against noise, impact or fire against fire

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  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Architecture (AREA)
  • Civil Engineering (AREA)
  • Structural Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Pest Control & Pesticides (AREA)
  • Dispersion Chemistry (AREA)
  • Paper (AREA)
  • Synthetic Leather, Interior Materials Or Flexible Sheet Materials (AREA)

Abstract

The present invention provides a kind of antibacterial green wallpaper, includes the component of following parts by weight：The low floating short glass fiber 9 17 of alginate fibre 13 22, acid fiber by polylactic 23 34, antioxidant 8 15, compatilizer 39, fire retardant 1.4 2.9, poly (propylene carbonate)/chitosan nano fiber 12 28, bamboo fibre 8 13, soybean fiber 19 32, alkali-free, rice slurry 45 58；The soluble solid content of the rice slurry is 52% 68%；The filament diameter of the low floating short glass fiber of the alkali-free is 9 17um, and the filament length of the low floating short glass fiber of the alkali-free is 5 12mm.Functionalization is dissolved into wallpaper by the present invention, meets the requirement of application and development of the wallpaper in modern house.

Description

A kind of antibacterial green wallpaper
Technical field
The present invention relates to decorative materials technology, and in particular to a kind of antibacterial green wallpaper.
Background technology
Ornament materials is the material base of building decoration engineering, is the actual effect of decorative engineering and the color of ornament materials Color, texture and the specific of texture show, and decorative material for internal wall is as part important in modern house decorations, Account for the largest percentage in overall house ornamentation.Wall decorative material currently on the market include coating, wallpaper, ceramics, glass, minute surface, Diatom ooze etc., species is enriched, and advantage is different, can flexibly be selected according to each room function and environment, numerous materials wherein more than wallpaper With the surface lining that most wide, kind are most in material, be widely used in restaurant in room interior wall and public place, market, On the wall in hotel.
Wallpaper is increasingly becoming decorate home material since the 1980s, is the quite extensive indoor dress of current application Exterior material.Initially originating from drawing on the paper Tang Dynasty, the rear wallpaper for just evolving into Modern Significance through Britain's production printing again, it develops Process successively experienced paper, scribble on paper, blistering paper, calico paper, the process to version cruddy paper, special process paper.It is but existing Wallpaper normally only there is single dicoration, mostly using artificial chemical materials, lack other comprehensive performances, it is difficult to meet Requirement of the people for wallpaper higher.
The content of the invention
In view of this, the present invention provides a kind of antibacterial green wallpaper, and the present invention is upgraded wallpaper from rudimentary to advanced, Comprehensive comprehensive performance is expanded to from single dicoration, material will also become from artificial chemical materials turns to new type natural environmental protection section Energy material, and functionalization is dissolved into wallpaper, meet the requirement of application and development of the wallpaper in modern house.
The technical scheme is that：A kind of antibacterial green wallpaper, it is characterised in that include the group of following parts by weight Point：Alginate fibre 13-22, acid fiber by polylactic 23-34, antioxidant 8-15, compatilizer 3-9, fire retardant 1.4-2.9, poly- carbonic acid The low floating short glass fiber 9-17 of sub- propyl ester/chitosan nano fiber 12-28, bamboo fibre 8-13, soybean fiber 19-32, alkali-free, Rice slurry 45-58；；The soluble solid content of the rice slurry is 52%-68%；The list of the low floating short glass fiber of the alkali-free Silk a diameter of 9-17um, the filament length of the low floating short glass fiber of the alkali-free is 5-12mm.
It is alginate fibre of the present invention, acid fiber by polylactic, poly (propylene carbonate)/chitosan nano fiber, bamboo fibre, big The low floating short glass fiber of legumin fiber, alkali-free, rice slurry can be prepared by any prior art.
Further, the compatilizer includes the component of following parts by weight：Chitin 2-6, glycerine 0.5-1.1, chlorine Change sodium 0.2-0.8, sodium potassium tartrate tetrahydrate 1-6, chitosan gel rubber 13-25, polyethylene oxide 1.8-3.7；The compatilizer can be shown The compatibility improved in the present invention between inorfil and organic fiber is write, while effectively reduces distributing for raw material components of the present invention Property, make still to be able to be stabilized under the action of light and heat in existing rice paper preparation process without easily distributing, keep this hair The bright performance of itself.
Further, the fire retardant includes the component of following parts by weight：Silicon nitride ceramic 35-48, nanometer ZSM- 5 molecular sieve 16-23.The average particle size of the fire retardant is 280-420um.
The silicon nitride ceramic can be compounded with nano-ZSM-5 molecular sieve synergistic, significantly improve the fire-retardant fireproof of rice paper Energy.The silicon nitride ceramic can be prepared with nano-ZSM-5 molecular sieve by any prior art.
Further, the antioxidant includes the component of following parts by weight：Grape seed polyphenols 1.5-2.8, mulberry leaf carry Take thing 1.2-2.6, lutein 2.3-4.1, bamboo extractive 1.9-2.7.The present invention uses the antioxidant of plant component, peace Loopful is protected, and can improve the compatibility with other components of the present invention, improves the service life of the present invention.
In the present invention, it is combined using plant fiber with organic fiber, wallpaper can be assigned by compounding the other components of the present invention New performance；Vegetalitas antioxidant is added in the present invention, be ensure that anti-aging property, is significantly improved service life；Make With fire retardant, greatly improve the fire retardant performance of the wallpaper of preparation；Inventive formulation is simple, and raw material are chosen conveniently, Use cost is low, and the wall paper products performance produced is stablized, and has certain anti-microbial property；The present invention has excellent comprehensive Can, it can be made by the preparation process of this area any prior art, meet application and development of the wallpaper in modern house It is required that.
Embodiment
With reference to embodiment, the present invention is described in further detail, but the implementation of the present invention is not limited to this.
Embodiment 1
A kind of antibacterial green wallpaper, it is characterised in that include the component of following parts by weight：Alginate fibre 13, acid fiber by polylactic 23rd, antioxidant 8, compatilizer 3, fire retardant 1.4, poly (propylene carbonate)/chitosan nano fiber 12, bamboo fibre 8, soybean egg The low floating short glass fiber 9 of white fiber 19, alkali-free, rice slurry 45；The soluble solid content of the rice slurry is 52%；It is described The filament diameter of the low floating short glass fiber of alkali-free is 9um, and the filament length of the low floating short glass fiber of the alkali-free is 5mm.
It is alginate fibre of the present invention, acid fiber by polylactic, poly (propylene carbonate)/chitosan nano fiber, bamboo fibre, big The low floating short glass fiber of legumin fiber, alkali-free, rice slurry can be prepared by any prior art.
Further, the compatilizer includes the component of following parts by weight：Chitin 2, glycerine 0.5, sodium chloride 0.2nd, sodium potassium tartrate tetrahydrate 1, chitosan gel rubber 13, polyethylene oxide 1.8；The compatilizer can significantly improve nothing in the present invention Compatibility between machine fiber and organic fiber, while the sporadic of raw material components of the present invention is effectively reduced, make in existing a surname It still is able to be stabilized without easily distributing under the action of light and heat in paper preparation process, keeps the performance of itself of the invention.
Further, the fire retardant includes the component of following parts by weight：Silicon nitride ceramic 35, nano-ZSM-5 point Son sieve 16.The average particle size of the fire retardant is 280um.
The silicon nitride ceramic can be compounded with nano-ZSM-5 molecular sieve synergistic, significantly improve the fire-retardant fireproof of rice paper Energy.The silicon nitride ceramic can be prepared with nano-ZSM-5 molecular sieve by any prior art.
Further, the antioxidant includes the component of following parts by weight：Grape seed polyphenols 1.5, mulberry-leaf extract 1.2nd, lutein 2.3, bamboo extractive 1.9.The present invention uses the antioxidant of plant component, safety and environmental protection, and can improve With the compatibility of other components of the present invention, service life of the invention is improved.
In the present invention, it is combined using plant fiber with organic fiber, wallpaper can be assigned by compounding the other components of the present invention New performance；Vegetalitas antioxidant is added in the present invention, be ensure that anti-aging property, is significantly improved service life；Make With fire retardant, greatly improve the fire retardant performance of the wallpaper of preparation；Inventive formulation is simple, and raw material are chosen conveniently, Use cost is low, and the wall paper products performance produced is stablized, and has certain anti-microbial property；The present invention has excellent comprehensive Can, it can be made by the preparation process of this area any prior art, meet application and development of the wallpaper in modern house It is required that.
Embodiment 2
A kind of antibacterial green wallpaper, it is characterised in that include the component of following parts by weight：Alginate fibre 22, acid fiber by polylactic 34th, antioxidant 15, compatilizer 9, fire retardant 2.9, poly (propylene carbonate)/chitosan nano fiber 28, bamboo fibre 13, soybean egg The low floating short glass fiber 17 of white fiber 32, alkali-free, rice slurry 58；The soluble solid content of the rice slurry is 68%；It is described The filament diameter of the low floating short glass fiber of alkali-free is 17um, and the filament length of the low floating short glass fiber of the alkali-free is 12mm.
It is alginate fibre of the present invention, acid fiber by polylactic, poly (propylene carbonate)/chitosan nano fiber, bamboo fibre, big The low floating short glass fiber of legumin fiber, alkali-free, rice slurry can be prepared by any prior art.
Further, the compatilizer includes the component of following parts by weight：Chitin 6, glycerine 1.1, sodium chloride 0.8th, sodium potassium tartrate tetrahydrate 6, chitosan gel rubber 25, polyethylene oxide 3.7；The compatilizer can significantly improve inorganic in the present invention Compatibility between fiber and organic fiber, while the sporadic of raw material components of the present invention is effectively reduced, make in existing rice paper It still is able to be stabilized without easily distributing under the action of light and heat in preparation process, keeps the performance of itself of the invention.
Further, the fire retardant includes the component of following parts by weight：Silicon nitride ceramic 48, nano-ZSM-5 point Son sieve 23.The average particle size of the fire retardant is 420um.
The silicon nitride ceramic can be compounded with nano-ZSM-5 molecular sieve synergistic, significantly improve the fire-retardant fireproof of rice paper Energy.The silicon nitride ceramic can be prepared with nano-ZSM-5 molecular sieve by any prior art.
Further, the antioxidant includes the component of following parts by weight：Grape seed polyphenols 2.8, mulberry-leaf extract 2.6th, lutein 4.1, bamboo extractive 2.7.The present invention uses the antioxidant of plant component, safety and environmental protection, and can improve With the compatibility of other components of the present invention, service life of the invention is improved.
Embodiment 3
A kind of antibacterial green wallpaper, it is characterised in that include the component of following parts by weight：Alginate fibre 17.5, polylactic acid are fine Dimension 28.5, antioxidant 11.5, compatilizer 6, fire retardant 2.15, poly (propylene carbonate)/chitosan nano fiber 20, bamboo fibre 10.5th, the low floating short glass fiber 13 of soybean fiber 25.5, alkali-free, rice slurry 51.5；The soluble solid of the rice slurry Thing content is 60%；The filament diameter of the low floating short glass fiber of the alkali-free is 13um, and the filament length of the low floating short glass fiber of the alkali-free is 8.5mm。
It is alginate fibre of the present invention, acid fiber by polylactic, poly (propylene carbonate)/chitosan nano fiber, bamboo fibre, big The low floating short glass fiber of legumin fiber, alkali-free, rice slurry can be prepared by any prior art.
Further, the compatilizer includes the component of following parts by weight：Chitin 4, glycerine 0.8, sodium chloride 0.5th, sodium potassium tartrate tetrahydrate 3.5, chitosan gel rubber 19, polyethylene oxide 2.75；The compatilizer can be significantly improved in the present invention Compatibility between inorfil and organic fiber, while the sporadic of raw material components of the present invention is effectively reduced, make existing It still is able to be stabilized without easily distributing under the action of light and heat in rice paper preparation process, keeps the performance of itself of the invention.
Further, the fire retardant includes the component of following parts by weight：Silicon nitride ceramic 41.5, nano-ZSM-5 Molecular sieve 19.5.The average particle size of the fire retardant is 350um.
The silicon nitride ceramic can be compounded with nano-ZSM-5 molecular sieve synergistic, significantly improve the fire-retardant fireproof of rice paper Energy.The silicon nitride ceramic can be prepared with nano-ZSM-5 molecular sieve by any prior art.
Further, the antioxidant includes the component of following parts by weight：Grape seed polyphenols 2.15, mulberry-leaf extract 1.9th, lutein 3.2, bamboo extractive 2.3.The present invention uses the antioxidant of plant component, safety and environmental protection, and can improve With the compatibility of other components of the present invention, service life of the invention is improved.
Embodiment 4
A kind of antibacterial green wallpaper, it is characterised in that include the component of following parts by weight：Alginate fibre 15, acid fiber by polylactic 30th, antioxidant 13, compatilizer 8, fire retardant 2, poly (propylene carbonate)/chitosan nano fiber 26, bamboo fibre 11, soybean protein The low floating short glass fiber 15 of fiber 30, alkali-free, rice slurry 55；The soluble solid content of the rice slurry is 65%；The nothing The filament diameter of the low floating short glass fiber of alkali is 15um, and the filament length of the low floating short glass fiber of the alkali-free is 10mm.
It is alginate fibre of the present invention, acid fiber by polylactic, poly (propylene carbonate)/chitosan nano fiber, bamboo fibre, big The low floating short glass fiber of legumin fiber, alkali-free, rice slurry can be prepared by any prior art.
Further, the compatilizer includes the component of following parts by weight：Chitin 3, glycerine 0.7, sodium chloride 0.7th, sodium potassium tartrate tetrahydrate 2, chitosan gel rubber 20, polyethylene oxide 2；The compatilizer can significantly improve inorganic fibre in the present invention Compatibility between dimension and organic fiber, while the sporadic of raw material components of the present invention is effectively reduced, make in existing rice paper system It still is able to be stabilized under the action of light and heat without easily distributing in standby technique, keeps the performance of itself of the invention.
Further, the fire retardant includes the component of following parts by weight：Silicon nitride ceramic 40, nano-ZSM-5 point Son sieve 20.The average particle size of the fire retardant is 300um.
The silicon nitride ceramic can be compounded with nano-ZSM-5 molecular sieve synergistic, significantly improve the fire-retardant fireproof of rice paper Energy.The silicon nitride ceramic can be prepared with nano-ZSM-5 molecular sieve by any prior art.
Further, the antioxidant includes the component of following parts by weight：Grape seed polyphenols 2, mulberry-leaf extract 2, Lutein 3, bamboo extractive 2.1.The present invention uses the antioxidant of plant component, safety and environmental protection, and can improve and this hair The compatibility of bright other components, improves the service life of the present invention.
Embodiment 5
A kind of antibacterial green wallpaper, it is characterised in that include the component of following parts by weight：Alginate fibre 20, acid fiber by polylactic 25th, antioxidant 10, compatilizer 5, fire retardant 2.6, poly (propylene carbonate)/chitosan nano fiber 14, bamboo fibre 9, soybean egg The low floating short glass fiber 11 of white fiber 23, alkali-free, rice slurry 50；The soluble solid content of the rice slurry is 54%；It is described The filament diameter of the low floating short glass fiber of alkali-free is 11um, and the filament length of the low floating short glass fiber of the alkali-free is 7mm.
It is alginate fibre of the present invention, acid fiber by polylactic, poly (propylene carbonate)/chitosan nano fiber, bamboo fibre, big The low floating short glass fiber of legumin fiber, alkali-free, rice slurry can be prepared by any prior art.
Further, the compatilizer includes the component of following parts by weight：Chitin 5, glycerine 1, sodium chloride 0.4, Sodium potassium tartrate tetrahydrate 5, chitosan gel rubber 23, polyethylene oxide 3；The compatilizer can significantly improve in the present invention inorfil with Compatibility between organic fiber, while the sporadic of raw material components of the present invention is effectively reduced, make to prepare work in existing rice paper It still is able to be stabilized without easily distributing under the action of light and heat in skill, keeps the performance of itself of the invention.
Further, the fire retardant includes the component of following parts by weight：Silicon nitride ceramic 47, nano-ZSM-5 point Son sieve 22.The average particle size of the fire retardant is 400um.
The silicon nitride ceramic can be compounded with nano-ZSM-5 molecular sieve synergistic, significantly improve the fire-retardant fireproof of rice paper Energy.The silicon nitride ceramic can be prepared with nano-ZSM-5 molecular sieve by any prior art.
Further, the antioxidant includes the component of following parts by weight：Grape seed polyphenols 2.6, mulberry-leaf extract 2.4th, lutein 3.6, bamboo extractive 2.5.The present invention uses the antioxidant of plant component, safety and environmental protection, and can improve With the compatibility of other components of the present invention, service life of the invention is improved.
Comparative example 1
A kind of antibacterial green wallpaper, it is characterised in that include the component of following parts by weight：Alginate fibre 15, acid fiber by polylactic 30th, antioxidant 13, compatilizer 8, poly (propylene carbonate)/chitosan nano fiber 26, bamboo fibre 11, soybean fiber 30, The low floating short glass fiber 15 of alkali-free, rice slurry 55；The soluble solid content of the rice slurry is 65%；The alkali-free is low floating The filament diameter of short glass fiber is 15um, and the filament length of the low floating short glass fiber of the alkali-free is 10mm.
It is alginate fibre of the present invention, acid fiber by polylactic, poly (propylene carbonate)/chitosan nano fiber, bamboo fibre, big The low floating short glass fiber of legumin fiber, alkali-free, rice slurry can be prepared by any prior art.
Further, the compatilizer includes the component of following parts by weight：Chitin 3, glycerine 0.7, sodium chloride 0.7th, sodium potassium tartrate tetrahydrate 2, chitosan gel rubber 20, polyethylene oxide 2；The compatilizer can significantly improve inorganic fibre in the present invention Compatibility between dimension and organic fiber, while the sporadic of raw material components of the present invention is effectively reduced, make in existing rice paper system It still is able to be stabilized under the action of light and heat without easily distributing in standby technique, keeps the performance of itself of the invention.
Further, the antioxidant includes the component of following parts by weight：Grape seed polyphenols 2, mulberry-leaf extract 2, Lutein 3, bamboo extractive 2.1.The present invention uses the antioxidant of plant component, safety and environmental protection, and can improve and this hair The compatibility of bright other components, improves the service life of the present invention.
Comparative example 2
A kind of antibacterial green wallpaper, it is characterised in that include the component of following parts by weight：Alginate fibre 20, acid fiber by polylactic 25th, compatilizer 5, fire retardant 2.6, poly (propylene carbonate)/chitosan nano fiber 14, bamboo fibre 9, soybean fiber 23, nothing The low floating short glass fiber 11 of alkali, rice slurry 50；The soluble solid content of the rice slurry is 54%；The alkali-free is low floating short The filament diameter of glass is 11um, and the filament length of the low floating short glass fiber of the alkali-free is 7mm.
It is alginate fibre of the present invention, acid fiber by polylactic, poly (propylene carbonate)/chitosan nano fiber, bamboo fibre, big The low floating short glass fiber of legumin fiber, alkali-free, rice slurry can be prepared by any prior art.
Further, the compatilizer includes the component of following parts by weight：Chitin 5, glycerine 1, sodium chloride 0.4, Sodium potassium tartrate tetrahydrate 5, chitosan gel rubber 23, polyethylene oxide 3；The compatilizer can significantly improve in the present invention inorfil with Compatibility between organic fiber, while the sporadic of raw material components of the present invention is effectively reduced, make to prepare work in existing rice paper It still is able to be stabilized without easily distributing under the action of light and heat in skill, keeps the performance of itself of the invention.
Further, the fire retardant includes the component of following parts by weight：Silicon nitride ceramic 47, nano-ZSM-5 point Son sieve 22.The average particle size of the fire retardant is 400um.
The silicon nitride ceramic can be compounded with nano-ZSM-5 molecular sieve synergistic, significantly improve the fire-retardant fireproof of rice paper Energy.The silicon nitride ceramic can be prepared with nano-ZSM-5 molecular sieve by any prior art.
Performance test
The parameters such as all embodiments of the invention, the fire resistance of comparative example, tensile index are detected by relevant national standard method, The material specification of detection is 100g/m2, it is as a result as shown in the table.
Test event Average after flame time/s Averagely burn time/s Average char length/s Tensile index/Nmg-1 Ageing-resistant whiteness（Absolute value）Decline/%
Embodiment 1 5.4 45 108 50 4.3
Embodiment 2 5.0 41 106 52 4.2
Embodiment 3 6.3 50 112 45 3.6
Embodiment 4 6.1 55 118 47 3.8
Embodiment 5 6.4 54 115 44 3.6
Comparative example 1 2.2 27 92 59 4.9
Comparative example 2 3.9 38 104 51 6.2
It is obvious to a person skilled in the art that the invention is not restricted to the details of above-mentioned one exemplary embodiment, and do not carrying on the back In the case of spirit or essential attributes from the present invention, the present invention can be realized in other specific forms.Therefore, no matter from which From the point of view of a bit, the present embodiments are to be considered as illustrative and not restrictive, and the scope of the present invention will by appended right Ask rather than described above limits, it is intended that all changes in the implication and scope of the equivalency of claim will be fallen Include in the present invention.
Moreover, it will be appreciated that although the present specification is described in terms of embodiments, not each embodiment is only wrapped Containing an independent technical solution, this narrating mode of specification is only that those skilled in the art should for clarity Using specification as an entirety, the technical solutions in the various embodiments may also be suitably combined, forms those skilled in the art It is appreciated that other embodiment.It is noted that the technical characteristic not being described in detail in the present invention, can be by appointing One prior art is realized.

Claims (5)

1. a kind of antibacterial green wallpaper, it is characterised in that include the component of following parts by weight：Alginate fibre 13-22, poly- breast Sour fiber 23-34, antioxidant 8-15, compatilizer 3-9, fire retardant 1.4-2.9, poly (propylene carbonate)/chitosan nano fiber The low floating short glass fiber 9-17 of 12-28, bamboo fibre 8-13, soybean fiber 19-32, alkali-free, rice slurry 45-58；The rice The soluble solid content of slurry is 52%-68%；The filament diameter of the low floating short glass fiber of the alkali-free is 9-17um, the alkali-free The filament length of low floating short glass fiber is 5-12mm.
2. antibacterial green wallpaper according to claim 1, it is characterised in that the compatilizer includes following parts by weight Component：It is chitin 2-6, glycerine 0.5-1.1, sodium chloride 0.2-0.8, sodium potassium tartrate tetrahydrate 1-6, chitosan gel rubber 13-25, poly- Ethylene oxide 1.8-3.7.
3. antibacterial green wallpaper according to claim 1, it is characterised in that the fire retardant includes following parts by weight Component：Silicon nitride ceramic 35-48, nano-ZSM-5 molecular sieve 16-23.
4. antibacterial green wallpaper according to claim 3, it is characterised in that the average particle size of the fire retardant is 280-420um。
5. antibacterial green wallpaper according to claim 1, it is characterised in that the antioxidant includes following parts by weight Several components：Grape seed polyphenols 1.5-2.8, mulberry-leaf extract 1.2-2.6, lutein 2.3-4.1, bamboo extractive 1.9- 2.7。
CN201711298872.0A 2017-12-08 2017-12-08 A kind of antibacterial green wallpaper Pending CN108004836A (en)

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