CN108003788A - Cheese mixing linseed oil natural paint and preparation method thereof - Google Patents
Cheese mixing linseed oil natural paint and preparation method thereof Download PDFInfo
- Publication number
- CN108003788A CN108003788A CN201711261039.9A CN201711261039A CN108003788A CN 108003788 A CN108003788 A CN 108003788A CN 201711261039 A CN201711261039 A CN 201711261039A CN 108003788 A CN108003788 A CN 108003788A
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- China
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- parts
- linseed oil
- cheese
- agent
- natural paint
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D189/00—Coating compositions based on proteins; Coating compositions based on derivatives thereof
- C09D189/005—Casein
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
- C08K2003/265—Calcium, strontium or barium carbonate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/06—Biodegradable
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses a kind of cheese mixing linseed oil natural paint and preparation method thereof, in terms of parts by weight, which includes：300 400 parts of cheese is activated, emulsifies 300 400 parts of linseed oil, 10 30 parts of emulsifying agent, 5 10 parts of wetting agent, 14 parts of preservative, 150 300 parts of water, 0 1490 parts of other auxiliary agents.The waste water and waste residue and coating dry film that the coating of the production present invention produces are degradable, mitigate environmental protection pressure, and the also absorbable formaldehyde of coating dry film, purify the air of a room；Coating dry film does not have harmful substance release.
Description
Technical field
The invention belongs to technical field of coatings, more particularly, to a kind of cheese mixing linseed oil natural paint and its system
Preparation Method.
Background technology
The advantages that aqueous architectural coating (emulsion paint) is because of its renovation rich in color, easy for construction, easy, in Chinese market increasingly
It is used widely.Wherein interior wall coating is even more the indoor hardware fitting for becoming most of consumer.The main component of emulsion paint
Including：Synthetic resin emulsion, pigment, filler, auxiliary agent, water, wherein synthetic resin emulsion are film forming matters.The effect bag of emulsion paint
Include：Protective effect, construct drying and forming-film after, coating building surface formed protective film, obstruct atmosphere pollution, extend building
The thing service life；Decoration function, the color of emulsion paint, gloss, moulding can adjust, beautifying constructure appearance；Special role, indivedual latexes
Paint has the function of fire prevention, sound insulation, antistatic etc..
With concern of the people to health and the enhancing of environmental consciousness, emulsion paint as interior wall coating to nonpoisonous and tasteless and
Performance requirement in terms of safety and environmental protection is higher and higher.Also there is part natural paint, such as glutinous rice, corn coating at present.
Emulsion paint is water paint, and water is nontoxic in itself as solvent, but other compositions (the synthesis tree in emulsion paint
Fat liquor, auxiliary agent etc.) it is petrochemicals, production process expends mass energy.Individual adjuvants (preservative, mould inhibitor etc.) are also
With certain toxic.Part natural paint, although as glutinous rice coating, corn coating propose natural environmental-protective concept, with grain
As main component so that food resource is produced for industrial coating, causes the waste of grain resource.
Therefore, it is necessary to provide a kind of coating of safety and environmental protection.
The content of the invention
A kind of the defects of the purpose of the present invention is overcoming the prior art, there is provided coating of safety and environmental protection.
To achieve these goals, the first aspect of the present invention provides a kind of cheese mixing linseed oil natural paint, with weight
Number meter is measured, which includes：300-400 parts of cheese is activated, emulsifies 300-400 parts of linseed oil, 10-30 parts of emulsifying agent, wetting
5-10 parts of agent, 1-4 parts of preservative, 150-300 parts of water, 0-1490 parts of other auxiliary agents.
The second aspect of the present invention provides a kind of preparation method of above-mentioned cheese mixing linseed oil natural paint, the preparation side
Method includes：
By the activation cheese, the emulsification linseed oil, emulsifying agent, wetting agent, preservative, water and other optional auxiliary agents
It is uniformly mixed, the cheese mixing linseed oil natural paint is made.
Technical scheme has the following advantages that：
(1) present invention uses cheese, linseed oil source is natural, is reproducible environment-friendly materials as film forming matter；
(2) waste water and waste residue and coating dry film that the coating of the production present invention produces are degradable, mitigate environmental protection pressure,
And the also absorbable formaldehyde of coating dry film, purifies the air of a room；Coating dry film does not have harmful substance release；
(3) present invention avoids causing the waste of grain resource without using grain raw materials such as glutinous rice.
Other features and advantages of the present invention will be described in detail in subsequent specific embodiment part.
Embodiment
The preferred embodiment of the present invention is described in more detail below.Although the following describe being preferable to carry out for the present invention
Mode, however, it is to be appreciated that may be realized in various forms the present invention without should be limited by embodiments set forth herein.Phase
Instead, there is provided these embodiments are of the invention more thorough and complete in order to make, and can be by the scope of the present invention intactly
It is communicated to those skilled in the art.
The first aspect of the present invention provides a kind of cheese mixing linseed oil natural paint, in terms of parts by weight, the coating bag
Include：300-400 parts of cheese is activated, emulsifies 300-400 parts of linseed oil, 10-30 parts of emulsifying agent, 5-10 parts of wetting agent, preservative 1-4
Part, 150-300 parts of water, 0-1490 parts of other auxiliary agents.
In the present invention, other auxiliary agents refer to that the paint field in addition to emulsifying agent, wetting agent and preservative is conventional
Auxiliary agent.
Linseed oil has double bond structure closer to the distance, is formed a film by oxidation solidify afterwards.Linseed oil is mixed into cheese, can be increased
Add the water resistance and adhesive force of cheese coating.
The present invention prepares coating using technical grade cheese, linseed oil these pure natural raw materials, and environmental protection and energy saving are safe and harmless.
In accordance with the present invention it is preferred that the activation cheese is the casein aqueous solution of alkali activation.
Preferably, in terms of parts by weight, the activation cheese includes：100-200 parts of casein, 0.5-1 parts of preservative, alkali
50-200 parts and 500-900 parts of water.
Casein is the phosphor protein product in animal milk, is a kind of native protein.Not soluble in water, spherical in shape is thick
Close folded state.It can be activated with alkali, under the conditions of weak base, casein can be dissolved in water.
In accordance with the present invention it is preferred that the mass concentration of the alkali is 10-30%.
Preferably, the alkali is preferably at least one of ammonium carbonate, sodium hydroxide and monoethanolamine.
In accordance with the present invention it is preferred that the emulsification linseed oil is linseed oil and the emulsion of water.
Preferably, in terms of parts by weight, the emulsification linseed oil includes：250-400 parts of linseed oil, 10-30 parts of emulsifying agent,
2-5 parts of preservative, 600-800 parts of water.
Due to flax, oil does not dissolve in water, need to add after emulsifying agent merges oil, water emulsification and participate in painting again.
In accordance with the present invention it is preferred that other described auxiliary agents include：100-500 parts of titanium dioxide, 200-450 parts of kaolin, carbon
Sour calcium 200-500 parts, 5-10 parts of defoamer, 0-20 parts of 5-10 parts of anti-settling agent and flatting silica.
In accordance with the present invention it is preferred that the defoamer is organic silicon defoamer, the anti-settling agent is anti-settling for silica
Agent, the flatting silica are silica flatting silica.
In accordance with the present invention it is preferred that the preservative is food preservative, it is preferably potassium sorbate, soybean oil lecithin
At least one of with linseed oil.
It is safe and non-toxic using food preservative.
The dosage of preservative in the natural paint of the present invention refers to the amount of the preservative individually added in natural paint, no
Include the dosage of preservative used in other each components in coating.
Preservative used in other components in preservative and coating used can be identical in the natural paint of the present invention
It is or different.
In accordance with the present invention it is preferred that the emulsifying agent is phosphatide emulsifier.
The dosage of emulsifying agent in the natural paint of the present invention refers to the amount of the emulsifying agent individually added in natural paint, no
Include the dosage of emulsifying agent used in other each components in coating.
Emulsifying agent used in other components in emulsifying agent and coating used can be identical in the natural paint of the present invention
It is or different.
In accordance with the present invention it is preferred that the wetting agent is organosilicon wetting agent.
The organosilicon wetting agent that the present invention selects is a kind of reproducible wetting agent.
The second aspect of the present invention provides the preparation method of above-mentioned cheese mixing linseed oil natural paint, the preparation method bag
Include：
By the activation cheese, the emulsification linseed oil, emulsifying agent, wetting agent, preservative, water and other optional auxiliary agents
It is uniformly mixed, the cheese mixing linseed oil natural paint is made.
Preferably, following components is added after metering：Sequentially add portions of de-ionized water, part emulsification linseed oil,
Partial activation cheese, emulsifying agent, part defoamer are stirred evenly into dispersion cylinder；Then kaolin, calcium carbonate, titanium are sequentially added
White powder, anti-settling agent, part preservative, high speed dispersion 20 minutes to fineness are less than 60um；Add remaining activation cheese, residue disappears
Infusion, wetting agent are uniformly dispersed；It is eventually adding remaining emulsification linseed oil to be uniformly dispersed, it is small to fineness adds flatting silica high speed dispersion
In 60um, remaining preservative, remaining deionized water are added, is filtered and packaged after stirring at low speed.
Preferably, casein, preservative, alkali and water are uniformly mixed, the activation cheese is made.It is further excellent
Elect as：Casein, portions of de-ionized water, preservative are added in a mixing bowl, open the dispersion machine of a mixing bowl, keeps rotating speed
1400 revs/min, remaining deionized water is added with alkali premix, is stirred 20 minutes, and the activation cheese is made.
Preferably, linseed oil, emulsifying agent, preservative and water are uniformly mixed, the emulsification linseed oil is made.Into
One step is preferably：Deionized water is added in emulsion tank, sequentially adds emulsifying agent, preservative, high-speed stirred is uniform, is slowly added to
Linseed oil, high-speed stirred 20 minutes, obtains emulsification linseed oil.
Preferably, cheese mixing linseed oil natural paint construction method of the invention is with common interiro wall latex paint,
Can roller coating or brush application.
Preferably, each raw material for preparing the cheese mixing linseed oil natural paint of the present invention can be by commercially available
Obtain.
The present invention is further illustrated by the following examples：
The dosage of each component is parts by weight in following embodiment.
Emulsifying agent used in following embodiment is phosphatide emulsifier, and anti-settling agent is silica anti-settling agent, is disappeared
Infusion is organic silicon defoamer, and flatting silica is silica flatting silica, and wetting agent is organosilicon wetting agent.
Embodiment 1：
The present embodiment provides a kind of cheese mixing linseed oil natural paint, specific preparation method are as follows：
(1) preparation of cheese is activated：160 parts of casein, 600 parts of deionized water, 0.8 part of potassium sorbate are added
Into a mixing bowl, the dispersion machine of a mixing bowl is opened, keeps 1400 revs/min of rotating speed, 80 parts of mass concentration is 20% hydrogen-oxygen
Change sodium water solution with being added after 300 parts of deionized water premix, stir 20 minutes, obtain activation cheese；
(2) preparation of linseed oil is emulsified：700 parts of deionized water is added in emulsion tank, sequentially adds 20 parts of breast
Agent, 5 parts of potassium sorbate, high-speed stirred is uniform, is slowly added to 350 parts of linseed oil, high-speed stirred 20 minutes, is emulsified
Linseed oil；
(3) preparation of cheese mixing linseed oil natural paint：200 parts of deionized water, 150 parts of emulsification linseed oil, 250
The activation cheese, 20 parts of emulsifying agent, 2 parts of defoamer of part are added in dispersion cylinder and stir evenly, and sequentially add 300 parts of height
Ridge soil, 200 parts of calcium carbonate, 200 parts of titanium dioxide, 7 parts of anti-settling agent, 2 parts of potassium sorbate, high speed dispersion 20 minutes is to thin
Degree is less than 60um.Add 150 parts of activation cheese, 3 parts of defoamer, 10 parts of wetting agent to be uniformly dispersed, add 150 parts of breast
Change linseed oil to be uniformly dispersed, add 5 parts of flatting silica high speed dispersion to fineness and be less than 60um, be eventually adding 2 parts of sorbic acid
Potassium, 5 parts of deionized water, filter and package after stirring at low speed.
Embodiment 2：
The present embodiment provides a kind of cheese mixing linseed oil natural paint, specific preparation method are as follows：
Activate the preparation of cheese：160 parts of casein, 600 parts of deionized water, 0.8 part of potassium sorbate are added to
In a mixing bowl, the dispersion machine of a mixing bowl is opened, keeps 1400 revs/min of rotating speed, 80 parts of mass concentration is 20% hydroxide
Sodium water solution stirs 20 minutes with being added after 300 parts of deionized water premix, obtains activation cheese；
Emulsify the preparation of linseed oil：700 parts of deionized water is added in emulsion tank, sequentially adds 20 parts of emulsification
Agent, 5 parts of potassium sorbate, high-speed stirred is uniform, is slowly added to 350 parts of linseed oil, high-speed stirred 20 minutes, it is sub- to obtain emulsification
Sesame oil；
The preparation of cheese mixing linseed oil natural paint：200 parts of deionized water, 150 parts of emulsification linseed oil, 250 parts
Activation cheese, 20 parts of emulsifying agent, 2 parts of defoamer be added in dispersion cylinder and stir evenly, sequentially add 400 parts of kaolinite
Soil, 200 parts of calcium carbonate, 100 parts of titanium dioxide, 7 parts of anti-settling agent, 2 parts of potassium sorbate, high speed dispersion 20 minutes to fineness
Less than 60um.Add 150 parts of activation cheese, 3 parts of defoamer, 10 parts of wetting agent to be uniformly dispersed, add 150 parts of emulsification
Linseed oil is uniformly dispersed, and adds 5 parts of flatting silica high speed dispersion to fineness and is less than 60um, be eventually adding 2 parts potassium sorbate,
5 parts of deionized water, filters and packages after stirring at low speed.
Embodiment 3：
The present embodiment provides a kind of cheese mixing linseed oil natural paint, specific preparation method are as follows：
(1) preparation of cheese is activated：160 parts of casein, 600 parts of deionized water, 0.8 part of potassium sorbate are added
Into a mixing bowl, the dispersion machine of a mixing bowl is opened, keeps 1400 revs/min of rotating speed, 80 parts of mass concentration is 20% hydrogen-oxygen
Change sodium water solution with being added after 300 parts of deionized water premix, stir 20 minutes, obtain activation cheese；
(2) preparation of linseed oil is emulsified：700 parts of deionized water is added in emulsion tank, sequentially adds 20 parts of breast
Agent, 5 parts of potassium sorbate, high-speed stirred is uniform, is slowly added to 350 parts of linseed oil, high-speed stirred 20 minutes, is emulsified
Linseed oil；
(3) preparation of cheese mixing linseed oil natural paint：200 parts of deionized water, 150 parts of emulsification linseed oil, 250
The activation cheese, 20 parts of emulsifying agent, 2 parts of defoamer of part are added in dispersion cylinder and stir evenly, and sequentially add 200 parts of height
Ridge soil, 200 parts of calcium carbonate, 100 parts of titanium dioxide, 7 parts of anti-settling agent, 2 parts of potassium sorbate, high speed dispersion 20 minutes is to thin
Degree is less than 60um.Add 150 parts of activation cheese, 3 parts of defoamer, 10 parts of wetting agent to be uniformly dispersed, add 150 parts of breast
Change linseed oil to be uniformly dispersed, add 5 parts of flatting silica high speed dispersion to fineness and be less than 60um, be eventually adding 2 parts of sorbic acid
Potassium, 5 parts of deionized water, filter and package after stirring at low speed.
Test case
The cheese mixing linseed oil natural paint prepared to embodiment 1-3 is according to GB/T 9756-2009《Synthetic resin breast
Liquid interior wall coating》Requirement measure condition in container, application property, low-temperature stability (3 circulations), the appearance of film of middle interior finish
And drying time；Specific the performance test results are shown in Table 1.
1 various embodiments of the present invention the performance test results of table
Various embodiments of the present invention are described above, described above is exemplary, and non-exclusive, and
It is not limited to disclosed each embodiment.In the case of without departing from the scope and spirit of illustrated each embodiment, for this skill
Many modifications and changes will be apparent from for the those of ordinary skill in art field.
Claims (10)
1. a kind of cheese mixing linseed oil natural paint, it is characterised in that in terms of parts by weight, which includes：Activate cheese
300-400 parts, emulsify 300-400 parts of linseed oil, 10-30 parts of emulsifying agent, 5-10 parts of wetting agent, 1-4 parts of preservative, water 150-
300 parts, 0-1490 parts of other auxiliary agents.
2. cheese mixing linseed oil natural paint according to claim 1, wherein, the activation cheese is dry for alkali activation
Casein aqueous solution；Preferably, in terms of parts by weight, the activation cheese includes：100-200 parts of casein, preservative 0.5-1
Part, 500-900 parts of 50-200 parts of alkali and water.
3. cheese mixing linseed oil natural paint according to claim 2, wherein, the mass concentration of the alkali is 10-
30%.
4. cheese mixing linseed oil natural paint according to claim 1, wherein, the emulsification linseed oil for linseed oil with
The emulsion of water；Preferably, in terms of parts by weight, the emulsification linseed oil includes：250-400 parts of linseed oil, emulsifying agent 10-30
Part, 2-5 parts of preservative, 600-800 parts of water.
5. cheese mixing linseed oil natural paint according to claim 1, wherein, other described auxiliary agents include：Titanium dioxide
100-500 parts, 200-450 parts of kaolin, 200-500 parts of calcium carbonate, 5-10 parts of defoamer, 5-10 parts of anti-settling agent and flatting silica 0-
20 parts.
6. cheese mixing linseed oil natural paint according to claim 5, wherein, the defoamer defoams for organosilicon
Agent, the anti-settling agent are silica anti-settling agent, and the flatting silica is silica flatting silica.
7. the cheese mixing linseed oil natural paint according to any one in claim 1,2 and 4, wherein, the anti-corrosion
Agent is food preservative, is preferably at least one of potassium sorbate, soybean oil lecithin and linseed oil.
8. the cheese mixing linseed oil natural paint according to claim 1 or 4, wherein, the emulsifying agent is phospholipid breast
Agent.
9. cheese mixing linseed oil natural paint according to claim 1, wherein, the wetting agent soaks for organosilicon
Agent.
10. the preparation method of the cheese mixing linseed oil natural paint according to any one in claim 1-9, its feature
It is, which includes：
By the activation cheese, the emulsification linseed oil, emulsifying agent, wetting agent, preservative, water and other optional auxiliary agents mixing
Uniformly, the cheese mixing linseed oil natural paint is made.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711261039.9A CN108003788B (en) | 2017-12-04 | 2017-12-04 | Cheese mixed linseed oil natural coating and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711261039.9A CN108003788B (en) | 2017-12-04 | 2017-12-04 | Cheese mixed linseed oil natural coating and preparation method thereof |
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| Publication Number | Publication Date |
|---|---|
| CN108003788A true CN108003788A (en) | 2018-05-08 |
| CN108003788B CN108003788B (en) | 2020-06-30 |
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ID=62056665
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| SU1775439A1 (en) * | 1990-01-08 | 1992-11-15 | Le N Proizv Ob Pigment | Casein-oil painter's paint |
| WO2005087883A1 (en) * | 2004-03-03 | 2005-09-22 | Albaco | Emulsion based on animal or vegetable oil standoils and natural emulsifiers |
| CN1786095A (en) * | 2005-12-13 | 2006-06-14 | 张刚 | Natural plant type paint and its preparation method |
| CN104804581A (en) * | 2015-04-09 | 2015-07-29 | 牛无畏 | Environment-friendly dry powder interior wall coating and preparation method thereof |
-
2017
- 2017-12-04 CN CN201711261039.9A patent/CN108003788B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| SU1775439A1 (en) * | 1990-01-08 | 1992-11-15 | Le N Proizv Ob Pigment | Casein-oil painter's paint |
| WO2005087883A1 (en) * | 2004-03-03 | 2005-09-22 | Albaco | Emulsion based on animal or vegetable oil standoils and natural emulsifiers |
| CN1786095A (en) * | 2005-12-13 | 2006-06-14 | 张刚 | Natural plant type paint and its preparation method |
| CN104804581A (en) * | 2015-04-09 | 2015-07-29 | 牛无畏 | Environment-friendly dry powder interior wall coating and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN108003788B (en) | 2020-06-30 |
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