CN108000001A - New type stainless steel. corrosion resistance flux-cored wire - Google Patents

New type stainless steel. corrosion resistance flux-cored wire Download PDF

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Publication number
CN108000001A
CN108000001A CN201810066828.5A CN201810066828A CN108000001A CN 108000001 A CN108000001 A CN 108000001A CN 201810066828 A CN201810066828 A CN 201810066828A CN 108000001 A CN108000001 A CN 108000001A
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China
Prior art keywords
parts
medicine core
cored wire
stainless steel
corrosion resistance
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CN201810066828.5A
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Chinese (zh)
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CN108000001B (en
Inventor
张建忠
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Jiangsu Fuermu Welding Ltd By Share Ltd
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Jiangsu Fuermu Welding Ltd By Share Ltd
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Priority to CN201810066828.5A priority Critical patent/CN108000001B/en
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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K35/00Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
    • B23K35/22Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by the composition or nature of the material
    • B23K35/24Selection of soldering or welding materials proper
    • B23K35/30Selection of soldering or welding materials proper with the principal constituent melting at less than 1550 degrees C
    • B23K35/3053Fe as the principal constituent
    • B23K35/308Fe as the principal constituent with Cr as next major constituent
    • B23K35/3086Fe as the principal constituent with Cr as next major constituent containing Ni or Mn
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K35/00Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
    • B23K35/02Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by mechanical features, e.g. shape
    • B23K35/0255Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by mechanical features, e.g. shape for use in welding
    • B23K35/0261Rods, electrodes, wires
    • B23K35/0266Rods, electrodes, wires flux-cored
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K35/00Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
    • B23K35/22Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by the composition or nature of the material
    • B23K35/36Selection of non-metallic compositions, e.g. coatings, fluxes; Selection of soldering or welding materials, conjoint with selection of non-metallic compositions, both selections being of interest
    • B23K35/3601Selection of non-metallic compositions, e.g. coatings, fluxes; Selection of soldering or welding materials, conjoint with selection of non-metallic compositions, both selections being of interest with inorganic compounds as principal constituents
    • B23K35/3608Titania or titanates
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K35/00Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
    • B23K35/22Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by the composition or nature of the material
    • B23K35/36Selection of non-metallic compositions, e.g. coatings, fluxes; Selection of soldering or welding materials, conjoint with selection of non-metallic compositions, both selections being of interest
    • B23K35/368Selection of non-metallic compositions of core materials either alone or conjoint with selection of soldering or welding materials

Abstract

The invention discloses a kind of new type stainless steel. corrosion resistance flux-cored wire, including medicine core and the crust that is coated on outside medicine core, the medicine core include the component of following parts by weight:20 40 parts of rutile, 2 10 parts of feldspar, manganese metal 25,15 25 parts of crome metal, 10 15 parts of molybdenum-iron, 10 20 parts of metallic nickel, arc stabilizer 25,25 parts of ferroso-ferric oxide, 15 parts of sodium fluoride, and 15 parts of silica flour, and in the medicine core powder of above-mentioned each component composition, total percetage by weight of following component is:Cr:18% 20%, Ni:10% 14%, Mo:2% 3%, C:≤ 0.03%, Si:≤ 1%, Mn:≤ 2%, S:≤ 0.03%, P:≤ 0.045%.The present invention has the performance of brilliance in all welding positions, and face of weld has smooth, stable electric arc, spatter loss coefficient is extremely low, and welding bead is glittering, and smoothly, welding slag can be removed easily, and has preferable intercrystalline corrosion tolerance almost without oxide-film.

Description

New type stainless steel. corrosion resistance flux-cored wire
Technical field
The present invention relates to technical field of welding materials, more particularly, to a kind of new type stainless steel. corrosion resistance flux-cored wire.
Background technology
The face of weld oxide-film of existing stainless flux-cored wire is serious, and face of weld is coarse, splashes during welding general, Intercrystalline corrosion tolerance is poor, and all-position welding is poor, or even molten iron tenesmus can occur for some poor product all-position weldings now As.
The content of the invention
The present invention is above-mentioned in order to overcome the shortcomings of, there is provided a kind of new type stainless steel. corrosion resistance flux-cored wire of energy all-position welding, Including medicine core and the crust being coated on outside medicine core, the medicine core includes the component of following parts by weight:20-40 parts of rutile, length 2-10 parts of stone, manganese metal 2-5,15-25 parts of crome metal, 10-15 parts of molybdenum-iron, 10-20 parts of metallic nickel, arc stabilizer 2-5, four oxidations three 2-5 parts of iron, 1-5 parts of sodium fluoride, and 1-5 parts of silica flour, and in the medicine core powder of above-mentioned each component composition, following component Total percetage by weight is:Cr:18%-20%, Ni:10%-14%, Mo:2%-3%, C:≤ 0.03%, Si:≤ 1%, Mn: ≤ 2%, S:≤ 0.03%, P:≤ 0.045%.
New type stainless steel. corrosion resistance flux-cored wire of the present invention, the arc stabilizer include potassium oxide and sodium oxide molybdena.
The weight ratio of new type stainless steel. corrosion resistance flux-cored wire of the present invention, potassium oxide and sodium oxide molybdena is 3:1.
New type stainless steel. corrosion resistance flux-cored wire of the present invention, the crust are 00Cr19Ni10 (304L) steel band, steel band include with The component of lower percetage by weight:C:≤ 0.03%, Si:≤ 1%, Mn:≤ 2%, Cr:18%-20%, Ni:8%-12%, S:≤ 0.03%, P:≤ 0.035%.
New type stainless steel. corrosion resistance flux-cored wire of the present invention, medicinal powder filling rate are 23%-25%.
The beneficial effects of the invention are as follows:
The present invention has the performance of brilliance in all welding positions, and face of weld has smoothly, stablizes almost without oxide-film Electric arc, spatter loss coefficient is extremely low, and welding bead is glittering, and smoothly, welding slag can be removed easily, and has preferable intercrystalline corrosion tolerance.
Embodiment
The present invention is described in further detail now.
A kind of new type stainless steel. corrosion resistance flux-cored wire, including medicine core and the crust that is coated on outside medicine core, medicinal powder filling rate be 23%-25%.The crust is 00Cr19Ni10 (304L) steel band, and steel band includes the component of following percetage by weight:C:≤ 0.03%, Si:≤ 1%, Mn:≤ 2%, Cr:18%-20%, Ni:8%-12%, S:≤ 0.03%, P:≤ 0.035%.304L The mechanical property of stainless steel:Yield strength >=205N/mm2, tensile strength >=520N/mm2, elongation percentage >=40%.
The medicine core includes the component of following parts by weight:20-40 parts of rutile, 2-10 parts of feldspar, manganese metal 2-5, metal 15-25 parts of chromium, 10-15 parts of molybdenum-iron, 10-20 parts of metallic nickel, arc stabilizer 2-5,2-5 parts of ferroso-ferric oxide, 1-5 parts of sodium fluoride, with And 1-5 parts of silica flour, wherein, it is 3 that arc stabilizer, which includes weight ratio,:1 potassium oxide and sodium oxide molybdena.And in above-mentioned each component composition In medicine core powder, total percetage by weight of following component is:Cr:18%-20%, Ni:10%-14%, Mo:2%-3%, C: ≤ 0.03%, Si:≤ 1%, Mn:≤ 2%, S:≤ 0.03%, P:≤ 0.045%.
The present invention, as crust, by five groups of uniformly mixed medicine core powders of steel band parcel, is drawn using 304L steel bands through rolling It is five groups of flux-cored wires of 1.2mm to pull into diameter, i.e. the stainless steel weldering flux-cored wire of embodiment 1-5.Each component is pressed in its medicine core The proportioning of following table 1 is made, unit g
Table 1:
In the molten golden chemical composition of the stainless flux-cored wire of 1 ratio of above-described embodiment production, manganese metal, chromium, nickel, molybdenum contain Amount is relatively low, and rutile and feldspar ratio are higher, and face of weld oxide-film is serious, and face of weld is coarse, splashes during welding general, All-position welding is poor.Therefore do not do physical testing.
The molten aurification welded in the stainless steel medicine core of 2 ratio of above-described embodiment production studies sub-wire, and manganese metal, chromium, nickel, molybdenum contain Amount is suitable, but stabilising arc agent content is relatively low, and the oxide-film of face of weld is still very serious, and smooth surface is splashed increases, all positon Welding is better than embodiment 1, therefore does not do Physical Experiment.
In the molten golden chemical composition of the stainless flux-cored wire of 3 ratio of above-described embodiment production, manganese metal, chromium, nickel, molybdenum contain Amount is suitable, but ferroso-ferric oxide content is relatively low, and the oxide-film of face of weld has taken on a new look, smooth surface, and splash bigger, Quan Wei Welding is put with embodiment 2, Physical Experiment Data is qualified, but anti intercrystalline corrosion experiment is unqualified.
In the molten golden chemical composition of the stainless flux-cored wire of 4 ratio of above-described embodiment production, the content of each component is closed Suitable, the oxide-film of face of weld does not have substantially, smooth surface, splashes small, and all-position welding is excellent, and Physical Experiment Data is qualified, resists Intergranular corrosion test scrapes through.
In the molten golden chemical composition of the stainless flux-cored wire of 5 ratio of above-described embodiment production, the content of each component is closed Suitable, the oxide-film of face of weld does not have, smooth surface, splashes small, and all-position welding is excellent, and Physical Experiment Data is qualified, anti-intergranular Corrosion test is qualified.
In conclusion the molten golden chemical composition of the stainless flux-cored wire produced in the ratio of the present invention, face of weld are several There is no oxide-film, there is smooth, stable electric arc, spatter loss coefficient is extremely low, and welding bead is glittering, and smoothly, welding slag can be removed easily, in institute There is the performance that welding position has brilliance, and there is preferable intercrystalline corrosion tolerance.
Above-mentioned according to the present invention is enlightenment, by above-mentioned description, relevant staff completely can without departing from In the range of this invention technological thought, various changes and amendments are carried out.The technical scope of this invention is not limited to In the content on specification, it is necessary to determine its technical scope according to right.

Claims (5)

1. a kind of new type stainless steel. corrosion resistance flux-cored wire, it is characterised in that including medicine core and the crust being coated on outside medicine core, the medicine Core includes the component of following parts by weight:
In the medicine core powder of above-mentioned each component composition, total percetage by weight of following component is:Cr:18%-20%, Ni: 10%-14%, Mo:2%-3%, C:≤ 0.03%, Si:≤ 1%, Mn:≤ 2%, S:≤ 0.03%, P:≤ 0.045%.
2. new type stainless steel. corrosion resistance flux-cored wire according to claim 1, it is characterised in that the arc stabilizer include potassium oxide and Sodium oxide molybdena.
3. new type stainless steel. corrosion resistance flux-cored wire according to claim 2, it is characterised in that the weight ratio of potassium oxide and sodium oxide molybdena For 3:1.
4. new type stainless steel. corrosion resistance flux-cored wire according to claim 1, it is characterised in that the crust is 00Cr19Ni10 (304L) steel band, steel band include the component of following percetage by weight:C:≤ 0.03%, Si:≤ 1%, Mn:≤ 2%, Cr: 18%-20%, Ni:8%-12%, S:≤ 0.03%, P:≤ 0.035%.
5. new type stainless steel. corrosion resistance flux-cored wire according to claim 1, it is characterised in that medicinal powder filling rate is 23%-25%.
CN201810066828.5A 2018-01-24 2018-01-24 Novel stainless steel flux-cored wire Active CN108000001B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201810066828.5A CN108000001B (en) 2018-01-24 2018-01-24 Novel stainless steel flux-cored wire

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CN201810066828.5A CN108000001B (en) 2018-01-24 2018-01-24 Novel stainless steel flux-cored wire

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109604867A (en) * 2018-12-30 2019-04-12 柳州凯通新材料科技有限公司 A kind of highly wear-resisting alloy steel welding wire medicine core
CN110102930A (en) * 2019-04-29 2019-08-09 江苏九洲新材料科技有限公司 A kind of E304L flux-cored wire matched with 304L steel
CN112872653A (en) * 2021-02-04 2021-06-01 苏州鑫之泰焊接材料有限公司 Stainless steel flux-cored wire without gas protection and preparation method thereof

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US5171968A (en) * 1991-09-30 1992-12-15 Inco Alloys International, Inc. Low porosity welding electrode
CN101134271A (en) * 2007-10-11 2008-03-05 北京工业大学 Full-position soldering biphase stainless steel flux-cored wire
CN101690996A (en) * 2009-10-16 2010-04-07 河北翼辰实业集团有限公司 All-position niobium -contained stainless steel flux-cored wire
CN101804533A (en) * 2010-04-27 2010-08-18 上海林肯电气有限公司 Gas shielded flux-cored wire for welding with low temperature, high toughness and full positions
CN102179640A (en) * 2011-04-26 2011-09-14 武汉铁锚焊接材料股份有限公司 High-strength and high-toughness metal powder flux-cored wire
CN102229029A (en) * 2011-05-30 2011-11-02 中冶焊接科技有限公司 Flux-cored wire for austenitic stainless steel all-position welding
CN102451961A (en) * 2010-10-20 2012-05-16 中冶焊接科技有限公司 Flux-cored wire for austenitic stainless steel welding
CN104117789A (en) * 2014-08-06 2014-10-29 武汉铁锚焊接材料股份有限公司 Low temperature steel flux-cored welding wire
CN104588915A (en) * 2014-12-09 2015-05-06 天津大桥金属焊丝有限公司 Gas shield build-up welding flux-cored wire for hot-forging die
CN106695156A (en) * 2016-12-27 2017-05-24 上海焊接器材有限公司 Super duplex stainless steel flux-cored wire
CN107052617A (en) * 2017-03-20 2017-08-18 武汉铁锚焊接材料股份有限公司 A kind of 1000MPa grade high-strengths all positon ultralow-hydrogen low flux-cored wire and its welding method

Patent Citations (11)

* Cited by examiner, † Cited by third party
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CN101690996A (en) * 2009-10-16 2010-04-07 河北翼辰实业集团有限公司 All-position niobium -contained stainless steel flux-cored wire
CN101804533A (en) * 2010-04-27 2010-08-18 上海林肯电气有限公司 Gas shielded flux-cored wire for welding with low temperature, high toughness and full positions
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CN104117789A (en) * 2014-08-06 2014-10-29 武汉铁锚焊接材料股份有限公司 Low temperature steel flux-cored welding wire
CN104588915A (en) * 2014-12-09 2015-05-06 天津大桥金属焊丝有限公司 Gas shield build-up welding flux-cored wire for hot-forging die
CN106695156A (en) * 2016-12-27 2017-05-24 上海焊接器材有限公司 Super duplex stainless steel flux-cored wire
CN107052617A (en) * 2017-03-20 2017-08-18 武汉铁锚焊接材料股份有限公司 A kind of 1000MPa grade high-strengths all positon ultralow-hydrogen low flux-cored wire and its welding method

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109604867A (en) * 2018-12-30 2019-04-12 柳州凯通新材料科技有限公司 A kind of highly wear-resisting alloy steel welding wire medicine core
CN110102930A (en) * 2019-04-29 2019-08-09 江苏九洲新材料科技有限公司 A kind of E304L flux-cored wire matched with 304L steel
CN112872653A (en) * 2021-02-04 2021-06-01 苏州鑫之泰焊接材料有限公司 Stainless steel flux-cored wire without gas protection and preparation method thereof

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