CN107999957A - Avoid the protective materials of laser punching damage cavity part opposite walls and insert method - Google Patents

Avoid the protective materials of laser punching damage cavity part opposite walls and insert method Download PDF

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Publication number
CN107999957A
CN107999957A CN201610960509.XA CN201610960509A CN107999957A CN 107999957 A CN107999957 A CN 107999957A CN 201610960509 A CN201610960509 A CN 201610960509A CN 107999957 A CN107999957 A CN 107999957A
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China
Prior art keywords
protective materials
opposite walls
ultrafast laser
part opposite
avoiding
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CN201610960509.XA
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CN107999957B (en
Inventor
张晓兵
纪亮
蔡敏
张伟
焦佳能
马宁
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AVIC Beijing Aeronautical Manufacturing Technology Research Institute
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AVIC Beijing Aeronautical Manufacturing Technology Research Institute
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K26/00Working by laser beam, e.g. welding, cutting or boring
    • B23K26/18Working by laser beam, e.g. welding, cutting or boring using absorbing layers on the workpiece, e.g. for marking or protecting purposes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K26/00Working by laser beam, e.g. welding, cutting or boring
    • B23K26/36Removing material
    • B23K26/38Removing material by boring or cutting
    • B23K26/382Removing material by boring or cutting by boring

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  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Optics & Photonics (AREA)
  • Plasma & Fusion (AREA)
  • Mechanical Engineering (AREA)
  • Laser Beam Processing (AREA)
  • Laminated Bodies (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Materials For Medical Uses (AREA)

Abstract

The invention discloses a kind of protective materials for avoiding ultrafast laser drilling damage cavity part opposite walls, including base material and adhesive, the base material is the spherical particle of aluminium oxide ceramics, and the component of described adhesive includes polyethylene alcohol and water, and the quality parts ratio of the polyethylene alcohol and water is 12:100;The spherical particle of aluminium oxide ceramics selects three kinds of specifications:Specification 1, diameter range:0.2~0.35mm;Specification 2, diameter range:0.4~0.6mm;Specification 3, diameter range:0.6~0.8mm;It can also be used in mixed way;Described adhesive further includes 10 surfactants of OP that the titania powder that the aluminium-hydroxide powder that mass fraction is 10 and/or mass fraction are 10 and/or mass fraction are 0.3.The protective materials of the present invention is suitable for ultrafast laser drilling, avoids ultrafast laser from damaging inner cavity opposite walls in drilling;It is easy to be filled in inner cavity and is easy to remove from inner cavity after completing drilling.

Description

Avoid the protective materials of laser punching damage cavity part opposite walls and insert method
Technical field
The invention belongs to technical field of laser processing, is related to a kind of ultrafast laser that is suitable for and adds in the cavity parts such as blade Work aperture and avoid the protective materials of ultrafast laser damage cavity part opposite walls after through hole and insert method.
Background technology
Laser punching is the engine thermal end pieces such as one of main application fields of Laser Processing, Laser Processing turbo blade Air film hole is the typical case of hole fabrication techniques.In the past mainly using millisecond pulse Laser Processing blade air film hole, but aperture exists Recast layer, even micro-crack, if the drilling on the turbo blade with thermal barrier coating, due to larger thermodynamic activity, easily lead The defects of causing coating delamination, chip off-falling.Picosecond, femtosecond laser remove material there is non-thermofusible, heat affecting is minimum, because This is suitable on turbo blade, is included on the turbo blade with thermal barrier coating processing high quality aperture, at present can be with Machining small hole wall is realized without recast layer, micro-crack, heat affected area, coating is almost without thermic defect.
As millisecond laser punching, picosecond, femtosecond laser drilling also face asking for damaged blade inner cavity after laser via Topic, as shown in Figure 1, therefore, it is necessary to avoid laser from directly acting on inner cavity opposite walls in blade inner cavity filling protective materials, this is anti- Protective material has the characteristics that to avoid laser breakdown within a certain period of time, it is clear that the time is longer, and protection effect is better.
For millisecond laser punching, protective materials more ripe at present is polytetrafluoroethylene (PTFE), is applied in engineering.But Ultrafast laser(Containing picosecond laser, femtosecond laser)Find that ultrafast laser easily penetrates polytetrafluoroethylene material, 1mm in drilling experiment The thick material, time, that is, breakdown, effective protection when can not realize drilling to blade inner cavity opposite walls less than 1s, without It is very serious using safeguard procedures, damage.
Can realize inner cavity effectively protection be to realize that ultrafast laser high quality hole fabrication techniques should in blade air film hole machined Key, therefore, is badly in need of exploitation suitable for the protective materials of ultrafast laser drilling and inserts method.
The content of the invention
The purpose of the present invention:A kind of brand-new protective materials is developed, suitable for ultrafast laser drilling, avoids ultrafast laser from existing Inner cavity opposite walls are damaged during drilling;It is easy to be filled in inner cavity and is easy to remove from inner cavity after completing drilling.
To achieve these goals, present invention employs following technical solution:
A kind of protective materials for avoiding ultrafast laser drilling damage cavity part opposite walls, including base material and adhesive, the base Material is the spherical particle of aluminium oxide ceramics, and the component of described adhesive includes polyvinyl alcohol(PVA)And water, the polyvinyl alcohol (PVA)Quality parts ratio with water is 12:100;
The spherical particle of aluminium oxide ceramics usually selects three kinds of specifications:Specification 1, diameter range:0.2~0.35mm;Specification 2, Diameter range:0.4~0.6mm;Specification 3, diameter range:0.6~0.8mm;It can also be used in mixed way;
The selection principle of the spherical particle of aluminium oxide ceramics is:The larger specification of particle size is usually selected, when its is anti-breakdown Between it is longer;But in the case of bore passages are less, such as within 1mm, bulky grain filling gap causes greatly protection effect on the contrary Difference, on the premise of the anti-breakdown time meets the requirements, can be selected the less specification of particle size;
The effect of described adhesive is that the alumina ceramic grain bonds together;
Described adhesive is being 12 including quality parts ratio:On the basis of 100 polyethylene alcohol and water, it can also include:Quality Number is 10 aluminium-hydroxide powder(AL(OH)3)And/or the titania powder that mass fraction is 10(TiO2)And/or quality Number is 0.3 OP-10 surfactants;
The configuration step of described adhesive is:Two kinds of aluminium hydroxide, titanium dioxide powder stirrings are added in water;Addition polymerization ethene Alcohol;Add OP-10 surfactants;Finally stir the mixture for uniformly.
Avoid the protective materials of ultrafast laser drilling damage cavity part opposite walls inserts method, is to fill out the protective materials Enter the method for inner cavity of component, including:
Method one:By prepared adhesive and the spherical particle of base material aluminium oxide ceramics with 1 ︰ 2~1 of quality parts ratio:5 are mixed Close, need the inner cavity protected with appropriate method such as manual expression or squeeze method etc., injection part after mixing, Gu Change.
Method two:Appropriate method is taken such as to pour into by hand or vibrate injection the spherical particle of base material aluminium oxide ceramics, Injection part needs the inner cavity protected, then adhesive is penetrated into inner cavity, adhesive is mixed with the spherical particle of aluminium oxide ceramics Uniformly;80 DEG C -120 DEG C naturally dries again, or complete naturally dry are heated to, makes protective materials dry and cures.
Beneficial effects of the present invention:1st, different materials ultrafast laser damage threshold testing experiment is based on first, preferably, is configured It is suitable for the protective materials of ultrafast laser drilling, has reached avoid ultrafast laser damage after through hole with cavity structure part The effect of inner cavity opposite walls, the material of research and development have no report both at home and abroad;2nd, protective materials is realized to be easy to insert and out of blade Removed in chamber:1)Protective materials base material has selected form of spherical particles aluminum oxide base material, has good mobility;2)It is configured with specially Granular material is bonded and is solidified togather with adhesive, and original state is mushy stage after adhesive mixing, same tool There is preferable mobility, suitably inject and fill up part irregular shape inner cavity, and realize close to tabular alumina ceramics material The protection effect of material.
Brief description of the drawings
Damage from laser inner cavity of component schematic diagram after through hole when Fig. 1 is unshielded material;
Fig. 2 is protective materials performance evaluation test principle schematic diagram of the present invention.
Embodiment
Below in conjunction with the attached drawing in the embodiment of the present invention, the technical solution in the embodiment of the present invention is carried out clear, complete Site preparation describes.
4 kinds of protective materials are configured with according to technical solution(Sample 2~5), and protection effect is verified.Sample 1 To be not coated with the metallic plate of protective materials.
Table 1 is the anti-breakdown time contrast of different size protective materials, and protective materials barrier propterty test principle schematic diagram is shown in The protective materials of Fig. 2,2mm thickness is placed in 1mm thick sheet metals lower surface, breakdown time refer to laser completely penetrate through protective materials formed it is logical The time in hole, it is clear that the protection effect of specification 3 is best, 1 breakdown time of specification(Effective protective time)Also above 10s.
The anti-breakdown time contrast of 1 varying particle size protective materials of table
Sample Composition Breakdown time/s
1 Metallic plate 7.7s
2 1 substrate particles protective materials of metallic plate+specification 19.4s
3 2 substrate particles protective materials of metallic plate+specification 88.3s
4 3 substrate particles protective materials of metallic plate+specification 120s
5 Metallic plate+specification 2 and 3 hybrid substrate particle protection material of specification 97s

Claims (7)

  1. A kind of 1. protective materials for avoiding ultrafast laser drilling damage cavity part opposite walls, it is characterised in that including base material and Adhesive, the base material are the spherical particle of aluminium oxide ceramics, and the component of described adhesive includes polyethylene alcohol and water, the poly- second The quality parts ratio of alkene alcohol and water is 12:100.
  2. 2. the protective materials according to claim 1 for avoiding ultrafast laser drilling damage cavity part opposite walls, its feature It is, the spherical particle of aluminium oxide ceramics selects three kinds of specifications:Specification 1, diameter range:0.2~0.35mm;Specification 2, diameter Scope:0.4~0.6mm;Specification 3, diameter range:0.6~0.8mm;It can also be used in mixed way.
  3. 3. the protective materials according to claim 2 for avoiding ultrafast laser drilling damage cavity part opposite walls, its feature It is, the selection principle of the spherical particle of aluminium oxide ceramics is:The larger specification of particle size is usually selected, but is led in inner cavity In the case of road is less, the less specification of particle size is selected.
  4. 4. the protective materials according to claim 1 for avoiding ultrafast laser drilling damage cavity part opposite walls, its feature It is, described adhesive is being 12 including quality parts ratio:On the basis of 100 polyethylene alcohol and water, further include:Mass fraction The OP-10 tables that the titania powder and/or mass fraction that aluminium-hydroxide powder and/or mass fraction for 10 are 10 are 0.3 Face activating agent.
  5. 5. the protective materials according to claim 4 for avoiding ultrafast laser drilling damage cavity part opposite walls, its feature It is, the configuration step of described adhesive is:Two kinds of aluminium hydroxide, titanium dioxide powder stirrings are added in water;Addition polymerization ethene Alcohol;Add OP-10 surfactants;Finally stir the mixture for uniformly.
  6. 6. any one protective materials for avoiding ultrafast laser drilling damage cavity part opposite walls inserts such as claim 1-5 Method, it is characterised in that:By prepared adhesive and the spherical particle of base material aluminium oxide ceramics with 1 ︰ 2~1 of quality parts ratio:5 Mixed, inject the inner cavity that part needs to protect after mixing, cure.
  7. 7. any one protective materials for avoiding ultrafast laser drilling damage cavity part opposite walls inserts such as claim 1-5 Method, it is characterised in that:The inner cavity that the spherical particle injection part of base material aluminium oxide ceramics is needed to protect, then adhesive is penetrated into In inner cavity, adhesive is set to be uniformly mixed with the spherical particle of aluminium oxide ceramics;80 DEG C -120 DEG C naturally dries again are heated to, or completely Naturally dry, makes protective materials dry and cures.
CN201610960509.XA 2016-10-28 2016-10-28 Protective material for preventing laser hole-making from damaging opposite wall of cavity part and filling method Active CN107999957B (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111702351A (en) * 2020-06-30 2020-09-25 中国航发动力股份有限公司 Integrated manufacturing method of turbine blade air film hole based on ceramic core
CN113770567A (en) * 2021-09-18 2021-12-10 中国航空制造技术研究院 Filling system and filling method for turbine blade laser hole-making protective material
CN114273802A (en) * 2020-09-27 2022-04-05 中国科学院宁波材料技术与工程研究所 Laser drilling back injury protection method and device
CN115026420A (en) * 2022-06-07 2022-09-09 哈尔滨工业大学 Method for avoiding damage to wall in ultrafast laser processing cavity

Citations (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1156021A1 (en) * 2000-05-19 2001-11-21 Asahi Glass Co., Ltd. Hollow aluminosilicate glass microspheres and process for their production
CN1453243A (en) * 2003-05-29 2003-11-05 上海交通大学 Prepn of large grain spherical submicron/nano composite fiber-ceramic powder
CN1511931A (en) * 2000-12-08 2004-07-14 申保安 Full loss mechanical lubricating oil
CN1919792A (en) * 2006-09-04 2007-02-28 青岛大学 Manufacture method of silicon carbide refractory ceramics material
US20070175872A1 (en) * 2006-01-27 2007-08-02 Rhoades Lawrence J Laser back wall protection by particulate shading
CN101220211A (en) * 2007-12-18 2008-07-16 苏州大学 Anti-laser composite resin and method for producing the same
CN102085606A (en) * 2009-12-04 2011-06-08 西门子公司 Filler material when drilling passageway holes in hollow components, method and device for same
CN102153335A (en) * 2011-04-02 2011-08-17 西南科技大学 Machinable aluminium oxide ceramics and preparation method of machinable aluminium oxide ceramics
CN102950378A (en) * 2012-09-19 2013-03-06 沈阳黎明航空发动机(集团)有限责任公司 Laser processing protective layer
CN103635281A (en) * 2011-07-05 2014-03-12 罗伯特·博世有限公司 Method for generating at least one through-hole and device for carrying out such a method
CN104651830A (en) * 2015-01-26 2015-05-27 华北电力大学 Powdered material and method for synthesizing ceramic particle reinforced cladding layer on aluminum alloy surface
CN104827194A (en) * 2015-05-13 2015-08-12 西安交通大学 Method for rear wall protection in laser processing of turbine blade by using water and silicon dioxide

Patent Citations (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1156021A1 (en) * 2000-05-19 2001-11-21 Asahi Glass Co., Ltd. Hollow aluminosilicate glass microspheres and process for their production
CN1511931A (en) * 2000-12-08 2004-07-14 申保安 Full loss mechanical lubricating oil
CN1453243A (en) * 2003-05-29 2003-11-05 上海交通大学 Prepn of large grain spherical submicron/nano composite fiber-ceramic powder
US20070175872A1 (en) * 2006-01-27 2007-08-02 Rhoades Lawrence J Laser back wall protection by particulate shading
CN1919792A (en) * 2006-09-04 2007-02-28 青岛大学 Manufacture method of silicon carbide refractory ceramics material
CN101220211A (en) * 2007-12-18 2008-07-16 苏州大学 Anti-laser composite resin and method for producing the same
CN102085606A (en) * 2009-12-04 2011-06-08 西门子公司 Filler material when drilling passageway holes in hollow components, method and device for same
CN102153335A (en) * 2011-04-02 2011-08-17 西南科技大学 Machinable aluminium oxide ceramics and preparation method of machinable aluminium oxide ceramics
CN103635281A (en) * 2011-07-05 2014-03-12 罗伯特·博世有限公司 Method for generating at least one through-hole and device for carrying out such a method
CN102950378A (en) * 2012-09-19 2013-03-06 沈阳黎明航空发动机(集团)有限责任公司 Laser processing protective layer
CN104651830A (en) * 2015-01-26 2015-05-27 华北电力大学 Powdered material and method for synthesizing ceramic particle reinforced cladding layer on aluminum alloy surface
CN104827194A (en) * 2015-05-13 2015-08-12 西安交通大学 Method for rear wall protection in laser processing of turbine blade by using water and silicon dioxide

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111702351A (en) * 2020-06-30 2020-09-25 中国航发动力股份有限公司 Integrated manufacturing method of turbine blade air film hole based on ceramic core
CN114273802A (en) * 2020-09-27 2022-04-05 中国科学院宁波材料技术与工程研究所 Laser drilling back injury protection method and device
CN113770567A (en) * 2021-09-18 2021-12-10 中国航空制造技术研究院 Filling system and filling method for turbine blade laser hole-making protective material
CN115026420A (en) * 2022-06-07 2022-09-09 哈尔滨工业大学 Method for avoiding damage to wall in ultrafast laser processing cavity
CN115026420B (en) * 2022-06-07 2024-10-01 哈尔滨工业大学 Method for avoiding wall damage in ultrafast laser processing cavity

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