CN107988849A - 一种新型防刮壁纸 - Google Patents

一种新型防刮壁纸 Download PDF

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CN107988849A
CN107988849A CN201711297753.3A CN201711297753A CN107988849A CN 107988849 A CN107988849 A CN 107988849A CN 201711297753 A CN201711297753 A CN 201711297753A CN 107988849 A CN107988849 A CN 107988849A
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姚景城
陈松
周振威
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Abstract

本发明提供一种新型防刮壁纸，包括以下重量份数的组分：大豆蛋白纤维11‑17、竹麻纤维23‑34、抗氧化剂6‑11、相容剂2‑7、阻燃剂0.8‑3.4、丙烯酸纤维18‑31、羟丁基壳聚糖24‑33、无碱低浮长玻纤6‑13、糯米浆料36‑49；所述糯米浆料的可溶性固形物含量为45%‑55%；所述无碱低浮长玻纤的单丝直径为28‑35um，所述无碱低浮长玻纤的单丝长度为9‑18mm。本发明将功能化融入到壁纸中，符合壁纸在现代家居中的应用和发展的要求。

Description

一种新型防刮壁纸
技术领域
本发明涉及装饰材料技术领域，具体涉及一种新型防刮壁纸。
背景技术
随着人民生活水平的不断提高，人民对装修的环保要求越来越重视，环保装修是指在对房屋进行装修时采用环保型的材料来对房屋进行装饰，使用的材料要是能够保护环境的，对环境造成的危害是最小的，真正的环保装修是不存在的，只有相对的环保装修。所以要做好环保装修就要选择较为环保的装修材料，才能有效的减少污染对人民身体健康的影响。
用壁纸装饰居室能营造特有的装饰氛围，并体现用户的个性。壁纸不仅价格便宜，而且图案及色彩丰富，装饰效果富有立体感，是许多用户选择的装饰材料。但是现有的壁纸一般仅具有单一的装饰性，大多采用人造化工材料，缺乏其它的综合性能，难以满足人们对于壁纸更高的要求。
发明内容
有鉴于此，本发明提供一种新型防刮壁纸，本发明将壁纸从低级到高级进行升级，从单一的装饰性扩展为全面的综合性能，材质也将从人造化工材料变化为新型天然环保节能材料，并将功能化融入到壁纸中，符合壁纸在现代家居中的应用和发展的要求。
本发明的技术方案为：一种新型防刮壁纸，其特征在于，包括以下重量份数的组分：大豆蛋白纤维 11-17、竹麻纤维23-34、抗氧化剂6-11、相容剂2-7、阻燃剂0.8-3.4、丙烯酸纤维18-31、羟丁基壳聚糖24-33、无碱低浮长玻纤6-13、糯米浆料36-49；所述糯米浆料的可溶性固形物含量为45%-55%；所述无碱低浮长玻纤的单丝直径为 28-35um，所述无碱低浮长玻纤的单丝长度为9-18mm。
本发明所述的大豆蛋白纤维、竹麻纤维、丙烯酸纤维、羟丁基壳聚糖、无碱低浮长玻纤、糯米浆料均可通过任一现有技术制备获得。
进一步的，所述相容剂包括以下重量份数的组分：羟乙基纤维素2-6、甘露醇0.2-0.7、氯酸钾0.03-0.09、酒石酸钾钠1-6、明胶4-11、聚甲基丙烯酸 0.8-2.2；所述相容剂可以显著提高本发明中无机纤维与有机纤维之间的相容性，同时有效降低本发明原料组分的散发性，使在现有的壁纸制备工艺中在光和热的作用下仍能够稳定存在而不易散发，保持本发明本身的性能。
进一步的，所述阻燃剂包括以下重量份数的组分：氮化硅陶瓷粉 19-27、纳米磷酸铝分子筛5-9。所述阻燃剂的平均颗粒粒径为130-270um。
所述氮化硅陶瓷粉可与纳米磷酸铝分子筛协效复配，显著提高壁纸的阻燃防火性能。所述氮化硅陶瓷粉与纳米磷酸铝分子筛可通过任一现有技术制备得到。
进一步的，所述抗氧化剂包括以下重量份数的组分：杨梅树皮素 3-7、桑叶提取物2-6、叶黄素 5-11。本发明采用植物成分的抗氧化剂，安全环保，并能够提高与本发明的其它组分的相容性，提高本发明的使用寿命。
本发明中，采用植物纤维与有机纤维相结合，复配本发明的其他组分可赋予壁纸新的性能；在本发明中添加植物性抗氧化剂，保证了抗老化性能，显著提高了使用寿命；使用了阻燃剂，使制备的壁纸的防火阻燃性能大大提高；本发明配方简单，原材料选购方便，使用成本低，生产出的壁纸产品性能稳定，防刮性能好；本发明具有优异的综合性能，可通过本领域任一现有技术的制备工艺制得，符合壁纸在现代家居中的应用和发展的要求。
具体实施方式
下面结合实施例对本发明作进一步详细的描述，但本发明的实施方式不限于此。
实施例1
一种新型防刮壁纸，其特征在于，包括以下重量份数的组分：大豆蛋白纤维 11、竹麻纤维23、抗氧化剂6、相容剂2、阻燃剂0.8、丙烯酸纤维18、羟丁基壳聚糖24、无碱低浮长玻纤6、糯米浆料36；所述糯米浆料的可溶性固形物含量为45%；所述无碱低浮长玻纤的单丝直径为28-35um，所述无碱低浮长玻纤的单丝长度为9mm。
本发明所述的大豆蛋白纤维、竹麻纤维、丙烯酸纤维、羟丁基壳聚糖、无碱低浮长玻纤、糯米浆料均可通过任一现有技术制备获得。
进一步的，所述相容剂包括以下重量份数的组分：羟乙基纤维素2、甘露醇0.2、氯酸钾0.03、酒石酸钾钠1、明胶4、聚甲基丙烯酸 0.8；所述相容剂可以显著提高本发明中无机纤维与有机纤维之间的相容性，同时有效降低本发明原料组分的散发性，使在现有的壁纸制备工艺中在光和热的作用下仍能够稳定存在而不易散发，保持本发明本身的性能。
进一步的，所述阻燃剂包括以下重量份数的组分：氮化硅陶瓷粉 19、纳米磷酸铝分子筛5。所述阻燃剂的平均颗粒粒径为130um。
所述氮化硅陶瓷粉可与纳米磷酸铝分子筛协效复配，显著提高壁纸的阻燃防火性能。所述氮化硅陶瓷粉与纳米磷酸铝分子筛可通过任一现有技术制备得到。
进一步的，所述抗氧化剂包括以下重量份数的组分：杨梅树皮素3、桑叶提取物 2、叶黄素 5。本发明采用植物成分的抗氧化剂，安全环保，并能够提高与本发明的其它组分的相容性，提高本发明的使用寿命。
本发明中，采用植物纤维与有机纤维相结合，复配本发明的其他组分可赋予壁纸新的性能；在本发明中添加植物性抗氧化剂，保证了抗老化性能，显著提高了使用寿命；使用了阻燃剂，使制备的壁纸的防火阻燃性能大大提高；本发明配方简单，原材料选购方便，使用成本低，生产出的壁纸产品性能稳定，防刮性能好；本发明具有优异的综合性能，可通过本领域任一现有技术的制备工艺制得，符合壁纸在现代家居中的应用和发展的要求。
本实施例优选的制备工艺为：将大豆蛋白纤维、竹麻纤维、丙烯酸纤维、羟丁基壳聚糖、无碱低浮长玻纤、糯米浆料按重量分数比混合并打浆至40-55°SR后送至混合浆池，按重量份数比加入抗氧化剂、相容剂、阻燃剂，搅拌均匀得到浆料；进入封闭式引纸的圆网纸机进行脱水成型，车速65m/min，形成含有壁纸纹肌理的湿纸页；所述浆料进入纸机的上网浓度为0.22%；所述圆网纸机中的圆网笼在其圆柱型骨架上，周向均匀焊接排列有不锈钢钢丝，不锈钢钢丝的直径为0.2mm，钢丝间间距为1.2mm；圆网笼和外部弧形板之间的圆网槽牛角道的尺寸参数为：圆网笼进口与外部弧形板的间距为55mm，圆网笼底部与弧形板间的间距为42mm，圆网笼出口与弧形板间的间距为32mm；将上述湿纸页经压榨脱水及烘缸干燥，获得成品。
实施例2
一种新型防刮壁纸，其特征在于，包括以下重量份数的组分：大豆蛋白纤维 17、竹麻纤维34、抗氧化剂11、相容剂7、阻燃剂3.4、丙烯酸纤维31、羟丁基壳聚糖33、无碱低浮长玻纤13、糯米浆料49；所述糯米浆料的可溶性固形物含量为55%；所述无碱低浮长玻纤的单丝直径为35um，所述无碱低浮长玻纤的单丝长度为18mm。
本发明所述的大豆蛋白纤维、竹麻纤维、丙烯酸纤维、羟丁基壳聚糖、无碱低浮长玻纤、糯米浆料均可通过任一现有技术制备获得。
进一步的，所述相容剂包括以下重量份数的组分：羟乙基纤维素6、甘露醇0.7、氯酸钾0.09、酒石酸钾钠6、明胶11、聚甲基丙烯酸2.2；所述相容剂可以显著提高本发明中无机纤维与有机纤维之间的相容性，同时有效降低本发明原料组分的散发性，使在现有的壁纸制备工艺中在光和热的作用下仍能够稳定存在而不易散发，保持本发明本身的性能。
进一步的，所述阻燃剂包括以下重量份数的组分：氮化硅陶瓷粉 27、纳米磷酸铝分子筛9。所述阻燃剂的平均颗粒粒径为270um。
所述氮化硅陶瓷粉可与纳米磷酸铝分子筛协效复配，显著提高壁纸的阻燃防火性能。所述氮化硅陶瓷粉与纳米磷酸铝分子筛可通过任一现有技术制备得到。
进一步的，所述抗氧化剂包括以下重量份数的组分：杨梅树皮素7、桑叶提取物6、叶黄素11。本发明采用植物成分的抗氧化剂，安全环保，并能够提高与本发明的其它组分的相容性，提高本发明的使用寿命。
实施例3
一种新型防刮壁纸，其特征在于，包括以下重量份数的组分：大豆蛋白纤维 14、竹麻纤维29、抗氧化剂9、相容剂2-7、阻燃剂2.1、丙烯酸纤维25、羟丁基壳聚糖29、无碱低浮长玻纤10、糯米浆料43；所述糯米浆料的可溶性固形物含量为50%；所述无碱低浮长玻纤的单丝直径为32um，所述无碱低浮长玻纤的单丝长度为14mm。
本发明所述的大豆蛋白纤维、竹麻纤维、丙烯酸纤维、羟丁基壳聚糖、无碱低浮长玻纤、糯米浆料均可通过任一现有技术制备获得。
进一步的，所述相容剂包括以下重量份数的组分：羟乙基纤维素4、甘露醇0.45、氯酸钾0.06、酒石酸钾钠3.5、明胶7.5、聚甲基丙烯酸1.5；所述相容剂可以显著提高本发明中无机纤维与有机纤维之间的相容性，同时有效降低本发明原料组分的散发性，使在现有的壁纸制备工艺中在光和热的作用下仍能够稳定存在而不易散发，保持本发明本身的性能。
进一步的，所述阻燃剂包括以下重量份数的组分：氮化硅陶瓷粉23、纳米磷酸铝分子筛7。所述阻燃剂的平均颗粒粒径为200um。
所述氮化硅陶瓷粉可与纳米磷酸铝分子筛协效复配，显著提高壁纸的阻燃防火性能。所述氮化硅陶瓷粉与纳米磷酸铝分子筛可通过任一现有技术制备得到。
进一步的，所述抗氧化剂包括以下重量份数的组分：杨梅树皮素5、桑叶提取物4、叶黄素8。本发明采用植物成分的抗氧化剂，安全环保，并能够提高与本发明的其它组分的相容性，提高本发明的使用寿命。
实施例4
一种新型防刮壁纸，其特征在于，包括以下重量份数的组分：大豆蛋白纤维 13、竹麻纤维25、抗氧化剂10、相容剂2-7、阻燃剂1.5、丙烯酸纤维27、羟丁基壳聚糖30、无碱低浮长玻纤8、糯米浆料46；所述糯米浆料的可溶性固形物含量为47%；所述无碱低浮长玻纤的单丝直径为30um，所述无碱低浮长玻纤的单丝长度为16mm。
本发明所述的大豆蛋白纤维、竹麻纤维、丙烯酸纤维、羟丁基壳聚糖、无碱低浮长玻纤、糯米浆料均可通过任一现有技术制备获得。
进一步的，所述相容剂包括以下重量份数的组分：羟乙基纤维素3、甘露醇0.6氯酸钾0.05、酒石酸钾钠5、明胶10、聚甲基丙烯酸1.8；所述相容剂可以显著提高本发明中无机纤维与有机纤维之间的相容性，同时有效降低本发明原料组分的散发性，使在现有的壁纸制备工艺中在光和热的作用下仍能够稳定存在而不易散发，保持本发明本身的性能。
进一步的，所述阻燃剂包括以下重量份数的组分：氮化硅陶瓷粉21、纳米磷酸铝分子筛8。所述阻燃剂的平均颗粒粒径为250um。
所述氮化硅陶瓷粉可与纳米磷酸铝分子筛协效复配，显著提高壁纸的阻燃防火性能。所述氮化硅陶瓷粉与纳米磷酸铝分子筛可通过任一现有技术制备得到。
进一步的，所述抗氧化剂包括以下重量份数的组分：杨梅树皮素4、桑叶提取物 5、叶黄素9。本发明采用植物成分的抗氧化剂，安全环保，并能够提高与本发明的其它组分的相容性，提高本发明的使用寿命。
实施例5
一种新型防刮壁纸，其特征在于，包括以下重量份数的组分：大豆蛋白纤维 11-17、竹麻纤维32、抗氧化剂7、相容剂2-7、阻燃剂2.1、丙烯酸纤维20、羟丁基壳聚糖26、无碱低浮长玻纤11、糯米浆料39；所述糯米浆料的可溶性固形物含量为52%；所述无碱低浮长玻纤的单丝直径为32um，所述无碱低浮长玻纤的单丝长度为12mm。
本发明所述的大豆蛋白纤维、竹麻纤维、丙烯酸纤维、羟丁基壳聚糖、无碱低浮长玻纤、糯米浆料均可通过任一现有技术制备获得。
进一步的，所述相容剂包括以下重量份数的组分：羟乙基纤维素5、甘露醇0.3、氯酸钾0.07、酒石酸钾钠2、明胶6、聚甲基丙烯酸1.1；所述相容剂可以显著提高本发明中无机纤维与有机纤维之间的相容性，同时有效降低本发明原料组分的散发性，使在现有的壁纸制备工艺中在光和热的作用下仍能够稳定存在而不易散发，保持本发明本身的性能。
进一步的，所述阻燃剂包括以下重量份数的组分：氮化硅陶瓷粉25、纳米磷酸铝分子筛6。所述阻燃剂的平均颗粒粒径为180um。
所述氮化硅陶瓷粉可与纳米磷酸铝分子筛协效复配，显著提高壁纸的阻燃防火性能。所述氮化硅陶瓷粉与纳米磷酸铝分子筛可通过任一现有技术制备得到。
进一步的，所述抗氧化剂包括以下重量份数的组分：杨梅树皮素6、桑叶提取物 3、叶黄素6。本发明采用植物成分的抗氧化剂，安全环保，并能够提高与本发明的其它组分的相容性，提高本发明的使用寿命。
对比例1
一种新型防刮壁纸，其特征在于，包括以下重量份数的组分：大豆蛋白纤维 13、竹麻纤维25、相容剂2-7、阻燃剂1.5、丙烯酸纤维27、羟丁基壳聚糖30、无碱低浮长玻纤8、糯米浆料46；所述糯米浆料的可溶性固形物含量为47%；所述无碱低浮长玻纤的单丝直径为30um，所述无碱低浮长玻纤的单丝长度为16mm。
本发明所述的大豆蛋白纤维、竹麻纤维、丙烯酸纤维、羟丁基壳聚糖、无碱低浮长玻纤、糯米浆料均可通过任一现有技术制备获得。
进一步的，所述相容剂包括以下重量份数的组分：羟乙基纤维素3、甘露醇0.6氯酸钾0.05、酒石酸钾钠5、明胶10、聚甲基丙烯酸1.8；所述相容剂可以显著提高本发明中无机纤维与有机纤维之间的相容性，同时有效降低本发明原料组分的散发性，使在现有的壁纸制备工艺中在光和热的作用下仍能够稳定存在而不易散发，保持本发明本身的性能。
进一步的，所述阻燃剂包括以下重量份数的组分：氮化硅陶瓷粉21、纳米磷酸铝分子筛8。所述阻燃剂的平均颗粒粒径为250um。
所述氮化硅陶瓷粉可与纳米磷酸铝分子筛协效复配，显著提高壁纸的阻燃防火性能。所述氮化硅陶瓷粉与纳米磷酸铝分子筛可通过任一现有技术制备得到。
对比例2
一种新型防刮壁纸，其特征在于，包括以下重量份数的组分：大豆蛋白纤维 11-17、竹麻纤维32、抗氧化剂7、相容剂2-7、丙烯酸纤维20、羟丁基壳聚糖26、无碱低浮长玻纤11、糯米浆料39；所述糯米浆料的可溶性固形物含量为52%；所述无碱低浮长玻纤的单丝直径为32um，所述无碱低浮长玻纤的单丝长度为12mm。
本发明所述的大豆蛋白纤维、竹麻纤维、丙烯酸纤维、羟丁基壳聚糖、无碱低浮长玻纤、糯米浆料均可通过任一现有技术制备获得。
进一步的，所述相容剂包括以下重量份数的组分：羟乙基纤维素5、甘露醇0.3、氯酸钾0.07、酒石酸钾钠2、明胶6、聚甲基丙烯酸1.1；所述相容剂可以显著提高本发明中无机纤维与有机纤维之间的相容性，同时有效降低本发明原料组分的散发性，使在现有的壁纸制备工艺中在光和热的作用下仍能够稳定存在而不易散发，保持本发明本身的性能。
进一步的，所述抗氧化剂包括以下重量份数的组分：杨梅树皮素6、桑叶提取物 3、叶黄素6。本发明采用植物成分的抗氧化剂，安全环保，并能够提高与本发明的其它组分的相容性，提高本发明的使用寿命。
性能测试
按相关的国家标准方法检测本发明所有实施例、对比例的阻燃性能、抗张指数等参数，检测的材料规格为100g/m2，结果如下表所示。
对于本领域技术人员而言，显然本发明不限于上述示范性实施例的细节，而且在不背离本发明的精神或基本特征的情况下，能够以其他的具体形式实现本发明。因此，无论从哪一点来看，均应将实施例看作是示范性的，而且是非限制性的，本发明的范围由所附权利要求而不是上述说明限定，因此旨在将落在权利要求的等同要件的含义和范围内的所有变化囊括在本发明内。
此外，应当理解，虽然本说明书按照实施方式加以描述，但并非每个实施方式仅包含一个独立的技术方案，说明书的这种叙述方式仅仅是为清楚起见，本领域技术人员应当将说明书作为一个整体，各实施例中的技术方案也可以经适当组合，形成本领域技术人员可以理解的其他实施方式。需注意的是，本发明中所未详细描述的技术特征，均可以通过任一现有技术实现。

Claims (5)

1.一种新型防刮壁纸，其特征在于，包括以下重量份数的组分：大豆蛋白纤维 11-17、竹麻纤维23-34、抗氧化剂6-11、相容剂2-7、阻燃剂0.8-3.4、丙烯酸纤维18-31、羟丁基壳聚糖24-33、无碱低浮长玻纤6-13、糯米浆料36-49；所述糯米浆料的可溶性固形物含量为45%-55%；所述无碱低浮长玻纤的单丝直径为 28-35um，所述无碱低浮长玻纤的单丝长度为9-18mm。
2.根据权利要求1所述的新型防刮壁纸，其特征在于，所述相容剂包括以下重量份数的组分：羟乙基纤维素2-6、甘露醇0.2-0.7、氯酸钾0.03-0.09、酒石酸钾钠1-6、明胶4-11、聚甲基丙烯酸 0.8-2.2。
3.根据权利要求1所述的新型防刮壁纸，其特征在于，所述阻燃剂包括以下重量份数的组分：氮化硅陶瓷粉 19-27、纳米磷酸铝分子筛5-9。
4.根据权利要求3所述的新型防刮壁纸，其特征在于，所述阻燃剂的平均颗粒粒径为130-270um。
5.根据权利要求1所述的新型防刮壁纸，其特征在于，所述抗氧化剂包括以下重量份数的组分：杨梅树皮素 3-7、桑叶提取物 2-6、叶黄素 5-11。
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