CN107987699A - It is a kind of suitable for aqueous surface finishing agent of automotive seat artificial polyvinyl chloride leather and preparation method thereof - Google Patents
It is a kind of suitable for aqueous surface finishing agent of automotive seat artificial polyvinyl chloride leather and preparation method thereof Download PDFInfo
- Publication number
- CN107987699A CN107987699A CN201711249000.5A CN201711249000A CN107987699A CN 107987699 A CN107987699 A CN 107987699A CN 201711249000 A CN201711249000 A CN 201711249000A CN 107987699 A CN107987699 A CN 107987699A
- Authority
- CN
- China
- Prior art keywords
- agent
- water
- polyvinyl chloride
- automotive seat
- added
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000003795 chemical substances by application Substances 0.000 title claims abstract description 50
- 239000010985 leather Substances 0.000 title claims abstract description 20
- 229920000915 polyvinyl chloride Polymers 0.000 title claims abstract description 19
- 239000004800 polyvinyl chloride Substances 0.000 title claims abstract description 19
- 238000002360 preparation method Methods 0.000 title claims description 9
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 40
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 32
- 239000000377 silicon dioxide Substances 0.000 claims abstract description 19
- 239000002562 thickening agent Substances 0.000 claims abstract description 15
- 239000006096 absorbing agent Substances 0.000 claims abstract description 14
- 239000011248 coating agent Substances 0.000 claims abstract description 14
- 238000000576 coating method Methods 0.000 claims abstract description 14
- 229920005989 resin Polymers 0.000 claims abstract description 14
- 239000011347 resin Substances 0.000 claims abstract description 14
- 239000013530 defoamer Substances 0.000 claims abstract description 13
- 239000000080 wetting agent Substances 0.000 claims abstract description 12
- 229920002635 polyurethane Polymers 0.000 claims abstract description 9
- 239000004814 polyurethane Substances 0.000 claims abstract description 9
- -1 waterborne Polymers 0.000 claims abstract description 8
- 239000004417 polycarbonate Substances 0.000 claims abstract description 7
- 229920000515 polycarbonate Polymers 0.000 claims abstract description 7
- 125000001931 aliphatic group Chemical group 0.000 claims abstract description 5
- 229920005749 polyurethane resin Polymers 0.000 claims abstract description 4
- 238000000034 method Methods 0.000 claims abstract description 3
- 238000002156 mixing Methods 0.000 claims description 13
- 238000003756 stirring Methods 0.000 claims description 9
- ZHPNWZCWUUJAJC-UHFFFAOYSA-N fluorosilicon Chemical compound [Si]F ZHPNWZCWUUJAJC-UHFFFAOYSA-N 0.000 claims description 6
- 238000006243 chemical reaction Methods 0.000 claims description 4
- 239000007788 liquid Substances 0.000 claims description 4
- 239000000843 powder Substances 0.000 claims description 4
- 239000007787 solid Substances 0.000 claims description 4
- ZCILGMFPJBRCNO-UHFFFAOYSA-N 4-phenyl-2H-benzotriazol-5-ol Chemical compound OC1=CC=C2NN=NC2=C1C1=CC=CC=C1 ZCILGMFPJBRCNO-UHFFFAOYSA-N 0.000 claims description 3
- 239000008367 deionised water Substances 0.000 claims description 3
- 229910021641 deionized water Inorganic materials 0.000 claims description 3
- 125000000118 dimethyl group Polymers [H]C([H])([H])* 0.000 claims description 3
- 230000002209 hydrophobic effect Effects 0.000 claims description 3
- 239000000203 mixture Substances 0.000 claims description 3
- 238000012856 packing Methods 0.000 claims description 3
- 229920005573 silicon-containing polymer Polymers 0.000 claims description 3
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 claims description 2
- 239000006185 dispersion Substances 0.000 claims description 2
- 229920000548 poly(silane) polymer Polymers 0.000 claims description 2
- 229920001296 polysiloxane Polymers 0.000 claims description 2
- 239000003906 humectant Substances 0.000 claims 1
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 abstract description 12
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 abstract description 8
- 239000000126 substance Substances 0.000 abstract description 5
- 230000032683 aging Effects 0.000 abstract description 4
- 229910052724 xenon Inorganic materials 0.000 abstract description 4
- FHNFHKCVQCLJFQ-UHFFFAOYSA-N xenon atom Chemical compound [Xe] FHNFHKCVQCLJFQ-UHFFFAOYSA-N 0.000 abstract description 4
- KZVVGZKAVZUACK-BJILWQEISA-N rilpivirine hydrochloride Chemical compound Cl.CC1=CC(\C=C\C#N)=CC(C)=C1NC1=CC=NC(NC=2C=CC(=CC=2)C#N)=N1 KZVVGZKAVZUACK-BJILWQEISA-N 0.000 abstract description 3
- 239000002649 leather substitute Substances 0.000 description 3
- 230000007613 environmental effect Effects 0.000 description 2
- 239000003973 paint Substances 0.000 description 2
- 229920001596 poly (chlorostyrenes) Polymers 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 238000004381 surface treatment Methods 0.000 description 2
- 150000001335 aliphatic alkanes Chemical class 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 230000003750 conditioning effect Effects 0.000 description 1
- 101150038956 cup-4 gene Proteins 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 239000004205 dimethyl polysiloxane Substances 0.000 description 1
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 1
- 239000004815 dispersion polymer Substances 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- FJQXCDYVZAHXNS-UHFFFAOYSA-N methadone hydrochloride Chemical compound Cl.C=1C=CC=CC=1C(CC(C)N(C)C)(C(=O)CC)C1=CC=CC=C1 FJQXCDYVZAHXNS-UHFFFAOYSA-N 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 229920001195 polyisoprene Polymers 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 238000004080 punching Methods 0.000 description 1
- 150000004756 silanes Chemical class 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1687—Use of special additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Abstract
The invention discloses a kind of face finish suitable for automotive seat artificial polyvinyl chloride leather, it is made of water-based aliphatic polyurethane matting resin, waterborne, polycarbonate polyurethane resin, organic siliconresin, water, flatting silica, defoamer, levelling agent, wetting agent, anti-wear agent, UV absorbers, thickener, the invention also discloses a kind of method for preparing above-mentioned coating.The coating volatile organic content content is low, and without the harmful substance such as toluene and butanone, its coating formed has the advantages that pliability is good, and glossiness is low, wear-resisting, flex endurant, resistant, good resistance to xenon lamp aging performance.
Description
Technical field
The present invention relates to a kind of coating and preparation method thereof, more particularly to one kind are artificial suitable for automotive seat polyvinyl chloride
Aqueous surface finishing agent of leather and preparation method thereof.
Background technology
Traditional artificial leather surface treatment is all to use oil paint, its film forming is poor, easily fades.In coating procedure
Solvent volatilizees in coating, and easily burning triggers security incident.And solvent has toxicity, harmful and pollution environment.
Present people's living standard and environmental consciousness not only improve, therefore develop new water-based artificial polyvinyl chloride leather and apply
Decorations agent replaces oiliness leather finishing agent to become inevitable requirement.
Especially for automobile industry, it is related to the rigid requirement to volatile organic content, to automotive interior smell
And harmful substance requirement is also increasingly stringent.Solvent-borne type inorganic agent contains substantial amounts of volatile organism, volatilizees during use big
The harmful substances such as toluene, butanone are measured, can not meet the requirement of artificial polyvinyl chloride leather surface treatment paint comprehensively, therefore have
Necessity develops a kind of water-based low-volatile automotive trim artificial polyvinyl chloride leather surface conditioning agent.
The content of the invention
The technical problems to be solved by the invention are to provide a kind of suitable for the water-based of automotive seat artificial polyvinyl chloride leather
Face finish, volatile organic content content is low, and without the harmful substance such as toluene and butanone, safety and environmental protection smell is low, its shape
Into good film flexibility, the advantages that glossiness is low, wear-resisting, flex endurant, resistant, good resistance to xenon lamp aging performance.
The present invention is to provide one kind for the technical solution that solution above-mentioned technical problem uses and is suitable for automotive seat polychlorostyrene
The aqueous surface finishing agent of vinyl leathercloth, including water-based aliphatic polyurethane matting resin, waterborne, polycarbonate polyurethane tree
Fat, fluorine silicon resin, water, flatting silica, defoamer, levelling agent, wetting agent, anti-wear agent, UV absorbers and thickener.
Further, each component mass percent is as follows：
Further, the water is deionized water, and the flatting silica is silica flatting silica.
Further, the defoamer is polysiloxanes and the mixture of hydrophobic solid；The levelling agent is poly-
Silanes levelling agent；The wetting agent is polyether-modified dimethyl silicone polymer solution；The anti-wear agent is paste superelevation
Molecular weight polyisoprene dimethyl siloxane dispersion liquid, the UV absorbers are inhaled for hydroxy phenyl benzotriazole ultraviolet light
Receive agent；The thickener is polyether-polyurethane thickener.
The present invention also provides a kind of suitable for the water-based of automotive seat artificial polyvinyl chloride leather for solution above-mentioned technical problem
The preparation method of face finish, comprises the following steps：A) successively by load weighted water-based aliphatic polyurethane matting resin and
Waterborne, polycarbonate is added in reaction kettle and stirs；Defoamer, levelling agent and wetting agent are sequentially added, is allowed to uniformly mixed；
B) load weighted silica flatting silica and water are added；C) hand feeling agent, UV absorbers and water are added, is added after stirring evenly
Enter thickener and adjust viscosity；D) coating finished product is made added with fluorine silicon resin.
Further, defoamer, levelling agent, wetting agent are added with stirring is linear in the step a), and speed of agitator is
800-1000 turns/min, stir mixing 30min；Speed of agitator is first reduced to 500-800 in the step b) and turns/min, with
After add silica dioxide delustring agent, the powder being sticked on wall is poured into stirred tank with water, after addition increase mixing speed extremely
1000-1400 turns/min, jitter time 40min；First said in the step c) mixing speed be reduced to 800-1000 turn/
Min, then sequentially adds anti-wear agent, UV absorbers and water, stirs 30min, is allowed to add thickener after being uniformly dispersed
Regulation system viscosity；Mixing speed is reduced to 500-600 turns/min and sequentially added in the step d) and adds fluorine silicon resin, is stirred
It is 20min to mix the time；Finally filtered with 100 mesh filter cloths, packing, is made coating finished product.
The present invention contrast prior art has following beneficial effect：It is provided by the invention to be suitable for automotive seat polychlorostyrene second
The aqueous surface finishing agent of alkene artificial leather, volatile organic content content is low, without the harmful substance such as toluene and butanone, its shape
Into coating have that pliability is good, the advantages that glossiness is low, wear-resisting, flex endurant, resistant, good resistance to xenon lamp aging performance.
Brief description of the drawings
Fig. 1 is the aqueous surface finishing agent preparation flow signal that the present invention is suitable for automotive seat artificial polyvinyl chloride leather
Figure.
Embodiment
The invention will be further described with reference to the accompanying drawings and examples.
Aqueous surface finishing agent provided by the invention suitable for automotive seat artificial polyvinyl chloride leather, includes water-based fat
Fat adoption urethane matting resin, waterborne, polycarbonate polyurethane resin, organic siliconresin, water, flatting silica, defoamer, levelling
Agent, wetting agent, anti-wear agent, UV absorbers and thickener.
Aqueous surface finishing agent provided by the invention suitable for automotive seat artificial polyvinyl chloride leather, each component it is excellent
Choosing is as follows：The water is deionized water, and the flatting silica is silica flatting silica, and the defoamer is poly- silica
The mixture of alkane and hydrophobic solid；The levelling agent is polysilanes levelling agent；The wetting agent is polyether-modified poly-
Dimethyl siloxane solution；The anti-wear agent is paste super high molecular weight dimethyl silicone polymer dispersion liquid, average molecular weight
It is preferably 60000~90000 all more than 60000；The UV absorbers are purple for hydroxy phenyl benzotriazole
Outer light absorber；The thickener is polyether-polyurethane thickener.
Aqueous surface finishing agent provided by the invention suitable for automotive seat artificial polyvinyl chloride leather, preparation method is such as
Shown in Fig. 1：
Respectively by the water-based aliphatic polyurethane matting resins of 110kg and 110kg waterborne, polycarbonate polyurethane resins, add
Enter into reaction kettle, speed of agitator is 800 turns/min, then linearly adds defoamer 2kg, levelling agent 2kg, wetting agent successively
10kg, defoamer, levelling agent and wetting agent, are fully dispersed in ester resin by mixing time 30min successively.
Mixing speed is reduced to 600 turns/min, prevents from splashing when adding powder, then adds load weighted silica
13kg, reaction kettle is poured with 100kg water by viscous wall powder with water, then is improved speed of agitator and be to 1200 turns/min, jitter time
40min。
Mixing speed is reduced to 800 turns/min, then sequentially adds hand feeling agent 8kg, water 60kg, UV absorbers
8kg, jitter time 30min, then add thickener 3.5kg and adjust viscosity.
Mixing speed is reduced to 600 turns/min, avoid always high-speed stirred produce a large amount of bubbles and cause mechanical demulsification,
Add organic siliconresin 30kg
Finally filtered with 100 mesh filter cloths, packing, it is about 450kg that coating finished product, which is made,.
According to the coating physical property such as table 1 below of embodiment proportioning production.
| Feature | Numerical value | Unit |
| Appearance | Off-white color liquid | |
| Solid content (120 DEG C, 1g) | 25 | Wt% |
| Density (25 DEG C) | 1.02 | g/cm3 |
| PH value | 8 | |
| Viscosity (25 DEG C, Cai's grace cup 4) | 30 | s |
| Storage stability (50 DEG C, 7d) | Without precipitation, without demulsification |
Table 1
Suitable curing agent is added, black pvc artificial leather roller coat is used subsequently to, finishing agent performance is tested after 24h,
As a result such as table 2.
| Test event | Standard | As a result |
| 60 ° of gloss | ASTM D2457 | 1.5 |
| Cold punching | GMW14126 | Nothing is turned white |
| Table is wear-resisting | GMW3208 | Pass through |
| Anti-flex performance | ISO 5402 | Coating is without breakage |
| Resistance to cleaning | GMW3402 | Without scuffing, without breakage |
| Resistance to xenon lamp aging | ISO 105-B06 601kJ/m2 | Pass through |
| Color fastness | ISO 15701 | Without scuffing, without breakage |
| Martindale's stain resistant | GMW 15377-2013 | 4 grades |
Table 2
Although the present invention is disclosed as above with preferred embodiment, so it is not limited to the present invention, any this area skill
Art personnel, without departing from the spirit and scope of the present invention, when can make a little modification and it is perfect, therefore the present invention protection
Scope, which is worked as, is subject to what claims were defined.
Claims (6)
1. a kind of aqueous surface finishing agent suitable for automotive seat artificial polyvinyl chloride leather, it is characterised in that include water-based fat
Fat adoption urethane matting resin, waterborne, polycarbonate polyurethane resin, fluorine silicon resin, water, flatting silica, defoamer, levelling agent, profit
Humectant, anti-wear agent, UV absorbers and thickener.
2. being suitable for the aqueous surface finishing agent of automotive seat artificial polyvinyl chloride leather as claimed in claim 1, its feature exists
In each component mass percent is as follows：
3. being suitable for the aqueous surface finishing agent of automotive seat artificial polyvinyl chloride leather as claimed in claim 2, its feature exists
In the water is deionized water, and the flatting silica is silica flatting silica.
4. being suitable for the aqueous surface finishing agent of automotive seat artificial polyvinyl chloride leather as claimed in claim 2, its feature exists
In the defoamer is polysiloxanes and the mixture of hydrophobic solid；The levelling agent is polysilanes levelling agent；Institute
The wetting agent stated is polyether-modified dimethyl silicone polymer solution；The anti-wear agent is paste super high molecular weight poly dimethyl silicon
Oxygen alkane dispersion liquid, the UV absorbers are hydroxy phenyl benzotriazole UV absorbers；The thickener is
Polyether-polyurethane thickener.
A kind of 5. preparation for preparing the face finish as claimed in claim 2 suitable for automotive seat artificial polyvinyl chloride leather
Method, it is characterised in that comprise the following steps：
A) load weighted water-based aliphatic polyurethane matting resin and waterborne, polycarbonate are added in reaction kettle and stirred successively；
Defoamer, levelling agent and wetting agent are sequentially added, is allowed to uniformly mixed；
B) load weighted silica flatting silica and water are added；
C) hand feeling agent, UV absorbers and water are added, thickener is stirring evenly and then adding into and adjusts viscosity；
D) coating finished product is made added with fluorine silicon resin.
6. the preparation method of the face finish according to claim 5 suitable for automotive seat artificial polyvinyl chloride leather,
It is characterized in that, defoamer, levelling agent, wetting agent are added with stirring is linear in the step a), speed of agitator 800-
1000 turns/min, stir mixing 30min；Speed of agitator is first reduced to 500-800 in the step b) and turns/min, is then added
Silica dioxide delustring agent, stirred tank is poured with water by the powder being sticked on wall, increases mixing speed after addition to 1000-
1400 turns/min, jitter time 40min；First say that mixing speed is reduced to 800-1000 and turns/min in the step c), with
After sequentially add anti-wear agent, UV absorbers and water, stir 30min, be allowed to add thickener after being uniformly dispersed and adjust body
It is viscosity；Mixing speed is reduced to 500-600 turns/min and sequentially added in the step d) and adds fluorine silicon resin, mixing time is
20min；Finally filtered with 100 mesh filter cloths, packing, is made coating finished product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711249000.5A CN107987699B (en) | 2017-12-01 | 2017-12-01 | Water-based surface coating agent suitable for polyvinyl chloride artificial leather of automobile seat and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711249000.5A CN107987699B (en) | 2017-12-01 | 2017-12-01 | Water-based surface coating agent suitable for polyvinyl chloride artificial leather of automobile seat and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN107987699A true CN107987699A (en) | 2018-05-04 |
| CN107987699B CN107987699B (en) | 2020-07-10 |
Family
ID=62034944
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201711249000.5A Active CN107987699B (en) | 2017-12-01 | 2017-12-01 | Water-based surface coating agent suitable for polyvinyl chloride artificial leather of automobile seat and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107987699B (en) |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108484950A (en) * | 2018-05-21 | 2018-09-04 | 昆山阿基里斯人造皮有限公司 | A kind of remaining method of pyrrolidones substance in control artificial leather |
| CN108642907A (en) * | 2018-05-21 | 2018-10-12 | 昆山阿基里斯人造皮有限公司 | A method of control artificial leather fogging |
| CN108912298A (en) * | 2018-07-23 | 2018-11-30 | 福建宝利特科技股份有限公司 | A kind of automobile leather surface treating agent and preparation method thereof |
| CN109207047A (en) * | 2018-11-15 | 2019-01-15 | 福建格林春天新材料股份有限公司 | Dedicated super sub- skin sense abrasion-resistance water coating of a kind of PVC surface decoration and preparation method thereof |
| CN109486393A (en) * | 2018-11-15 | 2019-03-19 | 福建格林春天新材料股份有限公司 | Dedicated bloom anti-pollution abrasion-resistance water coating of a kind of PVC surface decoration and preparation method thereof |
| CN110964423A (en) * | 2018-09-28 | 2020-04-07 | 贝内克-长顺汽车内饰材料（张家港）有限公司 | Coffee-resistant coating composition for leather surface and coffee-resistant leather |
| CN112409906A (en) * | 2020-12-22 | 2021-02-26 | 温州东泰树脂有限责任公司 | Wear-resistant treatment agent for artificial leather surface and preparation process thereof |
| CN114958122A (en) * | 2022-07-19 | 2022-08-30 | 江苏海田技术有限公司 | Water-based technical wood yellow-resistant matte clear finish and preparation method thereof |
| CN115559123A (en) * | 2022-10-25 | 2023-01-03 | 广东西顿新材料科技有限公司 | Water-based stain-resistant automobile synthetic leather finishing agent and preparation method thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101613568A (en) * | 2009-07-24 | 2009-12-30 | 宁海长和环保涂料有限公司 | Water extinction sizing agent |
| CN103740250A (en) * | 2013-12-06 | 2014-04-23 | 四川达威科技股份有限公司 | Preparation method of matting leather water-based polyurethane coating agent |
| CN105694699A (en) * | 2016-01-27 | 2016-06-22 | 优美特（北京）环境材料科技股份公司 | Extinction type aqueous polyurethane emulsion and preparation method of extinction type aqueous polyurethane emulsion |
| CN106349914A (en) * | 2016-08-25 | 2017-01-25 | 万华化学集团股份有限公司 | Aqueous matt surface finishing agent for PVC (Polyvinyl Chloride) leather and preparation method thereof |
| CN106752737A (en) * | 2016-11-14 | 2017-05-31 | 上海普力通新材料科技有限公司 | A kind of PVC floor ultraviolet-curing paint and preparation method thereof |
-
2017
- 2017-12-01 CN CN201711249000.5A patent/CN107987699B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101613568A (en) * | 2009-07-24 | 2009-12-30 | 宁海长和环保涂料有限公司 | Water extinction sizing agent |
| CN103740250A (en) * | 2013-12-06 | 2014-04-23 | 四川达威科技股份有限公司 | Preparation method of matting leather water-based polyurethane coating agent |
| CN105694699A (en) * | 2016-01-27 | 2016-06-22 | 优美特（北京）环境材料科技股份公司 | Extinction type aqueous polyurethane emulsion and preparation method of extinction type aqueous polyurethane emulsion |
| CN106349914A (en) * | 2016-08-25 | 2017-01-25 | 万华化学集团股份有限公司 | Aqueous matt surface finishing agent for PVC (Polyvinyl Chloride) leather and preparation method thereof |
| CN106752737A (en) * | 2016-11-14 | 2017-05-31 | 上海普力通新材料科技有限公司 | A kind of PVC floor ultraviolet-curing paint and preparation method thereof |
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108484950A (en) * | 2018-05-21 | 2018-09-04 | 昆山阿基里斯人造皮有限公司 | A kind of remaining method of pyrrolidones substance in control artificial leather |
| CN108642907A (en) * | 2018-05-21 | 2018-10-12 | 昆山阿基里斯人造皮有限公司 | A method of control artificial leather fogging |
| CN108642907B (en) * | 2018-05-21 | 2020-07-10 | 昆山阿基里斯新材料科技有限公司 | Method for controlling fogging property of artificial leather |
| CN108912298A (en) * | 2018-07-23 | 2018-11-30 | 福建宝利特科技股份有限公司 | A kind of automobile leather surface treating agent and preparation method thereof |
| CN110964423A (en) * | 2018-09-28 | 2020-04-07 | 贝内克-长顺汽车内饰材料（张家港）有限公司 | Coffee-resistant coating composition for leather surface and coffee-resistant leather |
| CN109207047A (en) * | 2018-11-15 | 2019-01-15 | 福建格林春天新材料股份有限公司 | Dedicated super sub- skin sense abrasion-resistance water coating of a kind of PVC surface decoration and preparation method thereof |
| CN109486393A (en) * | 2018-11-15 | 2019-03-19 | 福建格林春天新材料股份有限公司 | Dedicated bloom anti-pollution abrasion-resistance water coating of a kind of PVC surface decoration and preparation method thereof |
| CN112409906A (en) * | 2020-12-22 | 2021-02-26 | 温州东泰树脂有限责任公司 | Wear-resistant treatment agent for artificial leather surface and preparation process thereof |
| CN114958122A (en) * | 2022-07-19 | 2022-08-30 | 江苏海田技术有限公司 | Water-based technical wood yellow-resistant matte clear finish and preparation method thereof |
| CN115559123A (en) * | 2022-10-25 | 2023-01-03 | 广东西顿新材料科技有限公司 | Water-based stain-resistant automobile synthetic leather finishing agent and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN107987699B (en) | 2020-07-10 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN107987699A (en) | It is a kind of suitable for aqueous surface finishing agent of automotive seat artificial polyvinyl chloride leather and preparation method thereof | |
| CN105064034A (en) | Synthetic leather surface conditioning agent | |
| CN106349914B (en) | A kind of PVC leather aqueous matte surface finishing agent and preparation method thereof | |
| CN105505165A (en) | Scratch-resistant double-component waterborne glossy varnish and preparation method thereof | |
| CN105062341B (en) | With polyacetals modified aqueous polyurethane for helping film forming function and preparation method and application | |
| CN102367351A (en) | Waterborne two-component epoxy self-leveling floor paint and preparation method thereof | |
| CN101717603A (en) | Aqueous dull finishing coat, preparation method and use method thereof | |
| CN107384119A (en) | Color brilliant self-leveling floor coating of a kind of non-solvent epoxy and preparation method thereof | |
| CN106675380B (en) | Safe and environment-friendly water-based leather paint for automotive TPU (thermoplastic polyurethane) interior decoration and preparation method thereof | |
| CN107793903A (en) | A kind of coating composition and its application for being used to repair rubber floor covering cloth | |
| CN105316947A (en) | Water-based super-fogging super-blackening treating agent for synthetic leather and preparation method thereof | |
| CN102363705B (en) | Water-based single-component full-gloss clear finishing paint and preparation method thereof | |
| CN111944402A (en) | High-water-resistance water-based two-component matte top-coat paint and preparation method thereof | |
| CN102363704B (en) | Aqueous blocking agent and its preparation method | |
| WO2017088083A1 (en) | Water-based polishing treating agent for synthetic leather and preparation method therefor | |
| CN102363684B (en) | Aqueous two-component white priming paint and preparation method thereof | |
| WO2017088084A1 (en) | Aqueous skin-touch treatment agent for synthetic leather and preparation method for same | |
| CN115746643B (en) | High-permeability double-component primer and preparation method thereof | |
| CN112280450A (en) | PVC artificial leather water-based color-changing treatment agent and preparation method thereof | |
| CN111978811A (en) | Water-based single-component top-coat paint and preparation method thereof | |
| CN105421076A (en) | Aqueous high-gloss gloss oil used for artificial leather and preparation method thereof | |
| CN110358437A (en) | A kind of high-performance environment-friendly water paint and preparation method thereof | |
| WO2017088086A1 (en) | Aqueous brightening treatment agent for synthetic leather and preparation method for same | |
| CN113943526A (en) | Water-based two-component top-coat paint with low VOC (volatile organic compound) emission, and preparation method and application method thereof | |
| CN112062923B (en) | Waterborne polyurethane-urea dispersion for nail polish and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| PE01 | Entry into force of the registration of the contract for pledge of patent right | ||
| PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: An aqueous surface finishing agent suitable for PVC artificial leather of automobile seats and its preparation method Effective date of registration: 20220616 Granted publication date: 20200710 Pledgee: The Bank of Shanghai branch Caohejing Limited by Share Ltd. Pledgor: SHANGHAI 3N CHEMICALS Co.,Ltd. Registration number: Y2022310000064 |
|
| PC01 | Cancellation of the registration of the contract for pledge of patent right | ||
| PC01 | Cancellation of the registration of the contract for pledge of patent right |
Date of cancellation: 20221111 Granted publication date: 20200710 Pledgee: The Bank of Shanghai branch Caohejing Limited by Share Ltd. Pledgor: SHANGHAI 3N CHEMICALS Co.,Ltd. Registration number: Y2022310000064 |
|
| PE01 | Entry into force of the registration of the contract for pledge of patent right | ||
| PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: A water-based surface coating agent suitable for PVC artificial leather of car seats and its preparation method Effective date of registration: 20231115 Granted publication date: 20200710 Pledgee: Postal Savings Bank of China Limited Shanghai Jinshan District Branch Pledgor: SHANGHAI 3N CHEMICALS Co.,Ltd. Registration number: Y2023310000747 |