CN107964649A - Colour-fast coating processing technology - Google Patents
Colour-fast coating processing technology Download PDFInfo
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- CN107964649A CN107964649A CN201710568355.4A CN201710568355A CN107964649A CN 107964649 A CN107964649 A CN 107964649A CN 201710568355 A CN201710568355 A CN 201710568355A CN 107964649 A CN107964649 A CN 107964649A
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/0015—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterized by the colour of the layer
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/02—Pretreatment of the material to be coated
- C23C14/024—Deposition of sublayers, e.g. to promote adhesion of the coating
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/06—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the coating material
- C23C14/10—Glass or silica
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/22—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the process of coating
- C23C14/24—Vacuum evaporation
- C23C14/28—Vacuum evaporation by wave energy or particle radiation
- C23C14/30—Vacuum evaporation by wave energy or particle radiation by electron bombardment
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C28/00—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D
- C23C28/30—Coatings combining at least one metallic layer and at least one inorganic non-metallic layer
- C23C28/32—Coatings combining at least one metallic layer and at least one inorganic non-metallic layer including at least one pure metallic layer
- C23C28/322—Coatings combining at least one metallic layer and at least one inorganic non-metallic layer including at least one pure metallic layer only coatings of metal elements only
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C28/00—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D
- C23C28/30—Coatings combining at least one metallic layer and at least one inorganic non-metallic layer
- C23C28/34—Coatings combining at least one metallic layer and at least one inorganic non-metallic layer including at least one inorganic non-metallic material layer, e.g. metal carbide, nitride, boride, silicide layer and their mixtures, enamels, phosphates and sulphates
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- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D5/00—Electroplating characterised by the process; Pretreatment or after-treatment of workpieces
- C25D5/34—Pretreatment of metallic surfaces to be electroplated
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- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D7/00—Electroplating characterised by the article coated
- C25D7/005—Jewels; Clockworks; Coins
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- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
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- Mechanical Engineering (AREA)
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- Electrochemistry (AREA)
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Abstract
The present invention relates to processing of ornament technical field, and in particular to a kind of colour-fast coating processing technology, it comprises the following steps：（1）Nano coating is sprayed, electrostatic precipitation is carried out to the jewellery by electroplating surface processing, then sprays nano coating, after the completion of spraying, baking-curing nano coating；（2）Optical coating, to the jewellery after spraying nano coating, is cleaned, then carries out optical coating with silica and AF materials.According to processing technology of the present invention, after increasing nano coating and optical coatings to jewellery, the gold plate of jewellery has splendid wear-resisting property, strength hydrophobic oleophobic, lasting antibacterial, antifouling property, anti-fingerprint ability；Remain jewellery surface long term bright and clean, top layer is intact will not to wear, fade.
Description
Technical field
The invention belongs to processing of ornament technical field, and in particular to a kind of colour-fast coating processing technology.
Background technology
Jewellery process for treating surface is broadly divided into two major class of mechanical treatment and electrochemical treatments.Mechanical treatment mainly utilizes
Associated mechanical instrument polishes jewellery, is polished, sandblasting etc., to reach required technological requirement and effect.And electrochemistry
Processing is then to carry out burn into passivation and the processing of protectiveness to metal surface using the method for electrochemistry, and especially style is answered
Miscellaneous jewellery and the back side of jewellery fresh idea etc. are not easy the position for being polished, being polished to, and electrochemical process for treating is unique with more it
Superiority.
At present, electrochemical treatments technique is very much, mainly there is plating（Electric gold）, chemical plating, chemically transformed film technique etc..In head
Industry is adornd, using most still electroplating technologies.Jewellery surface is after polishing, polishing, then by treatment before plating and plating, shape
Into electrodeposited coating so that jewellery more seem bright, beautiful, while improve jewellery surface abrasion resistance, corrosion resistance.
Electric gold generally comprises the processing procedure on jewellery surface（1）Fried color polishing, sanding and polishing jewellery surface, to remove work
The sand hole on part surface, file trace etc.；（2）Oil removing, including ultrasonic cleaning and electrochemical degreasing, ultrasonic degreasing are to utilize ultrasonic wave
The mechanical force of vibration, makes to produce ten hundreds of minute bubbles in degreasant solution, these minute bubbles are produced when forming growth and closure
Raw strong impact power, the grease for attaching material surface, dirt depart from rapidly.Electrochemical degreasing is that ornaments are hung over alkaline electrolysis
On the cathode of liquid, the surface tension of solution interface, the hydrogen separated out on electrode are reduced using polarization of electrode effect when being electrolysed
Bubble and oxygen bubbles, have oil lamella strong tear effect and the mechanical agitation to solution, so as to promote oil film promptly
Come off from material surface and be changed into tiny oil droplet, accelerate, strengthen oil removal process.（3）Rinse, it is galvanizer to be rinsed with water
The indispensable part of skill, wash the purity level of quality and water for electroplating technology stability and electroplated product it is outer
The quality index such as sight, corrosion resistance have great influence.（4）Pickling, also known as weak etch activation, ornaments wash rear surface through oil removing
One layer of thin oxide film can be generated, the bond strength of coating and parent metal can be influenced, therefore, to be activated before plating.（5）Electricity
Gold, selects suitable temperature, current density, and cleaned ornaments are put into plating solution is electroplated.（6）Washing, drying.
But the proof gold coating on jewellery surface is easily worn, and exposes the true qualities of ground, influences beauty, therefore, ornaments plating
New technique should be developed afterwards, the coating on jewellery top layer is processed, and to improve the wearability of overlay coating, and then improved
The quality of jewellery.
The content of the invention
In order to solve the problems, such as that jewellery overlay coating existing in the prior art is easy to wear, fades, the present invention provides
A kind of colour-fast coating processing technology.The technical problem to be solved in the present invention is achieved through the following technical solutions：
A kind of colour-fast coating processing technology, it comprises the following steps：
（1）Spray nano coating
Electrostatic precipitation is carried out to the jewellery by electroplating surface processing, then sprays nano coating, after the completion of spraying, baking-curing
Nano coating；
（2）Optical coating
To the jewellery after spraying nano coating, cleaned, then carry out optical coating with silica and AF materials.
Further, in colour-fast coating processing technology of the present invention, the step（1）Spray nano coating, tool
Body process includes：
（1-1）Electrostatic precipitation：Adjust electrostatic air pressure gun, be directed at jewellery product, with 10 centimetres~15 centimetres of spacing to product into
Row dedusting；
（1-2）Plasma treatment：Distance is 2 millimeters~3 millimeters between plasma pipette tips and jewellery product；Processing to water droplet angle≤
10°；
（1-3）Spraying：Using branched spray gun with 360 ° of adjustment angle of gun, distance is 10 centimetres~15 between spray gun and jewellery product
Centimetre, carry out nano material spraying；
（1-4）Baking：To the nano coating after spraying at 70 DEG C ± 5 DEG C, toasted, until curing of coatings.
Further, in colour-fast coating processing technology of the present invention, the nano paint is H-3024 anodic oxygens
Change nano paint.
Further, in colour-fast coating processing technology of the present invention, the step（2）Optical coating, specific mistake
Journey includes：
（2-1）Ultrasonic cleaning：Wax removal water is added in supersonic cleaning machine, thoroughly removes jewellery product table mercolized wax dirt；
（2-2）Jewellery product after the completion of cleaning is aligned on coating machine umbrella stand, is added silica and AF materials, is first carried out base
Basal surface bombards 5 minutes, then carries out optical coating.
Further, in colour-fast coating processing technology of the present invention, the step（2-2）Detailed process is：
Jewellery product after the completion of cleaning is aligned on coating machine umbrella stand, silica and AF materials is added, in vacuum 6.5*
10-5 Torr, under the conditions of 30 DEG C ± 5 DEG C of temperature, opens ion gun and carries out substrate surface bombardment, and 120 V of voltage, 7 A of electric current~
9 A, bombard 5 minutes；
Treat that vacuum reaches 6.0*10-5 After Torr, electron gun is opened, sets technological parameter to carry out optical coating, technological parameter：
SiO2For 800 k of thickness, the mA of 100 mA of electric current~130；
AF materials are the k of 400 k of thickness~500, the mA of 130 mA of electric current~150.
Further, in colour-fast coating processing technology of the present invention, the jewellery handled by electroplating surface,
When its electrodeposited coating is electric layer gold, electricity gold processing detailed process comprises the following steps：
（i）Surface polishes；
（ii）Ultrasonic cleaning；
（iii）Electrochemical degreasing, jewellery are hung on the cathode of alkaline electrolyte, and electrolysis water temperature range is 45 DEG C~50
DEG C, 9 V of voltage, more than 45 seconds time, the flushing after electrolysis 8 minutes~10 minutes；
（iv）Pickling, is activated using dilute sulfuric acid, is soaked 3 seconds~5 seconds, and the jewellery crossed after pickling are done using distilled water flushing
Only；
（v）Electric gold；
（vi）Clean up and dry up, that is, obtain the gold-plated jewellery in top layer.
Further, in colour-fast coating processing technology of the present invention, the step（v）During electric gold, electric Jinsui River exists
For temperature range at 45 DEG C~50 DEG C, voltage is the V of 2.5 V~2.8,20 seconds~45 seconds time.
Compared with prior art, beneficial effects of the present invention：
1st, colour-fast coating processing technology of the present invention, jewellery top layer increase nano coating after plating and optics plating
Film layer, nano coating cause processing after jewellery surface have splendid wear-resisting property, strength hydrophobic oleophobic, lasting antibacterial,
Antifouling property, optical coatings cause the jewellery surface tension after processing to reduce, and dust reduces 90% with contact surface area, prevents
Dirty ability is further lifted, and with stronger hydrophobic, oil rub resistance, anti-fingerprint ability.
2nd, through the present invention colour-fast coating processing technology processing after Plating Ornaments sweat proof performance, salt spray resistance,
Moisture resistance properties and resistance to nursing product performance exceed professional standard, and binding force of cladding material performance reaches highest level, and wear-resisting property is very
Good, in addition, antifouling property is good, easy to clean, glossiness is also unaffected after long periods of wear, jewellery surface long term remain it is bright and clean,
The intact not easy to wear, colour fading in top layer.
3rd, colour-fast coating processing technology of the present invention, further optimizes electric technology for gold, leads to during electric gold
Cross the adjustment to technological parameter, it is possible to achieve gold plate color adjusts controllableization.
Detailed description of the invention
Unless otherwise indicated, the term used in the present invention in the specification and in the claims has following definitions.
Embodiment
Further detailed description is done to the present invention with reference to specific embodiment, but embodiments of the present invention are not limited to
This.The technology not being described further, can refer to ability conventional technical means and is implemented.
The error range of temperature is within ± 5 DEG C in following embodiments.Optical coating process uses UNIVAC E-Beam
2050 electron beam evaporation deposition machines (E-beam Evaporator).
Embodiment 1：Jewellery top layer electricity gold
When jewellery top layer electrodeposited coating is Gold plated Layer, electricity gold processing detailed process：
（i）Surface polishes, to remove the sand hole of workpiece surface, file trace.
Surface polishing is operated according to this area conventional steps, it may include fried color polishing, sanding and polishing kit
Workpiece surface is polished, the surface for making workpiece coarse becomes smooth glossy, timely and effectively to be repaired；Paraffin removal,
Repair, the fault of workpiece, defect, damage etc. are made up；Gluing（Oil）；Sandblasting；Oiling（Nail polish）；Removing glue, most
Electrobrightening afterwards.
（ii）Ultrasonic cleaning；Ultrasonic degreasing is the mechanical force using supersonic oscillations, makes to produce number in degreasant solution
Minute bubbles in terms of ten thousand, these minute bubbles produce strong impact power, the oil for attaching material surface when forming growth and closure
Fat, dirt depart from rapidly, so as to accelerate skimming processes, make degreasing more thorough, complex-shaped for handling, and have micropore, blind hole, narrow
Seam and degreasing require high material more effective.Using distilled water as cleaning solvent in supersonic cleaning machine, paraffin removal can be properly added
The auxiliary cleaning agents such as water.
（iii）Electrochemical degreasing, jewellery are hung on the cathode of alkaline electrolyte, are acted on using polarization of electrode when being electrolysed
The surface tension of solution interface is reduced, the bubble hydrogen and oxygen bubbles separated out on electrode, has oil lamella strong tear effect
With the mechanical agitation to solution, so that promoting oil film promptly to come off from material surface is changed into tiny oil droplet, add
Speed, strengthen oil removal process, and then obtains and almost thoroughly remove clean good deoiling effect.
By verification experimental verification, general electrolysis water temperature range is at 45 DEG C~50 DEG C, 9 V of voltage, more than 45 seconds time, clearly
Wash that effect is preferable, under particular case can root Ju clean surface degree difference, it is appropriate to adjust voltage and extend electrolysis time.Electrolysis
The time that product afterwards need to rinse is about 8 minutes~10 minutes.It is the indispensable part of electroplating technology to be rinsed with water,
The purity level of washing quality and water has for the quality index such as the stability and the appearance of electroplated product of electroplating technology, corrosion resistance
Great influence, rinsing should be thorough.
（iv）Pickling, ornaments can generate one layer of thin oxide film through oil removing, washing rear surface, can influence coating and parent metal
Bond strength, therefore, to be activated before plating, be activated usually using dilute sulfuric acid, material surface is produced slight erosion,
Expose the crystalline structure of metal, to ensure coating and base material bond strength, activating solution is generally all diluter, will not destroy material surface
Finish, it is activated after jewellery must wash again, electroplated again after clean.
Electricity gold is activated using 5% dilute sulfuric acid aqueous solution in the present embodiment, is soaked 3 seconds~5 seconds, the head crossed after pickling
Decorations are clean using distilled water flushing.
（v）Electric gold, in temperature range at 45 DEG C~50 DEG C, voltage is the V of 2.5 V~2.8 in electric Jinsui River, 20 seconds time~
45 seconds.
The collocation method in electric Jinsui River, is allocated or is directly bought the electricity gold prepared according to the quality of the layer gold to be plated
Water.Such as the electric Jinsui River of Europe Memec 24K gold is used in the present embodiment.
The results show, in the same circumstances, the temperature in Jinsui River can influence jewellery surface gold plate during electricity gold
Color, temperature is relatively low, then color is shinny, conversely, temperature drift, then color is partially white.Therefore, color adaptation that can be as needed is electric
Pressure and time, such as：When gold-plated again, the electricity gold time can suitably shorten, such as the secondary electric golden electricity golden time was at 20 seconds or so.
（vi）Using pure water or distilled water, clean up and dry up, that is, obtain the gold-plated jewellery in top layer.
Overlay coating processing technology in the present invention is suitable for coating as common Plating Ornaments such as gold, silver, rhodiums, this sentences plating
Exemplified by layer gold, treatment technique is verified using the sample prepared by embodiment 1 as experimental products.
Embodiment 2：The overlay coating processing of jewellery after gold-plated processing
Concrete processing procedure includes：Spray nano coating and carry out optical coating.
The（1）Step：Nano coating is sprayed, detailed process is as follows：
Special fixture need to be used, the jewellery processed as needed choose suitable gauge, and first gauge is filled on production line, rear to wear
Dustless gloves by product with traditional thread binding to producing line, operator must wear medical gloves operation when paying attention to filling product, prevent hand from directly touching
Touching product has finger mark.Production line of this area conventionally used for spraying nano coating, as long as can meet that technique needs are applicable in.
（1-1）Electrostatic precipitation:Electrostatic air pressure gun is adjusted, jewellery product is directed at, product is removed with 10 centimetres of spacing
Dirt.
Electrostatic precipitation is one kind of dedusting method, its principle in highfield air molecule be ionized for just from
Son and electronics, electronics, which marches on towards, runs into grit in anode process, be collected the negatively charged cathode that is adsorbed onto of grit.By this dedusting technology
Processing of ornament industry is introduced, it is fine for follow-up coating operation effectiveness.
（1-2）Plasma treatment：Distance is 2 millimeters between plasma pipette tips and jewellery product；Handle to water droplet angle≤10 °.
Plasma treatment refer to make the methods of involving high-energy radiation with electric discharge, high-frequency electromagnetic oscillation, impact inert gas or
Oxygen-containing gas produces plasma, handles being sprayed-on product surface, to change surface nature, is conducive to improve spraying
Coating performance, improves coating intensity.The technology is chiefly used in the processing of the frostings such as polyolefin, this technology is added applied to jewellery
Work process, the coating quality for improving nano coating, remarkable result can be respectively provided with by improving coating adherence.Water droplet angle detection side
It is owned by France in this area routine techniques, do not repeat herein.
（1-3）Spraying：Using branched spray gun with 360 ° of adjustment angle of gun, distance is 10 lis between spray gun and jewellery product
Rice, carries out nano material spraying.
In the present embodiment, sprayed using 8 spray guns with 360 ° of adjustment angle of gun, nano paint is H-3024 anodes
Oxidation nanometer coating.
（1-4）Baking：To the nano coating after spraying at 70 DEG C ± 5 DEG C, toasted, until curing of coatings.
After curing of coatings, you can medical gloves operation is worn in lower part, operating process, and left hand, which is pinned the gauge right hand and removed, have been carried out
The product of nano coating.
H-3024 coating nano coatings cause the jewellery surface after processing to have splendid wear-resisting property, strength are hydrophobic to dredge
Oily, lasting antibacterial, antifouling property.
The（2）Step：Optical coating, detailed process are as follows：
Optical coating process uses 2050 electron beam evaporation deposition machines of UNIVAC E-Beam (E-beam Evaporator),
Evaporation process is etched using Argon, SiO2Buffering；90 DEG C ~ 95 DEG C of chamber temperature；The big King Company AF plated films of AF material selections
Pill.
（2-1）Ultrasonic cleaning：Wax removal water is added in supersonic cleaning machine, thoroughly removes jewellery product table mercolized wax dirt.
In cleaning process, the clean-up performance of water and the concentration of Wax removal water in cleaning machine are checked；In cleaning machine water still it is dirtier then
Need to change water addition Wax removal water, continue to clean, general two to three days is changed once, adds the mL of paraffin removal 250mL ~ 500 every time.Specifically
Subtract dosage depending on clean-up performance, additive amount takes the circumstances into consideration to increase when wax dirt is more.
（2-2）Jewellery product after the completion of cleaning is aligned on coating machine umbrella stand, and the product of first-class fixture is pressed and has been cleaned
It is aligned to after on coating machine umbrella stand, pays attention to more than the 1cm that is spaced in of every product, checks that every product must be firmly linked with umbrella stand
On, it will not drop because umbrella stand rotation or mutually collide.
Silica and AF materials are added, SiO is first added on crucible2Particle, maintains an equal level with crucible edge；Then two are taken
Nano material（AF materials）Resistance is placed on to steam in tungsten boat.
Inspection closes plated film gate after having added nano material, vacuumizes, treats that vacuum is extracted into 6.5*10-5Torr, temperature 30
Ion gun is opened after ± 5 DEG C and carries out substrate surface bombardment, 120 V of voltage, 7 A of electric current, bombard 5 minutes.
Treat that vacuum reaches 6.0*10-5 After Torr, electron gun is opened, sets technological parameter to carry out optical coating, technique ginseng
Number：SiO2For 800 k of thickness, 100 mA of electric current；AF materials are 400 k of thickness, 130 mA of electric current.
Plated film completes final vacuum vacuum breaker, door is opened undercarriage in 5 minutes or so, optical coating technique is completed.
AF plated films, i.e. anti-fingerprint plated film, on the Gold plated Layer appearance on jewellery top layer without influence after plated film.Optically coated principle
It is：Outside jewellery top layer nano coating first after the cleaning, steam coating silicon dioxide, introduces silicon-oxygen（Si-O）Key, AF materials
For the solution of hydrofluoroether, containing active perfluoropolyether（PFPE）Compound, silicon-oxygen is introduced in product subsurface（Si-O）After key,
Product subsurface silicon-oxygen can just be made（Si-O）With fluorine element material (Coating Materials) chemical bonding reaction occurs for key, forms film layer.
AF materials optical film plating layers belong to hydrophobic film, can also be obviously improved the anti-aging and rub resistance ability of product,
Film surface friction coefficient substantially reduces, so as to increase the smooth degree of film surface, realizes anti-fingerprint, hydrophobic, anti-pollution, scratch resistance,
Characteristic easy to clean, it is low that fingerprint is stained with glutinous degree, easily wipes.
Optical coatings cause the jewellery surface tension after processing to reduce, dust and contact surface area reduction 90%, antifouling
Ability is further lifted, and with stronger hydrophobic, oil rub resistance, anti-fingerprint ability；Remain jewellery surface long term bright and clean,
Top layer is intact will not to wear, fade.
Embodiment 3：The overlay coating processing of jewellery after electric gold processing
Experimentation detail and points for attention are the same as embodiment 2.
The（1）Step：Spray nano coating
The jewellery processed as needed choose suitable gauge, and first gauge is filled on production line, wears dustless gloves afterwards by product
With traditional thread binding to producing line, operator must wear medical gloves operation when paying attention to filling product, prevent hand from directly touching product and having finger mark.
（1-1）Electrostatic precipitation:Electrostatic air pressure gun is adjusted, is directed at jewellery product, product is carried out with 15 centimetres of spacing
Dedusting.
（1-2）Plasma treatment：Distance is 3 millimeters between plasma pipette tips and jewellery product；Handle to water droplet angle≤10 °.
（1-3）Spraying：Using branched spray gun with 360 ° of adjustment angle of gun, distance is 10 lis between spray gun and jewellery product
Rice, carries out nano material spraying.
In the present embodiment, sprayed using 6 spray guns with 360 ° of adjustment angle of gun, nano paint is H-3024 anodes
Oxidation nanometer coating.
（1-4）Baking：To the nano coating after spraying at 70 DEG C ± 5 DEG C, toasted, until curing of coatings.
After curing of coatings, you can medical gloves operation is worn in lower part, operating process, and left hand, which is pinned the gauge right hand and removed, have been carried out
The product of nano coating.
H-3024 coating nano coatings cause the jewellery surface after processing to have splendid wear-resisting property, strength are hydrophobic to dredge
Oily, lasting antibacterial, antifouling property.
The（2）Step：Optical coating, detailed process are as follows：
Optical coating process uses 2050 electron beam evaporation deposition machines of UNIVAC E-Beam (E-beam Evaporator),
Evaporation process is etched using Argon, SiO2Buffering；90 DEG C ~ 95 DEG C of chamber temperature；The big King Company AF platings of AF material selections
Film pill.
（2-1）Ultrasonic cleaning：Wax removal water is added in supersonic cleaning machine, thoroughly removes jewellery product table mercolized wax dirt.
（2-2）Jewellery product after the completion of cleaning is aligned on coating machine umbrella stand, and the product of first-class fixture is pressed and has been cleaned
It is aligned to after on coating machine umbrella stand, pays attention to more than the 1cm that is spaced in of every product, checks that every product must be firmly linked with umbrella stand
On, it will not drop because umbrella stand rotation or mutually collide.
Silica and AF materials are added, SiO is first added on crucible2Particle, maintains an equal level with crucible edge；Then two are taken
Nano material（AF materials）Resistance is placed on to steam in tungsten boat.
Inspection closes plated film gate after having added nano material, vacuumizes, treats that vacuum is extracted into 6.5*10-5Torr, temperature 30
Ion gun is opened after ± 5 DEG C and carries out substrate surface bombardment, 120 V of voltage, 9 A of electric current, bombard 5 minutes.
Treat that vacuum reaches 6.0*10-5 After Torr, electron gun is opened, sets technological parameter to carry out optical coating, technique ginseng
Number：SiO2800 k of thickness, 130 mA of electric current；AF materials are 500 k of thickness, 150 mA of electric current.
Plated film completes final vacuum vacuum breaker, door is opened undercarriage in 5 minutes or so, optical coating technique is completed.
Embodiment 4：The overlay coating processing of jewellery after electric gold processing
Experimentation detail and points for attention are the same as embodiment 2.
The（1）Step：Spray nano coating
The jewellery processed as needed choose suitable gauge, and first gauge is filled on production line, wears dustless gloves afterwards by product
With traditional thread binding to producing line.
（1-1）Electrostatic precipitation:Electrostatic air pressure gun is adjusted, jewellery product is directed at, product is removed with 13 centimetres of spacing
Dirt.
（1-2）Plasma treatment：Distance is 3 millimeters between plasma pipette tips and jewellery product；Handle to water droplet angle≤10 °.
（1-3）Spraying：Using branched spray gun with 360 ° of adjustment angle of gun, distance is 14 lis between spray gun and jewellery product
Rice, carries out nano material spraying.
In the present embodiment, sprayed using 6 spray guns with 360 ° of adjustment angle of gun, nano paint is H-3024 anodes
Oxidation nanometer coating.
（1-4）Baking：To the nano coating after spraying at 70 DEG C ± 5 DEG C, toasted, until curing of coatings.
After curing of coatings, you can medical gloves operation is worn in lower part, operating process, and left hand, which is pinned the gauge right hand and removed, have been carried out
The product of nano coating.
The（2）Step：Optical coating, detailed process are as follows：
Optical coating process uses 2050 electron beam evaporation deposition machines of UNIVAC E-Beam (E-beam Evaporator),
Evaporation process is etched using Argon, SiO2Buffering；90 DEG C ~ 95 DEG C of chamber temperature；The big King Company AF platings of AF material selections
Film pill.
（2-1）Ultrasonic cleaning：Wax removal water is added in supersonic cleaning machine, thoroughly removes jewellery product table mercolized wax dirt.
（2-2）Jewellery product after the completion of cleaning is aligned on coating machine umbrella stand, and the product of first-class fixture is pressed and has been cleaned
It is aligned to after on coating machine umbrella stand, pays attention to more than the 1cm that is spaced in of every product, checks that every product must be firmly linked with umbrella stand
On, it will not drop because umbrella stand rotation or mutually collide.
Silica and AF materials are added, SiO is first added on crucible2Particle, maintains an equal level with crucible edge；Then two are taken
Nano material（AF materials）Resistance is placed on to steam in tungsten boat.
Inspection closes plated film gate after having added nano material, and technological parameter is set according to table 1 below：
Table 1：Technological parameter is set
In table 1：Rising Time time broadenings；Soak Time soaking times；Soak Power absorbabilities；Sec seconds.
In etching process, vacuumize, treat that vacuum is extracted into 6.5*10-5Ion gun is opened after Torr, 30 ± 5 DEG C of temperature to carry out
Substrate surface bombards, 120 V of voltage, 9 A of electric current, bombards 5 minutes.
In buffering and coating process：Treat that vacuum reaches 6.0*10-5 After Torr, electron gun is opened, according to technological parameter
Optical coating is carried out, plated film is extremely：SiO2For 800 k of thickness, 130 mA of electric current；AF materials are 500 k of thickness, electric current 150
mA.Plated film completes final vacuum vacuum breaker, door is opened undercarriage in 5 minutes or so, optical coating technique is completed.
Performance test embodiment：
By according to the processing method of 1-4 of the embodiment of the present invention, the jewellery after processing, carry out according to jewellery trade common detection methods
Overlay coating（Gold plated Layer）Performance test.Specific test event, test method are as follows.
, sweat proof test：It is intended to influence of the simulation human sweat to product subsurface.
Test method：One layer of cotton is laid on glassware bottom, leads and pours into synthetic perspiration, it is ensured that cotton drenches, will be real
Applying the jewellery product after example 2 ~ 4 is processed, manually sweat soaks, and is then placed in glassware, and close the lid.By vierics
Ware is put into insulating box, and temperature control is at 40 DEG C ± 2 DEG C.When 8 is small, check once, check whether product is etched, drops
Solution or overlay coating obscission.
Determination methods：48 corrosion-free traces when small, you can be judged to passing through test.Observing time extends to 96 in this experiment
Hour.
, salt fog performance test：It is intended to the resistance to corrosion of test product overlay coating
Test method：Test solution is configured, the acid test solution configured is poured into salt fog machine aqua storage tank, air pressure is adjusted, protects air pressure
Hold and modulate 0.07 ~ 0.17 megapascal in 0.2 ~ 0.4 megapascal, spraying pressure.Trial product to be measured is put into salt spray test chamber, opens electricity
35 ~ 40 DEG C of source, 30 DEG C of Adjustment Tests temperature and saturator temperature.After constant temperature, spray switch is opened, when setting is sprayed
Between, be traditionally arranged to be 48 it is small when.When 8 is small, check once, check whether product is etched, degrades or overlay coating
Obscission.
Determination methods：48 corrosion-free traces when small, you can be judged to passing through test.Observing time extends to 96 in this experiment
Hour.
, moisture resistance properties test：It is intended to test coating high moisture barrier performance
Test method：Calorstat temperature is arranged on 40 DEG C, after temperature reaches, sample is put into the closed appearance of relative humidity 95%
In device, with hygrometer control humidity, this container is put into insulating box, 100 it is small when after, take out sample, observation top layer change.
Determination methods：Overlay coating appearance is unchanged, and rust spot, corrosion, oxidation are qualification.Observing time extends in this experiment
To 200 it is small when.
, resistance to nursing product performance test：It is intended to test product coating resistance personal care product（Perfume, style keeping liquid etc.）Corruption
Corrosion energy
Test method：Ready Gulong perfume and hair style style keeping liquid spray are sprayed on product subsurface, are placed on room temperature, opposite
Humidity be 50% ~ 60% environment in, 24 it is small when after, take out check.
Determination methods：Coating surface is qualification without cosmetic variation.In this experiment observing time extend to 48 it is small when.
, binding force of cladding material performance test：The combination power to the coating appended by the base material of product is intended to test
Test method：Horizontal/parallel longitudinal cutting of scalpel is used on coating top layer, parallel lines are at intervals of 1 millimeter, after having cut,
The surface cut using the cleaning of clean rag, is attached to test surfaces, and ensure to adhere to completely by untapped rubber blanket
Surface, then takes adhesive plaster off, checks electrodeposited coating top layer dropping situations.
Determination methods：Independent 1 square millimeter of top layer of plating not exclusively comes off for qualification.Line interval is decreased in this experiment
0.5 millimeter.
, wearability test：It is intended to test the wear-resisting property of product surface coating
Test method：Ballast 450g palm brush is reciprocal, and whether observation coating wears, if exposes basalis.
Determination methods：Palm brush 1000 times it is not show-through for wearability it is qualified.Increase rider-type brush in the present embodiment to 3000 times.
>=3000 times
The results are shown in Table 2 for specific experiment：
Table 2：Performance test experimental result
| Performance test | Embodiment 2 | Embodiment 3 | Embodiment 4 |
| Sweat proof performance（h） | 96 it is small when after top layer it is unchanged | 96 it is small when after top layer it is unchanged | 96 it is small when after top layer it is unchanged |
| Salt spray resistance (h) | 96 it is small when after do not corrode | 96 it is small when after do not corrode | 96 it is small when after do not corrode |
| Moisture resistance properties（h） | 200 it is small when after top layer it is unchanged | 200 it is small when after top layer it is unchanged | 200 it is small when after top layer it is unchanged |
| Resistance to nursing product performance（h） | 48 it is small when after appearance it is unchanged | 48 it is small when after appearance it is unchanged | 48 it is small when after appearance it is unchanged |
| Binding force of cladding material performance | Higher than general standard | Higher than general standard | Higher than general standard |
| Wear-resisting property（h） | >=3000 times, do not wear | >=3000 times, do not wear | >=3000 times, do not wear |
From the performance test results of upper table 2, processing method of the invention, jewellery top layer Gold plated Layer has very excellent property
Can, it is in particular in that sweat proof performance, salt spray resistance, moisture resistance properties and resistance to nursing product performance exceed professional standard, coating knot
Performance reaches highest level with joint efforts, and wear-resisting property is very good, in addition, antifouling property is good, easy to clean, and glossiness after long periods of wear
It is unaffected.
The colour-fast coating processing technology that the present invention is developed, advanced technology, application is strong, and market prospects are very good.
Above content is that a further detailed description of the present invention in conjunction with specific preferred embodiments, it is impossible to is assert
The specific implementation of the present invention is confined to these explanations.For general technical staff of the technical field of the invention,
On the premise of not departing from present inventive concept, some simple deduction or replace can also be made, should all be considered as belonging to the present invention's
Protection domain.
Claims (7)
1. a kind of colour-fast coating processing technology, it comprises the following steps：
（1）Spray nano coating
Electrostatic precipitation is carried out to the jewellery by electroplating surface processing, then sprays nano coating, after the completion of spraying, baking-curing
Nano coating；
（2）Optical coating
To the jewellery after spraying nano coating, cleaned, then carry out optical coating with silica and AF materials.
2. colour-fast coating processing technology according to claim 1, it is characterised in that：The step（1）Nanometer is sprayed to apply
Layer, detailed process include：
（1-1）Electrostatic precipitation：Adjust electrostatic air pressure gun, be directed at jewellery product, with 10 centimetres~15 centimetres of spacing to product into
Row dedusting；
（1-2）Plasma treatment：Distance is 2 millimeters~3 millimeters between plasma pipette tips and jewellery product；Processing to water droplet angle≤
10°；
（1-3）Spraying：Using branched spray gun with 360 ° of adjustment angle of gun, distance is 10 centimetres~15 between spray gun and jewellery product
Centimetre, carry out nano material spraying；
（1-4）Baking：To the nano coating after spraying at 70 DEG C ± 5 DEG C, toasted, until curing of coatings.
3. colour-fast coating processing technology according to claim 1 or 2, it is characterised in that：The nano paint is H-
3024 anodic oxidation nano paints.
4. colour-fast coating processing technology according to claim 1, it is characterised in that：The step（2）Optical coating, tool
Body process includes：
（2-1）Ultrasonic cleaning：Wax removal water is added in supersonic cleaning machine, thoroughly removes jewellery product table mercolized wax dirt；
（2-2）Jewellery product after the completion of cleaning is aligned on coating machine umbrella stand, is added silica and AF materials, is first carried out base
Basal surface bombards 5 minutes, then carries out optical coating.
5. colour-fast coating processing technology according to claim 4, it is characterised in that：The step（2-2）Detailed process
For：
Jewellery product after the completion of cleaning is aligned on coating machine umbrella stand, silica and AF materials is added, in vacuum 6.5*
10-5 Torr, under the conditions of 30 DEG C ± 5 DEG C of temperature, opens ion gun and carries out substrate surface bombardment, and 120 V of voltage, 7 A of electric current~
9 A, bombard 5 minutes；
Treat that vacuum reaches 6.0*10-5 After Torr, electron gun is opened, sets technological parameter to carry out optical coating, technological parameter：
SiO2For 800 k of thickness, the mA of 100 mA of electric current~130；
AF materials are the k of 400 k of thickness~500, the mA of 130 mA of electric current~150.
6. colour-fast coating processing technology according to claim 1, it is characterised in that：It is described by electroplating surface handle
Jewellery, when its electrodeposited coating is electric layer gold, its electricity gold processing detailed process comprises the following steps：
（i）Surface polishes；
（ii）Ultrasonic cleaning；
（iii）Electrochemical degreasing, jewellery are hung on the cathode of alkaline electrolyte, and electrolysis water temperature range is 45 DEG C~50
DEG C, 9 V of voltage, more than 45 seconds time, the flushing after electrolysis 8 minutes~10 minutes；
（iv）Pickling, is activated using dilute sulfuric acid, is soaked 3 seconds~5 seconds, and the jewellery crossed after pickling are done using distilled water flushing
Only；
（v）Electric gold；
（vi）Clean up and dry up, that is, obtain the gold-plated jewellery in top layer.
7. colour-fast coating processing technology according to claim 6, it is characterised in that：The step（v）During electric gold, electricity
In temperature range at 45 DEG C~50 DEG C, voltage is the V of 2.5 V~2.8 in Jinsui River, 20 seconds~45 seconds time.
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Application publication date: 20180427 |