CN107964378A - One kind is embedding to determine cohesion adhesion type polymer membranes and preparation method thereof - Google Patents
One kind is embedding to determine cohesion adhesion type polymer membranes and preparation method thereof Download PDFInfo
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- CN107964378A CN107964378A CN201711320774.2A CN201711320774A CN107964378A CN 107964378 A CN107964378 A CN 107964378A CN 201711320774 A CN201711320774 A CN 201711320774A CN 107964378 A CN107964378 A CN 107964378A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J195/00—Adhesives based on bituminous materials, e.g. asphalt, tar, pitch
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/08—Macromolecular additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2301/00—Additional features of adhesives in the form of films or foils
- C09J2301/10—Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet
- C09J2301/12—Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet by the arrangement of layers
- C09J2301/122—Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet by the arrangement of layers the adhesive layer being present only on one side of the carrier, e.g. single-sided adhesive tape
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2301/00—Additional features of adhesives in the form of films or foils
- C09J2301/30—Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier
- C09J2301/302—Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier the adhesive being pressure-sensitive, i.e. tacky at temperatures inferior to 30°C
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2301/00—Additional features of adhesives in the form of films or foils
- C09J2301/40—Additional features of adhesives in the form of films or foils characterized by the presence of essential components
- C09J2301/408—Additional features of adhesives in the form of films or foils characterized by the presence of essential components additives as essential feature of the adhesive layer
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2400/00—Presence of inorganic and organic materials
- C09J2400/20—Presence of organic materials
- C09J2400/22—Presence of unspecified polymer
- C09J2400/226—Presence of unspecified polymer in the substrate
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2495/00—Presence of bitume
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- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
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Abstract
It is a kind of it is embedding determine cohesion adhesion type polymer membranes, including polymeric membrane and the gluing waterproof material on being coated on, the gluing waterproof material include：60~70 parts of matrix pitch, 10~20 parts of SBS rubber, 5~10 parts of carboxylic styrene-butadiene rubber, 2~4 parts of aphthenic acids, 3~5 parts of polypropylene, 5~7 parts of aromatic series hydrocarbon resin, 1~3 part of sulfonate, 1~2 part of polycarboxylic acids, 1~2 part of catalytic promoter, 0.5~1 part of antioxidant.Preparation method：Matrix pitch, SBS rubber, aphthenic acids, polypropylene and aromatic series hydrocarbon resin are added in retort, it is warming up to 180 DEG C, carboxylic styrene-butadiene rubber is added, 2h is stirred, is warming up to 190 DEG C of addition sulfonate and polycarboxylic acids, 150 DEG C are cooled to after stirring 0.5h, catalytic promoter, antioxidant are added, stirs 1h, by gains at 120~130 DEG C on polymeric membrane of the heat coated in 0.1~0.2mm, silicone oil isolation film is covered with the same time, and cooling, crimp into flexible sheet material waterproof roll.The present invention solves the bonding problem of organic material and cement base, effectively prevents concrete surface leak, infiltration, channeling water phenomenon.
Description
Technical field
The invention belongs to waterproof roll technical field, and in particular to it is a kind of it is embedding determine cohesion adhesion type polymer membranes and
Its preparation method.
Background technology
Adhesion type polymer membranes is a kind of building water-proof coiled material with multifunctionality, it could be theoretically argued that,
The compound special adhesive linkage of modified pitch base of macromolecule coiled material surface penetrates into coagulation with concrete construction basal plane by glue-line particle
Native surface void and capillary, by primary valence power, secondary valency power equicohesive effect, are tightly combined together, are formed as anchor
Anchor connection, allows polymer membranes firmly to grow on the basal plane of concrete construction, and not channeling water leak has been broken also in formation
Waterproof layer, thus such waterproof roll has high-strength bonding force, comprehensive leakproofness, high creep properties, can meet modern high-grade
The requirement of building and underground waterproof engineering, and constructing operation is convenient and efficient, safety and environmental protection non-environmental-pollution.
Be to be modified pitch in actual application, make pressure sensitive adhesive adhesion coating, coated in PE macromolecular sheet materials or
A kind of self-adhesive modified asphalt waterproof rolling material is made in no PE carcasses.In use, by the principle that pressure-sensitive physical absorption is bonded by waterproof
Coiled material is bonded in the surfaces of concrete building structures as waterproof layer, it is disadvantageous in that the modification existing defects to pitch,
The bonding of coiled material loosely, easily fall off, channeling water phenomena such as.
The content of the invention
For overcome the deficiencies in the prior art, embedding cohesion adhesion type macromolecule waterproof is determined the object of the present invention is to provide a kind of
Coiled material and preparation method thereof, is modified pitch by adding the polymer containing specific structure unit, obtained waterproof volume
Material bonding is firm, not easily to fall off, be not easy channeling water.
In order to achieve the above object, the technical solution adopted by the present invention is：
It is a kind of it is embedding determine cohesion adhesion type polymer membranes, including polymeric membrane and coated on the glue on polymeric membrane
Viscous waterproof material, the gluing waterproof material are made of the raw material components of following mass fraction：60~70 parts of matrix pitch, SBS
10~20 parts of rubber, 5~10 parts of carboxylic styrene-butadiene rubber, 2~4 parts of aphthenic acids, 3~5 parts of polypropylene, aromatic series hydrocarbon resin 5~7
Part, 1~3 part of sulfonate, 1~2 part of polycarboxylic acids, 1~2 part of catalytic promoter, 0.5~1 part of antioxidant.
Further, it is described it is embedding determine cohesion adhesion type polymer membranes, including polymeric membrane and coated on high score
Gluing waterproof material on sub- film, the gluing waterproof material are made of the raw material components of following mass fraction：Matrix pitch 60
~70 parts, 10~20 parts of SBS rubber, 5~10 parts of carboxylic styrene-butadiene rubber, 2~4 parts of aphthenic acids, 3~5 parts of polypropylene, aromatic series carbon
5~7 parts of hydrogen resin, 1~3 part of sulfonate, 1~2 part of polycarboxylic acids, 1~2 part of catalytic promoter, 0.5~1 part of antioxidant, end hydroxyl
2~5 parts of base polybutadiene, 2~3 parts of hydroxypropyl methyl ether.
Further, the matrix pitch is No. 90 heavy traffic paving asphalts.
Further, the sulfonate is organic sulfonate.
Further, the organic sulfonate is naphthalene sulfonic salt.
Further, the hydroxypropyl methyl ether is hydroxypropyl methyl cellulose ether.
Further, the catalytic promoter is Peracetic acid, perbenzoic acid or excessively sad tert-pentyl ester therein one
Kind.
Further, the phenol antioxidant is gingerol or gingerol oxime.
A kind of embedding preparation method for determining cohesion adhesion type polymer membranes, each component is according to above-mentioned mass fraction, bag
Include following steps：
Step 1：The preparation of gluing waterproof material
Each raw material components are weighed first, respectively by matrix pitch, SBS rubber, aphthenic acids, polypropylene and the hydrocarbon tree of aromatic series
Fat is added in retort, is warming up to 180 DEG C, is then added carboxylic styrene-butadiene rubber, react 2h under the conditions of high speed shear, be warming up to
190 DEG C add sulfonate and polycarboxylic acids, are cooled to 150 DEG C after stirring 0.5h, add catalytic promoter, stir after 0.5min again
Antioxidant is added, 1h is stirred, obtains gluing waterproof material；
Step 2：Waterproof roll is molded
Under the conditions of 120~130 DEG C, gluing waterproof material prepared by step 1 is applied by two pairs of rollers and fixed thick device is warm
On polymeric membrane coated in 0.1~0.2mm of thickness, while silicone oil isolation film is covered with, is cooled down using cold water spray system, formed
It is embedding to determine cohesion adhesion type macromolecule waterproof membrane, flexible sheet material is finally crimped into, that is, obtains embedding determining cohesion adhesion type macromolecule waterproof
Coiled material.
Further, the embedding preparation method for determining cohesion adhesion type polymer membranes, each component is according to above-mentioned matter
Number is measured, is included the following steps：
Step 1：The preparation of gluing waterproof material
Each raw material components are weighed first, respectively by matrix pitch, SBS rubber, aphthenic acids, polypropylene and the hydrocarbon tree of aromatic series
Fat is added in retort, is warming up to 180 DEG C, is then added carboxylic styrene-butadiene rubber, react 2h under the conditions of high speed shear, be warming up to
190 DEG C add sulfonate, polycarboxylic acids, end hydroxy butadiene and hydroxypropyl methyl ether, and 150 DEG C are cooled to after stirring 0.5h,
Catalytic promoter is added, antioxidant is added after stirring 0.5min, stirs 1h, obtain gluing waterproof material；
Step 2：Waterproof roll is molded
Under the conditions of 120~130 DEG C, gluing waterproof material prepared by step 1 is applied by two pairs of rollers and fixed thick device is warm
On polymeric membrane coated in 0.1~0.2mm of thickness, while silicone oil isolation film is covered with, is cooled down using cold water spray system, formed
It is embedding to determine cohesion adhesion type macromolecule waterproof membrane, flexible sheet material is finally crimped into, that is, obtains embedding determining cohesion adhesion type macromolecule waterproof
Coiled material.
Compared with prior art, the invention has the advantages that：
The present invention is improved from the formula of waterproof material, using the carboxylic styrene-butadiene rubber with hydroxyl (- OH) and end hydroxyl
Base polybutadiene, the polycarboxylic acids with carboxyl (- COOH), the hydroxypropyl methyl ether with ehter bond (- O-) and with sulfonic group
(-SO3H organic sulfonate) etc., compared with the substance modification matrix pitch that strong basis is rolled into a ball, while adds catalytic promoter and adds containing polarized
Work forms high-strength adhering and sealing layer, then using macromolecular sheet material as carrier, first allows high-strength adhering and sealing layer and macromolecular sheet material compound
Fusion, then using cement as interfacial agents, paving concrete building structures basal plane, when polymer membranes glue-line paving is in water
On cement mortar or concrete, in hydration process, hydroxyl, carboxyl and sulfonic group and hydrated cementitious in the special glue-line of coiled material surface
Product hydrated calcium silicate (CaOSiO2YH2O, abbreviation CSH gel) in-Si-OH, Ca2+, the generation such as-O-Si-O- bonding
Effect and reaction, the catalytic promoter of addition accelerate this reaction, high-strength adhering and sealing layer is produced cohesion with cement-based interface
Bonding action and it is embedding determine anchor conjunction, form continuous net-shaped structure, realize that polymer membranes is quickly strong with concrete building structures
Power bonds and sealing, efficiently solves the bonding problem of organic material and cement base inorganic material, realizes organic material and nothing
The effective of machine material bonds, and realizes and determines cohesive bonding with the embedding of concrete, thoroughly prevents concrete leak, infiltration, channeling water phenomenon.
Embodiment
With reference to specific embodiment, elaborate to the present invention.
Embodiment 1
It is a kind of it is embedding determine cohesion adhesion type polymer membranes, including polymeric membrane and coated on the glue on polymeric membrane
Viscous waterproof material, the gluing waterproof material are made of the raw material components of following mass fraction：No. 90 60 parts of heavy traffic paving asphalts, SBS
10 parts of rubber, 8 parts of carboxylic styrene-butadiene rubber, 4 parts of aphthenic acids, 5 parts of polypropylene, 6 parts of aromatic series hydrocarbon resin, 3 parts of naphthalene sulfonic salt,
1 part of polycarboxylic acids, 2 parts of Peracetic acid, 1 part of gingerol；
The embedding preparation method for determining cohesion adhesion type polymer membranes, step are as follows：
Step 1：The preparation of gluing waterproof material
Raw material is weighed according to each component mass ratio, first respectively by No. 90 heavy traffic paving asphalts, SBS rubber, aphthenic acids, polypropylene
Added with aromatic series hydrocarbon resin in retort, be warming up to 180 DEG C, then add carboxylic styrene-butadiene rubber, under the conditions of high speed shear
2h is reacted, 190 DEG C is warming up to and adds naphthalene sulfonic salt and polycarboxylic acids, 150 DEG C is cooled to after stirring 0.5h, adds peroxide second
Acid, adds gingerol after stirring 0.5min, stirs 1h, obtain gluing waterproof material；
Step 2：Waterproof roll is molded
Under the conditions of 120 DEG C, gluing waterproof material prepared by step 1 is applied by two pairs of rollers and determines thick device heat coating
On the polymeric membrane of thickness 0.1mm, while silicone oil isolation film is covered with, is cooled down using cold water spray system, formation is embedding to determine cohesion
Adhesion type macromolecule waterproof membrane, finally crimps into flexible sheet material, that is, obtains embedding determining cohesion adhesion type polymer membranes.
Embodiment 2
It is a kind of it is embedding determine cohesion adhesion type polymer membranes, including polymeric membrane and coated on the glue on polymeric membrane
Viscous waterproof material, the gluing waterproof material are made of the raw material components of following mass fraction：No. 90 60 parts of heavy traffic paving asphalts, SBS
10 parts of rubber, 8 parts of carboxylic styrene-butadiene rubber, 2 parts of aphthenic acids, 4 parts of polypropylene, 6 parts of aromatic series hydrocarbon resin, 2 parts of naphthalene sulfonic salt,
1.5 parts of polycarboxylic acids, excessively sad 1 part of tert-pentyl ester, 0.5 part of gingerol, 3 parts of end hydroxy butadiene, hydroxypropyl methyl cellulose ether 2
Part；
The embedding preparation method for determining cohesion adhesion type polymer membranes, step are as follows：
Step 1：The preparation of gluing waterproof material
Raw material is weighed according to each component mass ratio, first respectively by No. 90 heavy traffic paving asphalts, SBS rubber, aphthenic acids, polypropylene
Added with aromatic series hydrocarbon resin in retort, be warming up to 180 DEG C, then add carboxylic styrene-butadiene rubber, under the conditions of high speed shear
2h is reacted, 190 DEG C is warming up to and adds naphthalene sulfonic salt and polycarboxylic acids, end hydroxy butadiene and hydroxypropyl methyl cellulose
Ether, 150 DEG C are cooled to after stirring 0.5h, add sad tert-pentyl ester, are added gingerol after stirring 0.5min, are stirred 1h, obtain
Gluing waterproof material；
Step 2：Waterproof roll is molded
Under the conditions of 130 DEG C, gluing waterproof material prepared by step 1 is applied by two pairs of rollers and determines thick device heat coating
On the polymeric membrane of thickness 0.15mm, while silicone oil isolation film is covered with, is cooled down using cold water spray system, formation is embedding to determine cohesion
Adhesion type macromolecule waterproof membrane, finally crimps into flexible sheet material, that is, obtains embedding determining cohesion adhesion type polymer membranes.
Embodiment 3
It is a kind of it is embedding determine cohesion adhesion type polymer membranes, including polymeric membrane and coated on the glue on polymeric membrane
Viscous waterproof material, the gluing waterproof material are made of the raw material components of following mass fraction：No. 90 60 parts of heavy traffic paving asphalts, SBS
12 parts of rubber, 6 parts of carboxylic styrene-butadiene rubber, 3 parts of aphthenic acids, 4 parts of polypropylene, 5 parts of aromatic series hydrocarbon resin, 2 parts of naphthalene sulfonic salt,
1.5 parts of polycarboxylic acids, 1 part of Peracetic acid, 0.5 part of gingerol oxime, 3 parts of end hydroxy butadiene, 2 parts of hydroxypropyl methyl cellulose ether；
The embedding preparation method for determining cohesion adhesion type polymer membranes, step are as follows：
Step 1：The preparation of gluing waterproof material
Raw material is weighed according to each component mass ratio, first respectively by No. 90 heavy traffic paving asphalts, SBS rubber, aphthenic acids, polypropylene
Added with aromatic series hydrocarbon resin in retort, be warming up to 180 DEG C, then add carboxylic styrene-butadiene rubber, under the conditions of high speed shear
2h is reacted, 190 DEG C is warming up to and adds naphthalene sulfonic salt and polycarboxylic acids, end hydroxy butadiene and hydroxypropyl methyl cellulose
Ether, is cooled to 150 DEG C after stirring 0.5h, adds Peracetic acid, adds gingerol oxime after stirring 0.5min, stirs 1h, obtain glue
Viscous waterproof material；
Step 2：Waterproof roll is molded
Under the conditions of 130 DEG C, gluing waterproof material prepared by step 1 is applied by two pairs of rollers and determines thick device heat coating
On the polymeric membrane of thickness 0.15mm, while silicone oil isolation film is covered with, is cooled down using cold water spray system, formation is embedding to determine cohesion
Adhesion type macromolecule waterproof membrane, finally crimps into flexible sheet material, that is, obtains embedding determining cohesion adhesion type polymer membranes.
The embedding performance test results such as table for determining cohesion adhesion type polymer membranes prepared by the embodiment of the present invention 1~3
1, the results showed that, the tensile property of waterproof roll of the invention, impermeability, hold viscosity and be better than with concrete peel strength
Traditional adhesive waterproof coil.
The key technical indexes of the waterproof roll of the present invention of table 1 and traditional adhesive waterproof coil
Claims (9)
1. one kind is embedding to determine cohesion adhesion type polymer membranes, it is characterised in that including polymeric membrane and coated on high score
Gluing waterproof material on sub- film, the gluing waterproof material are made of the raw material components of following mass fraction：Matrix pitch 60
~70 parts, 10~20 parts of SBS rubber, 5~10 parts of carboxylic styrene-butadiene rubber, 2~4 parts of aphthenic acids, 3~5 parts of polypropylene, aromatic series carbon
5~7 parts of hydrogen resin, 1~3 part of sulfonate, 1~2 part of polycarboxylic acids, 1~2 part of catalytic promoter, 0.5~1 part of antioxidant.
2. one kind as claimed in claim 1 is embedding to determine cohesion adhesion type polymer membranes, it is characterised in that described gluing anti-
Water material further includes the end hydroxy butadiene of 2~5 parts of mass fraction, 2~3 parts of hydroxypropyl methyl ether.
3. one kind as claimed in claim 1 or 2 is embedding to determine cohesion adhesion type polymer membranes, it is characterised in that the base
Matter pitch is No. 90 heavy traffic paving asphalts.
4. one kind as claimed in claim 1 or 2 is embedding to determine cohesion adhesion type polymer membranes, it is characterised in that the sulphur
Hydrochlorate is naphthalene sulfonic salt.
5. one kind as claimed in claim 1 or 2 is embedding to determine cohesion adhesion type polymer membranes, it is characterised in that described to urge
Change accelerating agent is one kind in Peracetic acid, perbenzoic acid or excessively sad tert-pentyl ester.
6. one kind as claimed in claim 1 or 2 is embedding to determine cohesion adhesion type polymer membranes, it is characterised in that the phenol
Class antioxidant is gingerol or gingerol oxime.
7. one kind as claimed in claim 2 is embedding to determine cohesion adhesion type polymer membranes, it is characterised in that the hydroxypropyl
Methyl ether is hydroxypropyl methyl cellulose ether.
8. the embedding preparation method for determining cohesion adhesion type polymer membranes as claimed in claim 1, it is characterised in that including
Following steps：
Step 1：The preparation of gluing waterproof material
Each raw material components are weighed first, respectively add matrix pitch, SBS rubber, aphthenic acids, polypropylene and aromatic series hydrocarbon resin
Enter in retort, be warming up to 180 DEG C, then add carboxylic styrene-butadiene rubber, react 2h under the conditions of high speed shear, be warming up to 190 DEG C
Sulfonate and polycarboxylic acids are added, 150 DEG C is cooled to after stirring 0.5h, adds catalytic promoter, added after stirring 0.5min
Antioxidant, stirs 1h, obtains gluing waterproof material；
Step 2：Waterproof roll is molded
Under the conditions of 120~130 DEG C, gluing waterproof material prepared by step 1 is applied by two pairs of rollers and determines thick device heat coating
On the polymeric membrane of 0.1~0.2mm of thickness, while silicone oil isolation film is covered with, is cooled down using cold water spray system, it is embedding fixed to be formed
Cohesion adhesion type macromolecule waterproof membrane, finally crimps into flexible sheet material, that is, obtains embedding determining cohesion adhesion type polymer membranes.
9. the embedding preparation method for determining cohesion adhesion type polymer membranes as claimed in claim 2, it is characterised in that including
Following steps：
Step 1：The preparation of gluing waterproof material
Each raw material components are weighed first, respectively add matrix pitch, SBS rubber, aphthenic acids, polypropylene and aromatic series hydrocarbon resin
Enter in retort, be warming up to 180 DEG C, then add carboxylic styrene-butadiene rubber, react 2h under the conditions of high speed shear, be warming up to 190 DEG C
Sulfonate, polycarboxylic acids, end hydroxy butadiene and hydroxypropyl methyl ether are added, is cooled to 150 DEG C after stirring 0.5h, addition is urged
Change accelerating agent, add antioxidant after stirring 0.5min, stir 1h, obtain gluing waterproof material；
Step 2：Waterproof roll is molded
Under the conditions of 120~130 DEG C, gluing waterproof material prepared by step 1 is applied by two pairs of rollers and determines thick device heat coating
On the polymeric membrane of 0.1~0.2mm of thickness, while silicone oil isolation film is covered with, is cooled down using cold water spray system, it is embedding fixed to be formed
Cohesion adhesion type macromolecule waterproof membrane, finally crimps into flexible sheet material, that is, obtains embedding determining cohesion adhesion type polymer membranes.
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN115302891A (en) * | 2022-07-06 | 2022-11-08 | 南京苏伊尔工程材料有限公司 | Road waterproof anti-cracking coiled material and preparation method and application thereof |
| CN117801709A (en) * | 2024-02-29 | 2024-04-02 | 河北宇阳泽丽防水材料有限公司 | High-strength double-lap joint double-polymer film-based waterproof coiled material and preparation method thereof |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115302891A (en) * | 2022-07-06 | 2022-11-08 | 南京苏伊尔工程材料有限公司 | Road waterproof anti-cracking coiled material and preparation method and application thereof |
| CN117801709A (en) * | 2024-02-29 | 2024-04-02 | 河北宇阳泽丽防水材料有限公司 | High-strength double-lap joint double-polymer film-based waterproof coiled material and preparation method thereof |
| CN117801709B (en) * | 2024-02-29 | 2024-05-07 | 河北宇阳泽丽防水材料有限公司 | High-strength double-lap joint double-polymer film-based waterproof coiled material and preparation method thereof |
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