CN107956168A - A kind of printing with reactive dye fabric increases the gorgeous finishing agent of deep increasing and preparation method - Google Patents
A kind of printing with reactive dye fabric increases the gorgeous finishing agent of deep increasing and preparation method Download PDFInfo
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- CN107956168A CN107956168A CN201711173916.7A CN201711173916A CN107956168A CN 107956168 A CN107956168 A CN 107956168A CN 201711173916 A CN201711173916 A CN 201711173916A CN 107956168 A CN107956168 A CN 107956168A
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
- D06P5/02—After-treatment
- D06P5/04—After-treatment with organic compounds
- D06P5/08—After-treatment with organic compounds macromolecular
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
- D06P5/02—After-treatment
- D06P5/04—After-treatment with organic compounds
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- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
A kind of printing with reactive dye fabric of the present invention increases the gorgeous finishing agent of deep increasing and preparation method, raw material is by weight ratio by 20~30 parts of nonionic emulsifiers, 50~70 parts of methyl-silicone oils, 180~220 parts of hydroxy silicon oils, 8~12 parts of Methyl Hydrogen Polysiloxane Fluids, 25~30 parts of refined caster oils, 1~5 part of ethyl silicate 40,510~660 parts of deionized waters, it is made through liquid crystal emulsified method, it is free of ammonia nitrogen, soft smooth, washability is good.
Description
Technical field
The present invention relates to after-finishing of textile products agent, and in particular to be a kind of printing with reactive dye fabric increase it is deep increase it is gorgeous
Finishing agent and preparation method.
Background technology
With the continuous development of textile technology, requirement of the people to garment material is also higher and higher, one of them is exactly pair
Evaluation on the first sense organ of textile is the evaluation of color, and the color it is desirable to colored fabric is more bright-coloured, bright, and tone is more
Add superior.For reactive dye because its chromatography is complete, wet fastness is high, it has also become the preferred dyestuff of cellulose fibre stamp, activity dye
Expect that stamp as a kind of printing technique of most mainstream, is spread wide, is largely used in pure cotton, people cotton and tencel face
Material.
Printing with reactive dye can improve the vividness of color in slurry is prepared using substantial amounts of urea, and printing is expected below
On slurry must wash off, so result in substantial amounts of urea and enter in the waste water of discharge, cause the nitrogen content in waste water tight
Weight is exceeded.The discharge to ammonia nitrogen has stringent limitation at present, and the replacement of urea is used during printing with reactive dye
Product, but the shortcoming of substitute is exactly bright-colored degree and the degree of saturation deficiency after stamp.
It is to be covered in fiber surface using low-refraction material that after-finishing of textile products, which increases deep, makes incident light on the fabric anti-
Rate reduction is penetrated, and people is visually produced the sensation of " depth " to the color of fabric.Polyurethane, polyacrylic acid are introduced according to document
Ester, polysiloxane etc. are all the materials with low-refraction, there is different increasing depth effects to fiber.Wherein poly organo
The refractive index of alkane is relatively low, and the fabric after its arrangement also has soft, smooth feel concurrently while increasing deep.
CN200810163784.4 patents disclose one kind N- (β-aminoethyl)-γ-aminopropyltriethoxy dimethoxy
Silane-modified amido silicon oil makees fabric brightening agent, its using effect is notable to dark polyester fiber, and for dyeing
Cotton, polyester-cotton blend, wash the fabric effects such as viscous, wool and unobvious.
200810060886.3 patents of CN disclose one kind vinyl monomer, hydroxy silicon oil and response type function monomer
Deng the deep-dyeing agent prepared using emulsion polymerization technique.Since the initiator N hydroxymethyl acrylamide used in synthesis can be in fabric
The harmful formaldehyde of upper residual, the fabric feeling after the processing of this deep-dyeing agent hardens, is coarse, and contains ammonia nitrogen in raffinate
Group.
CN 201010288531.7 discloses a kind of organic siloxane emulsion group modified by multiple functions and one
The finishing agent of the Methyl Hydrogen Polysiloxane Fluid lotion composition of certainty ratio, this finishing agent has dyed cotton fabric increases the deep and gorgeous effect of increasing well
Fruit, but contain ammonia nitrogen group in product, it is impossible to increasingly environmentally friendly strict demand is adapted to, so as to influence the popularization and use of product.
The content of the invention
The object of the present invention is to provide one kind be free of ammonia nitrogen, soft smooth, washability is good, for reactive dye print
The increasing of flower fabric increases gorgeous finishing agent deeply, it be by a variety of silicone oil, castor oil, surfactant etc. by a certain percentage, using liquid crystal
Finishing agent made of emulsion process, this finishing agent have printing with reactive dye fabric good increasing depth and brightening effect, product to be free of
Ammonia nitrogen, will not increase the ammonia nitrogen index of sewage discharge, insalubrious material not remained on fabric.
Printing with reactive dye fabric of the present invention increases the deep gorgeous finishing agent preparation method of increasing:
Raw material is by weight ratio:
1st, 20~30 parts of nonionic emulsifiers and 10~30 parts of deionized waters are sufficiently stirred 20~30 minutes at normal temperatures, make to mix
Compound forms the sticky paste of water white transparency;
2 then add 50~70 parts of methyl-silicone oils, 180~220 parts of hydroxy silicon oils, 8~12 parts of Methyl Hydrogen Polysiloxane Fluids, 25~30
Part refined caster oil, 1~5 part of silester -40, continue stirring 30~40 minutes, form transparent sticky smectic at normal temperatures
Thing;
3 then add 500~630 parts of deionized waters, quickly stir 20~30 minutes, obtain product.
Product index:Milky white liquid
Effective content:≥30%
PH values:7±1
It is ionic:It is non-.
The nonionic emulsifier:For isomery C13 alcohol polyoxyethylene ether, C12-C14 secondary alcohol polyoxyethylene ether, two kinds mixed
Close and use;
The methyl-silicone oil:Viscosity is 300~1000mpa.s;
The hydroxy silicon oil:Viscosity is 10000~80000map.s;
The Methyl Hydrogen Polysiloxane Fluid:Hydrogen content is 1.5%~1.6%.
The technical advance of brightening agent of the present invention is:
1st, methyl-silicone oil and hydroxy silicon oil is selected to coordinate to replace common amido silicon oil to increase depth component as effective, in product
Without ammonia nitrogen composition, the ammonia nitrogen index of sewage discharge will not be increased, insalubrious material is not remained on fabric.
2nd, the larger hydroxy silicon oil of molecular weight is selected, film forming of the hydroxy silicon oil on cotton fabric can be significantly improved,
Fabric face forms the film with low-refraction, reduces the reflectivity of incident light, hence it is evident that increase the depth of printed fabric.
3rd, Methyl Hydrogen Polysiloxane Fluid has the refractive index lower than amino silicones, its addition can make deep dyeing further
Lifting, while net structure can be generated with the hydroxyl reaction in hydroxy silicon oil, film forming of the increase product on fabric, also increases
With the binding strength of the hydroxyl on fabric, there is certain tint retention to the dyestuff on fabric.
4th, because nonionic surfactant effect of stripping to color, dosage can excessively make the color on fabric easily molten
Enter into padding liquid, make the fabric color after arrangement dim, do not become clear, so using liquid crystal emulsified method, the less use of energy
Nonionic emulsifier, ensures that the color on fabric is not easy to be added in padding liquid, so as to can keep the fabric color after arrangement
Original vividness.
Although the 5, castor oil is not low-refraction material, after Over emulsfication, it can increase the vividness of color, compensate for
Organosilicon composition only increases does not increase gorgeous deficiency deeply.
6th, selection two kinds of non-ionic surfaces of isomery C13 alcohol polyoxyethylene ether and C12-C14 secondary alcohol polyoxyethylene ether are mixed and made
With the two is all Formation of liquid crystals emulsifying agent, and the emulsifiability of isomery C13 alcohol polyoxyethylene ether is good, and penetration is good, C12-C14
Secondary alcohol polyoxyethylene ether low temperature flow is good, easy to use, has good wetability, and the combination of the two can be carried more effectively
Emulsifying effectiveness is risen, and improves the penetration of product, effective ingredient in product is preferably adsorbed by fabric.
Embodiment
Embodiment 1
1st, by 15 parts of isomery C13 alcohol polyoxyethylene(12)Ether, 5 parts of C12-C14 secondary alcohol polyoxyethylene(5)Ether and 12 parts of deionized waters
It is sufficiently stirred at normal temperatures 25 minutes, mixture is formed the sticky paste of water white transparency;
2 then add 50 parts of viscosity be 1000mpa.s methyl-silicone oil, 200 parts of viscosity be 10000mpa.s hydroxy silicon oils, 12
Part Methyl Hydrogen Polysiloxane Fluid, 25 parts of refined caster oils, 2 parts of silester -40, continue stirring 30 minutes at normal temperatures, are formed transparent
Sticky smectic thing;
3rd, disposably add 572 parts of deionized waters in most backward mixture, quick stirring after twenty minutes milky lotion,
The deep gorgeous finishing agent product of increasing must be increased.
Embodiment 2
1st, by 10 parts of isomery C13 alcohol polyoxyethylene(7)Ether, 20 parts of C12-C14 secondary alcohol polyoxyethylene(9)Ether and 30 parts of deionized waters
It is sufficiently stirred at normal temperatures 30 minutes, mixture is formed the sticky paste of water white transparency;
2 then add 60 parts of viscosity be 350mpa.s methyl-silicone oil, 190 parts of viscosity be 20000mpa.s hydroxy silicon oils, 9.5
Part Methyl Hydrogen Polysiloxane Fluid, 28 parts of refined caster oils, 3.8 parts of silester -40, continue stirring 40 minutes at normal temperatures, are formed saturating
Bright sticky smectic thing;
3rd, disposably add 630 parts of deionized waters in most backward mixture, after quick stirring 25 minutes milky lotion,
The deep gorgeous finishing agent product of increasing must be increased.
Embodiment 3
1st, by 15 parts of isomery C13 alcohol polyoxyethylene(5)Ether, 10 parts of C12-C14 secondary alcohol polyoxyethylene(12)Ether and 25 parts of deionizations
Water is sufficiently stirred 20 minutes at normal temperatures, mixture is formed the sticky paste of water white transparency;
2 then add 55 parts of viscosity be 500mpa.s methyl-silicone oil, 220 parts of viscosity be 50000mpa.s hydroxy silicon oils, 9 parts
Methyl Hydrogen Polysiloxane Fluid, 30 parts of refined caster oils, 4.5 parts of silester -40, continue stirring 40 minutes at normal temperatures, are formed transparent
Sticky smectic thing;
3rd, disposably add 620 parts of deionized waters in most backward mixture, after quick stirring 30 minutes milky lotion,
The deep gorgeous finishing agent product of increasing must be increased.
Embodiment 4
1st, by 10 parts of isomery C13 alcohol polyoxyethylene(8)Ether, 15 parts of C12-C14 secondary alcohol polyoxyethylene(7)Ether and 25 parts of deionized waters
It is sufficiently stirred at normal temperatures 30 minutes, mixture is formed the sticky paste of water white transparency;
2 then add 50 parts of viscosity be 350mpa.s methyl-silicone oil, 195 parts of viscosity be 80000mpa.s hydroxy silicon oils, 8 parts
Methyl Hydrogen Polysiloxane Fluid, 30 parts of refined caster oils, 2.5 parts of silester -40, continue stirring 40 minutes at normal temperatures, are formed transparent
Sticky smectic thing;
3rd, disposably add 555 parts of deionized waters in most backward mixture, after quick stirring 30 minutes milky lotion,
The deep gorgeous finishing agent product of increasing must be increased.
Embodiment 5
1st, by 12 parts of isomery C13 alcohol polyoxyethylene(5)Ether, 15 parts of C12-C14 secondary alcohol polyoxyethylene(12)Ether and 30 parts of deionizations
Water is sufficiently stirred 30 minutes at normal temperatures, mixture is formed the sticky paste of water white transparency;
2 then add 70 parts of viscosity be 500mpa.s methyl-silicone oil, 180 parts of viscosity be 20000mpa.s hydroxy silicon oils, 11 parts
Methyl Hydrogen Polysiloxane Fluid, 30 parts of refined caster oils, 2 parts of silester -40, continue stirring 40 minutes, are formed transparent at normal temperatures
Sticky smectic thing;
3rd, disposably add 560 parts of deionized waters in most backward mixture, after quick stirring 30 minutes milky lotion,
The deep gorgeous finishing agent product of increasing must be increased.
Embodiment 6
1st, by 18 parts of isomery C13 alcohol polyoxyethylene(8)Ether, 10 parts of C12-C14 secondary alcohol polyoxyethylene(9)Ether and 28 parts of deionized waters
It is sufficiently stirred at normal temperatures 30 minutes, mixture is formed the sticky paste of water white transparency;
2 then add 65 parts of viscosity be 350mpa.s methyl-silicone oil, 200 parts of viscosity be 50000mpa.s hydroxy silicon oils, 9 parts
Methyl Hydrogen Polysiloxane Fluid, 28 parts of refined caster oils, 2.5 parts of silester -40, continue stirring 35 minutes at normal temperatures, are formed transparent
Sticky smectic thing;
3rd, disposably add 590 parts of deionized waters in most backward mixture, after quick stirring 30 minutes milky lotion,
The deep gorgeous finishing agent product of increasing must be increased.
Testing inspection
Water is added to be made into the working solution of 50g/L respectively the various embodiments described above 1-6 products, to red, purple, atroceruleous activity
Stamp pure-cotton fabric(Specification 40 × 40,133 × 72)Progress padding finishing, pick-up 70~80%, 120-130 DEG C of drying temperature,
150-160 DEG C of baking temperature, time 1-2 minute.Washing conditions press 4A methods in GB8629-2001.
To after arrangement and washing behind material computer colour photometer, measure K/S values in the maximum absorption wave strong point of each color, knot
Fruit such as following table:
Note:K/S values are bigger to represent that color is deeper.
The vividness of fabric is compared under standard sources, as a result see the table below:
Claims (2)
1. a kind of printing with reactive dye fabric increases the gorgeous finishing agent of deep increasing and preparation method, it is characterized in that:
Raw material is by weight ratio:
(1), 20~30 parts of nonionic emulsifiers and 10~30 parts of deionized waters are sufficiently stirred 20~30 minutes at normal temperatures, made
Mixture forms the sticky paste of water white transparency;
(2) then add 50~70 parts of methyl-silicone oils, 180~220 parts of hydroxy silicon oils, 8~12 parts of Methyl Hydrogen Polysiloxane Fluids, 25~
30 parts of refined caster oils, 1~5 part of silester -40, continue stirring 30~40 minutes at normal temperatures, form transparent sticky fat
Shape thing;
(3) and then 500~630 parts of deionized waters are added, quickly stirs 20~30 minutes, obtain product;
Product index:Milky white liquid
Effective content:≥30%
PH values:7±1
It is ionic:It is non-;
The nonionic emulsifier:For isomery C13 alcohol polyoxyethylene ether, C12-C14 secondary alcohol polyoxyethylene ether, two kinds of mixing make
With;
The methyl-silicone oil:Viscosity is 300~1000mpa.s;
The hydroxy silicon oil:Viscosity is 10000~80000map.s;
The Methyl Hydrogen Polysiloxane Fluid:Hydrogen content is 1.5%~1.6%.
2. the printing with reactive dye fabric as claim 1 preparation method obtains increases the deep gorgeous finishing agent of increasing.
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Cited By (4)
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CN109112856A (en) * | 2018-07-17 | 2019-01-01 | 嘉兴学院 | Cotton fabric digital printing process |
CN109594364A (en) * | 2018-11-29 | 2019-04-09 | 上海雅运新材料有限公司 | A kind of reactive printing urea substituting agent and preparation method thereof |
WO2023037922A1 (en) * | 2021-09-07 | 2023-03-16 | 京セラ株式会社 | Ink-jet treatment liquid, ink-jet textile printing device, and ink-jet textile printing method |
CN116376315A (en) * | 2023-03-07 | 2023-07-04 | 江南大学 | Preparation method and application of high-light fastness liquid crystal structure pigment |
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CN106835717A (en) * | 2017-03-07 | 2017-06-13 | 清远市宏图助剂有限公司 | A kind of bafta increases deep gorgeous organic silicone finishing agent of increasing and preparation method thereof |
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Publication number | Priority date | Publication date | Assignee | Title |
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WO2023037922A1 (en) * | 2021-09-07 | 2023-03-16 | 京セラ株式会社 | Ink-jet treatment liquid, ink-jet textile printing device, and ink-jet textile printing method |
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CN117178089A (en) * | 2021-09-07 | 2023-12-05 | 京瓷株式会社 | Treatment liquid for inkjet, inkjet printing device, and inkjet printing method |
CN116376315A (en) * | 2023-03-07 | 2023-07-04 | 江南大学 | Preparation method and application of high-light fastness liquid crystal structure pigment |
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