CN107988822A - The high dyestuff of disperse dyes Non-water washing stamp carries passing property adhesive and preparation method - Google Patents
The high dyestuff of disperse dyes Non-water washing stamp carries passing property adhesive and preparation method Download PDFInfo
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- CN107988822A CN107988822A CN201711022302.9A CN201711022302A CN107988822A CN 107988822 A CN107988822 A CN 107988822A CN 201711022302 A CN201711022302 A CN 201711022302A CN 107988822 A CN107988822 A CN 107988822A
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/52—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing synthetic macromolecular substances
- D06P1/5207—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- D06P1/525—Polymers of unsaturated carboxylic acids or functional derivatives thereof
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/12—Polymerisation in non-solvents
- C08F2/16—Aqueous medium
- C08F2/22—Emulsion polymerisation
- C08F2/24—Emulsion polymerisation with the aid of emulsifying agents
- C08F2/26—Emulsion polymerisation with the aid of emulsifying agents anionic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/12—Polymerisation in non-solvents
- C08F2/16—Aqueous medium
- C08F2/22—Emulsion polymerisation
- C08F2/24—Emulsion polymerisation with the aid of emulsifying agents
- C08F2/30—Emulsion polymerisation with the aid of emulsifying agents non-ionic
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F283/00—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G
- C08F283/12—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G on to polysiloxanes
- C08F283/124—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G on to polysiloxanes on to polysiloxanes having carbon-to-carbon double bonds
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/16—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using dispersed, e.g. acetate, dyestuffs
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/52—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing synthetic macromolecular substances
- D06P1/5207—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- D06P1/525—Polymers of unsaturated carboxylic acids or functional derivatives thereof
- D06P1/5257—(Meth)acrylic acid
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/34—Material containing ester groups
- D06P3/52—Polyesters
- D06P3/54—Polyesters using dispersed dyestuffs
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- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Dispersion Chemistry (AREA)
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Abstract
A kind of high dyestuff the invention discloses disperse dyes Non-water washing stamp carries passing property adhesive and preparation method, including following components and the quality proportioning of each component are：Water：70g, emulsifying agent：1~3g, acrylate monomer：20~45g, acrylic acid：0.5~2g, organic silicon monomer：0.3~3.5g, assistant for emulsifying agent：0.2~2.5g, initiator：0.1~0.6g, compared with prior art, can favorable reproducibility, processing equipment require it is low, method is easy, beneficial to industrialized production, organosilicon modified acrylic ester binding agent has relatively low solubility parameter, differs larger with solubility parameter of disperse dyes, the compatibility of dyestuff and stamp serous coat can be significantly reduced, promote dyestuff to be transferred to fabric face by serous coat orientation, the content of free dye in serous coat is reduced, so as to improve the surface tinctorial yield and crock fastness of PRINTED FABRIC；Another aspect silicone segments are soft, can be effectively improved PRINTED FABRIC feel.So high dyestuff carries passing property Non-water washing printing adhesive and has broad application prospects in stamp production.
Description
【Technical field】
The invention belongs to adhesive field, more particularly to a kind of organic-silicon-modified propylene that passing property is carried with high dyestuff
The preparation method of acid esters adhesive and the application as printing adhesive on terylene disperse dyes Non-water washing stamp.
【Background technology】
Traditional terylene Disperse Printing must remove not fixed dyestuff, stamp paste through soaping with multiple tracks washing step
Material and chemicals, not only energy consumption is high, and wastewater discharge is big, Treatment for Reuse difficulty is high.In order to realize efficient, energy saving and water
The zero-emission of waste water is washed, disperse dyes Non-water washing printing technique comes into being.The technology replaces pigment printing using disperse dyes
Pigment in mill base, utilizes the characteristic that (pad-dry-cure dyeing) is contaminated in polymer binder film forming characteristics and disperse dyes solid phase, base
In migration of the disperse dyes in serous coat, diffusion and fixed principle to polyester fiber, using similar to the short of pigment printing
Flow (stamp-drying-bakes) is processed to realize the non-evaporating purpose washed of terylene disperse dyes.This is asked for solving dyeing waste water
Topic and stamp engineering are energy saving, promote the transition and upgrade of textile industry and sustainable development to be of great significance.
At present, existing research is concentrated mainly on exploitation disperse dyes Non-water washing concentrator.Polymer binder, which is used as, to be divided
Dissipate the important component of dyestuff Non-water washing print paste, extreme influence PRINTED FABRIC color performance, color fastness and feel etc.
Printing performance.Can be with when being applied to textile printing according to Chinese patent CN 1282815A " a kind of environment-friendly type free steam cleaning printing slurry "
Save and evaporate and washing process, greatly reduce textile printing defect, eliminate pollution of the waste water to environment.But its print paste
Middle binder dosage is big, inevitably results in the problems such as PRINTED FABRIC feel is poor.Chinese patent CN 105113284A are " a kind of micro
Print paste and preparation method and application " uses micro polymeric decal technology, and it is soft to reach PRINTED FABRIC, section
Water is energy saving, reduces the purpose of sewage discharge.But the adhesive polymerized monomer in printing paste is complete within the fabric face short time
Into polymerization film formation, monomer polymerization will certainly be caused incomplete, adhesive film forming ability is poor, and PRINTED FABRIC poor color fastness etc. is asked
Topic.However, the disperse dyes and not all upper dye polyester fiber, some dyes in conventional Non-water washing serous coat will be dissolved in high score
In sub- glued membrane and diffusion mobility is to film top layer.During dress is taken, printing fabric is subjected to extraneous stronger mechanicals efforts
(such as rub, crumple repeatedly, stirring, rinsing) and environmental stimulus (such as heat, light, auxiliary agent), point on polymeric laminate top layer
Scattered dyestuff is just easily separated from the surface of glued membrane, causes discoloration and color fastness undesirable (staining, friction, washing, light fastness)
The problems such as, this largely limits the development and application of disperse dyes Non-water washing printing technique.
And increase the solubility parameters difference between polymer binder and disperse dyes, can there is polymer binder
High dyestuff carries passing property, that is, reduces " dissolving " of the disperse dyes in polymeric laminate, promotes disperse dyes into high polymer fibre
Portion's migration, diffusion and fixed, thus lifted disperse dyes Non-water washing PRINTED FABRIC color performance and color fastness, preferably solve
Certainly above-mentioned the problem of referring to.This patent is smaller by introducing solubility parameter, and surface energy is relatively low, and molecule segment is relatively soft to be gathered
Siloxanes segment carrys out modification acrylate, to improve diffusible main purpose of the disperse dyes in stamp serous coat, so as to carry
High dyestuff improves the feel of PRINTED FABRIC to the dye-uptake and colorfastness to rubbing of fabric.
Existing organosilicon modified acrylic ester binding agent mainly by low molecule organic silicon monomer directly with adhesive list
Body mixes, and one-step method prepares organosilicon modified acrylic ester binding agent.This directly mix monomer working system, technique are simple.But
It is difficult to be aggregated in acrylate segment there is organosilicon, causes organosilicon in adhesive latex in free distribution
Situation, so as to influence the storage stability and printing performance of adhesive.Therefore, the poly- silica of both-end vinyl is used in this patent
Alkane polymerize with acrylate monomer prepares organosilicon modified acrylic ester binding agent.The polymerization of acrylate is led at this stage
Will be using emulsion polymerization, this method is difficult to ensure that organic-silicon-modified monomer copolymerization to polyacrylic acid ester large molecule.
In addition the polyacrylate latex particle size difference generated is big, and Particle dispersity is poor, is easy to cause emulsion breaking and stability
It is poor with resistance to storage.This patent prepares organosilicon modified acrylic ester binding agent using fine emulsion polymerization, and main is excellent
Gesture is by being ultrasonically treated to lotion, makes emulsion particle diameter smaller, evenly, organic-silicon-modified monomer and crylic acid ester mixture are equal
Even, so the modified acroleic acid ester molecular structure prepared is controllable, emulsion particle is uniform in size, stability is good, and the acrylic acid prepared
Ester adhesive has preferable film forming.
【The content of the invention】
The purpose of the present invention is exactly to solve the problems of the prior art, proposes a kind of height of disperse dyes Non-water washing stamp
Dyestuff carries passing property adhesive and preparation method, can favorable reproducibility, processing equipment requires low, and method is easy, beneficial to industrial metaplasia
Production, organosilicon modified acrylic ester binding agent has relatively low solubility parameter, differed with solubility parameter of disperse dyes compared with
Greatly, the compatibility of dyestuff and stamp serous coat can be significantly reduced, promotes dyestuff to be oriented by serous coat and shifts；Another aspect organosilicon chain
Section is soft, can be effectively improved PRINTED FABRIC feel.So high dyestuff carries passing property Non-water washing printing adhesive in stamp production
Have broad application prospects.
To achieve the above object, the present invention proposes to arrive fabric face, the content of free dye in serous coat is reduced, so as to carry
A kind of high dyestuff of disperse dyes Non-water washing stamp of the surface tinctorial yield of high PRINTED FABRIC and colorfastness to rubbing carries the bonding of passing property
Agent, including following components and the quality proportioning of each component be：Water：70g, emulsifying agent：1~3g, acrylate monomer：20~
45g, acrylic acid：0.5~2g, organic silicon monomer：0.3~3.5g, assistant for emulsifying agent：0.2~2.5g, initiator：0.1~0.6g.
Preferably, the organic silicon monomer is both-end vinyl polysiloxane, its structural formula is as follows：
Wherein, n is average degree of polymerization, n=11~56.
Preferably, the acrylate monomer is methyl methacrylate and Isooctyl acrylate monomer.
Preferably, the emulsifying agent is lauryl sodium sulfate (SDS), propenyloxy group propyl alkyl phenolic group polyether thiourea
One or more of mixing in sour ammonium (V-20S), fatty alcohol polyoxyethylene ether (O-10).
Preferably, the assistant for emulsifying agent is hexadecane.
Preferably, the initiator uses ammonium persulfate.
To achieve the above object, the present invention proposes a kind of high dyestuff load the passing property bonding of disperse dyes Non-water washing stamp
The preparation method of agent, comprises the following steps：
A) preparation of pre-emulsion：Emulsifying agent and water are warming up to 40~60 under the conditions of 500~1000r/min of rotating speed
DEG C and stir 10~20 minutes, be cooled to room temperature the pre-emulsion for obtaining stable homogeneous；
B) preparation of miniemulsion：Acrylate monomer, acrylic acid, organic silicon monomer, assistant for emulsifying agent are uniformly mixed, and
It is added in above-mentioned pre-emulsion, 10~20min of high-speed stirred, obtains emulsion, then miniemulsion is obtained by Ultrasonic Pulverization,
High-speed stirred speed is 800~1400r/min, emulsion Ultrasonic Pulverization 15~25 minutes in ice-water bath；
C) synthesis of adhesive：1/3 miniemulsion weighed in b) step is poured into reaction vessel, adds 3.3g initiators
Solution, stirring are warming up to 70~78 DEG C, treat that lotion is warming up to 80~85 DEG C in blue light, and remaining 2/3 miniemulsion and 7g are triggered
Agent solution was added drop-wise in reaction vessel dropwise by two separatory funnels in two hours, 80~85 DEG C of insulations after being added dropwise to complete
Two hours, obtaining organosilicon-modified acrylate emulsion, i.e. the high dyestuff of disperse dyes Non-water washing stamp carries passing property adhesive,
Initiator solution is formed after being dissolved in by 0.3g ammonium persulfates in 10g water.
Beneficial effects of the present invention：The present invention carries out acrylic ester adhesive by both-end vinyl polysiloxane
Modified, the method favorable reproducibility, equipment requirement is low, beneficial to industrialized production.Organosilicon modified acrylic ester binding agent have compared with
Low solubility parameter, differs larger with solubility parameter of disperse dyes, it is compatible with stamp serous coat to significantly reduce dyestuff
Property, promote dyestuff to be transferred to fabric face from serous coat orientation, reduce the content of free dye in serous coat, knitted so as to improve stamp
The surface tinctorial yield and colorfastness to rubbing of thing；Another aspect silicone segments are soft, can be effectively improved PRINTED FABRIC feel.
So high dyestuff carries passing property Non-water washing printing adhesive and has broad application prospects in stamp production.
The feature and advantage of the present invention will be described in detail by embodiment combination attached drawing.
【Brief description of the drawings】
Fig. 1 is the grain size distribution of organosilicon-modified acrylate emulsion prepared by embodiment 1；
Fig. 2 is that organosilicon-modified acrylate emulsion prepared by embodiment 1 forms contact angle figure of the glued membrane to water；
Fig. 3 is that organosilicon-modified acrylate emulsion formation glued membrane prepared by embodiment 1 bakes front and rear surface X rays
Photoelectron spectroscopy (XPS) spectrogram；
Fig. 4 is that the high dyestuff of disperse dyes Non-water washing stamp prepared by embodiment 1 carries passing property adhesive to dacron print
Flower surface scan Electronic Speculum (SEM) figure.
【Embodiment】
With reference to specific embodiment, the present invention is further explained.It is to be understood that these embodiments are merely to illustrate this hair
It is bright rather than limit the scope of the invention.After reading the content taught by the present invention, those skilled in the art can be right
The present invention makes various changes or modifications, and such equivalent forms equally fall within the application patent appended claims book and limited
Scope.
Embodiment 1
(1) by 1.16g lauryl sodium sulfate (SDS), 0.77g propenyloxy group propyl alkyl phenolic group polyethers ammonium sulfate (V-
20S) it is dissolved in 0.77g fatty alcohol polyoxyethylene ether (O-10) in 70g deionized waters, (60 DEG C) stirrings (800r/min) of heating up
15 minutes, it is uniformly mixed, treats that solution is cooled to room temperature, obtain pre-emulsion.
(2) by 22g Isooctyl acrylate monomers, 18g methyl methacrylates and 1.6g both-end vinyl polysiloxane (structures
It is as follows, average degree of polymerization n for 24), 0.6g acrylic acid, hexadecane 1.5g be uniformly mixed, be added to above-mentioned pre-emulsion
In, in 1200r/min high-speed stirreds 15 minutes, Ultrasonic Pulverization obtained miniemulsion in 20 minutes in ice-water bath.
(3) weigh above-mentioned 1/3 miniemulsion to pour into reaction vessel, adding 3.3g initiator solutions, (0.3g ammonium persulfates are molten
Solution is in 10g water), stirring is warming up to 78 DEG C, treats that lotion is warming up to 82 DEG C in blue light, remaining 2/3 miniemulsion and 7g initiators
Solution was added drop-wise in reaction vessel dropwise by two separatory funnels in two hours, and two hours are kept the temperature for 82 DEG C after being added dropwise to complete,
Organosilicon-modified acrylate emulsion is obtained, i.e. the high dyestuff of disperse dyes Non-water washing stamp carries passing property adhesive.
(4) configure mill base using above-mentioned adhesive and stamp is carried out to dacron；
Paste formula：Adhesive 3.2g, thickener 1.5g, disperse red 92 (C.I.Disperse Red 92 200%) dye
Expect that 0.4g, water 34.9g amount to 40g；
Printing technology：Printed polyester → preliminary drying (90 DEG C, 5min) → bake (190 DEG C, 3min)
Under these conditions, sodium alginate (SA), acrylate (PA), organosilicon-modified acrylate (MPA1) it is molten
Solution degree parameter, and the surface tinctorial yield on the printing with reactive dye on dacron surface, colorfastness to rubbing and fabric hand
Feel (stiffness, pliability, smoothness) test result, as shown in table 1.
1 sodium alginate of table, acrylic ester adhesive, the solubility parameter of modified acrylic ester as binder
And the printing performance on dacron
The particle diameter distribution of organosilicon-modified acrylate emulsion prepared by embodiment 1, as shown in Figure 1, emulsion particle in lotion
Particle diameter is in 40~80nm, and particle diameter distribution is relatively narrow.
The preparation method of latex film：The organosilicon-modified acrylate emulsion of suitable preparation is weighed in tetrafluoroethene plate
In, place 5 days under room temperature (15~25 DEG C), then bake 3 minutes at 190 DEG C, form latex film.
Organosilicon-modified acrylate glued membrane prepared by embodiment 1 is to the contact angle of water, as shown in Figure 2.Modified acroleic acid
Ester gum film, up to 105.76 DEG C, shows the glue that the present embodiment organosilicon modified acrylic ester binding agent is formed to the contact angle of water
Film has excellent hydrophobicity.
Embodiment 1 prepare organosilicon-modified acrylate glued membrane bake front and rear surfaces element species and content such as Fig. 3 and
Table 8, bakes rear film surface silicon content and dramatically increases, and silicon carbon ratio is changed into 0.44 from theoretical value 0.02, and in pure organosilicon
Silicon carbon ratio 0.5 is not much different, and illustrates that bake rear silicon forms a near-complete silicon protective layer to surface migration, shows this reality
Applying an organosilicon modified acrylic ester binding agent stamp has preferable rub resistance color performance.
Organosilicon modified acrylic ester binding agent prepared by embodiment 1 carries out stamp, PRINTED FABRIC surface scan to fabric
Electronic Speculum is uniform-distribution with the organic of protrusion as shown in figure 4, the complete adhesive phase of fiber surface presentation in adhesive layer surface
Silicon, shows that the present embodiment organosilicon modified acrylic ester binding agent PRINTED FABRIC has soft feel.
From table 1 it follows that after organosilicon is modified acrylic ester adhesive, its solubility parameter significantly drops
It is low, differ greatly with solubility parameter of disperse dyes (22.56).Modified acrylic ester adhesive PRINTED FABRIC surface obtains color
Amount improves 11.0%, and wet friction color fastness lifts 1 grade, can obtain that decorative pattern is clear, soft PRINTED FABRIC.
Embodiment 2
(1) by 1.16g lauryl sodium sulfate (SDS), 0.77g propenyloxy group propyl alkyl phenolic group polyethers ammonium sulfate (V-
20S) it is dissolved in 0.77g fatty alcohol polyoxyethylene ether (O-10) in 70g deionized waters, (60 DEG C) stirrings (800r/min) of heating up
15 minutes, it is uniformly mixed, treats that solution is cooled to room temperature, obtain pre-emulsion.
(2) by 19g Isooctyl acrylate monomers, 21g methyl methacrylates and 1.6g both-end vinyl polysiloxane (structures
It is as follows, average degree of polymerization n for 24), 0.6g acrylic acid, hexadecane 1.5g be uniformly mixed, be added to above-mentioned pre-emulsion
In, in 1200r/min high-speed stirreds 15 minutes, Ultrasonic Pulverization obtained miniemulsion in 20 minutes in ice-water bath.
(3) weigh above-mentioned 1/3 miniemulsion to pour into reaction vessel, adding 3.3g initiator solutions, (0.3g ammonium persulfates are molten
Solution is in 10g water), stirring is warming up to 78 DEG C, treats that lotion is warming up to 82 DEG C in blue light, remaining 2/3 miniemulsion and 7g initiators
Solution was added drop-wise in reaction vessel dropwise by two separatory funnels in two hours, and two hours are kept the temperature for 82 DEG C after being added dropwise to complete,
Organosilicon-modified acrylate emulsion is obtained, i.e. the high dyestuff of disperse dyes Non-water washing stamp carries passing property adhesive.
(4) configure mill base using above-mentioned adhesive and stamp is carried out to dacron；
Paste formula：Adhesive 3.2g, thickener 1.5g, disperse red 92 (C.I.Disperse Red 92 200%) dye
Expect that 0.4g, water 34.9g amount to 40g；
Printing technology：Printed polyester → preliminary drying (90 DEG C, 5min) → bake (190 DEG C, 3min)
Under these conditions, sodium alginate (SA), acrylate (PA), organosilicon-modified acrylate (MPA2) it is molten
Solution degree parameter, and the surface tinctorial yield on the printing with reactive dye on dacron surface, colorfastness to rubbing and fabric hand
Feel (stiffness, pliability, smoothness) test result, as shown in table 2.
2 sodium alginate of table, acrylic ester adhesive, the solubility parameter of modified acrylic ester as binder and knitted in terylene
Printing performance on thing
From Table 2, it can be seen that after organosilicon is modified acrylic ester adhesive, its solubility parameter significantly drops
It is low, differ greatly with solubility parameter of disperse dyes (22.56).Modified acrylic ester adhesive PRINTED FABRIC surface obtains color
Amount improves 8.0%, and wet friction color fastness lifts 1 grade, can obtain that decorative pattern is clear, soft PRINTED FABRIC.
Embodiment 3
(1) 2.7g lauryl sodium sulfate (SDS) is dissolved in 70g deionized waters, heat up (60 DEG C) stirring (800r/
Min) 15 minutes, it is uniformly mixed, treats that solution is cooled to room temperature, obtain pre-emulsion.
(2) by 22g Isooctyl acrylate monomers, 18g methyl methacrylates and 1.6g both-end vinyl polysiloxane (structures
It is as follows, average degree of polymerization n for 24), 0.6g acrylic acid, 1.5g hexadecanes be uniformly mixed, be added to above-mentioned pre-emulsion
In, in 1200r/min high-speed stirreds 15 minutes, in ice-water bath Ultrasonic Pulverization 20 minutes band miniemulsion.
(3) weigh above-mentioned 1/3 miniemulsion to pour into reaction vessel, adding 3.3g initiator solutions, (0.3g ammonium persulfates are molten
Solution is in 10g water), stirring is warming up to 78 DEG C, treats that lotion is warming up to 82 DEG C in blue light, remaining 2/3 miniemulsion and 7g initiators
Solution was added drop-wise in reaction vessel dropwise by two separatory funnels in two hours, and two hours are kept the temperature for 82 DEG C after being added dropwise to complete,
Organosilicon-modified acrylate emulsion is obtained, i.e. the high dyestuff of disperse dyes Non-water washing stamp carries passing property adhesive.
(4) configure mill base using above-mentioned adhesive and stamp is carried out to dacron；
Paste formula：Adhesive 3.2g, thickener 1.5g, disperse red 92 (C.I.Disperse Red 92 200%) dye
Expect that 0.4g, water 34.9g amount to 40g；
Printing technology：Printed polyester → preliminary drying (90 DEG C, 5min) → bake (190 DEG C, 3min)
Under these conditions, sodium alginate (SA), acrylate (PA), organosilicon-modified acrylate (MPA3) it is molten
Solution degree parameter, and the surface tinctorial yield on the printing with reactive dye on dacron surface, colorfastness to rubbing and fabric hand
Feel (stiffness, pliability, smoothness) test result, as shown in table 3.
3 sodium alginate of table, acrylic ester adhesive, the solubility parameter of modified acrylic ester as binder and knitted in terylene
Printing performance on thing
From table 3 it is observed that after organosilicon is modified acrylic ester adhesive, its solubility parameter significantly drops
It is low, differ greatly with solubility parameter of disperse dyes (22.56).Modified acrylic ester adhesive PRINTED FABRIC surface obtains color
Amount improves 6.9%, and wet friction color fastness lifts 1 grade, can obtain that decorative pattern is clear, soft PRINTED FABRIC.
Embodiment 4
(1) by 0.75g lauryl sodium sulfate (SDS), 0.5g propenyloxy group propyl alkyl phenolic group polyethers ammonium sulfate (V-
20S) it is dissolved in 0.5g fatty alcohol polyoxyethylene ether (O-10) in 70g deionized waters, heat up (60 DEG C) stirring (800r/min) 15
Minute, it is uniformly mixed, treats that solution is cooled to room temperature, obtain pre-emulsion.
(2) by 22g Isooctyl acrylate monomers, 19g methyl methacrylates and 1.6g both-end vinyl polysiloxane (structures
It is as follows, average degree of polymerization n for 78), 0.6g acrylic acid, hexadecane 1.5g be uniformly mixed, be added to above-mentioned pre-emulsion
In, in 1200r/min high-speed stirreds 15 minutes, Ultrasonic Pulverization obtained miniemulsion in 20 minutes in ice-water bath.
(3) weigh above-mentioned 1/3 miniemulsion to pour into reaction vessel, adding 3.3g initiator solutions, (0.3g ammonium persulfates are molten
Solution is in 10g water), stirring is warming up to 78 DEG C, treats that lotion is warming up to 82 DEG C in blue light, remaining 2/3 miniemulsion and 7g initiators
Solution was added drop-wise in reaction vessel dropwise by two separatory funnels in two hours, and two hours are kept the temperature for 82 DEG C after being added dropwise to complete,
Organosilicon-modified acrylate emulsion is obtained, i.e. the high dyestuff of disperse dyes Non-water washing stamp carries passing property adhesive.
(4) configure mill base using above-mentioned adhesive and stamp is carried out to dacron；
Paste formula：Adhesive 3.2g, thickener 1.5g, disperse red 92 (C.I.Disperse Red 92 200%) dye
Expect that 0.4g, water 34.9g amount to 40g；
Printing technology：Printed polyester → preliminary drying (90 DEG C, 5min) → bake (190 DEG C, 3min)
Under these conditions, sodium alginate (SA), acrylate (PA), organosilicon-modified acrylate (MPA4) it is molten
Solution degree parameter, and the surface tinctorial yield on the printing with reactive dye on dacron surface, colorfastness to rubbing and fabric hand
Feel (stiffness, pliability, smoothness) test result, as shown in table 4.
4 sodium alginate of table, acrylic ester adhesive, the solubility parameter of modified acrylic ester as binder and knitted in terylene
Printing performance on thing
As can be seen from Table 4, after organosilicon is modified acrylic ester adhesive, its solubility parameter significantly drops
It is low, differ greatly with solubility parameter of disperse dyes (22.56).Modified acrylic ester adhesive PRINTED FABRIC surface obtains color
Amount improves 10.0%, and wet friction color fastness lifts 1 grade, can obtain that decorative pattern is clear, soft PRINTED FABRIC.
Embodiment 5
(1) by 1.16g lauryl sodium sulfate (SDS), 0.77g propenyloxy group propyl alkyl phenolic group polyethers ammonium sulfate (V-
20S) it is dissolved in 0.77g fatty alcohol polyoxyethylene ether (O-10) in 70g deionized waters, (60 DEG C) stirrings (800r/min) of heating up
15 minutes, it is uniformly mixed, treats that solution is cooled to room temperature, obtain pre-emulsion.
(2) by 22g Isooctyl acrylate monomers, 18g methyl methacrylates and 1.6g both-end vinyl polysiloxane (structures
It is as follows, average degree of polymerization n for 24), 0.6g acrylic acid, 2.2g hexadecanes be uniformly mixed, be added to above-mentioned pre-emulsion
In, in 1200r/min high-speed stirreds 15 minutes, Ultrasonic Pulverization obtained miniemulsion in 20 minutes in ice-water bath.
(3) weigh above-mentioned 1/3 miniemulsion to pour into reaction vessel, adding 3.3g initiator solutions, (0.3g ammonium persulfates are molten
Solution is in 10g water), stirring is warming up to 78 DEG C, treats that lotion is warming up to 82 DEG C in blue light, remaining 2/3 miniemulsion and 7g initiators
Solution was added drop-wise in reaction vessel dropwise by two separatory funnels in two hours, and two hours are kept the temperature for 82 DEG C after being added dropwise to complete,
Organosilicon-modified acrylate emulsion is obtained, i.e. the high dyestuff of disperse dyes Non-water washing stamp carries passing property adhesive.
(4) configure mill base using above-mentioned adhesive and stamp is carried out to dacron；
Paste formula：Adhesive 3.2g, thickener 1.5g, disperse red 92 (C.I.Disperse Red 92 200%) dye
Expect that 0.4g, water 34.9g amount to 40g；
Printing technology：Printed polyester → preliminary drying (90 DEG C, 5min) → bake (190 DEG C, 3min)
Under these conditions, sodium alginate (SA), acrylate (PA), organosilicon-modified acrylate (MPA5) it is molten
Solution degree parameter, and the surface tinctorial yield on the printing with reactive dye on dacron surface, colorfastness to rubbing and fabric hand
Feel (stiffness, pliability, smoothness) test result, as shown in table 5.
5 sodium alginate of table, acrylic ester adhesive, the solubility parameter of modified acrylic ester as binder and knitted in terylene
Printing performance on thing
As can be seen from Table 5, after organosilicon is modified acrylic ester adhesive, its solubility parameter significantly drops
It is low, differ greatly with solubility parameter of disperse dyes (22.56).Modified acrylic ester adhesive PRINTED FABRIC surface obtains color
Amount improves 13.8%, and wet friction color fastness lifts 1 grade, can obtain that decorative pattern is clear, soft PRINTED FABRIC.
Embodiment 6
(1) by 1.16g lauryl sodium sulfate (SDS), 0.77g propenyloxy group propyl alkyl phenolic group polyethers ammonium sulfate (V-
20S) it is dissolved in 0.77g fatty alcohol polyoxyethylene ether (O-10) in 70g deionized waters, (60 DEG C) stirrings (800r/min) of heating up
15 minutes, it is uniformly mixed, treats that solution is cooled to room temperature, obtain pre-emulsion.
(2) by 22g Isooctyl acrylate monomers, 18g methyl methacrylates and 1.6g both-end vinyl polysiloxane (structures
It is as follows, average degree of polymerization n for 24), 0.6g acrylic acid, hexadecane 1.5g be uniformly mixed, be added to above-mentioned pre-emulsion
In, in 1200r/min high-speed stirreds 15 minutes, Ultrasonic Pulverization obtained miniemulsion in 20 minutes in ice-water bath.
(3) weigh above-mentioned 1/3 miniemulsion to pour into reaction vessel, adding 3.3g initiator solutions, (0.3g ammonium persulfates are molten
Solution is in 10g water), stirring is warming up to 78 DEG C, treats that lotion is warming up to 82 DEG C in blue light, remaining 2/3 miniemulsion and 7g initiators
Solution was added drop-wise in reaction vessel dropwise by two separatory funnels in two hours, and two hours are kept the temperature for 82 DEG C after being added dropwise to complete,
Organosilicon-modified acrylate emulsion is obtained, i.e. the high dyestuff of disperse dyes Non-water washing stamp carries passing property adhesive.
(4) configure mill base using above-mentioned adhesive and stamp is carried out to dacron；
Paste formula：Adhesive 3.2g, thickener 1.5g, disperse red 92 (C.I.Disperse Red 92 200%) dye
Expect that 0.4g, water 34.9g amount to 40g；
Printing technology：Printed polyester → preliminary drying (90 DEG C, 5min) → bake (190 DEG C, 3min)
Under these conditions, sodium alginate (SA), acrylate (PA), organosilicon-modified acrylate (MPA6) it is molten
Solution degree parameter, and the surface tinctorial yield on the printing with reactive dye on dacron surface, colorfastness to rubbing and fabric hand
Feel (stiffness, pliability, smoothness) test result, as shown in table 6.
6 sodium alginate of table, acrylic ester adhesive, the solubility parameter of modified acrylic ester as binder and knitted in terylene
Printing performance on thing
As can be seen from Table 6, after organosilicon is modified acrylic ester adhesive, its solubility parameter significantly drops
It is low, differ greatly with solubility parameter of disperse dyes (22.56).Modified acrylic ester adhesive PRINTED FABRIC surface obtains color
Amount improves 9.7%, and wet friction color fastness lifts 1 grade, can obtain that decorative pattern is clear, soft PRINTED FABRIC.
Embodiment 7
(1) by 1.16g lauryl sodium sulfate (SDS), 0.77g propenyloxy group propyl alkyl phenolic group polyethers ammonium sulfate (V-
20S) it is dissolved in 0.77g fatty alcohol polyoxyethylene ether (O-10) in 70g deionized waters, (60 DEG C) stirrings (800r/min) of heating up
15 minutes, it is uniformly mixed, treats that solution is cooled to room temperature, obtain pre-emulsion.
(2) by 22g Isooctyl acrylate monomers, 18g methyl methacrylates and 1.6g both-end vinyl polysiloxane (structures
It is as follows, average degree of polymerization n for 24), 0.6g acrylic acid, hexadecane 1.5g be uniformly mixed, be added to above-mentioned pre-emulsion
In, in 1200r/min high-speed stirreds 15 minutes, Ultrasonic Pulverization obtained miniemulsion in 20 minutes in ice-water bath.
(3) weigh above-mentioned 1/3 miniemulsion to pour into reaction vessel, adding 3.3g initiator solutions, (0.3g ammonium persulfates are molten
Solution is in 10g water), stirring is warming up to 78 DEG C, treats that lotion is warming up to 82 DEG C in blue light, remaining 2/3 miniemulsion and 7g initiators
Solution was added drop-wise in reaction vessel dropwise by two separatory funnels in two hours, and two hours are kept the temperature for 82 DEG C after being added dropwise to complete,
Organosilicon-modified acrylate emulsion is obtained, i.e. the high dyestuff of disperse dyes Non-water washing stamp carries passing property adhesive.
(4) configure mill base using above-mentioned adhesive and stamp is carried out to dacron；
Paste formula：Adhesive 3.2g, thickener 1.5g, disperse red 92 (C.I.Disperse Red 92 200%) dye
Expect that 0.4g, water 34.9g amount to 40g；
Printing technology：Printed polyester → preliminary drying (90 DEG C, 5min) → bake (190 DEG C, 3min)
Under these conditions, sodium alginate (SA), acrylate (PA), organosilicon-modified acrylate (MPA7) it is molten
Solution degree parameter, and the surface tinctorial yield on the printing with reactive dye on dacron surface, colorfastness to rubbing and fabric hand
Feel (stiffness, pliability, smoothness) test result, as shown in table 7.
7 sodium alginate of table, acrylic ester adhesive, the solubility parameter of modified acrylic ester as binder and knitted in terylene
Printing performance on thing
As can be seen from Table 7, after organosilicon is modified acrylic ester adhesive, its solubility parameter significantly drops
It is low, differ greatly with solubility parameter of disperse dyes (22.37).Modified acrylic ester adhesive PRINTED FABRIC surface obtains color
Amount improves 9.94%, and wet friction color fastness lifts 1 grade, can obtain that decorative pattern is clear, soft PRINTED FABRIC.
Embodiment 8
(1) by 1.16g lauryl sodium sulfate (SDS), 0.77g propenyloxy group propyl alkyl phenolic group polyethers ammonium sulfate (V-
20S) it is dissolved in 0.77g fatty alcohol polyoxyethylene ether (O-10) in 70g deionized waters, (60 DEG C) stirrings (800r/min) of heating up
15 minutes, it is uniformly mixed, treats that solution is cooled to room temperature, obtain pre-emulsion.
(2) by 22g Isooctyl acrylate monomers, 18g methyl methacrylates and 3.2g both-end vinyl polysiloxane (structures
It is as follows, average degree of polymerization n for 24), 0.6g acrylic acid, hexadecane 1.5g be uniformly mixed, be added to above-mentioned pre-emulsion
In, in 1200r/min high-speed stirreds 15 minutes, Ultrasonic Pulverization obtained miniemulsion in 20 minutes in ice-water bath.
(3) weigh above-mentioned 1/3 miniemulsion to pour into reaction vessel, adding 3.3g initiator solutions, (0.3g ammonium persulfates are molten
Solution is in 10g water), stirring is warming up to 78 DEG C, treats that lotion is warming up to 82 DEG C in blue light, remaining 2/3 miniemulsion and 7g initiators
Solution was added drop-wise in reaction vessel dropwise by two separatory funnels in two hours, and two hours are kept the temperature for 82 DEG C after being added dropwise to complete,
Organosilicon-modified acrylate emulsion is obtained, i.e. the high dyestuff of disperse dyes Non-water washing stamp carries passing property adhesive.
(4) configure mill base using above-mentioned adhesive and stamp is carried out to dacron；
Paste formula：Adhesive 3.2g, thickener 1.5g, disperse red 92 (C.I.Disperse Red 92 200%) dye
Expect that 0.4g, water 34.9g amount to 40g；
Printing technology：Printed polyester → preliminary drying (90 DEG C, 5min) → bake (190 DEG C, 3min)
Under these conditions, sodium alginate (SA), acrylate (PA), organosilicon-modified acrylate (MPA8) it is molten
Solution degree parameter, and the surface tinctorial yield on the printing with reactive dye on dacron surface, colorfastness to rubbing and fabric hand
Feel (stiffness, pliability, smoothness) test result, as shown in table 8.
8 sodium alginate of table, acrylic ester adhesive, the solubility parameter of modified acrylic ester as binder and knitted in terylene
Printing performance on thing
As can be seen from Table 8, after organosilicon is modified acrylic ester adhesive, its solubility parameter significantly drops
It is low, differ greatly with solubility parameter of disperse dyes (22.37).Modified acrylic ester adhesive PRINTED FABRIC surface obtains color
Amount improves 17.4%, and wet friction color fastness lifts 1 grade, can obtain that decorative pattern is clear, soft PRINTED FABRIC.
Table 9
| C (atom %) | O (atom %) | Si (atom %) | Si/C | |
| Before baking (a) | 63.63 | 23.39 | 12.79 | 0.20 |
| After baking (b) | 53.35 | 23.58 | 23.26 | 0.44 |
| Theoretical content | 75.84 | 22.75 | 1.41 | 0.02 |
Table 9 forms glued membrane for organosilicon-modified acrylate emulsion prepared by embodiment 1 and bakes front and rear surface-element phase
To content.
Claims (7)
1. a kind of high dyestuff of disperse dyes Non-water washing stamp carries passing property adhesive, it is characterised in that：Including following components and respectively
The quality proportioning of component is：Water：70g, emulsifying agent：1~3g, acrylate monomer：20~45g, acrylic acid：0.5~2g, it is organic
Silicon monomer：0.3~3.5g, assistant for emulsifying agent：0.2~2.5g, initiator：0.1~0.6g.
2. a kind of high dyestuff of disperse dyes Non-water washing stamp as claimed in claim 1 carries passing property adhesive, it is characterised in that：
The organic silicon monomer is both-end vinyl polysiloxane, its structural formula is as follows：
Wherein, n is average degree of polymerization, n=11~56.
3. a kind of high dyestuff of disperse dyes Non-water washing stamp as claimed in claim 1 carries passing property adhesive, it is characterised in that：
The acrylate monomer is methyl methacrylate and Isooctyl acrylate monomer.
4. a kind of high dyestuff of disperse dyes Non-water washing stamp as claimed in claim 1 carries passing property adhesive, it is characterised in that：
The emulsifying agent is lauryl sodium sulfate (SDS), propenyloxy group propyl alkyl phenolic group polyethers ammonium sulfate (V-20S), fatty alcohol
One or more of mixing in polyoxyethylene ether (O-10).
5. a kind of high dyestuff of disperse dyes Non-water washing stamp as claimed in claim 1 carries passing property adhesive, it is characterised in that：
The assistant for emulsifying agent is hexadecane.
6. a kind of high dyestuff of disperse dyes Non-water washing stamp as claimed in claim 1 carries passing property adhesive, it is characterised in that：
The initiator uses ammonium persulfate.
7. a kind of high dyestuff of disperse dyes Non-water washing stamp carries the preparation method of passing property adhesive, it is characterised in that：Including with
Lower step：
A) preparation of pre-emulsion：Emulsifying agent and water are warming up to 40~60 DEG C under the conditions of 500~1000r/min of rotating speed and stirred
Mix 10~20 minutes, be cooled to room temperature the pre-emulsion for obtaining stable homogeneous；
B) preparation of miniemulsion：Acrylate monomer, acrylic acid, organic silicon monomer, assistant for emulsifying agent are uniformly mixed, and are added to
In above-mentioned pre-emulsion, 10~20min of high-speed stirred, obtains emulsion, then obtains miniemulsion, high-speed stirred by Ultrasonic Pulverization
Speed is 800~1400r/min, emulsion Ultrasonic Pulverization 15~25 minutes in ice-water bath；
C) synthesis of adhesive：1/3 miniemulsion weighed in b) step is poured into reaction vessel, adds 3.3g initiator solutions,
Stirring is warming up to 70~78 DEG C, treats that lotion is warming up to 80~85 DEG C in blue light, by remaining 2/3 miniemulsion and 7g initiator solutions
It was added drop-wise to dropwise in reaction vessel in two hours by two separatory funnels, two hours is kept the temperature for 80~85 DEG C after being added dropwise to complete,
Organosilicon-modified acrylate emulsion is obtained, i.e. the high dyestuff of disperse dyes Non-water washing stamp carries passing property adhesive, and initiator is molten
Liquid is formed after being dissolved in by 0.3g ammonium persulfates in 10g water.
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| CN109629263A (en) * | 2018-12-24 | 2019-04-16 | 上海雅运新材料有限公司 | A kind of imitative reactive adhesive composition and preparation method thereof |
| CN110607705A (en) * | 2019-09-16 | 2019-12-24 | 桐乡市星邦科技发展有限公司 | Polyester printing water-based slurry and preparation method thereof |
| CN110642999A (en) * | 2019-10-28 | 2020-01-03 | 浙江理工大学 | Preparation method and application of fluorosilicone modified acrylate emulsion |
| CN110863368A (en) * | 2019-12-02 | 2020-03-06 | 绍兴皂树纺织品有限公司 | Washing-free high-color-fastness pad dyeing process for heavy polyester blanket cloth |
| CN111286994A (en) * | 2020-03-16 | 2020-06-16 | 湖南鼎诺新材料科技有限公司 | Printing method of terylene less-water printing paste |
| CN113152120A (en) * | 2021-05-26 | 2021-07-23 | 成都德美精英化工有限公司 | Washing-free disperse printing thickener and preparation method thereof |
| CN113265888A (en) * | 2021-05-13 | 2021-08-17 | 苏州联胜化学有限公司 | High-fastness pigment printing adhesive and preparation method thereof |
| CN114016305A (en) * | 2021-09-27 | 2022-02-08 | 绍兴市华绅纺织品整理有限公司 | Steaming-washing-free printing method for disperse dye |
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| CN103224765A (en) * | 2013-04-03 | 2013-07-31 | 浙江理工大学 | Fluorine-silicon-modified acrylate adhesive, preparation method and application thereof |
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| CN109629263A (en) * | 2018-12-24 | 2019-04-16 | 上海雅运新材料有限公司 | A kind of imitative reactive adhesive composition and preparation method thereof |
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| CN110607705A (en) * | 2019-09-16 | 2019-12-24 | 桐乡市星邦科技发展有限公司 | Polyester printing water-based slurry and preparation method thereof |
| CN110642999A (en) * | 2019-10-28 | 2020-01-03 | 浙江理工大学 | Preparation method and application of fluorosilicone modified acrylate emulsion |
| CN110642999B (en) * | 2019-10-28 | 2022-06-03 | 浙江理工大学 | Preparation method and application of fluorosilicone modified acrylate emulsion |
| CN110863368A (en) * | 2019-12-02 | 2020-03-06 | 绍兴皂树纺织品有限公司 | Washing-free high-color-fastness pad dyeing process for heavy polyester blanket cloth |
| CN110863368B (en) * | 2019-12-02 | 2022-08-05 | 绍兴皂树纺织品有限公司 | Washing-free high-color-fastness pad dyeing process for heavy polyester blanket cloth |
| CN111286994A (en) * | 2020-03-16 | 2020-06-16 | 湖南鼎诺新材料科技有限公司 | Printing method of terylene less-water printing paste |
| CN113265888A (en) * | 2021-05-13 | 2021-08-17 | 苏州联胜化学有限公司 | High-fastness pigment printing adhesive and preparation method thereof |
| CN113152120A (en) * | 2021-05-26 | 2021-07-23 | 成都德美精英化工有限公司 | Washing-free disperse printing thickener and preparation method thereof |
| CN113152120B (en) * | 2021-05-26 | 2022-12-09 | 成都德美精英化工有限公司 | Washing-free disperse printing thickener and preparation method thereof |
| CN114016305A (en) * | 2021-09-27 | 2022-02-08 | 绍兴市华绅纺织品整理有限公司 | Steaming-washing-free printing method for disperse dye |
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