CN107955445A - A kind of fluorescent aqueous paint - Google Patents

A kind of fluorescent aqueous paint Download PDF

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Publication number
CN107955445A
CN107955445A CN201711359748.0A CN201711359748A CN107955445A CN 107955445 A CN107955445 A CN 107955445A CN 201711359748 A CN201711359748 A CN 201711359748A CN 107955445 A CN107955445 A CN 107955445A
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CN
China
Prior art keywords
fluorescent
aqueous paint
filler
water
fluorescent aqueous
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201711359748.0A
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Chinese (zh)
Inventor
顾建强
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Suzhou Saiside Engineering Equipment Co Ltd
Original Assignee
Suzhou Saiside Engineering Equipment Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Suzhou Saiside Engineering Equipment Co Ltd filed Critical Suzhou Saiside Engineering Equipment Co Ltd
Priority to CN201711359748.0A priority Critical patent/CN107955445A/en
Publication of CN107955445A publication Critical patent/CN107955445A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/22Luminous paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04Polyurethanes
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08Anti-corrosive paints
    • C09D5/10Anti-corrosive paints containing metal dust
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/18Fireproof paints including high temperature resistant paints
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24Acids; Salts thereof
    • C08K3/26Carbonates; Bicarbonates
    • C08K2003/265Calcium, strontium or barium carbonate
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/08Stabilised against heat, light or radiation or oxydation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Paints Or Removers (AREA)

Abstract

The present invention relates to a kind of fluorescent aqueous paint, belong to technical field of coatings.Contain termil in the fluorescent aqueous paint:1.18 1.32%, 2 n-octyl, 4 isothiazoline, 3 ketone:0.58 0.73%, methyl silanol potassium:1.55 1.73%, fluorescent pigment emulsion:0.66 0.92%, light stabilizer:0.18 0.37%, filler:2.33 3.45%, waterborne polyurethane resin:1.23 1.46%, polyvinyl alcohol:1.19 1.27%, waterborne epoxy modified resin:0.43‑0.55%、Mo:0.01‑0.03%、Nd:0.06‑0.09%、Ce:0.01 0.03% and water.The advantages that present invention is free of toxic organic solvents, pollution-free, but also will not cracking with lacquer painting, anti-aging, strong adhesive force.

Description

A kind of fluorescent aqueous paint
Technical field
The present invention relates to a kind of fluorescent aqueous paint, belong to technical field of coatings.
Background technology
In recent years, from the viewpoint of environmental problem, carrying out by the conversion of organic solvent type coatings hydrotropism's coating. In addition, coating generally requires the film performances such as excellent water resistance, alkali resistance, wear resistance, weatherability.
Water paint is to use water as decentralized medium and the coating of diluent, water-based compared with the coating of organic solvent type Coating had not only reduced the discharge of volatile organic solvent, but also can save resource, the energy(Production solvent need to consume the energy), while side Just transport and store.With the strengthening of people's awareness of environmental protection, the production environmental regulation related with what is used to chemical products is also got over Come it is tighter, therefore water paint become modern coatings industrial development main flow direction.
According to the dispersing morphology of resin in water, water paint can be divided into water and milk glue-type, water-dispersion type and water-soluble three classes. The coating used on the market at present is more using synthetic resin emulsion or acrylic acid as base-material, and by various pigment, filler and auxiliary agent etc. Synthesis.The major defect of this coating is the easy aging of film elasticity, and flintiness is bad, it is impossible to effectively protection wall plaster bottom Intensity, so as to produce metope cracking, come off, it is beautiful not only to influence building, but also metope cracks, and causes metope leak.
The content of the invention
The technical problem to be solved in the present invention is in view of the shortcomings of the prior art, propose a kind of fluorescence of corrosion-resistant and high-temperature resistant Water paint.
The present invention is to solve the technical solution that above-mentioned technical problem proposes to be:A kind of fluorescent aqueous paint, the water-based painting of fluorescence The mass percent of each component is in material:Termil:1.18-1.32%, Kathon: 0.58-0.73%, methyl silanol potassium:1.55-1.73%, fluorescent pigment emulsion:0.66-0.92%, light stabilizer:0.18-0.37%、 Filler:2.33-3.45%, waterborne polyurethane resin:1.23-1.46%, polyvinyl alcohol:It is 1.19-1.27%, waterborne epoxy modified Resin:0.43-0.55%、Mo:0.01-0.03%、Nd:0.06-0.09%、Ce:0.01-0.03%, surplus are water.
The improvement of above-mentioned technical proposal is:Filler is used in heavy calcium carbonate, kaolin, barium sulfate and mica powder One or more combination.
The improvement of above-mentioned technical proposal is:The mass percent of each component is in fluorescent aqueous paint:Tetrachloro isophthalic diformazan Nitrile:1.18%th, Kathon:0.58%th, methyl silanol potassium:1.55%th, fluorescent pigment emulsion:0.66%、 Light stabilizer:0.18%th, filler:2.33%th, waterborne polyurethane resin:1.23%th, polyvinyl alcohol:1.19%th, it is waterborne epoxy modified Resin:0.43%、Mo:0.01%、Nd:0.06%、Ce:0.01%, surplus is water;
Wherein filler is using heavy calcium carbonate and kaolinic combination, the mass mixing such as heavy calcium carbonate and kaolin.
The improvement of above-mentioned technical proposal is:The mass percent of each component is in fluorescent aqueous paint:Tetrachloro isophthalic diformazan Nitrile:1.32%th, Kathon:0.73%th, methyl silanol potassium:1.73%th, fluorescent pigment emulsion:0.92%、 Light stabilizer:0.37%th, filler:3.45%th, waterborne polyurethane resin:1.46%th, polyvinyl alcohol:1.27%th, it is waterborne epoxy modified Resin:0.55%、Mo:0.03%、Nd:0.09%、Ce:0.03%, surplus is water;
Wherein filler is using the combination of barium sulfate and mica powder, the mass mixing such as barium sulfate and mica powder.
It is of the invention to be using the beneficial effect of above-mentioned technical proposal:(1)Due to containing rare earth element in fluorescent aqueous paint, The performance of corrosion-and high-temp-resistant is made it have, adapts to the coating demand of various occasions;(2)The present invention is free of toxic organic solvents, It is pollution-free;(3)The present invention contains filler, ensure that the texture of lacquer painting;(4)The lacquer painting of the present invention will not cracking, the drawing of paint film Rate is stretched more than 300%, and the paint film hand rubbing after film forming will not split;(5)The fluorescent aqueous paint of the present invention is anti-aging, attached Put forth effort strong;(6)Due to adding fluorescent pigment emulsion so that coating has fluorescent effect, and color is more bright, and decorative effect is more It is good;(7)Due to adding light stabilizer, it is therefore prevented that fluorescent pigment fades, and ensure that the service life for changing fluorescent aqueous paint.
Embodiment
Embodiment 1
The mass percent of each component is in the fluorescent aqueous paint of the present embodiment:The quality hundred of each component in fluorescent aqueous paint Point ratio is:Termil:1.18%th, Kathon:0.58%th, methyl silanol potassium:1.55%、 Fluorescent pigment emulsion:0.66%th, light stabilizer:0.18%th, filler:2.33%th, waterborne polyurethane resin:1.23%th, polyvinyl alcohol: 1.19%th, waterborne epoxy modified resin:0.43%、Mo:0.01%、Nd:0.06%、Ce:0.01%, surplus is water;
Wherein filler is using heavy calcium carbonate and kaolinic combination, the mass mixing such as heavy calcium carbonate and kaolin.
Embodiment 2
The mass percent of each component is in the fluorescent aqueous paint of the present embodiment:The quality hundred of each component in fluorescent aqueous paint Point ratio is:Termil:1.32%th, Kathon:0.73%th, methyl silanol potassium:1.73%、 Fluorescent pigment emulsion:0.92%th, light stabilizer:0.37%th, filler:3.45%th, waterborne polyurethane resin:1.46%th, polyvinyl alcohol: 1.27%th, waterborne epoxy modified resin:0.55%、Mo:0.03%、Nd:0.09%、Ce:0.03%, surplus is water;
Wherein filler is using the combination of barium sulfate and mica powder, the mass mixing such as barium sulfate and mica powder.
The present invention is not limited to above-described embodiment.All technical solutions formed using equivalent substitution, all falling within the present invention will The protection domain asked.

Claims (4)

  1. A kind of 1. fluorescent aqueous paint, it is characterised in that:The mass percent of each component is in the fluorescent aqueous paint:Tetrachloro Isophthalodinitrile:1.18-1.32%, Kathon:0.58-0.73%, methyl silanol potassium:1.55- 1.73%th, fluorescent pigment emulsion:0.66-0.92%, light stabilizer:0.18-0.37%, filler:2.33-3.45%, water-based poly- ammonia Ester resin:1.23-1.46%, polyvinyl alcohol:1.19-1.27%, waterborne epoxy modified resin:0.43-0.55%、Mo:0.01- 0.03%、Nd:0.06-0.09%、Ce:0.01-0.03%, surplus are water.
  2. 2. fluorescent aqueous paint according to claim 1, it is characterised in that:The filler using heavy calcium carbonate, One or more kinds of combinations in kaolin, barium sulfate and mica powder.
  3. 3. fluorescent aqueous paint according to claim 2, it is characterised in that:The matter of each component in the fluorescent aqueous paint Measuring percentage is:Termil:1.18%th, Kathon:0.58%th, methyl silanol potassium: 1.55%th, fluorescent pigment emulsion:0.66%th, light stabilizer:0.18%th, filler:2.33%th, waterborne polyurethane resin:1.23%th, gather Vinyl alcohol:1.19%th, waterborne epoxy modified resin:0.43%、Mo:0.01%、Nd:0.06%、Ce:0.01%, surplus is water;
    Wherein filler is using heavy calcium carbonate and kaolinic combination, the mass mixing such as heavy calcium carbonate and kaolin.
  4. 4. fluorescent aqueous paint according to claim 2, it is characterised in that:The matter of each component in the fluorescent aqueous paint Measuring percentage is:Termil:1.32%th, Kathon:0.73%th, methyl silanol potassium: 1.73%th, fluorescent pigment emulsion:0.92%th, light stabilizer:0.37%th, filler:3.45%th, waterborne polyurethane resin:1.46%th, gather Vinyl alcohol:1.27%th, waterborne epoxy modified resin:0.55%、Mo:0.03%、Nd:0.09%、Ce:0.03%, surplus is water;
    Wherein filler is using the combination of barium sulfate and mica powder, the mass mixing such as barium sulfate and mica powder.
CN201711359748.0A 2017-12-17 2017-12-17 A kind of fluorescent aqueous paint Pending CN107955445A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201711359748.0A CN107955445A (en) 2017-12-17 2017-12-17 A kind of fluorescent aqueous paint

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201711359748.0A CN107955445A (en) 2017-12-17 2017-12-17 A kind of fluorescent aqueous paint

Publications (1)

Publication Number Publication Date
CN107955445A true CN107955445A (en) 2018-04-24

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Country Status (1)

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105131807A (en) * 2015-10-13 2015-12-09 厦门大学 Hydrophobic water-based fluorescent polyurethane paint and preparation method thereof
CN105131806A (en) * 2015-10-13 2015-12-09 厦门大学 Waterborne fluorescent polyurethane coating and preparation method thereof through prepolymer mixing
CN105176234A (en) * 2015-10-28 2015-12-23 苏州赛斯德工程设备有限公司 Fluorescent water-based coating and preparation method thereof
CN105219138A (en) * 2015-11-17 2016-01-06 杨洋 A kind of protection against corrosion environment protection architecture water-borne coatings and preparation method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105131807A (en) * 2015-10-13 2015-12-09 厦门大学 Hydrophobic water-based fluorescent polyurethane paint and preparation method thereof
CN105131806A (en) * 2015-10-13 2015-12-09 厦门大学 Waterborne fluorescent polyurethane coating and preparation method thereof through prepolymer mixing
CN105176234A (en) * 2015-10-28 2015-12-23 苏州赛斯德工程设备有限公司 Fluorescent water-based coating and preparation method thereof
CN105219138A (en) * 2015-11-17 2016-01-06 杨洋 A kind of protection against corrosion environment protection architecture water-borne coatings and preparation method thereof

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Application publication date: 20180424

RJ01 Rejection of invention patent application after publication