CN107955428A - A kind of formula and manufacturing process of color luminous pigment - Google Patents

A kind of formula and manufacturing process of color luminous pigment Download PDF

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Publication number
CN107955428A
CN107955428A CN201711397583.6A CN201711397583A CN107955428A CN 107955428 A CN107955428 A CN 107955428A CN 201711397583 A CN201711397583 A CN 201711397583A CN 107955428 A CN107955428 A CN 107955428A
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China
Prior art keywords
parts
pigment
formula
solid
color luminous
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CN201711397583.6A
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Chinese (zh)
Inventor
林超健
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Wenzhou Weiteli Pigment Technology Co Ltd
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Wenzhou Weiteli Pigment Technology Co Ltd
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Priority to CN201711397583.6A priority Critical patent/CN107955428A/en
Publication of CN107955428A publication Critical patent/CN107955428A/en
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D1/00Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08Anti-corrosive paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/22Luminous paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/29Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for multicolour effects

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Luminescent Compositions (AREA)

Abstract

The present invention relates to pigment technology field,The especially a kind of formula and manufacturing process of color luminous pigment,50 55 parts of barium sulfate,35 40 parts of magnesium sulfide,14 parts of 14 parts of aluminum phosphate and potassium nitrate are used as yellow uitramarine,60 65 parts of calcium sulfide,20 25 parts of magnesium sulfide,14 parts of 5 10 parts of vulcanized sodium and cobalt nitrate are used as violet pigment,50 55 parts of barium sulphide,35 40 parts of magnesium sulfide,14 parts of 14 parts of copper nitrate and potassium phosphate are used as red pigment,50 55 parts of calcium sulfide,14 parts of nitric acid,10 15 parts of barium sulfate,5 10 parts of 5 10 parts of sodium sulphate and potassium nitrate are used as viridine green,Then the allotment of pigment is passed through,The mixing of pigment and the configuration step of pigment,Obtained more color paintings have fluorescent effect,It is greatly improved the decorative effect of more color paintings.

Description

A kind of formula and manufacturing process of color luminous pigment
Technical field
The present invention relates to pigment technology field, more particularly to a kind of formula and manufacturing process of color luminous pigment.
Background technology
More color paintings are mainly used for imitative stone material effect, so also known as liquid stone, is also named horizon red wall coating.In application, By disposable spray finishing, beautiful, colorful pattern can be obtained.This group by disposable spray finishing formation is with passing through multiple tracks The method that process is sequentially completed the multi-color decorative pattern that could be formed is entirely different.But existing multicolor finish does not possess fluorescence effect Fruit, causes the decorative effect of more color paintings to be restricted.
The content of the invention
The purpose of the present invention is to solve multicolor finish exists in the prior art not possess the shortcomings that fluorescent effect, and carry The formula and manufacturing process of a kind of color luminous pigment gone out.
To achieve these goals, present invention employs following technical solution:
A kind of formula of color luminous pigment is designed, is according to mass fraction:Appropriate amount of ethanol, 50-55 parts of barium sulfate, magnesium sulfide 1-4 parts of 35-40 parts, 1-4 parts of aluminum phosphate and potassium nitrate are used as yellow uitramarine, 60-65 parts of calcium sulfide, 20-25 parts of magnesium sulfide, vulcanization 1-4 parts of 5-10 parts of sodium and cobalt nitrate are used as violet pigment, 50-55 parts of barium sulphide, 35-40 parts of magnesium sulfide, 1-4 parts of copper nitrate and phosphorus Sour potassium 1-4 parts are used as red pigment, 50-55 parts of calcium sulfide, 1-4 parts of nitric acid, 10-15 parts of barium sulfate, 5-10 parts of sodium sulphate and nitre Sour potassium 5-10 parts are used as viridine green, and 5-10 parts of 65-70 parts of calcium carbonate and waterglass are used as Chinese white, and 2-5 parts of thickener, prevents Rotten agent 3-6 parts, 1-4 parts of defoamer, 20-30 parts of photo-induced energy storage type luminescent powder.
Preferably, the concentration of the ethanol is 95-98%.
Preferably, the calcium carbonate is micro mist shape, its particle diameter is between 325-400 mesh.
Preferably, the photo-induced energy storage type luminescent powder is micro mist shape, its particle diameter is between 325-400 mesh.
A kind of color luminous pigment manufacturing process, includes the following steps:
The allotment of S1, pigment, according to the deployed solid of formula as described in claim one, then by solid to fluidize Mode is mixed into ethanol, and solid, the weight ratio of ethanol are 1:3;
The mixing of S2, pigment, the mixture of solid and ethanol deployed in S1 is put into crucible and is heated, then through cooling It is stand-by to obtain luminescenjt powder pigment for grind into powder afterwards;
The configuration of S3, pigment, the powder pigments prepared in S2 are put into aqueous pigment according to weight ratio 1:5 mixing, stirring are equal Color luminous pigment is obtained after even.
Preferably, the solid is put into clear water reserviors after supercooling, grinding and soaks removing dross, is then placed in hot-blast stove Middle drying.
Preferably, the time that the solid heats in crucible is 30-60min, and heating-up temperature is 600-900 DEG C.
The formula and manufacturing process of a kind of color luminous pigment proposed by the present invention, beneficial effect are:Change tradition Colorful pigment formula, by photo-induced energy storage type luminescent powder, thickener, preservative be added to more color paintings in so that more color paintings With fluorescent effect, the decorative effect of more color paintings is greatly improved.
Embodiment
The purpose of the present invention is to solve existing in the prior art, existing cow dung method for innocent treatment is costly, The shortcomings that not being suitable for small-sized pasture, and a kind of cow dung method for innocent treatment proposed.
Embodiment one
A kind of formula of color luminous pigment, is according to mass fraction:Appropriate amount of ethanol, the concentration of ethanol is 95%, barium sulfate 51 Part, 36 parts of magnesium sulfide, 1 part of aluminum phosphate and 1 part of potassium nitrate are used as yellow uitramarine, 61 parts of calcium sulfide, 21 parts of magnesium sulfide, vulcanized sodium 6 1 part of part and cobalt nitrate are used as violet pigment, and 1 part of 51 parts of barium sulphide, 36 parts of magnesium sulfide, 1 part of copper nitrate and potassium phosphate are as red Pigment, 6 parts of 51 parts of calcium sulfide, 1 part of nitric acid, 11 parts of barium sulfate, 6 parts of sodium sulphate and potassium nitrate are used as viridine green, calcium carbonate 66 Part and 6 parts of waterglass be used as Chinese white, 2 parts of thickener, 3 parts of preservative, 1 part of defoamer, 20 parts of photo-induced energy storage type luminescent powder, Calcium carbonate is micro mist shape, its particle diameter is between 325-400 mesh, and photo-induced energy storage type luminescent powder is micro mist shape, its particle diameter is in 325-400 Between mesh.
A kind of color luminous pigment manufacturing process, includes the following steps:
The allotment of S1, pigment, according to the deployed solid of formula as described in claim one, then by solid to fluidize Mode is mixed into ethanol, and solid, the weight ratio of ethanol are 1:3;
The mixing of S2, pigment, the mixture of solid and ethanol deployed in S1 is put into crucible and is heated, then through cooling It is stand-by to obtain luminescenjt powder pigment for grind into powder afterwards, and solid soaks removing dross being put into after supercooling, grinding in clear water reserviors, Drying in hot-blast stove is then placed in, the time that solid heats in crucible is 30min, and heating-up temperature is 600 DEG C;
The configuration of S3, pigment, the powder pigments prepared in S2 are put into aqueous pigment according to weight ratio 1:5 mixing, stirring are equal Color luminous pigment is obtained after even.
Embodiment two
A kind of formula of color luminous pigment, is according to mass fraction:Appropriate amount of ethanol, the concentration of ethanol is 96%, barium sulfate 52 Part, 37 parts of magnesium sulfide, 2 parts of aluminum phosphate and 2 parts of potassium nitrate are used as yellow uitramarine, 62 parts of calcium sulfide, 22 parts of magnesium sulfide, vulcanized sodium 7 2 parts of part and cobalt nitrate are used as violet pigment, and 2 parts of 52 parts of barium sulphide, 37 parts of magnesium sulfide, 2 parts of copper nitrate and potassium phosphate are as red Pigment, 7 parts of 52 parts of calcium sulfide, 2 parts of nitric acid, 12 parts of barium sulfate, 7 parts of sodium sulphate and potassium nitrate are used as viridine green, calcium carbonate 67 Part and 7 parts of waterglass be used as Chinese white, 3 parts of thickener, 4 parts of preservative, 2 parts of defoamer, 23 parts of photo-induced energy storage type luminescent powder, Calcium carbonate is micro mist shape, its particle diameter is between 325-400 mesh, and photo-induced energy storage type luminescent powder is micro mist shape, its particle diameter is in 325-400 Between mesh.
A kind of color luminous pigment manufacturing process, includes the following steps:
The allotment of S1, pigment, according to the deployed solid of formula as described in claim one, then by solid to fluidize Mode is mixed into ethanol, and solid, the weight ratio of ethanol are 1:3;
The mixing of S2, pigment, the mixture of solid and ethanol deployed in S1 is put into crucible and is heated, then through cooling It is stand-by to obtain luminescenjt powder pigment for grind into powder afterwards, and solid soaks removing dross being put into after supercooling, grinding in clear water reserviors, Drying in hot-blast stove is then placed in, the time that solid heats in crucible is 40min, and heating-up temperature is 700 DEG C;
The configuration of S3, pigment, the powder pigments prepared in S2 are put into aqueous pigment according to weight ratio 1:5 mixing, stirring are equal Color luminous pigment is obtained after even.
Embodiment three
A kind of formula of color luminous pigment, is according to mass fraction:Appropriate amount of ethanol, the concentration of ethanol is 97%, barium sulfate 53 Part, 38 parts of magnesium sulfide, 3 parts of aluminum phosphate and 3 parts of potassium nitrate are used as yellow uitramarine, 63 parts of calcium sulfide, 23 parts of magnesium sulfide, vulcanized sodium 8 3 parts of part and cobalt nitrate are used as violet pigment, and 3 parts of 53 parts of barium sulphide, 38 parts of magnesium sulfide, 3 parts of copper nitrate and potassium phosphate are as red Pigment, 8 parts of 53 parts of calcium sulfide, 3 parts of nitric acid, 13 parts of barium sulfate, 8 parts of sodium sulphate and potassium nitrate are used as viridine green, calcium carbonate 68 Part and 8 parts of waterglass be used as Chinese white, 4 parts of thickener, 5 parts of preservative, 3 parts of defoamer, 26 parts of photo-induced energy storage type luminescent powder, Calcium carbonate is micro mist shape, its particle diameter is between 325-400 mesh, and photo-induced energy storage type luminescent powder is micro mist shape, its particle diameter is in 325-400 Between mesh.
A kind of color luminous pigment manufacturing process, includes the following steps:
The allotment of S1, pigment, according to the deployed solid of formula as described in claim one, then by solid to fluidize Mode is mixed into ethanol, and solid, the weight ratio of ethanol are 1:3;
The mixing of S2, pigment, the mixture of solid and ethanol deployed in S1 is put into crucible and is heated, then through cooling It is stand-by to obtain luminescenjt powder pigment for grind into powder afterwards, and solid soaks removing dross being put into after supercooling, grinding in clear water reserviors, Drying in hot-blast stove is then placed in, the time that solid heats in crucible is 50min, and heating-up temperature is 800 DEG C;
The configuration of S3, pigment, the powder pigments prepared in S2 are put into aqueous pigment according to weight ratio 1:5 mixing, stirring are equal Color luminous pigment is obtained after even.
Example IV
A kind of formula of color luminous pigment, is according to mass fraction:Appropriate amount of ethanol, the concentration of ethanol is 98%, barium sulfate 54 Part, 39 parts of magnesium sulfide, 4 parts of aluminum phosphate and 4 parts of potassium nitrate are used as yellow uitramarine, 64 parts of calcium sulfide, 24 parts of magnesium sulfide, vulcanized sodium 9 4 parts of part and cobalt nitrate are used as violet pigment, and 4 parts of 54 parts of barium sulphide, 39 parts of magnesium sulfide, 4 parts of copper nitrate and potassium phosphate are as red Pigment, 9 parts of 54 parts of calcium sulfide, 4 parts of nitric acid, 14 parts of barium sulfate, 9 parts of sodium sulphate and potassium nitrate are used as viridine green, calcium carbonate 69 Part and 9 parts of waterglass be used as Chinese white, 5 parts of thickener, 6 parts of preservative, 4 parts of defoamer, 29 parts of photo-induced energy storage type luminescent powder, Calcium carbonate is micro mist shape, its particle diameter is between 325-400 mesh, and photo-induced energy storage type luminescent powder is micro mist shape, its particle diameter is in 325-400 Between mesh.
A kind of color luminous pigment manufacturing process, includes the following steps:
The allotment of S1, pigment, according to the deployed solid of formula as described in claim one, then by solid to fluidize Mode is mixed into ethanol, and solid, the weight ratio of ethanol are 1:3;
The mixing of S2, pigment, the mixture of solid and ethanol deployed in S1 is put into crucible and is heated, then through cooling It is stand-by to obtain luminescenjt powder pigment for grind into powder afterwards, and solid soaks removing dross being put into after supercooling, grinding in clear water reserviors, Drying in hot-blast stove is then placed in, the time that solid heats in crucible is 60min, and heating-up temperature is 900 DEG C;
The configuration of S3, pigment, the powder pigments prepared in S2 are put into aqueous pigment according to weight ratio 1:5 mixing, stirring are equal Color luminous pigment is obtained after even.
The foregoing is only a preferred embodiment of the present invention, but protection scope of the present invention be not limited thereto, Any one skilled in the art the invention discloses technical scope in, technique according to the invention scheme and its Inventive concept is subject to equivalent substitution or change, should be covered by the protection scope of the present invention.

Claims (7)

1. a kind of formula of color luminous pigment, it is characterised in that be according to mass fraction:Appropriate amount of ethanol, barium sulfate 50-55 Part, 35-40 parts of magnesium sulfide, 1-4 parts of aluminum phosphate and 1-4 parts of potassium nitrate are used as yellow uitramarine, 60-65 parts of calcium sulfide, magnesium sulfide 20- 1-4 parts of 25 parts, 5-10 parts of vulcanized sodium and cobalt nitrate are used as violet pigment, 50-55 parts of barium sulphide, 35-40 parts of magnesium sulfide, copper nitrate 1-4 parts are used as red pigment, 50-55 parts of calcium sulfide, 1-4 parts of nitric acid, 10-15 parts of barium sulfate, sodium sulphate 5- with 1-4 parts of potassium phosphate 10 parts are used as viridine green with 5-10 parts of potassium nitrate, and 5-10 parts of 65-70 parts of calcium carbonate and waterglass are used as Chinese white, thickener 2-5 parts, 3-6 parts of preservative, 1-4 parts of defoamer, 20-30 parts of photo-induced energy storage type luminescent powder.
2. the formula of a kind of color luminous pigment according to claim 1, it is characterised in that the concentration of the ethanol is 95-98%.
A kind of 3. formula of color luminous pigment according to claim 1, it is characterised in that the calcium carbonate is micro mist shape, Its particle diameter is between 325-400 mesh.
A kind of 4. formula of color luminous pigment according to claim 1, it is characterised in that the photo-induced energy storage type noctilucence Powder is micro mist shape, its particle diameter is between 325-400 mesh.
5. a kind of color luminous pigment manufacturing process, it is characterised in that include the following steps:
The allotment of S1, pigment, according to the deployed solid of formula as described in claim one, then by solid to fluidize Mode is mixed into ethanol, and solid, the weight ratio of ethanol are 1:3;
The mixing of S2, pigment, the mixture of solid and ethanol deployed in S1 is put into crucible and is heated, then through cooling It is stand-by to obtain luminescenjt powder pigment for grind into powder afterwards;
The configuration of S3, pigment, the powder pigments prepared in S2 are put into aqueous pigment according to weight ratio 1:5 mixing, stirring are equal Color luminous pigment is obtained after even.
6. the formula and manufacturing process of a kind of color luminous pigment according to claim 1, it is characterised in that the solid-state Thing is put into clear water reserviors after supercooling, grinding and soaks removing dross, is then placed in hot-blast stove dry.
7. the formula and manufacturing process of a kind of color luminous pigment according to claim 1, it is characterised in that the solid-state The time that thing heats in crucible is 30-60min, and heating-up temperature is 600-900 DEG C.
CN201711397583.6A 2017-12-21 2017-12-21 A kind of formula and manufacturing process of color luminous pigment Pending CN107955428A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109231836A (en) * 2018-10-22 2019-01-18 贵阳市白云区科创生产力促进中心 Imitative engraving noctilucent glaze material and its manufacture craft
CN111471352A (en) * 2020-05-21 2020-07-31 江苏帝摩斯光电科技有限公司 Gradient printing ink and gradient printing method

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1039259A (en) * 1988-07-14 1990-01-31 沈阳市和平市政工程公司 A kind of luminescent powder
CN1339545A (en) * 2000-08-28 2002-03-13 秦淑英 Colour liminous oil painting pigment
CN103382326A (en) * 2013-08-13 2013-11-06 苏州鑫汉纺纺织有限公司 Pigment

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1039259A (en) * 1988-07-14 1990-01-31 沈阳市和平市政工程公司 A kind of luminescent powder
CN1339545A (en) * 2000-08-28 2002-03-13 秦淑英 Colour liminous oil painting pigment
CN103382326A (en) * 2013-08-13 2013-11-06 苏州鑫汉纺纺织有限公司 Pigment

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109231836A (en) * 2018-10-22 2019-01-18 贵阳市白云区科创生产力促进中心 Imitative engraving noctilucent glaze material and its manufacture craft
CN111471352A (en) * 2020-05-21 2020-07-31 江苏帝摩斯光电科技有限公司 Gradient printing ink and gradient printing method

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