CN107954624A - A kind of concrete silicon crystal curing agent - Google Patents

A kind of concrete silicon crystal curing agent Download PDF

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Publication number
CN107954624A
CN107954624A CN201711354081.5A CN201711354081A CN107954624A CN 107954624 A CN107954624 A CN 107954624A CN 201711354081 A CN201711354081 A CN 201711354081A CN 107954624 A CN107954624 A CN 107954624A
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CN
China
Prior art keywords
concrete
parts
curing agent
silicon crystal
silicate
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Pending
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CN201711354081.5A
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Chinese (zh)
Inventor
张伟
张煜天
陶骏
陈英
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Suzhou Jin Run New Mstar Technology Ltd
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Suzhou Jin Run New Mstar Technology Ltd
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Priority to CN201711354081.5A priority Critical patent/CN107954624A/en
Publication of CN107954624A publication Critical patent/CN107954624A/en
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B40/00Processes, in general, for influencing or modifying the properties of mortars, concrete or artificial stone compositions, e.g. their setting or hardening ability
    • C04B40/0028Aspects relating to the mixing step of the mortar preparation
    • C04B40/0039Premixtures of ingredients

Abstract

The present invention relates to a kind of concrete silicon crystal curing agent, including silicate mixture, Nano silica sol and organic solvent.Concrete silicon crystal curing agent penetrates into concrete and the chemical reaction of continuation occurs with it, generation does not expand, do not shrink, the high strength glass matter compound that property is stablized, concrete substrate is strengthened, sealing and hardening, the overall structure of densification is formed it into, its intensity can strengthen over time and persistently, so as to reach hardening, strong, impervious, weathering resistance, wear-resistant, lifting chemoresistance, not play dirt, the not accumulation of salt in the surface soil, firm such as steel, coloured and dazzling concrete sealing effect;And the concrete hardener in this programme is waterborne liquid, safety and environmental protection;Suitable for various new-old concrete terraces, including magma terrace, terrazzo terrace, diamond dust abrasion-proof terrace etc., loose terrace serious to dusting has hardening and enhancing effect well.

Description

A kind of concrete silicon crystal curing agent
Technical field
The present invention relates to a kind of concrete hardener, more particularly to a kind of concrete silicon crystal curing agent.
Background technology
At present, the defects of concrete structure has been widely used in building field, but concrete structure is intrinsic has become Influence the principal element of concrete life cycle length;Alkali-aggregate reaction(Abbreviation ASR)Refer to cement in concrete raw material, Active ingredient reaction in alkali and aggregate in additive and water, gradually reacts after concreting shaping, product water suction Expansion makes concrete produce internal stress, causes that concrete expansion is dry and cracked, loses design performance;ASR adverse reactions are current full generation " mortal wound of concrete structure cancer " that boundary generally acknowledges, in addition easy of concrete structure also presence is grey, it is low with hardness to wear no resistance Defect.
To overcome drawbacks described above, usually there is three classes means to save the situation:
1. apply wearing layer in concrete foundation;
2. coating the high-molecular coatings such as epoxy resin in concrete surface, the wearability of concrete is improved;
3. using reactive materials such as curing agents, fundamentally to solve concrete inherent shortcoming.
Curing agent has three generation products at present, and the first generation is the sodium base product based on sodium metasilicate, and the second generation is potassium base silicic acid Salt curing agent, the third generation are lithium metasilicate base products;The hardening of the limited raising concrete of preceding two generations product energy, third generation product are It uniquely can effectively mitigate the material of ASR reactions, but since third generation product still has the limitation thus improvement of technology Unobvious.
If application publication number is a kind of concrete hardener and its system disclosed in the Chinese patent of " CN103864341A " Preparation Method, the setting time of this kind of curing agent is shorter, and Morse hardness is higher, also has certain mitigation to ASR reactions, but It is that this curing agent cost is higher, is not suitable for large batch of use.
Thus, we provide another concrete hardener herein, effectively alleviate while having preferable hardening effect ASR reacts.
The content of the invention
The object of the present invention is to provide a kind of concrete silicon crystal curing agent, for improve concrete floor hardening effect and Effectively alleviate ASR reactions.
The present invention above-mentioned technical purpose technical scheme is that:A kind of concrete silicon crystal hardening Agent, including silicate mixture, Nano silica sol and organic solvent.
Preferably, the silicate mixture for sodium metasilicate, potassium silicate, lithium metasilicate, sodium methyl silicate, prodan, Any several mixing in potassium fluosilicate, potassium fluosilicate, magnesium fluosilicate, zinc fluosilicate.
Preferably, the Nano silica sol particle diameter is 10-20nm.
Preferably, following component is by weight:
10-80 parts of silicate mixture
5-10 parts of Nano silica sol
10-20 parts of organic solvent.
Preferably, further including following component, following component is by weight:
1-5 parts of bleeding agent
5-10 parts of wetting agent
5-10 parts of defoamer
10-50 parts of water.
Preferably, the bleeding agent uses fatty alcohol polyoxyethylene ether.
Preferably, the defoamer uses organic silicon defoamer.
Preferably, the wetting agent is using in polyether silicone, lauryl sodium sulfate, neopelex It is a kind of or any several.
In conclusion the invention has the advantages that:
(1)Concrete silicon crystal curing agent penetrates into concrete and the chemical reaction of continuation occurs with it, and generation is not expanded, do not received Contracting, the high strength glass matter compound that property is stablized, strengthens concrete substrate, sealing and hardening, forms it into densification Overall structure, its intensity can strengthen over time and persistently, so as to reach hardening, strong, impervious, weathering resistance, anti- Abrasion, lifting chemoresistance, do not play dirt, the not accumulation of salt in the surface soil, firm such as steel, coloured and dazzling concrete sealing effect;And this programme In concrete silicon crystal curing agent be waterborne liquid, do not burn, be non-volatile, safety and environmental protection;Suitable for various new-old concretes Level ground, including magma terrace, terrazzo terrace, diamond dust abrasion-proof terrace etc., loose terrace serious to dusting have good hardening And enhancing effect;
(2)Concrete hardener main body in this programme is silicate mixture, can there is preferable binding ability with concrete, will During Nano silica sol and organic solvent are poured into silicate mixture and stir evenly;Organic solvent uses absolute ethyl alcohol, anhydrous Ethanol has stronger volatility, when curing agent is sprayed on concrete surface in the construction process, absolute ethyl alcohol with when Between passage volatilization, Nano silica sol polymerize to form high poly- silica gel, and with the volatilization of absolute ethyl alcohol, high poly- silica gel molecule by It is cumulative big, latticed high molecular crosslink thing is eventually formed, this latticed structure has stronger structural strength, and anhydrous The volatilization of ethanol occurs that self assembly phenomenon is evenly distributed wherein for uniformly volatilization, Nano silica sol, therefore is formed latticed High molecular crosslink thing even structure;Since Ludox can generate silicate, Ludox and silicic acid with part inorganic salt reaction Salt, there are certain similitude, can there is preferable intersolubility in structure, and silicate mixture can occur preferably with concrete Combination, thus Ludox using silicate mixture as medium also can be fabulous be attached to concrete surface;
(3)Silicate mixture can use sodium metasilicate, potassium silicate, lithium metasilicate, sodium methyl silicate, prodan, potassium fluosilicate fluorine The material such as magnesium silicate or zinc fluosilicate, wherein sodium, potassium, lithium are congeners, and property is similar, and this kind of material is after dehydration curing Form the material that glossiness is high, hardness is high;Likewise, Nano silica sol is losing organic solvent(Absolute ethyl alcohol)The net formed afterwards The high molecular crosslink thing of trellis also has preferable glossiness and hardness;And because this kind of material chemistry, physical property are stablized, because And with it is good harden, be strong, is impervious, weathering resistance, wear-resistant, lifting chemoresistance, do not play dirt, accumulation of salt in the surface soil etc. is not excellent The impact of performance;
(4)Nano silica sol is compared with Ludox, and particle diameter smaller, permeability is more preferable, is being oozed after concrete surface is sprayed to The synergistic effect of saturating agent and wetting agent, which issues to give birth to, oozes, therefore the hardening process of concrete is since inside concrete is, can be with Fill up gap and the hole that concrete is formed in casting process, also can fill concrete itself gap for concrete surface Hardening is laid a good foundation;
(5)Wetting agent and bleeding agent synergistic effect make concrete silicon crystal curing agent preferably be attached to concrete surface and melt therewith Close, wetting agent enables to be sprayed at the silicon crystal curing agent of concrete surface more by reducing surface tension, the interfacial tension of object Deep enters in concrete, and defoamer can reduce the minute bubbles generated in whipping process;Emulsifying agent is can to improve liquid Body collects the surface tension between each composition phase, is allowed to form uniform and stable dispersion, it is ensured that the concrete knot after hardening Structure intensity.
Embodiment
This specific embodiment is only explanation of the invention, it is not limitation of the present invention, people in the art Member as needed can make the present embodiment the modification of no creative contribution after this specification is read, but as long as at this All protected in the right of invention be subject to Patent Law.
Embodiment 1:
A kind of concrete silicon crystal curing agent, including silicate mixture, Nano silica sol and organic solvent;Wherein silicate mixes Thing can use sodium metasilicate, potassium silicate, lithium metasilicate, sodium methyl silicate, prodan, potassium fluosilicate, magnesium fluosilicate, zinc fluosilicate, Can only select it is therein it is a kind of may also be used in which it is a variety of mixed with arbitrary proportion after use, organic solvent is absolute ethyl alcohol; In the present embodiment, silicate mixture uses sodium metasilicate and potassium silicate with 1:1 mixed material.
Clean container is taken, adds 10 parts of silicate mixtures thereto, then stirred after pouring into 10 parts of organic solvents thereto Mix uniformly, add 5 parts of Nano silica sols thereto afterwards and stir, completion concrete silicon crystal hardening dispersed to three kinds of materials The preparation of agent.
Embodiment 2:
A kind of concrete silicon crystal curing agent, including silicate mixture, Nano silica sol and organic solvent;Wherein silicate mixes Thing can use sodium metasilicate, potassium silicate, lithium metasilicate, sodium methyl silicate, prodan, potassium fluosilicate, magnesium fluosilicate, zinc fluosilicate, Can only select it is therein it is a kind of may also be used in which it is a variety of mixed with arbitrary proportion after use, organic solvent is absolute ethyl alcohol; In the present embodiment, silicate mixture uses sodium methyl silicate and potassium silicate with 1:1 mixed material.
Clean container is taken, adds 80 parts of silicate mixtures thereto, then stirred after pouring into 20 parts of organic solvents thereto Mix uniformly, add 10 parts of Nano silica sols thereto afterwards and stirring is dispersed to three kinds of materials, it is hard to complete concrete silicon crystal The preparation of agent.
Embodiment 3:
A kind of concrete silicon crystal curing agent, including silicate mixture, Nano silica sol and organic solvent;Wherein silicate mixes Thing can use sodium metasilicate, potassium silicate, lithium metasilicate, sodium methyl silicate, prodan, potassium fluosilicate, magnesium fluosilicate, zinc fluosilicate, Can only select it is therein it is a kind of may also be used in which it is a variety of mixed with arbitrary proportion after use, organic solvent is absolute ethyl alcohol; In the present embodiment, silicate mixture uses sodium metasilicate and lithium metasilicate with 1:1 mixed material.
Clean container is taken, adds 35 parts of silicate mixtures thereto, then stirred after pouring into 15 parts of organic solvents thereto Mix uniformly, add 7 parts of Nano silica sols thereto afterwards and stir, completion concrete silicon crystal hardening dispersed to three kinds of materials The preparation of agent.
Embodiment 4:
A kind of concrete silicon crystal curing agent, including silicate mixture, Nano silica sol and organic solvent;Wherein silicate mixes Thing can use sodium metasilicate, potassium silicate, lithium metasilicate, sodium methyl silicate, prodan, potassium fluosilicate, magnesium fluosilicate, zinc fluosilicate, Can only select it is therein it is a kind of may also be used in which it is a variety of mixed with arbitrary proportion after use, organic solvent is absolute ethyl alcohol; In the present embodiment, silicate mixture uses sodium metasilicate and sodium methyl silicate with 3:1 mixed material.
Clean container is taken, adds 64 parts of silicate mixtures thereto, then stirred after pouring into 12 parts of organic solvents thereto Mix uniformly, add 8 parts of Nano silica sols thereto afterwards and stir, completion concrete silicon crystal hardening dispersed to three kinds of materials The preparation of agent.
Embodiment 5:
A kind of concrete silicon crystal curing agent, including silicate mixture, Nano silica sol and organic solvent, further include bleeding agent, Wetting agent, defoamer and water;Wherein silicate mixture can use sodium metasilicate, potassium silicate, lithium metasilicate, sodium methyl silicate, fluorine silicon Sour sodium, potassium fluosilicate, magnesium fluosilicate, zinc fluosilicate, can only select it is therein it is a kind of may also be used in which it is a variety of arbitrarily to compare Used after example mixing, organic solvent is absolute ethyl alcohol, and bleeding agent uses fatty alcohol polyoxyethylene ether, and defoamer is disappeared using organosilicon Infusion, wetting agent use polyether silicone, lauryl sodium sulfate or neopelex;In the present embodiment, silicic acid Salt mixture uses sodium metasilicate and potassium silicate with 3:1 mixed material, wetting agent use polyether silicone.
Clean container is taken, adds 50 parts of silicate mixtures thereto, then stirred after pouring into 10 parts of organic solvents thereto Mix uniformly, add 5 parts of Nano silica sols thereto afterwards and stirring is dispersed to three kinds of materials, then add 1 part thereto and ooze Stirred evenly after saturating agent, 5 parts of wetting agents, 5 parts of defoamers and 10 parts of water, complete the preparation of concrete silicon crystal curing agent.
Embodiment 6:
A kind of concrete silicon crystal curing agent, including silicate mixture, Nano silica sol and organic solvent, further include bleeding agent, Wetting agent, defoamer and water;Wherein silicate mixture can use sodium metasilicate, potassium silicate, lithium metasilicate, sodium methyl silicate, fluorine silicon Sour sodium, potassium fluosilicate, magnesium fluosilicate, zinc fluosilicate, can only select it is therein it is a kind of may also be used in which it is a variety of arbitrarily to compare Used after example mixing, organic solvent is absolute ethyl alcohol, and bleeding agent uses fatty alcohol polyoxyethylene ether, and defoamer is disappeared using organosilicon Infusion, wetting agent use polyether silicone, lauryl sodium sulfate or neopelex;In the present embodiment, silicic acid Salt mixture uses sodium metasilicate and potassium silicate with 3:1 mixed material, wetting agent use polyether silicone.
Clean container is taken, adds 80 parts of silicate mixtures thereto, then stirred after pouring into 20 parts of organic solvents thereto Mix uniformly, add 10 parts of Nano silica sols thereto afterwards and stirring is dispersed to three kinds of materials, then add 5 parts thereto and ooze Stirred evenly after saturating agent, 10 parts of wetting agents, 10 parts of defoamers and 50 parts of water, complete the preparation of concrete silicon crystal curing agent.
Embodiment 7:
A kind of concrete silicon crystal curing agent, including silicate mixture, Nano silica sol and organic solvent, further include bleeding agent, Wetting agent, defoamer and water;Wherein silicate mixture can use sodium metasilicate, potassium silicate, lithium metasilicate, sodium methyl silicate, fluorine silicon Sour sodium, potassium fluosilicate, magnesium fluosilicate, zinc fluosilicate, can only select it is therein it is a kind of may also be used in which it is a variety of arbitrarily to compare Used after example mixing, organic solvent is absolute ethyl alcohol, and bleeding agent uses fatty alcohol polyoxyethylene ether, and defoamer is disappeared using organosilicon Infusion, wetting agent use polyether silicone, lauryl sodium sulfate or neopelex;In the present embodiment, silicic acid Salt mixture uses sodium metasilicate and lithium metasilicate with 3:1 mixed material, wetting agent use polyether silicone.
Clean container is taken, adds 65 parts of silicate mixtures thereto, then stirred after pouring into 16 parts of organic solvents thereto Mix uniformly, add 8 parts of Nano silica sols thereto afterwards and stirring is dispersed to three kinds of materials, then add 2.5 parts thereto Stirred evenly after bleeding agent, 7.5 parts of wetting agents, 6.5 parts of defoamers and 30 parts of water, complete the preparation of concrete silicon crystal curing agent.
Embodiment 8:
A kind of concrete silicon crystal curing agent, including silicate mixture, Nano silica sol and organic solvent, further include bleeding agent, Wetting agent, defoamer and water;Wherein silicate mixture can use sodium metasilicate, potassium silicate, lithium metasilicate, sodium methyl silicate, fluorine silicon Sour sodium, potassium fluosilicate, magnesium fluosilicate, zinc fluosilicate, can only select it is therein it is a kind of may also be used in which it is a variety of arbitrarily to compare Used after example mixing, organic solvent is absolute ethyl alcohol, and bleeding agent uses fatty alcohol polyoxyethylene ether, and defoamer is disappeared using organosilicon Infusion, wetting agent use polyether silicone, lauryl sodium sulfate or neopelex;In the present embodiment, silicic acid Salt mixture uses sodium metasilicate and lithium metasilicate with 3:1 mixed material, wetting agent use polyether silicone.
Clean container is taken, adds 25 parts of silicate mixtures thereto, then stirred after pouring into 16 parts of organic solvents thereto Mix uniformly, add 8 parts of Nano silica sols thereto afterwards and stirring is dispersed to three kinds of materials, then add 3 parts thereto and ooze Stirred evenly after saturating agent, 9 parts of wetting agents, 9 parts of defoamers and 18 parts of water, complete the preparation of concrete silicon crystal curing agent.
Embodiment 9:
A kind of concrete silicon crystal curing agent, including silicate mixture, Nano silica sol and organic solvent, further include dispersant and Water-retaining agent;Wherein silicate mixture can use sodium metasilicate, potassium silicate, lithium metasilicate, sodium methyl silicate, prodan, fluosilicic acid Potassium, magnesium fluosilicate, zinc fluosilicate, can only select it is therein it is a kind of may also be used in which it is a variety of mixed with arbitrary proportion after make With, organic solvent is absolute ethyl alcohol, and dispersant uses polyethylene pyrrole network alkanone, ethyl acetate, cetyl trimethylammonium bromide, Water-retaining agent is using poly- sodium propionate, polyacrylic acid potassium;In the present embodiment, silicate mixture uses sodium metasilicate and lithium metasilicate with 3: 1 mixed material, dispersant use polypyrrole alkanone, and water-retaining agent uses poly- sodium propionate.
Clean container is taken, adds 18 parts of silicate mixtures thereto, then stirred after pouring into 10 parts of organic solvents thereto Mix uniformly, add 5 parts of Nano silica sols thereto afterwards and stirring is dispersed to three kinds of materials, then add 5 parts points thereto Powder and 5 parts of water-retaining agent, complete the preparation of concrete silicon crystal curing agent.
Embodiment 10:
A kind of concrete silicon crystal curing agent, including silicate mixture, Nano silica sol and organic solvent, further include dispersant and Water-retaining agent;Wherein silicate mixture can use sodium metasilicate, potassium silicate, lithium metasilicate, sodium methyl silicate, prodan, fluosilicic acid Potassium, magnesium fluosilicate, zinc fluosilicate, can only select it is therein it is a kind of may also be used in which it is a variety of mixed with arbitrary proportion after make With, organic solvent is absolute ethyl alcohol, and dispersant uses polyethylene pyrrole network alkanone, ethyl acetate, cetyl trimethylammonium bromide, Water-retaining agent is using poly- sodium propionate, polyacrylic acid potassium;In the present embodiment, silicate mixture uses sodium metasilicate, and dispersant uses Polypyrrole alkanone, water-retaining agent use poly- sodium propionate.
Clean container is taken, adds 80 parts of silicate mixtures thereto, then stirred after pouring into 20 parts of organic solvents thereto Mix uniformly, add 10 parts of Nano silica sols thereto afterwards and stirring is dispersed to three kinds of materials, then add 10 parts thereto Dispersant and 10 parts of water-retaining agent, complete the preparation of concrete silicon crystal curing agent.
Embodiment 11:
A kind of concrete silicon crystal curing agent, including silicate mixture, Nano silica sol and organic solvent, further include dispersant and Water-retaining agent;Wherein silicate mixture can use sodium metasilicate, potassium silicate, lithium metasilicate, sodium methyl silicate, prodan, fluosilicic acid Potassium, magnesium fluosilicate, zinc fluosilicate, can only select it is therein it is a kind of may also be used in which it is a variety of mixed with arbitrary proportion after make With, organic solvent is absolute ethyl alcohol, and dispersant uses polyethylene pyrrole network alkanone, ethyl acetate, cetyl trimethylammonium bromide, Water-retaining agent is using poly- sodium propionate, polyacrylic acid potassium;In the present embodiment, silicate mixture uses sodium metasilicate and lithium metasilicate with 3: 1 mixed material, dispersant use polypyrrole alkanone, and water-retaining agent uses poly- sodium propionate.
Clean container is taken, adds 65 parts of silicate mixtures thereto, then stirred after pouring into 15 parts of organic solvents thereto Mix uniformly, add 8 parts of Nano silica sols thereto afterwards and stirring is dispersed to three kinds of materials, then add 7.5 parts thereto Dispersant and 7.5 parts of water-retaining agent, complete the preparation of concrete silicon crystal curing agent.
Performance detection is carried out to the concrete silicon crystal curing agent being prepared in embodiment 1- embodiments 11, detection includes Permeability-thickness, setting time, Mohs' hardness, by the records of values after measurement in table 1:
Permeability-thickness(mm) Setting time(h) Mohs' hardness
Embodiment 1 7.6 2.1 6.5
Embodiment 2 8.1 2.5 7.5
Embodiment 3 7.7 2.4 7.1
Embodiment 4 7.9 2.2 7.4
Embodiment 5 8.0 2.1 6.7
Embodiment 6 7.8 2.3 7.3
Embodiment 7 7.6 2.5 7.0
Embodiment 8 7.6 2.3 7.5
Embodiment 9 7.8 2.4 6.9
Embodiment 10 8.0 2.2 6.8
Embodiment 11 7.9 2.3 6.6
Whether the color after observation concrete floor hardening is uniform and glossy and is recorded in table 2:
Color uniformity Glossiness Color uniformity Glossiness
Embodiment 1 Uniformly It is bright Embodiment 7 Uniformly It is bright
Embodiment 2 Uniformly It is bright Embodiment 8 Uniformly It is bright
Embodiment 3 Uniformly It is bright Embodiment 9 Uniformly It is bright
Embodiment 4 Uniformly It is bright Embodiment 10 Uniformly It is bright
Embodiment 5 Uniformly It is bright Embodiment 11 Uniformly It is bright
Embodiment 6 Uniformly It is bright

Claims (9)

  1. A kind of 1. concrete silicon crystal curing agent, it is characterised in that:Including silicate mixture, Nano silica sol and organic solvent.
  2. A kind of 2. concrete silicon crystal curing agent according to claim 1, it is characterised in that:The silicate mixture is silicon It is any several mixed in sour sodium, potassium silicate, lithium metasilicate, sodium methyl silicate, prodan, potassium fluosilicate, magnesium fluosilicate, zinc fluosilicate Close.
  3. A kind of 3. concrete silicon crystal curing agent according to claim 1, it is characterised in that:The Nano silica sol particle diameter is 10-20nm, the organic solvent are absolute ethyl alcohol.
  4. 4. a kind of concrete silicon crystal curing agent according to claim 1, it is characterised in that following component is by weight:
    10-80 parts of silicate mixture
    5-10 parts of Nano silica sol
    10-20 parts of organic solvent.
  5. A kind of 5. concrete silicon crystal curing agent according to claim 1, it is characterised in that:Following component is further included, below Component is by weight:
    1-5 parts of bleeding agent
    5-10 parts of wetting agent
    5-10 parts of defoamer
    10-50 parts of water.
  6. A kind of 6. concrete silicon crystal curing agent according to claim 5, it is characterised in that:The bleeding agent uses fatty alcohol Polyoxyethylene ether.
  7. A kind of 7. concrete silicon crystal curing agent according to claim 5, it is characterised in that:The defoamer uses organosilicon Defoamer.
  8. A kind of 8. concrete silicon crystal curing agent according to claim 5, it is characterised in that:The wetting agent uses polyethers silicon One kind or any several in oxygen alkane, lauryl sodium sulfate, neopelex.
  9. 9. a kind of concrete silicon crystal curing agent according to claim 1, it is characterised in that further include following component, below Component is by weight:
    5-10 parts of dispersant
    5-10 parts of water-retaining agent.
CN201711354081.5A 2017-12-15 2017-12-15 A kind of concrete silicon crystal curing agent Pending CN107954624A (en)

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CN109534852A (en) * 2018-12-29 2019-03-29 华砂砂浆有限责任公司 A kind of osmosis type liquid hardening agent and preparation method thereof
CN110294606A (en) * 2019-08-08 2019-10-01 深圳市中坡工业地板有限公司 For enhancing the powdery reinforcing material of concrete structural strength
CN111138170A (en) * 2020-01-15 2020-05-12 唐山市丰华陶瓷有限公司 FFC slurry for large-size products and preparation method thereof
CN111763060A (en) * 2020-06-09 2020-10-13 中南大学 Concrete protective layer reinforcing material, composite template cloth and application of concrete protective layer reinforcement
CN112593671A (en) * 2020-10-30 2021-04-02 华能江阴燃机热电有限责任公司 Inorganic grindstone system toughened terrace and manufacturing method thereof
CN113213967A (en) * 2021-05-12 2021-08-06 苏州金润新材料科技有限公司 Concrete crack and color difference treating agent and using method thereof
CN113912369A (en) * 2021-09-28 2022-01-11 德爱威(中国)有限公司 Ultrahigh wear-resistant sealing curing agent and preparation method thereof
CN113943172A (en) * 2020-07-18 2022-01-18 南京林业大学 Preparation method of composite solution for multi-scale enhancing concrete surface performance
CN114197281A (en) * 2021-12-29 2022-03-18 重庆中科建筑科技(集团)有限公司 Paving material curing method, paving material and curing agent
CN114349532A (en) * 2022-02-23 2022-04-15 北京易晟元环保工程有限公司 Liquid preparation for early curing of concrete and early curing method of concrete
CN114409305A (en) * 2022-01-19 2022-04-29 广东嘉宝莉科技材料有限公司 Liquid interface treating agent, environment-friendly waterproof slurry and preparation method and construction method thereof
CN114478064A (en) * 2021-12-28 2022-05-13 青岛理工大学 Concrete curing agent, curing coating and preparation method thereof
CN114575555A (en) * 2022-03-30 2022-06-03 杭州格灵新材料科技有限公司 Preparation method of high-hardness cement-based self-leveling nano-hardening decorative terrace
US11370715B2 (en) * 2020-03-11 2022-06-28 Floriss Chroma Ltd. Concrete hardener composition
CN115073747A (en) * 2021-03-11 2022-09-20 杭州包尔得新材料科技有限公司 Application of polyether modified organic silicon penetrating agent in preparation of organic silicon modified penetration enhancer
CN115124564A (en) * 2021-03-11 2022-09-30 杭州包尔得新材料科技有限公司 Silicon-containing anionic surfactant and preparation and application thereof
CN115321860A (en) * 2022-07-29 2022-11-11 中原环保万瑞郑州固废科技有限公司 Construction waste recycled aggregate surface modification and particle reinforcement method
CN116514432A (en) * 2023-05-11 2023-08-01 佛山市海翔新材料科技有限公司 Wear-resistant reinforcing agent for concrete and application method thereof

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