CN107938338A - One kind weaving antimildew and antibacterial agent and its preparation and application - Google Patents
One kind weaving antimildew and antibacterial agent and its preparation and application Download PDFInfo
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- CN107938338A CN107938338A CN201711045457.4A CN201711045457A CN107938338A CN 107938338 A CN107938338 A CN 107938338A CN 201711045457 A CN201711045457 A CN 201711045457A CN 107938338 A CN107938338 A CN 107938338A
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- antimildew
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M16/00—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/144—Alcohols; Metal alcoholates
- D06M13/148—Polyalcohols, e.g. glycerol or glucose
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/345—Nitriles
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/35—Heterocyclic compounds
- D06M13/355—Heterocyclic compounds having six-membered heterocyclic rings
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/46—Compounds containing quaternary nitrogen atoms
- D06M13/463—Compounds containing quaternary nitrogen atoms derived from monoamines
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/227—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of hydrocarbons, or reaction products thereof, e.g. afterhalogenated or sulfochlorinated
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
Abstract
The invention discloses one kind weaving antimildew and antibacterial agent and its preparation and application.The weaving antimildew and antibacterial agent includes the raw material of following percentage by weight：Mould inhibitor 10~30%, antiseptic 15~30%, emulsifying agent 1~10%, crosslinking agent 1~15%, solvent 20~65%；Wherein, the mould inhibitor is selected from least one of Tebuconazole, dimercaptodimethyl ammonium chloride, dioctadecyl dimethyl ammonium chloride, pyrithione urea, benzene thiophene cyanogen；The antiseptic is selected from least one of Bravo, Hinokitiol, sodium pyrithione, hexamethylene.The weaving antimildew and antibacterial agent antimildew and antibacterial effect of the present invention is good, and the performance of yarn fabric is produced without influence and unharmful substance, and environmental protection, security are good, non-stimulated to skin；Simple production process, less, cost is low for short production cycle, energy consumption, is conducive to promote in medium-sized and small enterprises.
Description
Technical field
The present invention relates to Prevention of Mould Development field, more particularly to a kind of weaving antimildew and antibacterial agent and its preparation and application.
Background technology
With advances in technology and the improvement of people's living standards, people require environmental sanitation higher and higher, self guarantor
Shield consciousness is increasingly enhanced, and the comfortable of clothes, healthcare function are paid attention to increasingly, and is existed on clothes and fabric substantial amounts of various micro-
Biology, although most of is non-pathogenic, their breeding can make skin be subject to abnormal stimulation.The sweat of human skin
The exfoliation of liquid, sebum and epidermis, to bacterial reproduction with suitable condition, under bacterial action, easily decomposes and produces foul smell, formed mould
Bacterium, induces skin disease and infectious disease, poor particularly with the fabric of synthetic fibers, its moisture absorption, wet putting, it is easier to cause micro- life
The breeding of thing, therefore, the research of the antibacterial deodourizing processing of fiber are increasingly prevailing.
Fiber or textile act on of both being played after antimildew and antibacterial is handled：First, protection uses textile
People, if antibacterial fabric can kill staphylococcus aureus, refer to the bacteriums such as a T.mentagrophytes, Escherichia coli, urea decomposer and
Fungi, then can infection prevention disease propagation, prevent underwear and socks from producing stench, prevent that ringworm of the foot bacterium breeds on socks,
Prevent baby from, because erythema occurs for diaper, improving the immunocompetence of old man and patient, can guard against cross infection in hospital (i.e.
MRSA infects)；Second, fibre damage is prevented, due to killing black-koji mould, chaetomium globosum, tubercle bacillus and lemon yellow green grass or young crops
The various moulds such as mould, can prevent fibrous material discoloration, tendering and textile from going mouldy in storage.
Certain progress is achieved in terms of existing weaving antimildew and antibacterial, but there is also deficiency, is mainly shown as：1st, mould inhibitor
Security is poor, has irritation to skin；2nd, complex process, so manufacture cost is higher, it is difficult to promoted in medium-sized and small enterprises；3、
Very big influence, especially gas permeability and flexibility are caused to the performance of yarn fabric；4th, nuisance is discharged during pharmacy effect
Matter, pollution air.
The content of the invention
The technical problem to be solved in the present invention is to provide one kind weaving antimildew and antibacterial agent and its preparation and application, this hair
Bright weaving antimildew and antibacterial agent antimildew and antibacterial effect is good, and the performance of yarn fabric is produced without influence and unharmful substance, ring
Guarantor, security are good, non-stimulated to skin；Simple production process, less, cost is low, is conducive to medium and small for short production cycle, energy consumption
Enterprise promotes.
In order to solve the above-mentioned technical problem, the technical scheme is that：
In a first aspect, weaving antimildew and antibacterial agent the present invention provides one kind, include the raw material of following percentage by weight：
Mould inhibitor 10~30%, antiseptic 15~30%, emulsifying agent 1~10%, crosslinking agent 1~15%, solvent 20~
65%；
Wherein, the mould inhibitor be selected from Tebuconazole, dimercaptodimethyl ammonium chloride, dioctadecyl dimethyl ammonium chloride,
At least one of pyrithione urea, benzene thiophene cyanogen；
The antiseptic in Bravo, Hinokitiol, sodium pyrithione, hexamethylene at least one
Kind.
Preferably, the mould inhibitor includes dimercaptodimethyl ammonium chloride, dioctadecyl dimethyl ammonium chloride, pyridine sulphur
Ketone urea, wherein, the dimercaptodimethyl ammonium chloride, dioctadecyl dimethyl ammonium chloride, the weight ratio of pyrithione urea are
2~4:1~4:0.5~5.
Preferably, the antiseptic includes Bravo, sodium pyrithione, hexamethylene, wherein, it is described
Bravo, sodium pyrithione, the weight ratio of hexamethylene are 1~5:2~4:1~3.
Preferably, the emulsifying agent is selected from least one of this disk, tween.
Preferably, the crosslinking agent in soluble epoxide crosslinking agent, ethylene imide, crosslinked polyethylene, propane diols extremely
Few one kind.
Preferably, the crosslinking agent includes crosslinked polyethylene, propane diols, soluble epoxide crosslinking agent
It is further preferred that the weight ratio of the crosslinked polyethylene, propane diols is 2~5:1.
Preferably, the solvent is selected from least one of water, propyl alcohol, ethanol.
Preferably, the weaving antimildew and antibacterial agent, includes the raw material of following percentage by weight：Including following percentage by weight
Raw material：Mould inhibitor 14~27%, antiseptic 19~25%, emulsifying agent 2~9%, crosslinking agent 2~10%, solvent 33~
63%.
Second aspect, present invention also offers it is a kind of prepare as described in relation to the first aspect weaving antimildew and antibacterial agent method,
Include the following steps：
Mixture A is obtained after mould inhibitor, antiseptic are mixed, solvent and the mixture A are mixed to get mixture B,
Emulsifying agent and the mixture B are mixed to get mixture C again, then mixture C and crosslinking agent are mixed to get to mould proof resist of weaving
Microbial inoculum.
The third aspect, present invention also offers it is a kind of as described in relation to the first aspect weaving antimildew and antibacterial agent application method,
Include the following steps：
By weaving antimildew and antibacterial agent as described in relation to the first aspect and water according to 0.1~5:100 ratio is mixed to prepare work
Liquid, pending textile is immersed in working solution, after soaking 5~10s, under the conditions of 0.1~1MPa pressure rolling to liquid carrying rate not
Higher than 70%, then after drying under the conditions of 100~150 DEG C, shape 30~40s at 150~200 DEG C.
Compared with prior art, the beneficial effects of the present invention are：
(1) production and processing is simple：Temperature needed for the weaving antimildew and antibacterial agent production of the present invention is not high, with short production cycle,
Energy consumption is few, and raw material is simple and easy to get, and cost is low.
(2) use scope is wide, easy to use：The weaving antimildew and antibacterial agent processing time is short of the present invention, saves the plenty of time
Cost, processing is simple, and cost is low, saves cost of labor；Weaving can be soaked and sprayed, it is easy to use, can be any
Ratio is dissolved in the water, and dissolves in most of organic solvents and oily solution, use scope and mode are various.
(3) antimildew and antibacterial effect is good：The mould inhibitor and antiseptic of the weaving antimildew and antibacterial agent of the present invention are Compositional type, most
Low Mlc is low, and antibacterial general wide, it is strong that ability is killed in the suppression to common mould and bacterium.
(4) security is good：Weaving medicament used in antimildew and antibacterial agent of the present invention is mostly less toxic or nontoxic, to eye
Small or non-stimulated with skin irritation, after compounding, proportion is less, and result is nontoxic, non-stimulated after tested.
(5) high temperature resistant：The weaving antimildew and antibacterial agent of the present invention has a variety of high temperature resistant medicaments, even in by high temperature
Reason, its antimildew and antibacterial effect is still fine, can be used under the conditions of not higher than 240 DEG C, and can be provided for user more makes
Use space.
(6) associativity is good, and effect is lasting：The weaving antimildew and antibacterial agent of the present invention is added with crosslinking agent, helps medicament more
Be attached to inside textile fabric and and textile fabric strong bonded, even across repeatedly washing, effect is still constant.
Brief description of the drawings
Fig. 1 is the mildew schematic diagram for the control group 1 that effect example 1 of the present invention is provided；
Fig. 2 is the mildew schematic diagram for the test group 1 that effect example 1 of the present invention is provided；
Fig. 3 is the mildew schematic diagram for the control group 2 that effect example 1 of the present invention is provided；
Fig. 4 is the mildew schematic diagram for the test group 2 that effect example 1 of the present invention is provided；
Fig. 5 is the mildew schematic diagram for the control group 3 that effect example 1 of the present invention is provided；
Fig. 6 is the mildew schematic diagram for the test group 3 that effect example 1 of the present invention is provided.
Embodiment
The embodiment of the present invention is described further below in conjunction with the accompanying drawings.It should be noted that for
The explanation of these embodiments is used to help understand the present invention, but does not form limitation of the invention.In addition, retouched below
As long as involved technical characteristic does not form mutual group of conflict each other in each embodiment of the invention stated
Close.
In order to solve the above-mentioned technical problem, the technical scheme is that：
In a first aspect, weaving antimildew and antibacterial agent the present invention provides one kind, include the raw material of following percentage by weight：
Mould inhibitor 10~30%, antiseptic 15~30%, emulsifying agent 1~10%, crosslinking agent 1~15%, solvent 20~
65%；
Wherein, the mould inhibitor be selected from Tebuconazole, dimercaptodimethyl ammonium chloride, dioctadecyl dimethyl ammonium chloride,
At least one of pyrithione urea, benzene thiophene cyanogen；
The antiseptic in Bravo, Hinokitiol, sodium pyrithione, hexamethylene at least one
Kind.
In embodiments of the present invention, the mould inhibitor includes dimercaptodimethyl ammonium chloride, double octadecyldimethyls
Ammonium chloride, pyrithione urea, wherein, the dimercaptodimethyl ammonium chloride, dioctadecyl dimethyl ammonium chloride, pyridine sulphur
The weight ratio of ketone urea is 2~4:1~4:0.5~5.
In a preferred embodiment of this invention, the dimercaptodimethyl ammonium chloride, dioctadecyl dimethyl ammonium chloride,
The weight ratio of pyrithione urea is 3:3:1.
In embodiments of the present invention, the antiseptic includes Bravo, sodium pyrithione, cosmocil stearate acid
Salt, wherein, the Bravo, sodium pyrithione, the weight ratio of hexamethylene are 1~5:2~4:1~3.
In a preferred embodiment of this invention, the Bravo, sodium pyrithione, the weight of hexamethylene
Amount is than being 4:3:2.
In embodiments of the present invention, the emulsifying agent is selected from least one of this disk, tween.
In a preferred embodiment of this invention, the emulsifying agent is Tween-80.
In embodiments of the present invention, the crosslinking agent be selected from soluble epoxide crosslinking agent, ethylene imide, crosslinked polyethylene,
At least one of propane diols.
In embodiments of the present invention, the crosslinking agent includes crosslinked polyethylene, propane diols, wherein, the poly- second of crosslinking
Alkene, the weight ratio of propane diols are 2~5:1.
In a preferred embodiment of this invention, the propane diols, the weight ratio of crosslinked polyethylene are 3:1.
In embodiments of the present invention, the solvent is selected from least one of water, propyl alcohol, ethanol.
In a preferred embodiment of this invention, the solvent is water.
In embodiments of the present invention, the weaving antimildew and antibacterial agent, includes the raw material of following percentage by weight：Mould inhibitor
14~27%, antiseptic 19~25%, emulsifying agent 2~9%, crosslinking agent 2~10%, solvent 33~63%.
In embodiments of the present invention, the weaving antimildew and antibacterial agent, includes the raw material of following percentage by weight：Mould inhibitor
25%th, antiseptic 20%, emulsifying agent 3%, crosslinking agent 3%, solvent 49%；
Wherein, the mould inhibitor is dimercaptodimethyl ammonium chloride, dioctadecyl dimethyl ammonium chloride, pyrithione urea
According to 3:3:1 weight ratio mixes；
The antiseptic is Bravo, sodium pyrithione, hexamethylene are according to 4:3:2 weight ratio is mixed
Conjunction forms；
The emulsifying agent is Tween-80；
The crosslinking agent is propane diols, crosslinked polyethylene is according to 3:1 weight ratio mixes.
Second aspect, present invention also offers it is a kind of prepare as described in relation to the first aspect weaving antimildew and antibacterial agent method,
Include the following steps：
Mixture A is obtained after mould inhibitor, antiseptic are mixed, solvent and the mixture A are mixed to get mixture B,
Emulsifying agent and the mixture B are mixed to get mixture C again, then mixture C and crosslinking agent are mixed to get to mould proof resist of weaving
Microbial inoculum.
The third aspect, present invention also offers it is a kind of as described in relation to the first aspect weaving antimildew and antibacterial agent application method,
Include the following steps：
By weaving antimildew and antibacterial agent as described in relation to the first aspect and water according to 0.1~5:100 ratio is mixed to prepare work
Liquid, pending textile is immersed in working solution, after soaking 5~10s, under the conditions of 0.1~1MPa pressure rolling to liquid carrying rate not
Higher than 70%, then after drying under the conditions of 100~150 DEG C, shape 30~40s at 150~200 DEG C.
The technical solution in the embodiment of the present invention is specifically described below in conjunction with attached drawing.
Embodiment 1
An embodiment of the present invention provides a kind of preparation method for antimildew and antibacterial agent of weaving, include the following steps：
(1) raw material of following percentage by weights is taken：Mould inhibitor 25%, antiseptic 20%, emulsifying agent 3%, crosslinking agent 3%,
Water 49%, wherein, the mould inhibitor is dimercaptodimethyl ammonium chloride (DDAC), dioctadecyl dimethyl ammonium chloride
(DODMAC), pyrithione urea (PM) is according to 3:3:1 weight ratio mixes；The antiseptic is Bravo, pyrithione
Sodium (SPT), hexamethylene (PHMB) are according to 4:3:2 weight ratio mixes；The emulsifying agent is to spit
Temperature -80；The crosslinking agent is propane diols, crosslinked polyethylene is according to 3:1 weight ratio mixes.
(2) mould inhibitor obtained by step (1), the antiseptic obtained by step (1) are sufficiently mixed to obtain mixture A, stirred
Mixture B is obtained after stirring the water obtained by step (1) and mixture A under conditions of mixing, continues to stir and will walk
Suddenly the emulsifying agent obtained by (1), which is added dropwise in mixture B, is made transparent mixture C, then adds crosslinking agent and obtain transparent liquid
Body weaving antimildew and antibacterial agent.
Effect example 1
(1) fungicidal properties is tested：
1. 100% terylene and the ribbon of 100% cotton and 4cm × 2cm that prepare a diameter of 3.8cm ± 0.5cm sizes are each
It is a；It is without any processing, sample as a control group；
2. by the weaving antimildew and antibacterial agent of the gained of the present embodiment 1 with water according to 1:100 ratio is mixed to prepare working solution, accurate
For the ribbon of 100% terylene of a diameter of 3.8cm ± 0.5cm sizes, cotton and 4cm × 2cm, and it is immersed into work respectively
In liquid, after soaking 8s, pressure rolling to liquid carrying rate is not higher than 70% under the conditions of 0.5MPa, then after drying under the conditions of 120 DEG C,
Test group sample is obtained after 170 DEG C of sizing 30s；
3. mould proof level estimate is carried out to control sample and test group sample according to GBT 24346-2009 standards respectively,
Strain is tested to mix mould, including aspergillus niger, Chaetomium globosum, aspergillus versicolor, aspergillus flavus, test environment is 28 ± 1 DEG C, 90 ±
5% humidity, the result that culture is observed after 7 days is referring to table 1 and Fig. 1~6.
The mould proof level estimate result of table 1
From table 1 and Fig. 1~6, without the processed terylene of working solution containing 1% weaving antimildew and antibacterial agent, cotton,
Ribbon surface is 4 without mould, mould proof grade, without mould proof ability.Through the working solution containing 1% weaving antimildew and antibacterial agent
Processed terylene, cotton, ribbon surface are 0 without mould, mould proof grade, have mould proof ability.
(2) anti-microbial property test：Prepare the green color stripe cloth of a diameter of 3.8cm ± 0.5cm sizes, rice colour cloth, main surface material,
Lining, ribbon are as sample to be tested, according to the evaluation third portion succusion of GB/T 20944.3-2008 antibacterial textile performances
The anti-microbial property of sample to be tested is tested, is blank control sample by not antibacterial processed white cotton is prepared；Test knot
Fruit is referring to table 2.
2 anti-microbial property test result of table
Embodiment 2
An embodiment of the present invention provides a kind of preparation method for antimildew and antibacterial agent of weaving, include the following steps：
(1) raw material of following percentage by weights is taken：Mould inhibitor 14%, antiseptic 19%, emulsifying agent 2%, crosslinking agent 2%,
Propyl alcohol 63%, wherein, the mould inhibitor is dimercaptodimethyl ammonium chloride (DDAC), dioctadecyl dimethyl ammonium chloride
(DODMAC), pyrithione urea (PM) is according to 3:1:3 weight ratio mixes；The antiseptic is Bravo, pyrithione
Sodium (SPT), hexamethylene (PHMB) are according to 1:2:2 weight ratio mixes；The emulsifying agent is to spit
Temperature -80；The crosslinking agent is propane diols, crosslinked polyethylene is according to 3:1 weight ratio mixes.
(2) mould inhibitor obtained by step (1), the antiseptic obtained by step (1) are sufficiently mixed to obtain mixture A, stirred
Mixture B is obtained after stirring the propyl alcohol obtained by step (1) and mixture A under conditions of mixing, continues to stir and incites somebody to action
Emulsifying agent obtained by step (1), which is added dropwise in mixture B, is made transparent mixture C, and addition crosslinking agent obtains transparent liquid
Body weaving antimildew and antibacterial agent.
Embodiment 3
An embodiment of the present invention provides a kind of preparation method for antimildew and antibacterial agent of weaving, include the following steps：
(1) raw material of following percentage by weights is taken：Mould inhibitor 24%, antiseptic 22%, emulsifying agent 8%, crosslinking agent 4%,
Water 42%, wherein, the mould inhibitor is dimercaptodimethyl ammonium chloride (DDAC), dioctadecyl dimethyl ammonium chloride
(DODMAC), pyrithione urea (PM) is according to 2:1:5 weight ratio mixes；The antiseptic is Bravo, pyrithione
Sodium (SPT), hexamethylene (PHMB) are according to 3:3:2 weight ratio mixes；The emulsifying agent is to spit
Temperature -80；The crosslinking agent is propane diols, crosslinked polyethylene is according to 2:1 weight ratio mixes.
(2) mould inhibitor obtained by step (1), the antiseptic obtained by step (1) are sufficiently mixed to obtain mixture A, stirred
Mixture B is obtained after stirring the water obtained by step (1) and mixture A under conditions of mixing, continues to stir and will walk
Suddenly the emulsifying agent obtained by (1), which is added dropwise in mixture B, is made transparent mixture C, and addition crosslinking agent obtains transparency liquid
Weaving antimildew and antibacterial agent.
Embodiment 4
An embodiment of the present invention provides a kind of preparation method for antimildew and antibacterial agent of weaving, include the following steps：
(1) raw material of following percentage by weights is taken：Mould inhibitor 25%, antiseptic 20%, emulsifying agent 9%, crosslinking agent 5%,
Solvent 41%, wherein, the mould inhibitor is dimercaptodimethyl ammonium chloride (DDAC), dioctadecyl dimethyl ammonium chloride
(DODMAC), pyrithione urea (PM) is according to 3:3:1 weight ratio mixes；The antiseptic is Bravo, pyrithione
Sodium (SPT), hexamethylene (PHMB) are according to 1:4:3 weight ratio mixes；The emulsifying agent is to spit
Temperature -80；The solvent is according to 2 by ethanol and propyl alcohol:1 weight ratio mixes；The crosslinking agent is propane diols, crosslinking
Polyethylene is according to 3:1 weight ratio mixes.
(2) mould inhibitor obtained by step (1), the antiseptic obtained by step (1) are sufficiently mixed to obtain mixture A, stirred
Mixture B is obtained after stirring the solvent obtained by step (1) and mixture A under conditions of mixing, continues to stir and incites somebody to action
Emulsifying agent obtained by step (1), which is added dropwise in mixture B, is made transparent mixture C, and addition crosslinking agent obtains transparent liquid
Body weaving antimildew and antibacterial agent.
Embodiment 5
An embodiment of the present invention provides a kind of preparation method for antimildew and antibacterial agent of weaving, include the following steps：
(1) raw material of following percentage by weights is taken：Mould inhibitor 10%, antiseptic 30%, emulsifying agent 1%, crosslinking agent 1%,
Water 58%, wherein, the mould inhibitor is dimercaptodimethyl ammonium chloride (DDAC), dioctadecyl dimethyl ammonium chloride
(DODMAC), pyrithione urea (PM) is according to 3:3:0.5 weight ratio mixes；The antiseptic is Bravo, pyridine sulphur
Ketone sodium (SPT), hexamethylene (PHMB) are according to 4:3:1 weight ratio mixes；The emulsifying agent is to spit
Temperature -80；The crosslinking agent is propane diols, crosslinked polyethylene is according to 2:1 weight ratio mixes.
(2) mould inhibitor obtained by step (1), the antiseptic obtained by step (1) are sufficiently mixed to obtain mixture A, stirred
Mixture B is obtained after stirring the water obtained by step (1) and mixture A under conditions of mixing, continues to stir and will walk
Suddenly the emulsifying agent obtained by (1), which is added dropwise in mixture B, is made transparent mixture C, then adds crosslinking agent and obtain transparent liquid
Body weaving antimildew and antibacterial agent.
Embodiment 6
An embodiment of the present invention provides a kind of preparation method for antimildew and antibacterial agent of weaving, include the following steps：
(1) raw material of following percentage by weights is taken：Mould inhibitor 30%, antiseptic 15%, emulsifying agent 10%, crosslinking agent
15%th, water 30%, wherein, the mould inhibitor is dimercaptodimethyl ammonium chloride (DDAC), dioctadecyl dimethyl ammonium chloride
(DODMAC), pyrithione urea (PM) is according to 4:3:5 weight ratio mixes；The antiseptic is Bravo, pyrithione
Sodium (SPT), hexamethylene (PHMB) are according to 5:3:3 weight ratio mixes；The emulsifying agent is to spit
Temperature -80；The crosslinking agent is propane diols, crosslinked polyethylene is according to 5:1 weight ratio mixes.
(2) mould inhibitor obtained by step (1), the antiseptic obtained by step (1) are sufficiently mixed to obtain mixture A, stirred
Mixture B is obtained after stirring the water obtained by step (1) and mixture A under conditions of mixing, continues to stir and will walk
Suddenly the emulsifying agent obtained by (1), which is added dropwise in mixture B, is made transparent mixture C, then adds crosslinking agent and obtain transparent liquid
Body weaving antimildew and antibacterial agent.
Embodiment 7
An embodiment of the present invention provides a kind of preparation method for antimildew and antibacterial agent of weaving, include the following steps：
(1) raw material of following percentage by weights is taken：Mould inhibitor 27%, antiseptic 25%, emulsifying agent 5%, crosslinking agent 10%,
Water 33%, wherein, the mould inhibitor is dimercaptodimethyl ammonium chloride (DDAC), dioctadecyl dimethyl ammonium chloride
(DODMAC), pyrithione urea (PM) is according to 3:2:1 weight ratio mixes；The antiseptic is Bravo, pyrithione
Sodium (SPT), hexamethylene (PHMB) are according to 2:3:2 weight ratio mixes；The emulsifying agent is to spit
Temperature -80；The crosslinking agent is propane diols, crosslinked polyethylene is according to 4:1 weight ratio mixes.
(2) mould inhibitor obtained by step (1), the antiseptic obtained by step (1) are sufficiently mixed to obtain mixture A, stirred
Mixture B is obtained after stirring the water obtained by step (1) and mixture A under conditions of mixing, continues to stir and will walk
Suddenly the emulsifying agent obtained by (1), which is added dropwise in mixture B, is made transparent mixture C, then adds crosslinking agent and obtain transparent liquid
Body weaving antimildew and antibacterial agent.
Comparative example 1
An embodiment of the present invention provides a kind of preparation method for antimildew and antibacterial agent of weaving, include the following steps：
(1) raw material of following percentage by weights is taken：Mould inhibitor 25%, emulsifying agent 3%, crosslinking agent 3%, water 69%, wherein,
The mould inhibitor is dimercaptodimethyl ammonium chloride (DDAC), dioctadecyl dimethyl ammonium chloride (DODMAC), pyrithione
Urea (PM) is according to 3:3:1 weight ratio mixes；The emulsifying agent is Tween-80；The crosslinking agent is propane diols, crosslinking
Polyethylene is according to 3:1 weight ratio mixes.
(2) mixture B is obtained after stirring the mould inhibitor obtained by step (1) and water, continues to stir and will walk
Suddenly the emulsifying agent obtained by (1), which is added dropwise in mixture B, is made transparent mixture C, then adds crosslinking agent and obtain transparent liquid
Body weaving antimildew and antibacterial agent.
Comparative example 2
Comparative example of the present invention provides a kind of preparation method for antimildew and antibacterial agent of weaving, and includes the following steps：
(1) raw material of following percentage by weights is taken：Mould inhibitor 14%, antiseptic 19%, emulsifying agent 2%, crosslinking agent 2%,
Propyl alcohol 63%, wherein, the mould inhibitor for dioctadecyl dimethyl ammonium chloride (DODMAC), pyrithione urea (PM) according to
1:3 weight ratio mixes；The antiseptic is Bravo, sodium pyrithione (SPT), hexamethylene
(PHMB) according to 1:2:2 weight ratio mixes；The emulsifying agent is Tween-80；The crosslinking agent is propane diols, crosslinking
Polyethylene is according to 3:1 weight ratio mixes.
(2) mould inhibitor obtained by step (1), the antiseptic obtained by step (1) are sufficiently mixed to obtain mixture A, stirred
Mixture B is obtained after stirring the water obtained by step (1) and mixture A under conditions of mixing, continues to stir and will walk
Suddenly the emulsifying agent obtained by (1), which is added dropwise in mixture B, is made transparent mixture C, and addition crosslinking agent obtains transparency liquid
Weaving antimildew and antibacterial agent.
Comparative example 3
Comparative example of the present invention provides a kind of preparation method for antimildew and antibacterial agent of weaving, and includes the following steps：
(1) raw material of following percentage by weights is taken：Mould inhibitor 24%, antiseptic 22%, emulsifying agent 8%, crosslinking agent 4%,
Water 42%, wherein, the mould inhibitor is dioctadecyl dimethyl ammonium chloride (DODMAC), pyrithione urea (PM) is according to 1:5
Weight ratio mix；The antiseptic is Bravo, sodium pyrithione (SPT), hexamethylene
(PHMB) according to 3:3:2 weight ratio mixes；The emulsifying agent is Tween-80；The crosslinking agent is propane diols, crosslinking
Polyethylene is according to 2:1 weight ratio mixes.
(2) mould inhibitor obtained by step (1), the antiseptic obtained by step (1) are sufficiently mixed to obtain mixture A, stirred
Mixture B is obtained after stirring the water obtained by step (1) and mixture A under conditions of mixing, continues to stir and will walk
Suddenly the emulsifying agent obtained by (1), which is added dropwise in mixture B, is made transparent mixture C, and addition crosslinking agent obtains transparency liquid
Weaving antimildew and antibacterial agent.
Comparative example 4
An embodiment of the present invention provides a kind of preparation method for antimildew and antibacterial agent of weaving, include the following steps：
(1) raw material of following percentage by weights is taken：Mould inhibitor 25%, antiseptic 20%, emulsifying agent 9%, crosslinking agent 5%,
Water 41%, wherein, the mould inhibitor is dimercaptodimethyl ammonium chloride (DDAC), pyrithione urea (PM) is according to 3:1 weight
Than mixing；The antiseptic is Bravo, hexamethylene (PHMB) is according to 1:3 weight ratio mixing
Form；The emulsifying agent is Tween-80；The solvent is according to 2 by ethanol and propyl alcohol:1 weight ratio mixes；It is described
Crosslinking agent is propane diols, crosslinked polyethylene is according to 3:1 weight ratio mixes.
(2) mould inhibitor obtained by step (1), the antiseptic obtained by step (1) are sufficiently mixed to obtain mixture A, stirred
Mixture B is obtained after stirring the water obtained by step (1) and mixture A under conditions of mixing, continues to stir and will walk
Suddenly the emulsifying agent obtained by (1), which is added dropwise in mixture B, is made transparent mixture C, and addition crosslinking agent obtains transparency liquid
Weaving antimildew and antibacterial agent.
Effect example 2
It is below the performance test explanation of weaving antimildew and antibacterial agent according to the present invention：
(1) animal toxicity is tested：Using acute oral toxicity test, rat and each 110 of mouse, mouse weight 18 are selected
~22g, 180~220g of rat body weight, are divided into 11 groups, every group 10.The preparation of animal：Before experiment, general overnight fasting, no
Water restriction.The preparation of tested material：Using water as solvent, respectively by the embodiment of the present invention 1~7, the weaving of the gained of comparative example 1~4
Antimildew and antibacterial agent is diluted to 1:5 dilution, up to tested material.Gavage gives the maximum capacity of tested material.Contamination method：With
Gavage mode once gives tested material to animal.Poisoning manifestations and death toll and the death time of animal are observed after contamination, and it is right
Dead animal and observation period, everywhere dead animal was autopsied, and visually observed, and discovery has abnormal tissue or internal organs, still needs
Further make histopathological examination, 14 days observing times.With specific reference to Ministry of Health of the People's Republic of China《Disinfection technology is advised
Model》(2006) acute oral toxicity test method as defined in 4.1 carries out animal toxicity test, and records final result.
(2) skin irritation is tested：Using Skin Irritation Test, rabbit and each 5 of cavy are selected.The preparation of animal：
24h before experiment, the hair of rabbit or guinea pig back backbone both sides is removed, must not damage skin with depilatory agent or scissors.Unhairing model
Enclose, left and right each about 3cm × 3cm.The preparation of tested material：Using water as solvent, respectively by the embodiment of the present invention 1~7, comparative example 1
The weaving antimildew and antibacterial agent of~4 gained is diluted to 1:5 dilution.Tested material 0.5ml (g) is coated on the skin of side by next day,
Opposite side applies solvent as control, and the 4h after smearing, is cleaned with water or non-stimulated suitable solvent, removes residue.Apply daily
Smear once, continuously smear 14d.The 24h observations result after each smear.Observed for the ease of the smearing and result of tested material, must
Will when answer cropping.The same trial zone of processing method of check plot；With specific reference to Ministry of Health of the People's Republic of China《Disinfection technology is advised
Model》Multiple intact skin Irritation Test Method as defined in (2006) 4.4.3.3 carries out skin irritation test, and records most
Terminate fruit.
(3) eye irritation is tested：Using acute eye irritation test, rabbit 5 is selected.The preparation of test fluid：Using water as
Solvent, is diluted to 1 by the weaving antimildew and antibacterial agent of the embodiment of the present invention 1~7, the gained of comparative example 1~4 respectively:5 dilution.
Tested material 0.1ml is drawn, it is intracapsular to instill rabbit side eye conjunctiva.Another branch hole is used as normal control using physiological saline.Drip tested
After thing, eye is passively closed into 4s, normal saline flushing is used after 30s.1h, 24h, 48h, 72h, 7d, 14d and 21d after eye drip,
Visually observe and record damage and the recovery situation of rabbit eye conjunctiva, iris and cornea.If necessary, with 2% Fluress
Or slit-lamp, lens examination cornea and iris change.With specific reference to Ministry of Health of the People's Republic of China《Disinfection technology standard》
(2006) acute eye irritation test method as defined in 4.5 carries out eye irritation test, and records final result.
(4) fungicidal properties is tested：It is prepared by tested material：The purified cotton cloth of a diameter of 3.8cm ± 0.5cm sizes, by embodiment 1
~7 and the gained of comparative example 1~4 weaving antimildew and antibacterial agent with water according to 0.1~5:100 weight ratio is mixed to prepare 11 kinds of works
Make liquid, 11 pieces of purified cotton cloths are immersed in above-mentioned 11 kinds of working solutions respectively, after soaking 8s, pressure rolling is extremely under the conditions of 0.5MPa
Liquid carrying rate is not higher than 70%, then after drying under the conditions of 120 DEG C, shape 30s at 170 DEG C.According to standard GB/T24346-2009
Weaving of the test method of the evaluation of textile fungicidal properties to the embodiment of the present invention 1~7, the gained of comparative example 1~4 is mould proof anti-
Microbial inoculum carries out anti-microbial property test, and records final result.
(5) anti-microbial property test：Prepare the purified cotton cloth of some pieces of a diameter of 3.8cm ± 0.5cm sizes, by embodiment 1
~7 and the gained of comparative example 1~4 weaving antimildew and antibacterial agent with water according to 0.1~5:100 weight ratio is mixed to prepare 11 kinds of works
Make liquid, 11 pieces of purified cotton cloths are immersed in above-mentioned 11 kinds of working solutions respectively, after soaking 8s, pressure rolling is extremely under the conditions of 0.5MPa
Liquid carrying rate is not higher than 70%, then after drying under the conditions of 120 DEG C, shape 30s at 170 DEG C.According to standard GBT20944.2-
The test method of the evaluation part 2 absorption process of 2007 antibacterial textile performances is to the embodiment of the present invention 1~7, comparative example 1~4
The weaving antimildew and antibacterial agent of gained carries out anti-microbial property test, and records final result.
3 testing result of table
As shown in Table 3, compared with the weaving antimildew and antibacterial agent of comparative example 1~4, the weaving of the embodiment of the present invention 1~7 is mould proof
The mould proof grade of the processed cotton of antiseptic is 0 grade, antibiotic rate>99%, the weaving of this explanation embodiment of the present invention 1~7
Antimildew and antibacterial agent has played the advantage of each component, improves fungus and mildew resistance security, reduces the resistance to the action of a drug of microorganism, and each group divides it
Between be not it is simple be added effect, but far beyond it is anticipated that with extremely strong building performance.Spun in the embodiment of the present invention 1~7
Knit in antimildew and antibacterial agent, the bactericidal mould proof effect for the weaving antimildew and antibacterial agent prescription that the embodiment of the present invention 1~4 is provided is preferable.
Embodiments of the present invention are explained in detail above in association with attached drawing, but the invention is not restricted to described implementation
Mode.For a person skilled in the art, in the case where not departing from the principle of the invention and spirit, to these embodiment party
Formula carries out a variety of change, modification, replacement and modification, still falls within protection scope of the present invention.
Claims (10)
1. one kind weaving antimildew and antibacterial agent, it is characterised in that：Include the raw material of following percentage by weight：
Mould inhibitor 10~30%, antiseptic 15~30%, emulsifying agent 1~10%, crosslinking agent 1~15%, solvent 20~65%；
Wherein, the mould inhibitor is selected from Tebuconazole, dimercaptodimethyl ammonium chloride, dioctadecyl dimethyl ammonium chloride, pyridine
At least one of thioketones urea, benzene thiophene cyanogen；
The antiseptic is selected from least one of Bravo, Hinokitiol, sodium pyrithione, hexamethylene.
2. weaving antimildew and antibacterial agent according to claim 1, it is characterised in that：The mould inhibitor includes didecyldimethylammonium
Ammonium chloride, dioctadecyl dimethyl ammonium chloride, pyrithione urea, wherein, the dimercaptodimethyl ammonium chloride, double octadecanes
Base alkyl dimethyl ammonium chloride, the weight ratio of pyrithione urea are 2~4:1~4:0.5~5.
3. weaving antimildew and antibacterial agent according to claim 1, it is characterised in that：The antiseptic includes Bravo, pyridine
Thioketones sodium, hexamethylene, wherein, the Bravo, sodium pyrithione, hexamethylene
Weight ratio is 1~5:2~4:1~3.
4. weaving antimildew and antibacterial agent according to claim 1, it is characterised in that：The emulsifying agent is in this disk, tween
At least one.
5. weaving antimildew and antibacterial agent according to claim 1, it is characterised in that：The crosslinking agent is handed over selected from soluble epoxide
Join at least one of agent, ethylene imide, crosslinked polyethylene, propane diols.
6. weaving antimildew and antibacterial agent according to claim 5, it is characterised in that：The crosslinking agent include crosslinked polyethylene,
Propane diols, wherein, the crosslinked polyethylene, the weight ratio of propane diols are 2~5:1.
7. weaving antimildew and antibacterial agent according to claim 1, it is characterised in that：The solvent is in water, propyl alcohol, ethanol
At least one.
8. weaving antimildew and antibacterial agent according to claim 1, it is characterised in that：Include the raw material of following percentage by weight：
Mould inhibitor 14~27%, antiseptic 19~25%, emulsifying agent 2~9%, crosslinking agent 2~10%, solvent 33~63%.
A kind of 9. method for preparing claim 1~8 any one of them weaving antimildew and antibacterial agent, it is characterised in that：Including such as
Lower step：
Mixture A is obtained after mould inhibitor, antiseptic are mixed, solvent and the mixture A are mixed to get mixture B, then will
Emulsifying agent is mixed to get mixture C with the mixture B, then mixture C and crosslinking agent are mixed to get weaving antimildew and antibacterial agent.
A kind of 10. application method of claim 1~8 any one of them weaving antimildew and antibacterial agent, it is characterised in that：Including such as
Lower step：
By claim 1~8 any one of them weaving antimildew and antibacterial agent with water according to 0.1~5:100 ratio is mixed to prepare
Working solution, pending textile is immersed in working solution, and after soaking 5~10s, pressure rolling is to liquid under the conditions of 0.1~1MPa
Rate is not higher than 70%, then after drying under the conditions of 100~150 DEG C, shape 30~40s at 150~200 DEG C.
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| CN108576035A (en) * | 2018-05-07 | 2018-09-28 | 广州佳伲思抗菌材料有限公司 | A kind of mildew removing agent and preparation method thereof |
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| CN110037023A (en) * | 2019-04-19 | 2019-07-23 | 广州佳伲斯防霉抗菌科技有限公司 | A kind of antimildew disinfectant and preparation method thereof for container |
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| CN111471814A (en) * | 2019-01-24 | 2020-07-31 | 河南拓普锐生物科技有限公司 | Leather mildew inhibitor containing benzothiophene and preparation method thereof |
| CN111471815A (en) * | 2019-01-24 | 2020-07-31 | 河南拓普锐生物科技有限公司 | Efficient low-toxicity water-based leather mildew inhibitor and preparation method thereof |
| CN113584884A (en) * | 2021-08-25 | 2021-11-02 | 杭州萧山丝化印染有限公司 | Antibacterial functional fabric and preparation method thereof |
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| CN108576035A (en) * | 2018-05-07 | 2018-09-28 | 广州佳伲思抗菌材料有限公司 | A kind of mildew removing agent and preparation method thereof |
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| CN111471815A (en) * | 2019-01-24 | 2020-07-31 | 河南拓普锐生物科技有限公司 | Efficient low-toxicity water-based leather mildew inhibitor and preparation method thereof |
| CN110037023A (en) * | 2019-04-19 | 2019-07-23 | 广州佳伲斯防霉抗菌科技有限公司 | A kind of antimildew disinfectant and preparation method thereof for container |
| CN111118904A (en) * | 2019-12-27 | 2020-05-08 | 江苏神涛环保科技有限公司 | Textile antibacterial finishing agent |
| CN113584884A (en) * | 2021-08-25 | 2021-11-02 | 杭州萧山丝化印染有限公司 | Antibacterial functional fabric and preparation method thereof |
| CN114568429A (en) * | 2022-03-29 | 2022-06-03 | 浙江绿岛科技有限公司 | Bacteriostatic and mildewproof aerosol based on self-film forming and preparation method thereof |
| CN116807210A (en) * | 2023-04-11 | 2023-09-29 | 瑞年科技(广东)有限公司 | Multifunctional mildew-proof tablecloth |
| CN117005190A (en) * | 2023-08-28 | 2023-11-07 | 广州广微环境科技有限公司 | Mildew-proof antibacterial agent for textiles and preparation method thereof |
| CN117005190B (en) * | 2023-08-28 | 2023-12-19 | 广州广微环境科技有限公司 | Mildew-proof antibacterial agent for textiles and preparation method thereof |
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