CN107937165A - A kind of spectacle antifogging cleaning solution and preparation method thereof - Google Patents
A kind of spectacle antifogging cleaning solution and preparation method thereof Download PDFInfo
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K3/00—Materials not provided for elsewhere
- C09K3/18—Materials not provided for elsewhere for application to surfaces to minimize adherence of ice, mist or water thereto; Thawing or antifreeze materials for application to surfaces
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/12—Water-insoluble compounds
- C11D3/124—Silicon containing, e.g. silica, silex, quartz or glass beads
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/162—Organic compounds containing Si
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2006—Monohydric alcohols
- C11D3/201—Monohydric alcohols linear
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2086—Hydroxy carboxylic acids-salts thereof
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/008—Polymeric surface-active agents
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
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Abstract
The invention discloses a kind of spectacle antifogging cleaning solution and preparation method thereof, and prepare the raw material of spectacle antifogging cleaning solution is included by its parts by weight：5 parts~10 parts of 10 parts~15 parts of ethyl orthosilicate, 10 parts~15 parts of vinyltriethoxysilane, 0.5 part~2 parts of nano-titanium dioxide, 40 parts~50 parts of absolute ethyl alcohol, 1 part~5 parts of potassium sorbate, 0.5 part~3 parts of surfactant and deionized water.The good antifogging effect of spectacle antifogging cleaning solution prepared by the present invention, antifog time length, obvious to the cleaning action of glasses, application method is succinct, will not cause damage to glasses, and raw material is cheap and easily-available, and preparation method is simple, is adapted to large-scale production.
Description
Technical field
The present invention relates to chemical coating field, and in particular to a kind of spectacle antifogging cleaning solution and preparation method thereof.
Background technology
It is frequently problem in life that eyeglass, which hazes, and the reason for hazing, one kind was hotter in eyeglass mainly by two kinds
Gas run into liquefaction phenomenon caused by colder eyeglass, it is a kind of be by the moisture evaporation of the skin surface of glasses sealing,
Gas condensation on eyeglass produces.According to the reason that hazes, defogging method can be divided into, first, reducing air humidity or reducing temperature
Difference, first, changing material surface performance.Reduce air humidity generally makes material temperature be maintained at mist by heating glass material
Drip more than adiabatic condensation temperature, but such method is not suitable for applying in glasses direction, and complex manufacturing technology.Change material surface
It can include coating hydrophily antifog film and coating hydrophobicity antifog film.Hydrophily antifog film is to reduce contact of the substrate surface to water
Angle, makes water droplet in material surface drawout, and gradually forms uniform water film, avoids the light reflection and refraction produced by water droplet.
Hydrophobicity antifog film prevents water droplet from adsorbing in material surface, when material tilts one to improve contact angle of the substrate surface to water
Determine angle, until since gravity tumbles water droplet, ensure the translucency of material.But by hydrophily or hydrophobic material in mirror
After piece surface forms new film layer, certain matter for influencing, reducing eyeglass can be produced on the intensity, wearability and light transmittance of eyeglass
Amount, and eyeglass hazes and only can just occur under given conditions, only carries out processing before atomization occurs to lens surface and is only
It is optimum, you can to ensure the clarity of eyeglass, and can effectively to prevent the generation that eyeglass hazes.
Chinese patent CN102618217A discloses a kind of antimicrobial form fog-proof wet towel, and nothing is uniformly sprayed on by antifog antimicrobial fluid
In woven fabric, each component and content (weight %) of antifog antimicrobial fluid are：Polyacrylic acid modified nano-particle liquid, Kathon CG, surplus
For water, each component and content (weight %) of the polyacrylic acid modified nano-particle liquid are：Nano particles of silicon dioxide,
KH-560, AEO-23, acrylic acid, EGDMA, ammonium persulfate and water.The invention uses polyacrylic acid modified nano-particle liquid, solution
The mottling problem for traditional product of having determined, and the wiping carrier using non-woven fabrics as antifog antimicrobial fluid, avoid in wiping process
The paper scrap or fiber of generation, but the standby antimicrobial form fog-proof wet towel of the patent system is antifog ineffective.
Chinese patent CN102269828A discloses a kind of preparation method of nanocomposite optical antifog film, including step is as follows：
(1) preparation of precursor colloidal sol；(2) preparation of compound anti-mist solution；(3) optical base-substrate pre-processes；(4) plated film and curing, should
Novel nano optics antifog film is by the use of Si-O-Si net structures colloidal sol as preceding extract, and uses sol-gal process and ethene
The sudden reaction of base double bond connects acrylic compounds water wetted material on precursor side chain, ensure that water wetted material is connected with precursor
Stability, solve the shortcomings that water wetted material easily comes off from optical element surface.But nanocomposite optical prepared by the invention
Antifog film is fixed on optical element surface by antifog film using the cured mode of plated film, the light transmittance and surface to optical element
Wearability necessarily influences, it is impossible to ensures higher light transmittance and preferable surface strength.
Therefore, it is badly in need of a kind of antifog positive effect, with cleaning action, application method is simple, can't be to eyeglass
Light transmittance and the spectacle antifogging cleaning solution that impacts of intensity and preparation method thereof.
The content of the invention
The present invention is in view of the above-mentioned problems, provide a kind of spectacle antifogging cleaning solution and preparation method thereof.
Technical solution is used by the present invention solves the above problems：The raw material of spectacle antifogging cleaning solution is prepared by its weight
Part includes：10 parts~15 parts of ethyl orthosilicate, 10 parts~15 parts of vinyltriethoxysilane, nano-titanium dioxide 0.5 part~2
Part, 40 parts~50 parts of absolute ethyl alcohol, 1 part~5 parts of potassium sorbate, 0.5 part~3 parts of surfactant and deionized water 5 parts~10
Part.Wherein, potassium sorbate can effectively inhibit the activity of mould, saccharomycete and aerobic bacteria, moreover it is possible to prevent harmful microorganism
Growth and breeding, the effect of antibacterial bacteriostatic can be played by being added in spectacle antifogging cleaning solution, keep the cleaning of eyeglass
Property.
Further, prepare the raw material of spectacle antifogging cleaning solution is included by its parts by weight：13 parts of ethyl orthosilicate, vinyl
13 parts of triethoxysilane, 1.2 parts of nano-titanium dioxide, 45 parts of absolute ethyl alcohol, 3 parts of potassium sorbate, 1.5 parts of surfactant and
8 parts of deionized water.
Further, nano-titanium dioxide is the high-dispersion nano titanium dioxide prepared using agglutinating nature yeast.Wherein,
Nano-titanium dioxide has a superpower hydrophily after ultraviolet irradiates, and the contact angle of titanic oxide material and water can be also reduced to
Within ten degree, after a single use, part nano-titanium dioxide residual is had in eyeglass lens surface, is again introduced into the environment that hazes
There can be certain anti-fog effect afterwards.
Further, the preparation method of nano-titanium dioxide includes the following steps：Butyl titanate is added to anhydrous second
In alcohol, add nitric acid in the state of stirring, when stirring reaction 16 is small~24 it is small when, vacuum drying obtains nano-titanium dioxide.
Further, surfactant described in surfactant is neopelex and ethoxylated dodecyl alcohol
One or two.Wherein neopelex is anionic surfactant, and ethoxylated dodecyl alcohol is neutrality
Both compounding uses can be increased cleaning action, can also improve the hydrophily of lens surface, by condensation by surfactant
Water droplet is laid in lens surface, improves anti misting capability, glasses further can be cleaned antifog while, raising mirror
The clarity of piece.
Another goal of the invention of the present invention is to provide a kind of preparation method of above-mentioned spectacle antifogging cleaning solution, including as follows
Step：
Nano-titanium dioxide, potassium sorbate, surfactant, are dissolved in absolute ethyl alcohol by step S10 by above-mentioned parts by weight,
Sonic oscillation disperses 3 minutes~5 minutes, obtains mixed liquor A；
Ethyl orthosilicate and vinyltriethoxysilane, are added in reactor, added by step S20 by above-mentioned parts by weight
Enter absolute ethyl alcohol, be stirred under constant temperature 30 minutes~45 minutes, the deionized water of above-mentioned parts by weight is added, with hydrochloric acid
Adjust solution pH to 4.0~4.5, the reaction was continued 3 it is small when~3.5 it is small when, obtain mixed liquid B；
Step S30, the temperature for adjusting mixed liquid B are 30 DEG C~40 DEG C, add mixed liquor A, are thoroughly mixed 10 minutes
~15 minutes, pH to 7~8 is adjusted with saturation sodium hydroxide solution, obtains spectacle antifogging cleaning solution.
Further, in step S10, the additive amount of absolute ethyl alcohol is the 1/10~1/9 of gross weight.
Further, in step S20, the temperature of constant temperature is 60 DEG C~65 DEG C.
Further, in step S20, the additive amount of absolute ethyl alcohol is the 8/9~9/10 of gross weight.
It is an advantage of the invention that：
1. the raw material of spectacle antifogging cleaning solution of the present invention includes ethyl orthosilicate and vinyltriethoxysilane, pass through control
Reaction condition processed, occurs hydrolytic-polymeric reaction, and generation has certain hydrophilic compound, wiped lens surface, can be with
Good antifogging action is played, also contains nano-titania particle in raw material, the particle is after the ultraviolet irradiation in air
Stronger hydrophily can be shown, the anti-fog effect of eyeglass can be further improved；
2. addition sorbic acid can play the effect of antibacterial bacteriostatic in the spectacle antifogging cleaning solution of the present invention, eyeglass is kept
Spatter property；Add anion surfactant and nonionic surface active agent, both compounding uses can be with antifog while
Glasses are further cleaned, improve the clarity of eyeglass；
3. the good antifogging effect of spectacle antifogging cleaning solution prepared by the present invention, antifog time length, to the cleaning action of glasses
Substantially, application method is succinct, will not cause damage to glasses, and raw material is cheap and easily-available, and preparation method is simple, is adapted to extensive
Production.
Embodiment
The embodiment of the present invention is described in detail below, but what the present invention can be defined by the claims and cover
Multitude of different ways is implemented.
Embodiment 1
A kind of spectacle antifogging cleaning solution and preparation method thereof
The raw material composition of spectacle antifogging cleaning solution：
13 parts of ethyl orthosilicate, 12 parts of vinyltriethoxysilane, 1.2 parts of nano-titanium dioxide, 45 parts of absolute ethyl alcohol,
8 parts of 3 parts of potassium sorbate, 1.6 parts of surfactant and deionized water.
Nano-titanium dioxide is made by the steps：Butyl titanate is added in absolute ethyl alcohol, in the shape of stirring
Nitric acid is added under state, when stirring reaction 20 is small, vacuum drying obtains nano-titanium dioxide.
Spectacle antifogging cleaning solution is prepared via a method which：
Nano-titanium dioxide, potassium sorbate, surfactant, 1/9 anhydrous second is dissolved in by above-mentioned parts by weight by step S10
In alcohol, sonic oscillation disperses 4 minutes, obtains mixed liquor A；
Ethyl orthosilicate and vinyltriethoxysilane, are added in reactor, added by step S20 by above-mentioned parts by weight
Enter remaining absolute ethyl alcohol, be stirred under 65 DEG C of constant temperature 40 minutes, add the deionized water of above-mentioned parts by weight, with
The pH of hydrochloric acid conditioning solution to 4.0, the reaction was continued 3 it is small when, obtain mixed liquid B；
Step S30, the temperature for adjusting mixed liquid B are 30 DEG C, add mixed liquor A, are thoroughly mixed 12 minutes, with saturation
Sodium hydroxide solution adjusts pH to 7, obtains spectacle antifogging cleaning solution.
Application method：Spectacle antifogging cleaning solution prepared by the present invention is applied to eyeglass both sides, and it is light with glasses cloth
Dab and wipe.
Embodiment 2
A kind of spectacle antifogging cleaning solution and preparation method thereof
The raw material composition of spectacle antifogging cleaning solution：
12 parts of ethyl orthosilicate, 10 parts of vinyltriethoxysilane, 0.2 part of nano-titanium dioxide, 40 parts of absolute ethyl alcohol,
5 parts of 5 parts of potassium sorbate, 0.5 part of surfactant and deionized water.
Nano-titanium dioxide is made by the steps：Butyl titanate is added in absolute ethyl alcohol, in the shape of stirring
Nitric acid is added under state, when stirring reaction 24 is small, vacuum drying obtains nano-titanium dioxide.
Spectacle antifogging cleaning solution is prepared via a method which：
Step S10, by above-mentioned parts by weight by nano-titanium dioxide, potassium sorbate, surfactant be dissolved in 1/10 it is anhydrous
In ethanol, sonic oscillation disperses 5 minutes, obtains mixed liquor A；
Ethyl orthosilicate and vinyltriethoxysilane, are added in reactor, added by step S20 by above-mentioned parts by weight
Enter remaining absolute ethyl alcohol, be stirred under 60 DEG C of constant temperature 30 minutes, add the deionized water of above-mentioned parts by weight, with
The pH of hydrochloric acid conditioning solution to 4.5, the reaction was continued 3 it is small when, obtain mixed liquid B；
Step S30, the temperature for adjusting mixed liquid B are 35 DEG C, add mixed liquor A, are thoroughly mixed 15 minutes, with saturation
Sodium hydroxide solution adjusts pH to 8, obtains spectacle antifogging cleaning solution.
Application method：Spectacle antifogging cleaning solution prepared by the present invention is applied to eyeglass both sides, and it is light with glasses cloth
Dab and wipe.
Embodiment 3
A kind of spectacle antifogging cleaning solution and preparation method thereof
The raw material composition of spectacle antifogging cleaning solution：
15 parts of ethyl orthosilicate, 13 parts of vinyltriethoxysilane, 1.5 parts of nano-titanium dioxide, 50 parts of absolute ethyl alcohol,
10 parts of 1 part of potassium sorbate, 2.0 parts of surfactant and deionized water.
Nano-titanium dioxide is made by the steps：Butyl titanate is added in absolute ethyl alcohol, in the shape of stirring
Nitric acid is added under state, when stirring reaction 16 is small, vacuum drying obtains nano-titanium dioxide.
Spectacle antifogging cleaning solution is prepared via a method which：
Nano-titanium dioxide, potassium sorbate, surfactant, 1/9 anhydrous second is dissolved in by above-mentioned parts by weight by step S10
In alcohol, sonic oscillation disperses 5 minutes, obtains mixed liquor A；
Ethyl orthosilicate and vinyltriethoxysilane, are added in reactor, added by step S20 by above-mentioned parts by weight
Enter remaining absolute ethyl alcohol, be stirred under 65 DEG C of constant temperature 45 minutes, add the deionized water of above-mentioned parts by weight, with
The pH of hydrochloric acid conditioning solution to 4.0, the reaction was continued 3.5 it is small when, obtain mixed liquid B；
Step S30, the temperature for adjusting mixed liquid B are 40 DEG C, add mixed liquor A, are thoroughly mixed 10 minutes, with saturation
Sodium hydroxide solution adjusts pH to 7.5, obtains spectacle antifogging cleaning solution.
Application method：Spectacle antifogging cleaning solution prepared by the present invention is applied to eyeglass both sides, and it is light with glasses cloth
Dab and wipe.
Embodiment 4
A kind of spectacle antifogging cleaning solution and preparation method thereof
The raw material composition of spectacle antifogging cleaning solution：
10 parts of ethyl orthosilicate, 15 parts of vinyltriethoxysilane, 2.0 parts of nano-titanium dioxide, 45 parts of absolute ethyl alcohol,
10 parts of 4 parts of potassium sorbate, 3.0 parts of surfactant and deionized water.
Nano-titanium dioxide is made by the steps：Butyl titanate is added in absolute ethyl alcohol, in the shape of stirring
Nitric acid is added under state, when stirring reaction 18 is small, vacuum drying obtains nano-titanium dioxide.
Spectacle antifogging cleaning solution is prepared via a method which：
Step S10, by above-mentioned parts by weight by nano-titanium dioxide, potassium sorbate, surfactant be dissolved in 1/10 it is anhydrous
In ethanol, sonic oscillation disperses 3 minutes, obtains mixed liquor A；
Ethyl orthosilicate and vinyltriethoxysilane, are added in reactor, added by step S20 by above-mentioned parts by weight
Enter remaining absolute ethyl alcohol, be stirred under 55 DEG C of constant temperature 50 minutes, add the deionized water of above-mentioned parts by weight, with
The pH of hydrochloric acid conditioning solution to 4.0, the reaction was continued 4 it is small when, obtain mixed liquid B；
Step S30, the temperature for adjusting mixed liquid B are 45 DEG C, add mixed liquor A, are thoroughly mixed 10 minutes, with saturation
Sodium hydroxide solution adjusts pH to 7.2, obtains spectacle antifogging cleaning solution.
Application method：Spectacle antifogging cleaning solution prepared by the present invention is applied to eyeglass both sides, or eyeglass is soaked
In antifog cleaning solution prepared by the present invention, and gently wiped with glasses cloth.
Embodiment 5
A kind of spectacle antifogging cleaning solution and preparation method thereof
The raw material composition of spectacle antifogging cleaning solution：
10 parts of ethyl orthosilicate, 12 parts of vinyltriethoxysilane, 1.5 parts of nano-titanium dioxide, 45 parts of absolute ethyl alcohol,
12 parts of 2 parts of potassium sorbate, 2.5 parts of surfactant and deionized water.
Nano-titanium dioxide is made by the steps：Butyl titanate is added in absolute ethyl alcohol, in the shape of stirring
Nitric acid is added under state, when stirring reaction 22 is small, vacuum drying obtains nano-titanium dioxide.
Spectacle antifogging cleaning solution is prepared via a method which：
Nano-titanium dioxide, potassium sorbate, surfactant, 1/9 anhydrous second is dissolved in by above-mentioned parts by weight by step S10
In alcohol, sonic oscillation disperses 5 minutes, obtains mixed liquor A；
Ethyl orthosilicate and vinyltriethoxysilane, are added in reactor, added by step S20 by above-mentioned parts by weight
Enter remaining absolute ethyl alcohol, be stirred under 65 DEG C of constant temperature 45 minutes, add the deionized water of above-mentioned parts by weight, with
The pH of hydrochloric acid conditioning solution to 4.5, the reaction was continued 3 it is small when, obtain mixed liquid B；
Step S30, the temperature for adjusting mixed liquid B are 35 DEG C, add mixed liquor A, are thoroughly mixed 12 minutes, with saturation
Sodium hydroxide solution adjusts pH to 7.5, obtains spectacle antifogging cleaning solution.
Application method：Spectacle antifogging cleaning solution prepared by the present invention is applied to eyeglass both sides, and it is light with glasses cloth
Dab and wipe.
Experimental example
In order to further illustrate the technological progress of the present invention, now further illustrated using experiment.
Experiment material：The spectacle antifogging cleaning solution that commercially available spectacle antifogging liquid, the embodiment of the present invention 1~5 are produced.
Experimental method：Commercially available spectacle antifogging liquid is smeared into the both sides of eyeglass respectively, the embodiment of the present invention 1~5 is made
Standby spectacle antifogging cleaning solution, and wiped clean；It is put on 50 DEG C of the water surface, keeps and 15 centimetres of water surface distance, record eyeglass
Eyeglass state, and it is repeatedly tested, records eyeglass state.Experimental result is as shown in table 1.
The test result of spectacle antifogging cleaning solution prepared by 1. embodiment 1~5 of table
Experimental result surface, the good antifogging effect of spectacle antifogging cleaning solution prepared by the present invention, antifog time length can be multiple
Antifog, the single antifog time of the antifog cleaning solution prepared with commercially available spectacle antifogging liquid phase ratio, the present invention is longer, also has multiple
Anti- fog effect, can also clean eyeglass while preventing from hazing, and have the function that antibacterial bacteriostatic, and preparation method
Simply, easy to operate, to glasses, good damage is hindered invariably, convenient to use.
It these are only the preferred embodiment of the present invention, be not intended to limit the invention, for those skilled in the art
For member, the invention may be variously modified and varied.Any modification within the spirit and principles of the invention, being made,
Equivalent substitution, improvement etc., should all be included in the protection scope of the present invention.
Claims (9)
1. a kind of spectacle antifogging cleaning solution, it is characterised in that prepare the raw material of the spectacle antifogging cleaning solution by its parts by weight bag
Include：10 parts~15 parts of ethyl orthosilicate, 10 parts~15 parts of vinyltriethoxysilane, 0.5 part~2 parts of nano-titanium dioxide,
5 parts~10 parts of 40 parts~50 parts of absolute ethyl alcohol, 1 part~5 parts of potassium sorbate, 0.5 part~3 parts of surfactant and deionized water.
2. spectacle antifogging cleaning solution according to claim 1, it is characterised in that prepare the original of the spectacle antifogging cleaning solution
Material is included by its parts by weight：It is 13 parts of ethyl orthosilicate, 13 parts of vinyltriethoxysilane, 1.2 parts of nano-titanium dioxide, anhydrous
8 parts of 45 parts of ethanol, 3 parts of potassium sorbate, 1.5 parts of surfactant and deionized water.
3. spectacle antifogging cleaning solution according to claim 1, it is characterised in that the nano-titanium dioxide is using solidifying
High-dispersion nano titanium dioxide prepared by glue-sol method.
4. spectacle antifogging cleaning solution according to claim 3, it is characterised in that the preparation method of the nano-titanium dioxide
Include the following steps：Butyl titanate is added in absolute ethyl alcohol, nitric acid is added in the state of stirring, stirring reaction 16 is small
When~24 it is small when, vacuum drying obtain nano-titanium dioxide.
5. spectacle antifogging cleaning solution according to claim 1, it is characterised in that the surfactant is detergent alkylate
The one or two of sodium sulfonate and ethoxylated dodecyl alcohol.
A kind of 6. preparation method according to spectacle antifogging cleaning solution according to any one of claims 1 to 5, it is characterised in that
Comprise the following steps：
Nano-titanium dioxide, potassium sorbate, surfactant, are dissolved in absolute ethyl alcohol by step S10 by the parts by weight, ultrasound
Vibrating dispersion 3 minutes~5 minutes, obtains mixed liquor A；
Ethyl orthosilicate and vinyltriethoxysilane, are added in reactor by step S20 by the parts by weight, add nothing
Water-ethanol, is stirred 30 minutes~45 minutes under constant temperature, adds the deionized water of the parts by weight, adjusted with hydrochloric acid
The pH of solution to 4.0~4.5, the reaction was continued 3 it is small when~3.5 it is small when, obtain mixed liquid B；
Step S30, the temperature for adjusting mixed liquid B are 30 DEG C~40 DEG C, add mixed liquor A, are thoroughly mixed 10 minutes~15
Minute, pH to 7~8 is adjusted with saturation sodium hydroxide solution, obtains spectacle antifogging cleaning solution.
7. preparation method according to claim 6, it is characterised in that in step S10, the additive amount of the absolute ethyl alcohol is
The 1/10~1/9 of gross weight.
8. preparation method according to claim 6, it is characterised in that in step S20, the temperature of the constant temperature for 60 DEG C~
65℃。
9. preparation method according to claim 6, it is characterised in that in step S20, the additive amount of the absolute ethyl alcohol is
The 8/9~9/10 of gross weight.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711132898.8A CN107937165A (en) | 2017-11-15 | 2017-11-15 | A kind of spectacle antifogging cleaning solution and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711132898.8A CN107937165A (en) | 2017-11-15 | 2017-11-15 | A kind of spectacle antifogging cleaning solution and preparation method thereof |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112379536A (en) * | 2020-11-03 | 2021-02-19 | 浙江跃维新材料科技有限公司 | General type glasses antifogging brush and preparation method, use method and application thereof |
| CN113881252A (en) * | 2021-08-24 | 2022-01-04 | 东南大学 | Super-hydrophilic anti-fog coating with good durability and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1597810A (en) * | 2003-09-18 | 2005-03-23 | 中国科学院理化技术研究所 | Antifogging antibacterial multifunctional coating and preparation method and application thereof |
| CN1687199A (en) * | 2005-04-19 | 2005-10-26 | 华东理工大学 | Exterior coating antifogging film and preparation method |
| CN102269828A (en) * | 2010-11-01 | 2011-12-07 | 中南大学肝胆肠外科研究中心 | Preparation method of nano-optical anti-fog film |
| CN106477913A (en) * | 2016-10-21 | 2017-03-08 | 常州亚环环保科技有限公司 | A kind of preparation method of persistent form compound anti-mist film |
-
2017
- 2017-11-15 CN CN201711132898.8A patent/CN107937165A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1597810A (en) * | 2003-09-18 | 2005-03-23 | 中国科学院理化技术研究所 | Antifogging antibacterial multifunctional coating and preparation method and application thereof |
| CN1687199A (en) * | 2005-04-19 | 2005-10-26 | 华东理工大学 | Exterior coating antifogging film and preparation method |
| CN102269828A (en) * | 2010-11-01 | 2011-12-07 | 中南大学肝胆肠外科研究中心 | Preparation method of nano-optical anti-fog film |
| CN106477913A (en) * | 2016-10-21 | 2017-03-08 | 常州亚环环保科技有限公司 | A kind of preparation method of persistent form compound anti-mist film |
Non-Patent Citations (2)
| Title |
|---|
| 欧阳友生: "《工业杀菌剂》", 31 March 2001, 化学工业出版社 * |
| 筏义人: "《高分子表面的基础和应用》", 30 June 1990, 化学工业出版社 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112379536A (en) * | 2020-11-03 | 2021-02-19 | 浙江跃维新材料科技有限公司 | General type glasses antifogging brush and preparation method, use method and application thereof |
| CN113881252A (en) * | 2021-08-24 | 2022-01-04 | 东南大学 | Super-hydrophilic anti-fog coating with good durability and preparation method thereof |
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Application publication date: 20180420 |