CN107937047A - A kind of biodiesel - Google Patents

A kind of biodiesel Download PDF

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Publication number
CN107937047A
CN107937047A CN201711200453.9A CN201711200453A CN107937047A CN 107937047 A CN107937047 A CN 107937047A CN 201711200453 A CN201711200453 A CN 201711200453A CN 107937047 A CN107937047 A CN 107937047A
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CN
China
Prior art keywords
parts
emulsifying agent
biodiesel
water
methanol
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201711200453.9A
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Chinese (zh)
Inventor
蒙呈星
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Guangxi Fengtai Energy Technology Co Ltd
Original Assignee
Guangxi Fengtai Energy Technology Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Guangxi Fengtai Energy Technology Co Ltd filed Critical Guangxi Fengtai Energy Technology Co Ltd
Priority to CN201711200453.9A priority Critical patent/CN107937047A/en
Publication of CN107937047A publication Critical patent/CN107937047A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/02Liquid carbonaceous fuels essentially based on components consisting of carbon, hydrogen, and oxygen only
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/106Liquid carbonaceous fuels containing additives mixtures of inorganic compounds with organic macromolecular compounds
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/12Inorganic compounds
    • C10L1/1233Inorganic compounds oxygen containing compounds, e.g. oxides, hydroxides, acids and salts thereof
    • C10L1/125Inorganic compounds oxygen containing compounds, e.g. oxides, hydroxides, acids and salts thereof water
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/18Organic compounds containing oxygen
    • C10L1/19Esters ester radical containing compounds; ester ethers; carbonic acid esters
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/18Organic compounds containing oxygen
    • C10L1/192Macromolecular compounds
    • C10L1/198Macromolecular compounds obtained otherwise than by reactions involving only carbon-to-carbon unsaturated bonds homo- or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon to carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid
    • C10L1/1985Macromolecular compounds obtained otherwise than by reactions involving only carbon-to-carbon unsaturated bonds homo- or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon to carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid polyethers, e.g. di- polygylcols and derivatives; ethers - esters
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00Technologies for the production of fuel of non-fossil origin
    • Y02E50/10Biofuels, e.g. bio-diesel

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  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Liquid Carbonaceous Fuels (AREA)

Abstract

The invention discloses a kind of biodiesel, by weight, is made of following components:40 50 parts of castor oil;30 40 parts of methanol;30 40 parts of diesel oil;15 parts of emulsifying agent, 1 is pressed by fatty alcohol polyoxyethylene ether and methyl benzoate:2 weight ratio composition;10 20 parts of water.Proportioning of the invention by rationally designing each component, especially with the emulsifying agent of special proportioning, make it is fully emulsified between the components such as diesel oil and water, also can be synergistic between each component, make gained finished product that there is excellent efficiency of combustion (Cetane number up to more than 65);Intersolubility stablize, finished product storage more than 1 year be not in lamination.

Description

A kind of biodiesel
Technical field
The present invention relates to the fuel diesel that motor vehicle uses, and in particular to a kind of biodiesel.
Background technology
With the fast development of national economy and the raising of living standards of the people, China needs to increase increasingly to the energy, Liquid fuel using oil as raw material consumes sustainable growth.At the same time, traditional petroleum resources are increasingly deficient.Therefore, study It is imperative with exploitation alternative fuel.International vehicle fuel development trend and China's energy lower part of the body all explicitly point out, and automobile will be by Step reduces the use of fossil fuels, expands the dosage of Aalcohols fuel and bio-fuel.Hamelinck points out, at present methanol and Fischer-Tropsch method synthetic fuels are best power fuels.
At present, as the increasingly raising of economic rapid growth and living standards of the people, the environmental consciousness of people constantly increase By force, the research of the clean biometric energy has caused extensive concern.Biodiesel is that one kind is oxygen-containing, is substantially free of sulphur and aromatic hydrocarbon Green recyclable fuel.It is a kind of fuel oil of improvement, is mainly made of carbon hydrogen element, the gas harmful discharged after burning Component is seldom, is the clean biometric fuel of alternative petrifaction diesel.
Compared with traditional fossil fuel, biodiesel has unique advantage, is mainly reflected in the following aspects:One Be it is nontoxic easily decompose, good environmental protection;Second, biodiesel oxygen content is high, combustion process oxygen demand is few, it burns, ignition quality It can be better than petrifaction diesel;Third, biodiesel Cetane number is higher, the capability of antidetonance is better than petrifaction diesel;Fourth, its flash-point is higher, Be conducive to transport safely.These advantages cause biodiesel to become the hot spot of Recent study, and greatly developing biodiesel has Significance, but the Cetane number of existing biodiesel is preferable not enough.
The content of the invention
The technical problem to be solved in the present invention is to provide a kind of biodiesel with more high cetane number.
Biodiesel of the present invention, by weight, is made of following components:
40-50 parts of castor oil;
30-40 parts of methanol;
30-40 parts of diesel oil;
1-5 parts of emulsifying agent, 1 is pressed by fatty alcohol polyoxyethylene ether and methyl benzoate:2 weight ratio composition;
10-20 parts of water.
The weight proportion of each component is preferably in above-mentioned technical proposal:
40-45 parts of castor oil;
30-35 parts of methanol;
35-40 parts of diesel oil;
3-5 parts of emulsifying agent;
10-15 parts of water.
The weight proportion of optimal each component is in above-mentioned technical proposal:
40 parts of castor oil;
30 parts of methanol;
40 parts of diesel oil;
4 parts of emulsifying agent;
10 parts of water.
The preparation method of biodiesel of the present invention is same as the prior art, is preferably prepared by the following method:Will Castor oil, methanol, diesel oil, emulsifying agent and water are added sequentially in reaction kettle, stir 30-40min, are filtered, to obtain the final product.
Compared with prior art, the method have the characteristics that:The proportioning of each component is rationally designed, is matched somebody with somebody especially with special The emulsifying agent of ratio, make it is fully emulsified between the components such as diesel oil and water, also can be synergistic between each component, there is gained finished product Excellent efficiency of combustion (Cetane number up to more than 65);Intersolubility is stablized, and finished product more than 1 year is not in that layering shows in storage As.
Embodiment
With reference to specific embodiment, the present invention is described in further detail, to more fully understand present disclosure, but The present invention is not limited to following embodiments.
Number described in following embodiment is parts by weight.
The preparation method of biodiesel is described in following embodiment:By castor oil, methanol, diesel oil, emulsifying agent and water according to It is secondary to be added in reaction kettle, start blender stirring 30min, filter, to obtain the final product.
Embodiment 1
40 parts of castor oil;
30 parts of methanol;
40 parts of diesel oil;
4 parts of emulsifying agent, 1 is pressed by fatty alcohol polyoxyethylene ether and methyl benzoate:2 weight ratio composition;
10 parts of water.
Comparative example 1
As different from Example 1, emulsifying agent is fatty alcohol polyoxyethylene ether.
Comparative example 2
As different from Example 1, emulsifying agent is methyl benzoate.
Comparative example 3
As different from Example 1, emulsifying agent presses 1 by fatty alcohol polyoxyethylene ether and methyl benzoate:1 weight ratio group Into.
Comparative example 4
As different from Example 1, emulsifying agent presses 1 by fatty alcohol polyoxyethylene ether and methyl benzoate:3 weight ratio group Into.
Embodiment 2
50 parts of castor oil;
40 parts of methanol;
30 parts of diesel oil;
1 part of emulsifying agent, 1 is pressed by fatty alcohol polyoxyethylene ether and methyl benzoate:2 weight ratio composition;
15 parts of water.
Embodiment 3
45 parts of castor oil;
35 parts of methanol;
35 parts of diesel oil;
5 parts of emulsifying agent, 1 is pressed by fatty alcohol polyoxyethylene ether and methyl benzoate:2 weight ratio composition;
20 parts of water.
Biodiesel made from the various embodiments described above and each comparative example is tested for the property by GB/T20828-2007, is tied Fruit is as described in Table 1:
Table 1:

Claims (3)

1. a kind of biodiesel, by weight, is made of following components:
40-50 parts of castor oil;
30-40 parts of methanol;
30-40 parts of diesel oil;
1-5 parts of emulsifying agent, 1 is pressed by fatty alcohol polyoxyethylene ether and methyl benzoate:2 weight ratio composition;
10-20 parts of water.
2. biodiesel according to claim 1, it is characterised in that:The weight proportion of each component is:
40-45 parts of castor oil;
30-35 parts of methanol;
35-40 parts of diesel oil;
3-5 parts of emulsifying agent;
10-15 parts of water.
3. according to the biodiesel described in claim 1, it is characterised in that:The weight proportion of each component is:
40 parts of castor oil;
30 parts of methanol;
40 parts of diesel oil;
4 parts of emulsifying agent;
10 parts of water.
CN201711200453.9A 2017-11-24 2017-11-24 A kind of biodiesel Pending CN107937047A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201711200453.9A CN107937047A (en) 2017-11-24 2017-11-24 A kind of biodiesel

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201711200453.9A CN107937047A (en) 2017-11-24 2017-11-24 A kind of biodiesel

Publications (1)

Publication Number Publication Date
CN107937047A true CN107937047A (en) 2018-04-20

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
CN201711200453.9A Pending CN107937047A (en) 2017-11-24 2017-11-24 A kind of biodiesel

Country Status (1)

Country Link
CN (1) CN107937047A (en)

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1031104A (en) * 1987-08-01 1989-02-15 天津大学 Series of fuel combustion improving agent for diesel engine fuel
CN103881770A (en) * 2014-03-21 2014-06-25 高建华 Energy-saving low-emission biodiesel
CN102653690B (en) * 2011-03-04 2014-12-03 徐海野 Environmentally-friendly, efficient and low-cost alcohol-oil synthetic fuel
CN104357101A (en) * 2014-11-06 2015-02-18 金景达(北京)环保动力科技有限公司 High-efficiency stable composite biodiesel fuel

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1031104A (en) * 1987-08-01 1989-02-15 天津大学 Series of fuel combustion improving agent for diesel engine fuel
CN102653690B (en) * 2011-03-04 2014-12-03 徐海野 Environmentally-friendly, efficient and low-cost alcohol-oil synthetic fuel
CN103881770A (en) * 2014-03-21 2014-06-25 高建华 Energy-saving low-emission biodiesel
CN104357101A (en) * 2014-11-06 2015-02-18 金景达(北京)环保动力科技有限公司 High-efficiency stable composite biodiesel fuel

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