CN107936654A - A kind of composite pigment formula and processing technology of good weatherability - Google Patents
A kind of composite pigment formula and processing technology of good weatherability Download PDFInfo
- Publication number
- CN107936654A CN107936654A CN201711395972.5A CN201711395972A CN107936654A CN 107936654 A CN107936654 A CN 107936654A CN 201711395972 A CN201711395972 A CN 201711395972A CN 107936654 A CN107936654 A CN 107936654A
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- parts
- pigment
- agent
- good weatherability
- mica powder
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/06—Artists' paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D105/00—Coating compositions based on polysaccharides or on their derivatives, not provided for in groups C09D101/00 or C09D103/00
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D189/00—Coating compositions based on proteins; Coating compositions based on derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D201/00—Coating compositions based on unspecified macromolecular compounds
- C09D201/02—Coating compositions based on unspecified macromolecular compounds characterised by the presence of specified groups, e.g. terminal or pendant functional groups
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D4/00—Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
- C09D4/06—Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09D159/00 - C09D187/00
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Paints Or Removers (AREA)
- Pigments, Carbon Blacks, Or Wood Stains (AREA)
- Cosmetics (AREA)
Abstract
The present invention relates to pigment production technical field, the composite pigment formula of especially a kind of good weatherability, its raw material is formulated as follows in parts by weight:35 parts of pigment powder, 25 parts of pigment dispersing agent, 35 parts of starch stearate, 24 parts of sodium trimetaphosphate, 14 parts of auxiliary agent, 24 parts of weather resisting agent, 10 15 parts of epoxy glue, 25 parts of flaky mica powder.The invention also provides a kind of production technology of the composite pigment of good weatherability.The present invention is made paints using environment friendly and pollution-free component, can be reduced the infringement to environment, in addition be with the addition of weather resisting agent, effectively improve the weather resistance of pigment, reduces its oxidation being subject to, and improves final product quality.
Description
Technical field
The present invention relates to pigment production technical field, more particularly to a kind of composite pigment formula of good weatherability and production work
Skill.
Background technology
Pigment (Pigment) is used for the powdered substance coloured.In the media such as water, grease, resin, organic solvent not
Dissolving, but can equably disperse in these media and medium can be coloured, and there is certain covering power.The face of the fine arts
Expect that basic demand particle is more fine and smooth better, color is more bright-coloured better, and more sustained color is better (stability will be got well).Watercolor
The watercolors of pigment are nearly all transparent except white.It could so meet the needs of watercolor cover dye.Gouache color is initial
It is the powder that white is added in watercolors, makes color opaque and invent.Since watercolors are transparent, so one
It is difficult modification that denier, which is drawn wrong,.And gouache color can be changed easily very much due to opaque.Added again in gouache color later
The raw materials such as Arabic gum further improve its performance.Pigment weatherability of the prior art is poor, easily discoloration and oxygen
Change.
The content of the invention
The purpose of the present invention is to solve shortcoming existing in the prior art, and a kind of good weatherability proposed is compound
Pigment formula and production technology.
To achieve these goals, present invention employs following technical solution:
A kind of composite pigment formula of good weatherability is designed, its raw material is formulated as follows in parts by weight:
3-5 parts of pigment powder, 2-5 parts of pigment dispersing agent, 3-5 parts of starch stearate, 2-4 parts of sodium trimetaphosphate, 1-4 parts of auxiliary agent,
2-4 parts of weather resisting agent, 10-15 parts of epoxy glue, 2-5 parts of flaky mica powder.
Preferably, its raw material is formulated as follows in parts by weight:
3-4 parts of pigment powder, 2-4 parts of pigment dispersing agent, 3-4 parts of starch stearate, 3-4 parts of sodium trimetaphosphate, 2-4 parts of auxiliary agent,
2-3 parts of weather resisting agent, 12-14 parts of epoxy glue, 3-4 parts of flaky mica powder.
Preferably, its raw material is formulated as follows in parts by weight:
It is 3.5 parts of pigment powder, 3 parts of pigment dispersing agent, 3.5 parts of starch stearate, 3.5 parts of sodium trimetaphosphate, 3 parts of auxiliary agent, weather-proof
2.5 parts of agent, 13 parts of epoxy glue, 3.5 parts of flaky mica powder.
Preferably, auxiliary agent is made of dispersant, preservative, defoamer, moisturizing emulsifying agent and film forming agent, dispersant, anti-corrosion
Agent, defoamer, the weight ratio of moisturizing emulsifying agent and film forming agent are 2:2:1:1:1.
Preferably, emulsifying agent be sorbose alcohol ester, soybean lecithin, lauric monoglyceride mixture, it is sorbose alcohol ester, big
Fabaceous Lecithin, lauric monoglyceride weight ratio are 1:1:3.
Preferably, epoxy glue is the mixture of natural plant gum, animal glue and shadowless glue, natural plant gum, animal glue and shadowless glue
Weight ratio is 1:1:1.
Preferably, weather resisting agent component is in parts by weight:The double 20-30 of 20-30 parts of nonyl phenyl ester, thio-2 acid
Part, 4-30 parts of ESCALOL 567,2-5 parts of dispersant.
The invention also provides a kind of production technology of the composite pigment of good weatherability, comprise the following steps:
S1, flaky mica powder surface preparation:Flaky mica powder is inserted in the mixed solution of absolute ethyl alcohol and acetone and is stirred, with
Greasy dirt, the impurity on mica powder surface are removed, then flaky mica powder is filtered and is taken out, it is spare after making mixed solution volatilization clean;
S2, add epoxy glue, auxiliary agent, flaky mica powder into mixing kettle, maintains temperature to stir 15min at 45 ± 5 DEG C;
S3, add starch stearate, sodium trimetaphosphate into mixing kettle, is heated to 55-65 DEG C, maintains 10min;
S4, add pigment powder, pigment dispersing agent, weather resisting agent into mixing kettle, is heated to 75-85 DEG C, persistently stirs 15min;
S5, be cooled to 25-35 DEG C, stands 1-3h and obtains pigment finished product.
A kind of composite pigment formula and processing technology of good weatherability proposed by the present invention, beneficial effect are:The present invention
Made paints using environment friendly and pollution-free component, the infringement to environment can be reduced, in addition with the addition of weather resisting agent, effectively improve face
The weather resistance of material, reduces its oxidation being subject to, and improves final product quality.
Embodiment
The technical solution in the embodiment of the present invention is clearly and completely described below, it is clear that described embodiment
Only part of the embodiment of the present invention, instead of all the embodiments.
Embodiment 1
A kind of composite pigment formula of good weatherability, its raw material are formulated as follows in parts by weight:
3 parts of pigment powder, 2 parts of pigment dispersing agent, 3 parts of starch stearate, 2 parts of sodium trimetaphosphate, 1 part of auxiliary agent, 2 parts of weather resisting agent,
10 parts of epoxy glue, 2 parts of flaky mica powder.
Auxiliary agent is made of dispersant, preservative, defoamer, moisturizing emulsifying agent and film forming agent, dispersant, preservative, defoaming
The weight ratio of agent, moisturizing emulsifying agent and film forming agent is 2:2:1:1:1.
Emulsifying agent for sorbose alcohol ester, soybean lecithin, lauric monoglyceride mixture, sorbose alcohol ester, soybean lecithin,
Lauric monoglyceride weight ratio is 1:1:3.
Epoxy glue is the mixture of natural plant gum, animal glue and shadowless glue, and the weight ratio of natural plant gum, animal glue and shadowless glue is
1:1:1。
Weather resisting agent component is in parts by weight:20 parts of nonyl phenyl ester, thio-2 acid double 20 parts, 2- hydroxyl -4- first
4 parts of epoxide benzophenone, 2 parts of dispersant.
The invention also provides a kind of production technology of the composite pigment of good weatherability, comprise the following steps:
S1, flaky mica powder surface preparation:Flaky mica powder is inserted in the mixed solution of absolute ethyl alcohol and acetone and is stirred, with
Greasy dirt, the impurity on mica powder surface are removed, then flaky mica powder is filtered and is taken out, it is spare after making mixed solution volatilization clean;
S2, add epoxy glue, auxiliary agent, flaky mica powder into mixing kettle, maintains temperature to stir 15min at 45 ± 5 DEG C;
S3, add starch stearate, sodium trimetaphosphate into mixing kettle, is heated to 55 DEG C, maintains 10min;
S4, add pigment powder, pigment dispersing agent, weather resisting agent into mixing kettle, is heated to 75 DEG C, persistently stirs 15min;
S5, be cooled to 25 DEG C, stands 1h and obtains pigment finished product.
Embodiment 2
A kind of composite pigment formula of good weatherability, its raw material are formulated as follows in parts by weight:
3 parts of pigment powder, 2 parts of pigment dispersing agent, 3 parts of starch stearate, 3 parts of sodium trimetaphosphate, 2 parts of auxiliary agent, 2 parts of weather resisting agent,
12 parts of epoxy glue, 3 parts of flaky mica powder.
Auxiliary agent is made of dispersant, preservative, defoamer, moisturizing emulsifying agent and film forming agent, dispersant, preservative, defoaming
The weight ratio of agent, moisturizing emulsifying agent and film forming agent is 2:2:1:1:1.
Emulsifying agent for sorbose alcohol ester, soybean lecithin, lauric monoglyceride mixture, sorbose alcohol ester, soybean lecithin,
Lauric monoglyceride weight ratio is 1:1:3.
Epoxy glue is the mixture of natural plant gum, animal glue and shadowless glue, and the weight ratio of natural plant gum, animal glue and shadowless glue is
1:1:1。
Weather resisting agent component is in parts by weight:22 parts of nonyl phenyl ester, thio-2 acid double 22 parts, 2- hydroxyl -4- first
8 parts of epoxide benzophenone, 3 parts of dispersant.
The invention also provides a kind of production technology of the composite pigment of good weatherability, comprise the following steps:
S1, flaky mica powder surface preparation:Flaky mica powder is inserted in the mixed solution of absolute ethyl alcohol and acetone and is stirred, with
Greasy dirt, the impurity on mica powder surface are removed, then flaky mica powder is filtered and is taken out, it is spare after making mixed solution volatilization clean;
S2, add epoxy glue, auxiliary agent, flaky mica powder into mixing kettle, maintains temperature to stir 15min at 45 ± 5 DEG C;
S3, add starch stearate, sodium trimetaphosphate into mixing kettle, is heated to 58 DEG C, maintains 10min;
S4, add pigment powder, pigment dispersing agent, weather resisting agent into mixing kettle, is heated to 80 DEG C, persistently stirs 15min;
S5, be cooled to 28 DEG C, stands 2h and obtains pigment finished product.
Embodiment 3
A kind of composite pigment formula of good weatherability, its raw material are formulated as follows in parts by weight:
It is 3.5 parts of pigment powder, 3 parts of pigment dispersing agent, 3.5 parts of starch stearate, 3.5 parts of sodium trimetaphosphate, 3 parts of auxiliary agent, weather-proof
2.5 parts of agent, 13 parts of epoxy glue, 3.5 parts of flaky mica powder.
Auxiliary agent is made of dispersant, preservative, defoamer, moisturizing emulsifying agent and film forming agent, dispersant, preservative, defoaming
The weight ratio of agent, moisturizing emulsifying agent and film forming agent is 2:2:1:1:1.
Emulsifying agent for sorbose alcohol ester, soybean lecithin, lauric monoglyceride mixture, sorbose alcohol ester, soybean lecithin,
Lauric monoglyceride weight ratio is 1:1:3.
Epoxy glue is the mixture of natural plant gum, animal glue and shadowless glue, and the weight ratio of natural plant gum, animal glue and shadowless glue is
1:1:1。
Weather resisting agent component is in parts by weight:28 parts of nonyl phenyl ester, thio-2 acid double 28 parts, 2- hydroxyl -4- first
20 parts of epoxide benzophenone, 4 parts of dispersant.
The invention also provides a kind of production technology of the composite pigment of good weatherability, comprise the following steps:
S1, flaky mica powder surface preparation:Flaky mica powder is inserted in the mixed solution of absolute ethyl alcohol and acetone and is stirred, with
Greasy dirt, the impurity on mica powder surface are removed, then flaky mica powder is filtered and is taken out, it is spare after making mixed solution volatilization clean;
S2, add epoxy glue, auxiliary agent, flaky mica powder into mixing kettle, maintains temperature to stir 15min at 45 ± 5 DEG C;
S3, add starch stearate, sodium trimetaphosphate into mixing kettle, is heated to 58 DEG C, maintains 10min;
S4, add pigment powder, pigment dispersing agent, weather resisting agent into mixing kettle, is heated to 78 DEG C, persistently stirs 15min;
S5, be cooled to 28 DEG C, stands 2h and obtains pigment finished product.
Embodiment 4
A kind of composite pigment formula of good weatherability, its raw material are formulated as follows in parts by weight:
5 parts of pigment powder, 5 parts of pigment dispersing agent, 5 parts of starch stearate, 4 parts of sodium trimetaphosphate, 4 parts of auxiliary agent, 4 parts of weather resisting agent,
15 parts of epoxy glue, 5 parts of flaky mica powder.
Auxiliary agent is made of dispersant, preservative, defoamer, moisturizing emulsifying agent and film forming agent, dispersant, preservative, defoaming
The weight ratio of agent, moisturizing emulsifying agent and film forming agent is 2:2:1:1:1.
Emulsifying agent for sorbose alcohol ester, soybean lecithin, lauric monoglyceride mixture, sorbose alcohol ester, soybean lecithin,
Lauric monoglyceride weight ratio is 1:1:3.
Epoxy glue is the mixture of natural plant gum, animal glue and shadowless glue, and the weight ratio of natural plant gum, animal glue and shadowless glue is
1:1:1。
Weather resisting agent component is in parts by weight:30 parts of nonyl phenyl ester, thio-2 acid double 30 parts, 2- hydroxyl -4- first
30 parts of epoxide benzophenone, 5 parts of dispersant.
The invention also provides a kind of production technology of the composite pigment of good weatherability, comprise the following steps:
S1, flaky mica powder surface preparation:Flaky mica powder is inserted in the mixed solution of absolute ethyl alcohol and acetone and is stirred, with
Greasy dirt, the impurity on mica powder surface are removed, then flaky mica powder is filtered and is taken out, it is spare after making mixed solution volatilization clean;
S2, add epoxy glue, auxiliary agent, flaky mica powder into mixing kettle, maintains temperature to stir 15min at 45 ± 5 DEG C;
S3, add starch stearate, sodium trimetaphosphate into mixing kettle, is heated to 65 DEG C, maintains 10min;
S4, add pigment powder, pigment dispersing agent, weather resisting agent into mixing kettle, is heated to 85 DEG C, persistently stirs 15min;
S5, be cooled to 35 DEG C, stands 3h and obtains pigment finished product.
The foregoing is only a preferred embodiment of the present invention, but protection scope of the present invention be not limited thereto,
Any one skilled in the art the invention discloses technical scope in, technique according to the invention scheme and its
Inventive concept is subject to equivalent substitution or change, should be covered by the protection scope of the present invention.
Claims (8)
1. the composite pigment formula of a kind of good weatherability, it is characterised in that its raw material is formulated as follows in parts by weight:
3-5 parts of pigment powder, 2-5 parts of pigment dispersing agent, 3-5 parts of starch stearate, 2-4 parts of sodium trimetaphosphate, 1-4 parts of auxiliary agent,
2-4 parts of weather resisting agent, 10-15 parts of epoxy glue, 2-5 parts of flaky mica powder.
2. the composite pigment formula of a kind of good weatherability according to claim 1, it is characterised in that its raw material is according to weight
Number meter formula is as follows:
3-4 parts of pigment powder, 2-4 parts of pigment dispersing agent, 3-4 parts of starch stearate, 3-4 parts of sodium trimetaphosphate, 2-4 parts of auxiliary agent,
2-3 parts of weather resisting agent, 12-14 parts of epoxy glue, 3-4 parts of flaky mica powder.
3. the composite pigment formula of a kind of good weatherability according to claim 1, it is characterised in that its raw material is according to weight
Number meter formula is as follows:
It is 3.5 parts of pigment powder, 3 parts of pigment dispersing agent, 3.5 parts of starch stearate, 3.5 parts of sodium trimetaphosphate, 3 parts of auxiliary agent, weather-proof
2.5 parts of agent, 13 parts of epoxy glue, 3.5 parts of flaky mica powder.
A kind of 4. composite pigment formula of good weatherability according to claim 1, it is characterised in that:Auxiliary agent by dispersant,
Preservative, defoamer, moisturizing emulsifying agent and film forming agent composition, dispersant, preservative, defoamer, moisturizing emulsifying agent and film forming agent
Weight ratio be 2:2:1:1:1.
A kind of 5. composite pigment formula of good weatherability according to claim 4, it is characterised in that:Emulsifying agent is sorbose
Alcohol ester, soybean lecithin, lauric monoglyceride mixture, sorbose alcohol ester, soybean lecithin, lauric monoglyceride weight ratio are
1:1:3。
A kind of 6. composite pigment formula of good weatherability according to claim 1, it is characterised in that:Epoxy glue is plant
The mixture of glue, animal glue and shadowless glue, the weight ratio of natural plant gum, animal glue and shadowless glue is 1:1:1.
A kind of 7. composite pigment formula of good weatherability according to claim 1, it is characterised in that weather resisting agent component according to
Parts by weight are calculated as:20-30 parts of nonyl phenyl ester, thio-2 acid double 20-30 parts, ESCALOL 567 4-30
Part, 2-5 parts of dispersant.
8. the production technology of the composite pigment of a kind of good weatherability according to claim 1, it is characterised in that including following
Step:
S1, flaky mica powder surface preparation:Flaky mica powder is inserted in the mixed solution of absolute ethyl alcohol and acetone and is stirred, with
Greasy dirt, the impurity on mica powder surface are removed, then flaky mica powder is filtered and is taken out, it is spare after making mixed solution volatilization clean;
S2, add epoxy glue, auxiliary agent, flaky mica powder into mixing kettle, maintains temperature to stir 15min at 45 ± 5 DEG C;
S3, add starch stearate, sodium trimetaphosphate into mixing kettle, is heated to 55-65 DEG C, maintains 10min;
S4, add pigment powder, pigment dispersing agent, weather resisting agent into mixing kettle, is heated to 75-85 DEG C, persistently stirs 15min;
S5, be cooled to 25-35 DEG C, stands 1-3h and obtains pigment finished product.
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CN201711395972.5A CN107936654A (en) | 2017-12-21 | 2017-12-21 | A kind of composite pigment formula and processing technology of good weatherability |
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CN201711395972.5A CN107936654A (en) | 2017-12-21 | 2017-12-21 | A kind of composite pigment formula and processing technology of good weatherability |
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109251045A (en) * | 2018-09-18 | 2019-01-22 | 明光瑞尔非金属材料有限公司 | A kind of color-adjustable refractory brick and preparation method thereof |
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CN1654556A (en) * | 2005-02-23 | 2005-08-17 | 王建强 | Luminous rock color painting and its product and preparation method |
CN101531840A (en) * | 2009-04-16 | 2009-09-16 | 宋阳 | Colored daub painting pigment and process for preparing same |
CN105017829A (en) * | 2015-06-30 | 2015-11-04 | 河南行知专利服务有限公司 | Biological environmental-friendly pigment used for artistic designing |
CN107201673A (en) * | 2017-06-05 | 2017-09-26 | 南通祥升纱业有限公司 | Modified pigment formula is used in one kind weaving |
-
2017
- 2017-12-21 CN CN201711395972.5A patent/CN107936654A/en active Pending
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1654556A (en) * | 2005-02-23 | 2005-08-17 | 王建强 | Luminous rock color painting and its product and preparation method |
CN101531840A (en) * | 2009-04-16 | 2009-09-16 | 宋阳 | Colored daub painting pigment and process for preparing same |
CN105017829A (en) * | 2015-06-30 | 2015-11-04 | 河南行知专利服务有限公司 | Biological environmental-friendly pigment used for artistic designing |
CN107201673A (en) * | 2017-06-05 | 2017-09-26 | 南通祥升纱业有限公司 | Modified pigment formula is used in one kind weaving |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109251045A (en) * | 2018-09-18 | 2019-01-22 | 明光瑞尔非金属材料有限公司 | A kind of color-adjustable refractory brick and preparation method thereof |
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