CN107936461A - A kind of low gloss low noise ABS resin composition - Google Patents

A kind of low gloss low noise ABS resin composition Download PDF

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Publication number
CN107936461A
CN107936461A CN201711319457.9A CN201711319457A CN107936461A CN 107936461 A CN107936461 A CN 107936461A CN 201711319457 A CN201711319457 A CN 201711319457A CN 107936461 A CN107936461 A CN 107936461A
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China
Prior art keywords
abs resin
resin composition
low noise
low gloss
low
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CN201711319457.9A
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Chinese (zh)
Inventor
孙付宇
李欣
李文龙
钱文轩
刘纪庆
张海洋
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Tianjin Kingfa Advanced Materials Co Ltd
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Tianjin Kingfa Advanced Materials Co Ltd
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Priority to CN201711319457.9A priority Critical patent/CN107936461A/en
Publication of CN107936461A publication Critical patent/CN107936461A/en
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L55/00Compositions of homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C08L23/00 - C08L53/00
    • C08L55/02ABS [Acrylonitrile-Butadiene-Styrene] polymers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/08Polymer mixtures characterised by other features containing additives to improve the compatibility between two polymers

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The present invention provides a kind of low gloss low noise ABS resin composition, said composition is made of the raw material including following parts by weight:61 99 parts of ABS resin, 0 20 parts of heat-resistant agent, 5 15 parts of compatilizer, 03 parts of delustering agent, 5 10 parts of improvement of damping resin, 1 1.3 parts of auxiliary agent.Low gloss low noise ABS resin composition of the present invention assigns its noise reduction performance by high-damping resin to improve the damping and amortization of ABS resin, the suitable compatilizer of simultaneous selection improves the compatibility between blending resin, obtained ABS resin composition has relatively low glossiness, and has excellent mechanical property and processing performance;Preparation process is simple, and equipment requirement is low, is adapted to industrialized production, can be widely applied to the fields such as vehicle appliance.

Description

A kind of low gloss low noise ABS resin composition
Technical field
The invention belongs to polymeric material field, more particularly, to a kind of low gloss low noise ABS resin composition.
Background technology
ABS is acrylonitrile-butadiene-styrene terpolymer, by polystyrene (PS), styrene-acrylonitrile (SAN), The various performances of styrene (BS) are organically united, and since ABS resin has coordinated the superior function of three kinds of components, it has concurrently Tough, firmly, the excellent mechanical property of just phase equilibrium, good processing performance and chemical stability, are readily molded into type, and have concurrently tough Property and flexibility, high comprehensive performance.It is widely used in the row such as auto industry, electronic apparatus industry, light industry household electrical appliances, weaving and building Industry.
In recent years, automobile industry is higher and higher to the attention rate of in-car noise, and in-car noise is mainly derived from in-car Friction between the extruding of conjunction component and component, in-car noise directly influence the physical and mental health of driver and passenger compared with conference, Even influence whether the security driven.Automotive interior material generally has the requirement of dumb light, so advantageously reduces driver Visual fatigue, so as to improve drive safety.The glossiness on surface is higher, and it is real to need the secondary operation such as spray dumb light paint Existing dumb light and beautiful effect.With the raising of environmental requirement dynamics, being directly molded into the scheme of low gloss product not only can be with Environmental pollution caused by reducing painting process, and cost can be greatly reduced, improve production efficiency.
In order to improve the noise problem of in-car, usual way is to reduce noise using lubricating grease or patch felt, but It is the tedious process of this method, of high cost, and it is unable to reach persistent noise resistance effect.Chinese patent CN1583864A is sent out Understand a kind of car sound-proof damping noise reduction thermoplastic sheets, by pouring into a mould flexible polyurethane foams below product, make sheet material The sound-proof damping acoustic damping materials as vehicle are integrally formed with foam.Chinese patent CN102229736A discloses a kind of lightweight drop Make an uproar modified ABS material, add the inorganic filler of hollow granule type in the invention in formula, the special construction of hollow granule makes Material has certain decrease of noise functions, while density of material is very low, has for automotive light weight technology and damping noise reduction etc. very high Application value.
The product for being not only, in the other field such as automotive field, household electrical appliances, electronic apparatus, to reduce noise undoubtedly can be to consumer More healthy comfortable experience is brought, the acoustic damping materials of invention design high-damping are imperative.ABS material is widely used in multiple National field, therefore the ABS resin for developing design noise reduction has important value and significance.
The content of the invention
In view of this, the present invention is directed to propose a kind of low gloss low noise ABS resin composition, there is high damping can drop Low noise, reduces the ABS resin composition of abnormal sound.
To reach above-mentioned purpose, the technical proposal of the invention is realized in this way:
A kind of low gloss low noise ABS resin composition, said composition are made of the raw material including following parts by weight:
Preferably, the composition is made of the raw material including following parts by weight:
Further, the ABS resin is the mixing of one or both of polymerisation in bulk or emulsion polymerization ABS resin Thing.
Further, the heat-resistant agent is N-phenylmaleimide polymer.
Further, the compatilizer is SAN graft modification resins.
Further, the delustering agent is wollastonite or mica powder.
Further, the improvement of damping resin is maleic anhydride grafted polyurethane resin or methyl propenoic acid glycidyl The mixture of one or both of ester grafted polyurethane resin.
Further, the auxiliary agent is one or more of mixing in antioxidant, light stabilizer, lubricant or toner Thing;The antioxidant is one kind in Hinered phenols or phosphite ester kind antioxidant;The light stabilizer is benzotriazole The combination of class UV absorbents and high molecular weight hindered amine light stabilizer, the benzotriazole uv absorbers and high molecular weight by The mass ratio for hindering amine light stabilizer is 1:1;The lubricant is pentaerythritol stearate.
The preparation method of the low gloss low noise ABS resin composition, includes the following steps:By ABS resin, heat-resisting Agent, compatilizer, delustering agent, improvement of damping resin, auxiliary agent are uniformly mixed, and are then added in double screw extruder, by melting Blending extrusion is granulated up to the low gloss low noise ABS resin composition.
The purposes of the low gloss low noise ABS resin composition, the composition are applied to automobile and household electrical appliances row Industry.
Relative to the prior art, low gloss low noise ABS resin composition of the present invention has the advantage that:
Low gloss low noise ABS resin composition of the present invention improves the resistance of ABS resin by high-damping resin Buddhist nun's property and assign its noise reduction performance, the suitable compatilizer of simultaneous selection improves the compatibility between blending resin, obtained ABS trees Oil/fat composition has relatively low glossiness, and has excellent mechanical property and processing performance;Preparation process is simple, equipment requirement It is low, it is adapted to industrialized production, can be widely applied to the fields such as vehicle appliance.
Embodiment
In addition to being defined, technical term used has universal with those skilled in the art of the invention in following embodiments The identical meanings of understanding.Test reagent used, is routine biochemistry reagent unless otherwise specified in following embodiments;It is described Experimental method, is conventional method unless otherwise specified.
ABS resin 1 selects continuous bulk production, Shanghai Gaoqiao petro-chemical corporation, trade mark ABS in the embodiment described 3325MT;
ABS resin 2 selects emulsion method production, platform, trade mark ABS AG15A1 in the embodiment described;
Heat-resistant agent selects N-phenylmaleimide polymer, Japan Electric chemistry, trade mark MS- in the embodiment described NI;
Compatilizer selects SAN-g-GMA resins, the liter of Nantong day, trade mark SAG-005 in the embodiment described;
Delustering agent selects mica powder in the embodiment described, and Jiangmen city essence reaches mica material Co., Ltd, trade mark HYC500; Wollastonite, Dalian is firm to reach fine mineral Co., Ltd, trade mark YW-8A
Improvement of damping Choice of Resin TPU-g-MAH resins in the embodiment described, refreshing field particle science and technology;
In the embodiment described antioxidant selection hindered phenol antioxygen and phosphite ester kind antioxidant mixture, be by The production of Ciba companies provides;
Light stabilizer presses 1 by UV absorbers and high molecular weight hindered amine in the embodiment described:1 mixing, wherein purple Outer absorbent is selected from the Tinuvin 328 of Ciba companies, and high molecular weight hindered amine is selected from the CHIMASSORB of Ciba companies 944FDL;
Lubricant is pentaerythritol stearate in the embodiment described, is to be produced to provide by LOZA companies, the trade mark is GLYCOLUBE-P。
With reference to embodiment, the present invention will be described in detail.
Embodiment 1
A kind of low gloss low noise ABS resin composition, said composition are made of the raw material including following parts by weight:ABS 1 87 parts of resin, 5 parts of compatilizer, 2 parts of delustering agent, 5 parts of improvement of damping resin, 0.5 part of light stabilizer, 0.2 part of antioxidant, lubrication 0.3 part of agent.
The preparation method of the low gloss low noise ABS resin composition, includes the following steps:By ABS resin 1, phase Appearance agent, delustering agent, improvement of damping resin, light stabilizer, antioxidant, lubrication prescription are uniformly mixed, and are then added to double screw extruder In the main barrel of (screw diameter 35mm, draw ratio L/D=48), each section of control temperature of main barrel (goes out from charge door to head Mouthful) it is respectively 220 DEG C, 230 DEG C, 240 DEG C, 245 DEG C, 240 DEG C, twin-screw rotating speed is 300 revs/min, is squeezed by melt blending Go out to be granulated up to the low gloss low noise ABS resin composition.
Embodiment 2
A kind of low gloss low noise ABS resin composition, said composition are made of the raw material including following parts by weight:ABS 1 81.7 parts of resin, 5 parts of compatilizer, 2 parts of delustering agent, 10 parts of improvement of damping resin, 0.5 part of light stabilizer, 0.5 part of antioxidant, 0.3 part of lubricant.
The preparation method of the low gloss low noise ABS resin composition, includes the following steps:By ABS resin 1, phase Appearance agent, delustering agent, improvement of damping resin, light stabilizer, antioxidant, lubrication prescription are uniformly mixed, and are then added to double screw extruder In the main barrel of (screw diameter 35mm, draw ratio L/D=48), each section of control temperature of main barrel (goes out from charge door to head Mouthful) it is respectively 220 DEG C, 230 DEG C, 240 DEG C, 245 DEG C, 240 DEG C, twin-screw rotating speed is 300 revs/min, is squeezed by melt blending Go out to be granulated up to the low gloss low noise ABS resin composition.
Embodiment 3
A kind of low gloss low noise ABS resin composition, said composition are made of the raw material including following parts by weight:ABS 1 71.7 parts of resin, 2 10 parts of ABS resin, 10 parts of compatilizer, 2 parts of delustering agent, 5 parts of improvement of damping resin, light stabilizer 0.5 Part, 0.5 part of antioxidant, 0.3 part of lubricant.
The preparation method of the low gloss low noise ABS resin composition, includes the following steps:By ABS resin 1, ABS Resin 2, compatilizer, delustering agent, improvement of damping resin, light stabilizer, antioxidant, lubrication prescription are uniformly mixed, and are then added to double spiral shells In the main barrel of bar extruder (screw diameter 35mm, draw ratio L/D=48), each section of control temperature of main barrel is (from charge door Exported to head) it is respectively 220 DEG C, 230 DEG C, 240 DEG C, 245 DEG C, 240 DEG C, twin-screw rotating speed is 300 revs/min, through superfusion Melt blending extrusion to be granulated up to the low gloss low noise ABS resin composition.
Embodiment 4
A kind of low gloss low noise ABS resin composition, said composition are made of the raw material including following parts by weight:ABS 1 56.8 parts of resin, 5 parts of ABS resin, 15 parts of compatilizer, 2 parts of delustering agent, 10 parts of improvement of damping resin, 10 parts of heat-resistant agent, light is steady Determine 0.5 part of agent, 0.2 part of antioxidant, 0.5 part of lubricant.
The preparation method of the low gloss low noise ABS resin composition, includes the following steps:By ABS resin 1, ABS Resin 2, compatilizer, delustering agent, improvement of damping resin, heat-resistant agent, light stabilizer, antioxidant, lubrication prescription are uniformly mixed, and are then added Into the main barrel of double screw extruder (screw diameter 35mm, draw ratio L/D=48), each section of control temperature of main barrel (from Charge door to head exports) it is respectively 220 DEG C, 230 DEG C, 240 DEG C, 245 DEG C, 240 DEG C, twin-screw rotating speed is 300 revs/min, By melt blending extruding pelletization up to the low gloss low noise ABS resin composition.
Embodiment 5
A kind of low gloss low noise ABS resin composition, said composition are made of the raw material including following parts by weight:ABS 1 51 parts of resin, 10 parts of ABS resin, 10 parts of compatilizer, 3 parts of delustering agent, improvement of damping resin 5,20 parts of heat-resistant agent, light stabilizer 0.5 part, 0.2 part of antioxidant, 0.3 part of lubricant.
The preparation method of the low gloss low noise ABS resin composition, includes the following steps:By ABS resin 1, ABS Resin 2, compatilizer, delustering agent, improvement of damping resin, heat-resistant agent, light stabilizer, antioxidant, lubrication prescription are uniformly mixed, and are then added Into the main barrel of double screw extruder (screw diameter 35mm, draw ratio L/D=48), each section of control temperature of main barrel (from Charge door to head exports) it is respectively 220 DEG C, 230 DEG C, 240 DEG C, 245 DEG C, 240 DEG C, twin-screw rotating speed is 300 revs/min, By melt blending extruding pelletization up to the low gloss low noise ABS resin composition.
Comparative example 1
A kind of ABS resin composition, said composition are made of the raw material including following parts by weight:1 99 parts of ABS resin, light 0.5 part of stabilizer, 0.2 part of antioxidant, 0.3 part of lubricant.
The preparation method of the low gloss low noise ABS resin composition, includes the following steps:By ABS resin 1, light Stabilizer, antioxidant, lubrication prescription are uniformly mixed, and are then added to double screw extruder (screw diameter 35mm, draw ratio L/D= 48) in main barrel, each section of main barrel control temperature (being exported from charge door to head) is respectively 220 DEG C, 230 DEG C, 240 DEG C, 245 DEG C, 240 DEG C, twin-screw rotating speed is 300 revs/min, by melt blending extruding pelletization up to the low gloss low noise ABS resin composition.
Comparative example 2
A kind of ABS resin composition, said composition are made of the raw material including following parts by weight:1 73.8 parts of ABS resin, 10 parts of ABS resin, 5 parts of compatilizer, 10 parts of heat-resistant agent, 0.5 part of light stabilizer, 0.2 part of antioxidant, 0.5 part of lubricant.
The preparation method of the low gloss low noise ABS resin composition, includes the following steps:By ABS resin 1, ABS Resin 2, compatilizer, heat-resistant agent, light stabilizer, antioxidant, lubrication prescription are uniformly mixed, and are then added to double screw extruder (screw rod A diameter of 35mm, draw ratio L/D=48) main barrel in, each section of main barrel control temperature (being exported from charge door to head) point Wei not be 220 DEG C, 230 DEG C, 240 DEG C, 245 DEG C, 240 DEG C, twin-screw rotating speed is 300 revs/min, by melt blending extruding pelletization Up to the low gloss low noise ABS resin composition.
By product made from embodiment 1-5 and comparative example 1-2 in convection oven in 80 DEG C it is dry 4 it is small when after, use plastics Injection (mo(u)lding) machine is molded into iso standard batten, tertia card and 100mm*100mm*3mm models, and injection temperature is 240 DEG C;Will The batten and model of injection formed 50% relative humidity, 23 DEG C place at least 24 it is small when after be tested for the property.
Properties of product test method is as follows:
Charpy impact strengths, are tested according to 179 standards of ISO;
Vicat softening point, is tested according to 306 standards of ISO;
Bending modulus, is tested according to 178 standards of ISO;
Melt index, is tested according to 1133 standards of ISO;
Glossiness, is tested according to 2813 standards of ISO;
Noise dangerous values are evaluated, and are tested according to German automobiles Industry Association standard.
The performance test results of each sample are shown in Table 2.
2 the performance test results of table
Note:10 sections of noise dangerous values point, 1-3 is low-risk, and 4-5 is gray area, and 6-10 is excessive risk
From table 2:ABS resin composition prepared by the present invention adds inorganic filler delustering agent compared with reference examples, can It is obvious to reduce glossiness;Improvement of damping resin is added, can obviously reduce noise dangerous values;Compatilizer is added at the same time, improves damping Compatibility between reinforced resin and matrix ABS resin, therefore the ABS resin composition excellent combination property being prepared, this hair Bright obtained low gloss low noise ABS resin can be applied in the door of the fields such as automobile and household electrical appliances, especially superior automobile Handle and column guard board.
The foregoing is merely illustrative of the preferred embodiments of the present invention, is not intended to limit the invention, all essences in the present invention With within principle, any modification, equivalent replacement, improvement and so on, should all be included in the protection scope of the present invention god.

Claims (10)

  1. A kind of 1. low gloss low noise ABS resin composition, it is characterised in that:Said composition is by including the raw materials of following parts by weight It is made:
  2. 2. low gloss low noise ABS resin composition according to claim 1, it is characterised in that:The composition by Raw material including following parts by weight is made:
  3. 3. low gloss low noise ABS resin composition according to claim 2, it is characterised in that:The ABS resin is The mixture of one or both of polymerisation in bulk or emulsion polymerization ABS resin.
  4. 4. low gloss low noise ABS resin composition according to claim 2, it is characterised in that:The heat-resistant agent is N-phenylmaleimide polymer.
  5. 5. low gloss low noise ABS resin composition according to claim 2, it is characterised in that:The compatilizer is SAN graft modification resins.
  6. 6. low gloss low noise ABS resin composition according to claim 2, it is characterised in that:The delustering agent is Wollastonite or mica powder.
  7. 7. low gloss low noise ABS resin composition according to claim 2, it is characterised in that:The improvement of damping Resin is maleic anhydride grafted polyurethane resin or one kind in glycidyl methacrylate graft polyurethane resin or two The mixture of kind.
  8. 8. low gloss low noise ABS resin composition according to claim 2, it is characterised in that:The auxiliary agent is anti- One or more of mixtures in oxygen agent, light stabilizer, lubricant or toner;The antioxidant is Hinered phenols or phosphorous One kind in acid esters kind antioxidant;The light stabilizer is benzotriazole uv absorbers and high molecular weight hindered amine light stabilizer The mass ratio of the combination of agent, the benzotriazole uv absorbers and high molecular weight hindered amine light stabilizer is 1:1;Described Lubricant is pentaerythritol stearate.
  9. 9. the preparation method of the low gloss low noise ABS resin composition any one of claim 1-8, its feature exist In:Include the following steps:ABS resin, heat-resistant agent, compatilizer, delustering agent, improvement of damping resin, auxiliary agent are uniformly mixed, then It is added in double screw extruder, by melt blending extruding pelletization up to the low gloss low noise ABS resin composition.
  10. 10. the purposes of the low gloss low noise ABS resin composition any one of claim 1-8, it is characterised in that:Institute The composition stated is applied to automobile and household electric appliances.
CN201711319457.9A 2017-12-12 2017-12-12 A kind of low gloss low noise ABS resin composition Pending CN107936461A (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110317427A (en) * 2019-07-03 2019-10-11 南宁珀源能源材料有限公司 Novel special backing plate of photovoltaic buddha's warrior attendant wire-electrode cutting
CN112745629A (en) * 2020-12-14 2021-05-04 金发科技股份有限公司 Reinforced ABS composition and preparation method and application thereof
CN113136086A (en) * 2021-04-30 2021-07-20 会通新材料股份有限公司 ABS composite material and preparation method thereof
WO2021147992A1 (en) * 2020-01-23 2021-07-29 上海锦湖日丽塑料有限公司 High-damping and low-noise abs composition and preparation method therefor

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Publication number Priority date Publication date Assignee Title
JPH05230323A (en) * 1992-02-17 1993-09-07 Kanegafuchi Chem Ind Co Ltd Sliding member reduced in rubbing noise
CN102532794A (en) * 2012-01-16 2012-07-04 重庆巨翁塑料制造有限公司 Matt ABS (acrylonitrile butadiene styrene) board and preparation method thereof
CN103044874A (en) * 2011-10-14 2013-04-17 合肥杰事杰新材料股份有限公司 Low-glossiness polycarbonate/styrene base resin composition and preparation method thereof
JP2016023258A (en) * 2014-07-23 2016-02-08 日油株式会社 Pc/abs resin composition and resin molded article thereof
CN106633604A (en) * 2016-12-25 2017-05-10 合肥会通新材料有限公司 Low-shrinkage ABS composite for solving problem of abnormal sound and preparation method thereof
CN107177156A (en) * 2017-06-20 2017-09-19 上海金发科技发展有限公司 A kind of high-damping noise reduction ABS resin composition

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH05230323A (en) * 1992-02-17 1993-09-07 Kanegafuchi Chem Ind Co Ltd Sliding member reduced in rubbing noise
CN103044874A (en) * 2011-10-14 2013-04-17 合肥杰事杰新材料股份有限公司 Low-glossiness polycarbonate/styrene base resin composition and preparation method thereof
CN102532794A (en) * 2012-01-16 2012-07-04 重庆巨翁塑料制造有限公司 Matt ABS (acrylonitrile butadiene styrene) board and preparation method thereof
JP2016023258A (en) * 2014-07-23 2016-02-08 日油株式会社 Pc/abs resin composition and resin molded article thereof
CN106633604A (en) * 2016-12-25 2017-05-10 合肥会通新材料有限公司 Low-shrinkage ABS composite for solving problem of abnormal sound and preparation method thereof
CN107177156A (en) * 2017-06-20 2017-09-19 上海金发科技发展有限公司 A kind of high-damping noise reduction ABS resin composition

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110317427A (en) * 2019-07-03 2019-10-11 南宁珀源能源材料有限公司 Novel special backing plate of photovoltaic buddha's warrior attendant wire-electrode cutting
WO2021147992A1 (en) * 2020-01-23 2021-07-29 上海锦湖日丽塑料有限公司 High-damping and low-noise abs composition and preparation method therefor
CN112745629A (en) * 2020-12-14 2021-05-04 金发科技股份有限公司 Reinforced ABS composition and preparation method and application thereof
CN112745629B (en) * 2020-12-14 2022-08-19 金发科技股份有限公司 Reinforced ABS composition and preparation method and application thereof
CN113136086A (en) * 2021-04-30 2021-07-20 会通新材料股份有限公司 ABS composite material and preparation method thereof
CN113136086B (en) * 2021-04-30 2022-04-12 会通新材料股份有限公司 ABS composite material and preparation method thereof

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Application publication date: 20180420