CN107936429A - A kind of environmentally friendly Wood-plastic floor of sugarcane fibre enhancing - Google Patents
A kind of environmentally friendly Wood-plastic floor of sugarcane fibre enhancing Download PDFInfo
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- CN107936429A CN107936429A CN201711245441.8A CN201711245441A CN107936429A CN 107936429 A CN107936429 A CN 107936429A CN 201711245441 A CN201711245441 A CN 201711245441A CN 107936429 A CN107936429 A CN 107936429A
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- parts
- wood
- plastic floor
- sugarcane fibre
- sugarcane
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/22—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers modified by chemical after-treatment
- C08L27/24—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers modified by chemical after-treatment halogenated
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/14—Polymer mixtures characterised by other features containing polymeric additives characterised by shape
- C08L2205/16—Fibres; Fibrils
Abstract
The invention discloses a kind of sugarcane fibre to strengthen environmentally friendly Wood-plastic floor, and the Wood-plastic floor includes following components in parts by weight：80 100 parts of chliorinated polyvinyl chloride powder, 40 50 parts of bamboo powder, 20 30 parts of sugarcane fibre, 15 30 parts of polyethylene, 5 15 parts of titanium dioxide, 20 30 parts of fume colloidal silica, 25 parts of paraffin oil, 0.5 2 parts of calcium stearate, 0.5 2 parts of antioxidant.In the present invention, the wood source in Wood-plastic floor is bamboo powder and sugarcane fibre, its source for can rapid regeneration mao bamboon, there is the advantages of growth cycle is short, and intensity is high, there is the advantages of environmental protection, of low cost using Wood-plastic floor that it is raw material.Therefore, the present invention has the advantages that：（1）The raw material used is environmental friendly regenerated；（2）Obtained Wood-plastic floor has excellent mechanical property；（3）Production cost is low.
Description
Technical field
The present invention relates to a kind of floor field, strengthens environmentally friendly Wood-plastic floor more particularly, to a kind of sugarcane fibre.
Background technology
Wood-plastic composite panel is a kind of mainly high for basic material and thermoplasticity by timber (lignose, plant cellulose)
Molecular material (plastics) and processing aid etc., heat extrusion molding through die apparatus again after mixing and manufactured high-tech is green
Color environment-friendly materials, have the performance and feature of timber and plastics concurrently, can substitute the novel environment friendly hitech materials of timber and plastics.Wood
It is to use floor made of wood plastic composite to mould floor, possesses the processing characteristics as timber, uses common instrument
Sawing, drilling, upper nail, it is very convenient, it can be used as common wood.At the same time have timber woodiness touch and plastics it is resistance to
Water Anticorrosive Character so that it becomes a kind of function admirable and very durable outdoor water-proof anti-corrosion building materials.
Responded actively in China under climate change, the energetically form of implementation energy-saving and emission-reduction, if in building template industry, energy
Using alternative steel and the material of bamboo and wood, environmental benefit, social benefit are undoubtedly huge.Building template market needs at present
Ask more than 200,000,000,000, wood plastic building mould can reach in 3~5 years following 30%-50% that will occupy the market share, the output value
More than 60000000000, market prospects are very wide.Wood plastic composite is as building template in use, construction can be increased substantially
Efficiency, shortens the construction time.Wood-plastic formwork can save 30% or so compared with conventional template single synthesis use cost, and supplementary costs can
40% or so is reduced, directly reduces engineering-built cost nearly 5%.Show peace Wood plastic boards are a variety of with green, low-carbon, economic dispatch
Advantage.
Such as a kind of a kind of Wood-plastic floor reported in Chinese patent literature, its application publication number CN 105602157A,
The invention includes the raw material of following parts by weight：PVC80~100 part, 60~100 parts of wood materials, precipitated calcium carbonate 20~40
Part, 1~2 part of foaming agent, 4.5~5.5 parts of stabilizer, 2.5~3.5 parts of lubricant, 5~8 parts of haloflex, plasticizer 0.5
~2 parts, 0.5~1.5 part of bulking agent, 1~1.5 part of antioxidant；The wood materials are rice husk meal and wood powder.The invention provides one
Kind of safety and environmental protection, functional, on-deformable Wood-plastic floor, such a Wood-plastic floor efficiently use obsolete material, economize on resources,
Production cost is reduced, but the wood materials in its raw material are dusty material for rice husk meal and wood powder, and it rises in Wood-plastic floor
The booster action arrived is high not as the booster action of fibrous material, its overall mechanical properties also has more substantially room for promotion.In addition
Although rice husk meal has the function that refuse reclamation, the source of wood powder generally requires to fall trees to obtain, its process is not
Environmental protection.
The content of the invention
The present invention is the Wood-plastic floor insufficient strength in order to overcome the wood powder source in Wood-plastic floor in the prior art not environmentally
The problem of high, there is provided a kind of wood powder source for enabling in Wood-plastic floor is not environmentally renewable, floor product intensity it is high one
The environmentally friendly Wood-plastic floor of kind sugarcane fibre enhancing.
To achieve these goals, the present invention uses following technical scheme：
A kind of environmentally friendly Wood-plastic floor of sugarcane fibre enhancing, sugarcane fibre enhancing Wood-plastic floor include in parts by weight
Following components：80-100 parts of chliorinated polyvinyl chloride powder, 40-50 parts of bamboo powder, 20-30 parts of sugarcane fibre, 15-30 parts of polyethylene, titanium
5-15 parts of white powder, 20-30 parts of fume colloidal silica, 2-5 parts of paraffin oil, 0.5-2 parts of calcium stearate, 0.5-2 parts of antioxidant.
Preferably, the sugarcane fibre enhancing Wood-plastic floor includes following components in parts by weight：Chlorination gathers
90-100 parts of vinyl chloride powder, 45-50 parts of bamboo powder, 25-30 parts of sugarcane fibre, 15-25 parts of polyethylene, 5-12 parts of titanium dioxide, gas phase
20-25 parts of method white carbon, 2-5 parts of paraffin oil, 0.5-2 parts of calcium stearate, 0.5-1.5 parts of antioxidant.
In the present invention, the wood source in Wood-plastic floor is bamboo powder and sugarcane fibre, its source for can rapid regeneration hair
Bamboo, has the advantages of growth cycle is short, and intensity is high, has the advantages of environmental protection, of low cost using its Wood-plastic floor as raw material.
Wherein, sugarcane fibre has excellent reinforcing effect, is added to the mechanics that Wood-plastic floor can be effectively improved in Wood-plastic floor
Intensity.The addition of polyvinyl resin can effectively act as the effect of toughness reinforcing so that obtained Wood-plastic floor can be born necessarily
Impact without fragmentation.
The bamboo powder is surface-treated with passing through, its step is as follows：100 parts of bamboo powders are taken to be added to containing 100 parts of second respectively
In sour ethanol solution, ultrasound 5 minutes, be heated to 50 DEG C stirring reaction 2-3 it is small when, filtering, by obtained filter cake with 50 parts
Washes of absolute alcohol three times, when vacuum drying 3-4 is small at 50-60 DEG C, obtains modified bamboo powder.
In the acetic acid ethanol solution, the ratio of weight and number of acetic acid and absolute ethyl alcohol is 35-50: 100.
Preferably, the silane coupling agent be silane resin acceptor kh-550, it is Silane coupling reagent KH-570, silane coupled
One or more mixtures in agent KH-590 or silane coupling agent KH-792.
A kind of environmentally friendly Wood-plastic floor of sugarcane fibre enhancing according to claim 1 or 2, it is characterized in that, described is sweet
Sugarcane fiber reinforcement Wood-plastic floor is made up of extruding-out process technique, its step is as follows：First weighed according to weight fraction each
Component is placed in batch mixer and mixes, then the extrusion molding at 180-185 DEG C, and after thing cooling to be extruded, cutting obtains sugarcane fibre
Dimension enhancing Wood-plastic floor.
Therefore, the present invention has the advantages that：(1) raw material used is environmental friendly regenerated；(2) Wood-plastic floor made from has
There is excellent mechanical property；(3) production cost is low.
Embodiment
Technical scheme is made to further describe explanation below by specific embodiment.
If without specified otherwise, the raw material that use is said in the embodiment of the present invention is raw material commonly used in the art, is implemented
Method employed in example, is the conventional method of this area.
Embodiment 1
A kind of environmentally friendly Wood-plastic floor of sugarcane fibre enhancing, sugarcane fibre enhancing Wood-plastic floor include in parts by weight
Following components：80 parts of chliorinated polyvinyl chloride powder, 40 parts of bamboo powder, 20 parts of sugarcane fibre, 15 parts of polyethylene, 5 parts of titanium dioxide, vapor phase method
20 parts of white carbon, 2 parts of paraffin oil, 0.5 part of calcium stearate, 0.5 part of antioxidant.
The bamboo powder is surface-treated with passing through, its step is as follows：100 parts of bamboo powders are taken to be added to containing 100 parts of second respectively
In sour ethanol solution, the ratio of weight and number of the acetic acid and absolute ethyl alcohol is 35-50: 100, and ultrasound 5 minutes, is heated to
When 50 DEG C of stirring reaction 2-3 are small, filtering, it is small to be dried in vacuo 3 by obtained filter cake with 50 parts of washes of absolute alcohol three times, at 50 DEG C
When, obtain modified bamboo powder.
The sugarcane fibre enhancing Wood-plastic floor is made up of extruding-out process technique, its step is as follows：First according to
Weight fraction, which weighs each component and is placed in batch mixer, to be mixed, the then extrusion molding at 180 DEG C, after thing cooling to be extruded, is cut
Cut to obtain sugarcane fibre enhancing Wood-plastic floor.
Embodiment 2
A kind of environmentally friendly Wood-plastic floor of sugarcane fibre enhancing, sugarcane fibre enhancing Wood-plastic floor include in parts by weight
Following components：100 parts of chliorinated polyvinyl chloride powder, 50 parts of bamboo powder, 30 parts of sugarcane fibre, 30 parts of polyethylene, 15 parts of titanium dioxide, gas phase
30 parts of method white carbon, 5 parts of paraffin oil, 2 parts of calcium stearate, 2 parts of antioxidant.
The bamboo powder is surface-treated with passing through, its step is as follows：100 parts of bamboo powders are taken to be added to containing 100 parts of second respectively
In sour ethanol solution, ultrasound 5 minutes, be heated to 50 DEG C of stirring reactions 3 it is small when, filtering, by obtained filter cake with 50 parts of nothings
Water-ethanol cleans three times, when vacuum drying 3-4 is small at 65 DEG C, modified bamboo powder is obtained, wherein the acetic acid ethanol solution
In, the ratio of weight and number of acetic acid and absolute ethyl alcohol is 50: 100.
The sugarcane fibre enhancing Wood-plastic floor is made up of extruding-out process technique, its step is as follows：First according to
Weight fraction, which weighs each component and is placed in batch mixer, to be mixed, the then extrusion molding at 185 DEG C, after thing cooling to be extruded, is cut
Cut to obtain sugarcane fibre enhancing Wood-plastic floor.
Embodiment 3
A kind of environmentally friendly Wood-plastic floor of sugarcane fibre enhancing, sugarcane fibre enhancing Wood-plastic floor include in parts by weight
Following components：90 parts of chliorinated polyvinyl chloride powder, 45 parts of bamboo powder, 25 parts of sugarcane fibre, 15 parts of polyethylene, 5 parts of titanium dioxide, vapor phase method
20 parts of white carbon, 2 parts of paraffin oil, 0.5 part of calcium stearate, 0.5 part of antioxidant.
The bamboo powder is surface-treated with passing through, its step is as follows：100 parts of bamboo powders are taken to be added to containing 100 parts of second respectively
In sour ethanol solution, ultrasound 5 minutes, be heated to 50 DEG C of stirring reactions 2 it is small when, filtering, by obtained filter cake with 50 parts of nothings
Water-ethanol cleans three times, be dried in vacuo at 55 DEG C 4 it is small when, obtain modified bamboo powder, in the acetic acid ethanol solution, acetic acid
Ratio of weight and number with absolute ethyl alcohol is 40: 100.
The sugarcane fibre enhancing Wood-plastic floor is made up of extruding-out process technique, its step is as follows：First according to
Weight fraction, which weighs each component and is placed in batch mixer, to be mixed, the then extrusion molding at 185 DEG C, after thing cooling to be extruded, is cut
Cut to obtain sugarcane fibre enhancing Wood-plastic floor.
Embodiment 4
A kind of environmentally friendly Wood-plastic floor of sugarcane fibre enhancing, sugarcane fibre enhancing Wood-plastic floor include in parts by weight
Following components：100 parts of chliorinated polyvinyl chloride powder, 50 parts of bamboo powder, 30 parts of sugarcane fibre, 25 parts of polyethylene, 12 parts of titanium dioxide, gas phase
25 parts of method white carbon, 5 parts of paraffin oil, 2 parts of calcium stearate, 1.5 parts of antioxidant.
The bamboo powder is surface-treated with passing through, its step is as follows：100 parts of bamboo powders are taken to be added to containing 100 parts of second respectively
In sour ethanol solution, ultrasound 5 minutes, be heated to 50 DEG C of stirring reactions 2 it is small when, filtering, by obtained filter cake with 50 parts of nothings
Water-ethanol cleans three times, be dried in vacuo at 55 DEG C 4 it is small when, obtain modified bamboo powder, in the acetic acid ethanol solution, acetic acid
Ratio of weight and number with absolute ethyl alcohol is 45: 100.
The sugarcane fibre enhancing Wood-plastic floor is made up of extruding-out process technique, its step is as follows：First according to
Weight fraction, which weighs each component and is placed in batch mixer, to be mixed, the then extrusion molding at 183 DEG C, after thing cooling to be extruded, is cut
Cut to obtain sugarcane fibre enhancing Wood-plastic floor.
Embodiment 5
A kind of environmentally friendly Wood-plastic floor of sugarcane fibre enhancing, sugarcane fibre enhancing Wood-plastic floor include in parts by weight
Following components：95 parts of chliorinated polyvinyl chloride powder, 48 parts of bamboo powder, 26 parts of sugarcane fibre, 20 parts of polyethylene, 6 parts of titanium dioxide, vapor phase method
20 parts of white carbon, 5 parts of paraffin oil, 1 part of calcium stearate, 1 part of antioxidant.
The bamboo powder is surface-treated with passing through, its step is as follows：100 parts of bamboo powders are taken to be added to containing 100 parts of second respectively
In sour ethanol solution, ultrasound 5 minutes, be heated to 50 DEG C stirring reaction 2.5 it is small when, filtering, by obtained filter cake with 50 parts
Washes of absolute alcohol be dried in vacuo three times, at 55 DEG C 4 it is small when, obtain modified bamboo powder, in the acetic acid ethanol solution, second
The ratio of weight and number of acid and absolute ethyl alcohol is 38: 100.
The sugarcane fibre enhancing Wood-plastic floor is made up of extruding-out process technique, its step is as follows：First according to
Weight fraction, which weighs each component and is placed in batch mixer, to be mixed, the then extrusion molding at 185 DEG C, after thing cooling to be extruded, is cut
Cut to obtain sugarcane fibre enhancing Wood-plastic floor.
The mechanics property analysis of embodiment 1-5
| Project | Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 | Embodiment 5 |
| Tensile strength (MPa) | 39.7 | 43.5 | 40.6 | 42.8 | 44.4 |
| Elongation at break (%) | 218 | 256 | 232 | 249 | 258 |
| Impact strength (KJ/m2) | 15.6 | 19.1 | 16.6 | 16.5 | 18.2 |
| Vicat softening temperature (DEG C) | 106 | 115 | 108 | 112 | 105 |
Claims (5)
1. a kind of environmentally friendly Wood-plastic floor of sugarcane fibre enhancing, it is characterized in that, the sugarcane fibre strengthens Wood-plastic floor according to weight
Amount number meter includes following components：80-100 parts of chliorinated polyvinyl chloride powder, 40-50 parts of bamboo powder, 20-30 parts of sugarcane fibre, poly- second
15-30 parts of alkene, 5-15 parts of titanium dioxide, 20-30 parts of fume colloidal silica, 2-5 parts of paraffin oil, 0.5-2 parts of calcium stearate, antioxidant
0.5-2 parts.
2. a kind of environmentally friendly Wood-plastic floor of sugarcane fibre enhancing according to claim 1, it is characterized in that, the sugarcane fibre
Enhancing Wood-plastic floor includes following components in parts by weight：It is 90-100 parts of chliorinated polyvinyl chloride powder, 45-50 parts of bamboo powder, sweet
25-30 parts of sugarcane fiber, 15-25 parts of polyethylene, 5-12 parts of titanium dioxide, 20-25 parts of fume colloidal silica, 2-5 parts of paraffin oil, tristearin
Sour calcium 0.5-2 parts, 0.5-1.5 parts of antioxidant.
3. a kind of environmentally friendly Wood-plastic floor of sugarcane fibre enhancing according to claim 1 or 2, it is characterized in that, the bamboo powder
It is surface-treated with passing through, its step is as follows：Take 100 parts of bamboo powders to be added to containing in 100 parts of acetic acid ethanol solutions respectively, surpass
Sound 5 minutes, be heated to 50 DEG C stirring reaction 2-3 it is small when, filtering, by obtained filter cake with 50 parts of washes of absolute alcohol three times, 50-
When vacuum drying 3-4 is small at 60 DEG C, modified bamboo powder is obtained.
4. a kind of environmentally friendly Wood-plastic floor of sugarcane fibre enhancing according to claim 3, it is characterized in that, the acetic acid is anhydrous
In ethanol solution, the ratio of weight and number of acetic acid and absolute ethyl alcohol is 35-50:100.
5. a kind of environmentally friendly Wood-plastic floor of sugarcane fibre enhancing according to claim 1 or 2, it is characterized in that, the sugarcane
Fiber reinforcement Wood-plastic floor is made up of extruding-out process technique, its step is as follows：First each group is weighed according to weight fraction
It is placed in batch mixer and mixes, then the extrusion molding at 180-185 DEG C, after thing cooling to be extruded, cutting obtains sugarcane fibre
Strengthen Wood-plastic floor.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711245441.8A CN107936429A (en) | 2017-11-30 | 2017-11-30 | A kind of environmentally friendly Wood-plastic floor of sugarcane fibre enhancing |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711245441.8A CN107936429A (en) | 2017-11-30 | 2017-11-30 | A kind of environmentally friendly Wood-plastic floor of sugarcane fibre enhancing |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107936429A true CN107936429A (en) | 2018-04-20 |
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| CN201711245441.8A Pending CN107936429A (en) | 2017-11-30 | 2017-11-30 | A kind of environmentally friendly Wood-plastic floor of sugarcane fibre enhancing |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111454485A (en) * | 2020-03-30 | 2020-07-28 | 嘉兴学院 | Antistatic wood-plastic composite material and preparation method thereof |
| CN111925663A (en) * | 2020-07-23 | 2020-11-13 | 江苏理文化工有限公司 | CPVC panel |
-
2017
- 2017-11-30 CN CN201711245441.8A patent/CN107936429A/en active Pending
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111454485A (en) * | 2020-03-30 | 2020-07-28 | 嘉兴学院 | Antistatic wood-plastic composite material and preparation method thereof |
| CN111925663A (en) * | 2020-07-23 | 2020-11-13 | 江苏理文化工有限公司 | CPVC panel |
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Application publication date: 20180420 |