CN105237815B - A kind of environment-friendly type macromolecule material and preparation method thereof - Google Patents
A kind of environment-friendly type macromolecule material and preparation method thereof Download PDFInfo
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- CN105237815B CN105237815B CN201510699466.XA CN201510699466A CN105237815B CN 105237815 B CN105237815 B CN 105237815B CN 201510699466 A CN201510699466 A CN 201510699466A CN 105237815 B CN105237815 B CN 105237815B
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- 239000000463 material Substances 0.000 title claims abstract description 28
- 229920002521 macromolecule Polymers 0.000 title claims abstract description 24
- 238000002360 preparation method Methods 0.000 title claims abstract description 18
- 239000000203 mixture Substances 0.000 claims abstract description 24
- 238000001125 extrusion Methods 0.000 claims abstract description 19
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 claims abstract description 15
- 229920002134 Carboxymethyl cellulose Polymers 0.000 claims abstract description 15
- 239000001768 carboxy methyl cellulose Substances 0.000 claims abstract description 15
- 235000010948 carboxy methyl cellulose Nutrition 0.000 claims abstract description 15
- 239000008112 carboxymethyl-cellulose Substances 0.000 claims abstract description 15
- 229910052708 sodium Inorganic materials 0.000 claims abstract description 15
- 239000011734 sodium Substances 0.000 claims abstract description 15
- 239000000661 sodium alginate Substances 0.000 claims abstract description 15
- 235000010413 sodium alginate Nutrition 0.000 claims abstract description 15
- 229940005550 sodium alginate Drugs 0.000 claims abstract description 15
- 229920002472 Starch Polymers 0.000 claims abstract description 14
- 229920002301 cellulose acetate Polymers 0.000 claims abstract description 14
- -1 polymethoxysiloxanes Polymers 0.000 claims abstract description 14
- 239000008107 starch Substances 0.000 claims abstract description 14
- 235000019698 starch Nutrition 0.000 claims abstract description 14
- 229920001285 xanthan gum Polymers 0.000 claims abstract description 14
- FXZAUBIBKADOBA-UHFFFAOYSA-N 1,4-bis(2-methylpropoxy)-1,4-dioxobutane-2-sulfonic acid;sodium Chemical compound [Na].CC(C)COC(=O)CC(S(O)(=O)=O)C(=O)OCC(C)C FXZAUBIBKADOBA-UHFFFAOYSA-N 0.000 claims abstract description 12
- 238000003756 stirring Methods 0.000 claims abstract description 10
- NDWUBGAGUCISDV-UHFFFAOYSA-N 4-hydroxybutyl prop-2-enoate Chemical compound OCCCCOC(=O)C=C NDWUBGAGUCISDV-UHFFFAOYSA-N 0.000 claims abstract description 5
- 239000008187 granular material Substances 0.000 claims abstract 2
- 239000002253 acid Substances 0.000 claims description 8
- 150000002148 esters Chemical class 0.000 claims description 8
- VUVZASHBYYMLRC-UHFFFAOYSA-N heptane-2,3-diol Chemical compound CCCCC(O)C(C)O VUVZASHBYYMLRC-UHFFFAOYSA-N 0.000 claims description 2
- YZYASTRURKBPPS-UHFFFAOYSA-N C(CCC(=O)OCCCCCC(C)C)(=O)OCCCCCC(C)C.[Na] Chemical compound C(CCC(=O)OCCCCCC(C)C)(=O)OCCCCCC(C)C.[Na] YZYASTRURKBPPS-UHFFFAOYSA-N 0.000 claims 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims 1
- 239000005864 Sulphur Substances 0.000 claims 1
- 230000006835 compression Effects 0.000 abstract description 4
- 238000007906 compression Methods 0.000 abstract description 4
- 239000002861 polymer material Substances 0.000 description 14
- 150000001336 alkenes Chemical class 0.000 description 5
- 230000000052 comparative effect Effects 0.000 description 5
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 5
- 229920000642 polymer Polymers 0.000 description 3
- UWNADWZGEHDQAB-UHFFFAOYSA-N 2,5-dimethylhexane Chemical group CC(C)CCC(C)C UWNADWZGEHDQAB-UHFFFAOYSA-N 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 150000001335 aliphatic alkanes Chemical class 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 239000011147 inorganic material Substances 0.000 description 1
- 239000011368 organic material Substances 0.000 description 1
- 229920001568 phenolic resin Polymers 0.000 description 1
- 239000005011 phenolic resin Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 125000000020 sulfo group Chemical group O=S(=O)([*])O[H] 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 229920003051 synthetic elastomer Polymers 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 239000012209 synthetic fiber Substances 0.000 description 1
- 239000005061 synthetic rubber Substances 0.000 description 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
- Extrusion Moulding Of Plastics Or The Like (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Polysaccharides And Polysaccharide Derivatives (AREA)
Abstract
The invention discloses a kind of environment-friendly type macromolecule material and preparation method thereof, described environment-friendly type macromolecule material contains 26 parts of cellulose acetate, 5 10 parts of sodium alginate, 38 parts of carboxymethyl cellulose, 37 parts of 4 hydroxybutyl acrylate, 59 parts of xanthans, 27 parts of polymethoxysiloxanes, 6 12 parts of sodium carboxymethyl starch, 4 10 parts of sulfosuccinic acid diisobutyl ester sodium；Described preparation method comprises the steps：（1）Above-mentioned composition is put into agitator tank by weight, heating-up temperature stirs 20 50min to 70 80 DEG C；（2）Step（1）Mixture extruded again with double screw extruder, after extrusion granulate, be environment-friendly type macromolecule material.The environment-friendly type macromolecule material of preparation has the characteristics of tensile strength is high, elongation at break is high, compression strength is good.
Description
Technical field
The invention belongs to polymeric material field, and in particular to a kind of feature of environmental protection high polymer material and preparation method thereof.
Background technology
High polymer material refers to the material being made up of the larger compound molecule of relative molecular mass.By its source, high score
Sub- material can be divided into naturally, and synthesis, semisynthetic material includes plastics, synthetic fibers, synthetic rubber, coating, adhesive and height
Molecule based composite material.Since the appearance of macromolecule phenolic resin in 1907, high polymer material generally has many gold because of it
Belong to the advantage that can not replace with inorganic material and obtain rapid development.However, what is mass produced now is also simply seeking
The polymer substance that can be used under the conditions of often, i.e. commodity polymer.They have mechanical strength and poor rigidity, heat resistance are low
The shortcomings of.In addition, pollution of the conventional high polymer material to environment is also larger, with people to environmental protection increasingly
Pay attention to, people have carried out a large amount of exploitations to environment-friendly type macromolecule material.
The content of the invention
The technical problem to be solved：Conventional high polymer material is generally organic material polymer, itself and not environmentally, it is and right
Sublimity has larger pollution, and the purpose of the present invention is to disclose a kind of environment-friendly type macromolecule material and preparation method thereof, and is had
Preferable tensile property, elongation at break and compression strength.
Technical scheme
The present invention is achieved through the following technical solutions：
A kind of environment-friendly type macromolecule material, includes the composition of following weight parts：
2-6 parts of cellulose acetate,
5-10 parts of sodium alginate,
3-8 parts of carboxymethyl cellulose,
3-7 parts of 4- hydroxybutyl acrylates,
5-9 parts of xanthans,
2-7 parts of polymethoxysiloxanes,
6-12 parts of sodium carboxymethyl starch,
4-10 parts of sulfosuccinic acid diisobutyl ester sodium.
Further, a kind of described environment-friendly type macromolecule material, includes the composition of following weight parts：
3-5 parts of cellulose acetate,
6-9 parts of sodium alginate,
4-7 parts of carboxymethyl cellulose,
4-6 parts of 4- hydroxybutyl acrylates,
6-8 parts of xanthans,
3-6 parts of polymethoxysiloxanes,
8-11 parts of sodium carboxymethyl starch,
5-9 parts of sulfosuccinic acid diisobutyl ester sodium.
A kind of preparation method of described environment-friendly type macromolecule material, comprises the steps：
（1）Take 2-6 parts of cellulose acetate, 5-10 parts of sodium alginate, 3-8 parts of carboxymethyl cellulose, 4- hydroxyls respectively by weight
3-7 parts of base butyl propyleneglycol acid esters, 5-9 parts of xanthans, 2-7 parts of polymethoxysiloxanes, 6-12 parts of sodium carboxymethyl starch, sulfo group amber
Amber 4-10 parts of diisobutyl ester sodium of acid, above-mentioned composition is put into agitator tank, and heating-up temperature stirs 20-50min to 70-80 DEG C；
（2）Step（1）Mixture extruded again with double screw extruder, double-screw extruder screw draw ratio be 10:
1-14:1, extrusion temperature is：One area's temperature is 110-130 DEG C, and two area's temperature are 140-150 DEG C, and three area's temperature are 160-170
DEG C, granulated after extrusion, be environment-friendly type macromolecule material.
A kind of preparation method of described environment-friendly type macromolecule material, described preparation method step（1）Middle heating-up temperature
To 75 DEG C.
A kind of preparation method of described environment-friendly type macromolecule material, described preparation method step（2）Middle twin-screw is squeezed
It is 12 to go out machine screw slenderness ratio:1.
A kind of preparation method of described environment-friendly type macromolecule material, described preparation method step（2）Zhong-1 block temperature
For 120 DEG C, two area's temperature are 145 DEG C, and three area's temperature are 165 DEG C.
Beneficial effect：In order to improve tensile strength, elongation at break and other performances of environment-friendly type macromolecule material, in original
On the basis of some high polymer materials, polymethoxysiloxanes, sodium carboxymethyl starch, sulfosuccinic acid diisobutyl ester sodium are added,
After mentioned component is mixed with original xanthans, carboxymethyl cellulose, sodium alginate, the performance boost to material is larger.Prepare
High polymer material there is very excellent tensile strength, elongation at break and compression strength.
Specific embodiment
The present invention is further described with reference to specific embodiment.
Embodiment 1
（1）Take 6 parts of cellulose acetate, 5 parts of sodium alginate, 8 parts of carboxymethyl cellulose, 4- hydroxybutyls third respectively by weight
3 parts of olefin(e) acid ester, 9 parts of xanthans, 2 parts of polymethoxysiloxanes, 12 parts of sodium carboxymethyl starch, sulfosuccinic acid diisobutyl ester sodium 4
Part, above-mentioned composition is put into agitator tank, heating-up temperature stirs 50min to 70 DEG C；
（2）Step（1）Mixture extruded again with double screw extruder, double-screw extruder screw draw ratio be 14:
1, extrusion temperature is：One area's temperature is 130 DEG C, and two area's temperature are 150 DEG C, and three area's temperature are 160 DEG C, are granulated after extrusion, are ring
Guarantor's type high polymer material.
Embodiment 2
（1）Take 2 parts of cellulose acetate, 10 parts of sodium alginate, 3 parts of carboxymethyl cellulose, 4- hydroxybutyls respectively by weight
7 parts of acrylate, 5 parts of xanthans, 7 parts of polymethoxysiloxanes, 6 parts of sodium carboxymethyl starch, sulfosuccinic acid diisobutyl ester sodium
10 parts, above-mentioned composition is put into agitator tank, heating-up temperature stirs 20min to 80 DEG C；
（2）Step（1）Mixture extruded again with double screw extruder, double-screw extruder screw draw ratio be 10:
1, extrusion temperature is：One area's temperature is 110 DEG C, and two area's temperature are 140 DEG C, and three area's temperature are 170 DEG C, are granulated after extrusion, are ring
Guarantor's type high polymer material.
Embodiment 3
（1）Take 5 parts of cellulose acetate, 9 parts of sodium alginate, 4 parts of carboxymethyl cellulose, 4- hydroxybutyls third respectively by weight
6 parts of olefin(e) acid ester, 8 parts of xanthans, 3 parts of polymethoxysiloxanes, 8 parts of sodium carboxymethyl starch, sulfosuccinic acid diisobutyl ester sodium 9
Part, above-mentioned composition is put into agitator tank, heating-up temperature stirs 50min to 70 DEG C；
（2）Step（1）Mixture extruded again with double screw extruder, double-screw extruder screw draw ratio be 14:
1, extrusion temperature is：One area's temperature is 130 DEG C, and two area's temperature are 150 DEG C, and three area's temperature are 160 DEG C, are granulated after extrusion, are ring
Guarantor's type high polymer material.
Embodiment 4
（1）Take 3 parts of cellulose acetate, 6 parts of sodium alginate, 7 parts of carboxymethyl cellulose, 4- hydroxybutyls third respectively by weight
4 parts of olefin(e) acid ester, 6 parts of xanthans, 6 parts of polymethoxysiloxanes, 11 parts of sodium carboxymethyl starch, sulfosuccinic acid diisobutyl ester sodium 5
Part, above-mentioned composition is put into agitator tank, heating-up temperature stirs 20min to 80 DEG C；
（2）Step（1）Mixture extruded again with double screw extruder, double-screw extruder screw draw ratio be 10:
1, extrusion temperature is：One area's temperature is 110 DEG C, and two area's temperature are 140 DEG C, and three area's temperature are 170 DEG C, are granulated after extrusion, are ring
Guarantor's type high polymer material.
Embodiment 5
（1）Take 4 parts of cellulose acetate, 8 parts of sodium alginate, 6 parts of carboxymethyl cellulose, 4- hydroxybutyls third respectively by weight
5 parts of olefin(e) acid ester, 7 parts of xanthans, 4 parts of polymethoxysiloxanes, 9 parts of sodium carboxymethyl starch, sulfosuccinic acid diisobutyl ester sodium 7
Part, above-mentioned composition is put into agitator tank, heating-up temperature stirs 20min to 75 DEG C；
（2）Step（1）Mixture extruded again with double screw extruder, double-screw extruder screw draw ratio be 12:
1, extrusion temperature is：One area's temperature is 120 DEG C, and two area's temperature are 145 DEG C, and three area's temperature are 165 DEG C, are granulated after extrusion, are ring
Guarantor's type high polymer material.
Comparative example 1
（1）Take 6 parts of cellulose acetate, 5 parts of sodium alginate, 8 parts of carboxymethyl cellulose, polymethoxy silica respectively by weight
2 parts of alkane, 12 parts of sodium carboxymethyl starch, 4 parts of sulfosuccinic acid diisobutyl ester sodium, above-mentioned composition are put into agitator tank, heating
Temperature stirs 50min to 70 DEG C；
（2）Step（1）Mixture extruded again with double screw extruder, double-screw extruder screw draw ratio be 14:
1, extrusion temperature is：One area's temperature is 130 DEG C, and two area's temperature are 150 DEG C, and three area's temperature are 160 DEG C, are granulated after extrusion, are ring
Guarantor's type high polymer material.
Comparative example 2
（1）Take 6 parts of cellulose acetate, 5 parts of sodium alginate, 8 parts of carboxymethyl cellulose, 4- hydroxybutyls third respectively by weight
3 parts of olefin(e) acid ester, 9 parts of xanthans, 2 parts of polymethoxysiloxanes, above-mentioned composition are put into agitator tank, heating-up temperature to 70
DEG C, stir 50min；
（2）Step（1）Mixture extruded again with double screw extruder, double-screw extruder screw draw ratio be 14:
1, extrusion temperature is：One area's temperature is 130 DEG C, and two area's temperature are 150 DEG C, and three area's temperature are 160 DEG C, are granulated after extrusion, are ring
Guarantor's type high polymer material.
Tensile strength, elongation at break and the pressure resistance of the environment-friendly type macromolecule material of embodiment 1 to 5 and comparative example 1 and 2
Degree is as follows：
| Tensile strength（MPa） | Elongation at break（%） | Compression strength（MPa） | |
| Embodiment 1 | 21.6 | 131 | 31.2 |
| Embodiment 2 | 22.4 | 134 | 30.7 |
| Embodiment 3 | 25.1 | 147 | 36.2 |
| Embodiment 4 | 24.4 | 144 | 35.4 |
| Embodiment 5 | 27.5 | 156 | 39.1 |
| Comparative example 1 | 19.8 | 101 | 26.4 |
| Comparative example 2 | 18.7 | 109 | 25.7 |
Claims (2)
1. a kind of environment-friendly type macromolecule material, it is characterised in that described environment-friendly type macromolecule material includes following weight parts
Composition：
2-6 parts of cellulose acetate,
5-10 parts of sodium alginate,
3-8 parts of carboxymethyl cellulose,
3-7 parts of 4- hydroxybutyl acrylates,
5-9 parts of xanthans,
2-7 parts of polymethoxysiloxanes,
6-12 parts of sodium carboxymethyl starch,
4-10 parts of sulfosuccinic acid diisobutyl ester sodium；
A kind of described environment-friendly type macromolecule material is prepared by following preparation methods：
（1）Take 2-6 parts of cellulose acetate, 5-10 parts of sodium alginate, 3-8 parts of carboxymethyl cellulose, 4- hydroxyls respectively by weight
3-7 parts of base butyl propyleneglycol acid esters, 5-9 parts of xanthans, 2-7 parts of polymethoxysiloxanes, 6-12 parts of sodium carboxymethyl starch, sulphur
4-10 parts of base di-iso-octyl succinate sodium, above-mentioned composition is put into agitator tank, and heating-up temperature stirs 20- to 70-80 DEG C
50min ；
（2）Step（1）Mixture extruded again with double screw extruder, double-screw extruder screw draw ratio is
10:1-14:1, extrusion temperature is：One area's temperature is 110-130 DEG C, and two area's temperature are 140-150 DEG C, and three area's temperature are
160-170 DEG C, granulate after extrusion, be environment-friendly type macromolecule material；
Described preparation method step（1）Middle heating-up temperature is to 75 DEG C；
Described preparation method step（2）Middle double-screw extruder screw draw ratio is 12:1；
Described preparation method step（2）Zhong-1 block temperature is 120 DEG C, and two area's temperature are 145 DEG C, and three area's temperature are 165 DEG C.
2. a kind of environment-friendly type macromolecule material according to claim 1, it is characterised in that described environment-friendly type macromolecule
Material includes the composition of following weight parts：
3-5 parts of cellulose acetate,
6-9 parts of sodium alginate,
4-7 parts of carboxymethyl cellulose,
4-6 parts of 4- hydroxybutyl acrylates,
6-8 parts of xanthans,
3-6 parts of polymethoxysiloxanes,
8-11 parts of sodium carboxymethyl starch,
5-9 parts of sulfosuccinic acid diisobutyl ester sodium.
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| CN105237815A CN105237815A (en) | 2016-01-13 |
| CN105237815B true CN105237815B (en) | 2017-08-01 |
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| CN107446168A (en) * | 2017-09-07 | 2017-12-08 | 绵阳旺通科技有限公司 | A kind of high-performance environment protection type high polymer material and preparation method thereof |
| CN108192152A (en) * | 2017-12-29 | 2018-06-22 | 何俊 | A kind of environment-friendly type macromolecule material and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102504343A (en) * | 2011-11-09 | 2012-06-20 | 青岛科技大学 | Method for preparing recyclable biological packaging material |
| CN103724641A (en) * | 2013-11-30 | 2014-04-16 | 青岛海之林生物科技开发有限公司 | Preparation method for blend membrane of sodium alginate, amylum and carboxymethyl cellulose |
| CN104945818A (en) * | 2015-05-22 | 2015-09-30 | 铜陵方正塑业科技有限公司 | Rice-hull-ash-modified full-degradable plastic film and preparation method thereof |
| CN104974381A (en) * | 2014-04-08 | 2015-10-14 | 上海耐特复合材料制品有限公司 | Starch-based biodegradable composite material and preparation method thereof |
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2015
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Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102504343A (en) * | 2011-11-09 | 2012-06-20 | 青岛科技大学 | Method for preparing recyclable biological packaging material |
| CN103724641A (en) * | 2013-11-30 | 2014-04-16 | 青岛海之林生物科技开发有限公司 | Preparation method for blend membrane of sodium alginate, amylum and carboxymethyl cellulose |
| CN104974381A (en) * | 2014-04-08 | 2015-10-14 | 上海耐特复合材料制品有限公司 | Starch-based biodegradable composite material and preparation method thereof |
| CN104945818A (en) * | 2015-05-22 | 2015-09-30 | 铜陵方正塑业科技有限公司 | Rice-hull-ash-modified full-degradable plastic film and preparation method thereof |
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