CN107916575A - 一种复合抗菌整理剂及其制备方法 - Google Patents
一种复合抗菌整理剂及其制备方法 Download PDFInfo
- Publication number
- CN107916575A CN107916575A CN201711240111.XA CN201711240111A CN107916575A CN 107916575 A CN107916575 A CN 107916575A CN 201711240111 A CN201711240111 A CN 201711240111A CN 107916575 A CN107916575 A CN 107916575A
- Authority
- CN
- China
- Prior art keywords
- finishing agent
- agar
- antibacterial finishing
- composite antibacterial
- preparation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 230000000844 anti-bacterial effect Effects 0.000 title claims abstract description 42
- 239000002131 composite material Substances 0.000 title claims abstract description 20
- 238000002360 preparation method Methods 0.000 title claims abstract description 13
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 52
- 229920001817 Agar Polymers 0.000 claims abstract description 31
- 239000008272 agar Substances 0.000 claims abstract description 31
- KIUKXJAPPMFGSW-DNGZLQJQSA-N (2S,3S,4S,5R,6R)-6-[(2S,3R,4R,5S,6R)-3-Acetamido-2-[(2S,3S,4R,5R,6R)-6-[(2R,3R,4R,5S,6R)-3-acetamido-2,5-dihydroxy-6-(hydroxymethyl)oxan-4-yl]oxy-2-carboxy-4,5-dihydroxyoxan-3-yl]oxy-5-hydroxy-6-(hydroxymethyl)oxan-4-yl]oxy-3,4,5-trihydroxyoxane-2-carboxylic acid Chemical compound CC(=O)N[C@H]1[C@H](O)O[C@H](CO)[C@@H](O)[C@@H]1O[C@H]1[C@H](O)[C@@H](O)[C@H](O[C@H]2[C@@H]([C@@H](O[C@H]3[C@@H]([C@@H](O)[C@H](O)[C@H](O3)C(O)=O)O)[C@H](O)[C@@H](CO)O2)NC(C)=O)[C@@H](C(O)=O)O1 KIUKXJAPPMFGSW-DNGZLQJQSA-N 0.000 claims abstract description 18
- 229920002674 hyaluronan Polymers 0.000 claims abstract description 18
- 229960003160 hyaluronic acid Drugs 0.000 claims abstract description 18
- 239000000463 material Substances 0.000 claims abstract description 17
- 229910052751 metal Inorganic materials 0.000 claims abstract description 14
- 239000002184 metal Substances 0.000 claims abstract description 14
- 229910044991 metal oxide Inorganic materials 0.000 claims abstract description 12
- 150000004706 metal oxides Chemical class 0.000 claims abstract description 12
- 239000006210 lotion Substances 0.000 claims description 20
- 239000007788 liquid Substances 0.000 claims description 15
- 239000002270 dispersing agent Substances 0.000 claims description 10
- 239000003094 microcapsule Substances 0.000 claims description 10
- 235000013336 milk Nutrition 0.000 claims description 10
- 239000008267 milk Substances 0.000 claims description 10
- 210000004080 milk Anatomy 0.000 claims description 10
- 238000001556 precipitation Methods 0.000 claims description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 10
- 239000000203 mixture Substances 0.000 claims description 7
- 239000003995 emulsifying agent Substances 0.000 claims description 6
- NDVLTYZPCACLMA-UHFFFAOYSA-N silver oxide Chemical compound [O-2].[Ag+].[Ag+] NDVLTYZPCACLMA-UHFFFAOYSA-N 0.000 claims description 6
- 238000013019 agitation Methods 0.000 claims description 5
- 239000008367 deionised water Substances 0.000 claims description 5
- 229910021641 deionized water Inorganic materials 0.000 claims description 5
- 238000010438 heat treatment Methods 0.000 claims description 5
- 239000005457 ice water Substances 0.000 claims description 5
- 238000002156 mixing Methods 0.000 claims description 5
- 239000000843 powder Substances 0.000 claims description 5
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 4
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical group [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 4
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 4
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 3
- 229920002085 Dialdehyde starch Polymers 0.000 claims description 3
- SXRSQZLOMIGNAQ-UHFFFAOYSA-N Glutaraldehyde Chemical group O=CCCCC=O SXRSQZLOMIGNAQ-UHFFFAOYSA-N 0.000 claims description 3
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 3
- 239000002253 acid Substances 0.000 claims description 3
- 229910052802 copper Inorganic materials 0.000 claims description 3
- 239000010949 copper Substances 0.000 claims description 3
- ZDXPYRJPNDTMRX-UHFFFAOYSA-N glutamine Natural products OC(=O)C(N)CCC(N)=O ZDXPYRJPNDTMRX-UHFFFAOYSA-N 0.000 claims description 3
- 235000010482 polyoxyethylene sorbitan monooleate Nutrition 0.000 claims description 3
- 229920000053 polysorbate 80 Polymers 0.000 claims description 3
- 229920000036 polyvinylpyrrolidone Polymers 0.000 claims description 3
- 239000001267 polyvinylpyrrolidone Substances 0.000 claims description 3
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 claims description 3
- 229910001923 silver oxide Inorganic materials 0.000 claims description 3
- 229910052725 zinc Inorganic materials 0.000 claims description 3
- 239000011701 zinc Substances 0.000 claims description 3
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims description 2
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 2
- 238000004945 emulsification Methods 0.000 claims description 2
- 229910052709 silver Inorganic materials 0.000 claims description 2
- 239000004332 silver Substances 0.000 claims description 2
- 239000011135 tin Substances 0.000 claims description 2
- 229910052718 tin Inorganic materials 0.000 claims description 2
- 239000011787 zinc oxide Substances 0.000 claims description 2
- 239000004744 fabric Substances 0.000 abstract description 11
- HZLCGUXUOFWCCN-UHFFFAOYSA-N 2-hydroxynonadecane-1,2,3-tricarboxylic acid Chemical compound CCCCCCCCCCCCCCCCC(C(O)=O)C(O)(C(O)=O)CC(O)=O HZLCGUXUOFWCCN-UHFFFAOYSA-N 0.000 abstract description 8
- 229940040563 agaric acid Drugs 0.000 abstract description 8
- 230000003115 biocidal effect Effects 0.000 abstract description 2
- 230000001681 protective effect Effects 0.000 abstract description 2
- 239000002421 finishing Substances 0.000 description 26
- 150000001875 compounds Chemical class 0.000 description 4
- 238000007711 solidification Methods 0.000 description 4
- 230000008023 solidification Effects 0.000 description 4
- 239000004753 textile Substances 0.000 description 4
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- 210000000481 breast Anatomy 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 244000005700 microbiome Species 0.000 description 2
- 238000009988 textile finishing Methods 0.000 description 2
- 241000894006 Bacteria Species 0.000 description 1
- 241000588724 Escherichia coli Species 0.000 description 1
- 241000589517 Pseudomonas aeruginosa Species 0.000 description 1
- 206010040904 Skin odour abnormal Diseases 0.000 description 1
- 241000191967 Staphylococcus aureus Species 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 230000001580 bacterial effect Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000009395 breeding Methods 0.000 description 1
- 230000001488 breeding effect Effects 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000004332 deodorization Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000029142 excretion Effects 0.000 description 1
- 125000000404 glutamine group Chemical group N[C@@H](CCC(N)=O)C(=O)* 0.000 description 1
- 230000009931 harmful effect Effects 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 208000015181 infectious disease Diseases 0.000 description 1
- 230000004060 metabolic process Effects 0.000 description 1
- 230000000813 microbial effect Effects 0.000 description 1
- 235000015097 nutrients Nutrition 0.000 description 1
- 235000016709 nutrition Nutrition 0.000 description 1
- 230000035764 nutrition Effects 0.000 description 1
- 210000002374 sebum Anatomy 0.000 description 1
- 230000028327 secretion Effects 0.000 description 1
- 208000017520 skin disease Diseases 0.000 description 1
- 210000003859 smegma Anatomy 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 210000004243 sweat Anatomy 0.000 description 1
- 210000000106 sweat gland Anatomy 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 238000009941 weaving Methods 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M23/00—Treatment of fibres, threads, yarns, fabrics or fibrous goods made from such materials, characterised by the process
- D06M23/12—Processes in which the treating agent is incorporated in microcapsules
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/38—Oxides or hydroxides of elements of Groups 1 or 11 of the Periodic Table
- D06M11/42—Oxides or hydroxides of copper, silver or gold
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/44—Oxides or hydroxides of elements of Groups 2 or 12 of the Periodic Table; Zincates; Cadmates
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/83—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with metals; with metal-generating compounds, e.g. metal carbonyls; Reduction of metal compounds on textiles
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
- D06M15/03—Polysaccharides or derivatives thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M16/00—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Biochemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Microbiology (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
本发明公开了一种复合抗菌整理剂及其制备方法，所述整理剂呈球形或椭球形，平均粒径为5～11μm，其芯材与壁材的质量比为1:0.5～1.7；所述芯材为金属或金属氧化物，壁材由琼脂和透明质酸组成。本发明所述抗菌整理剂能够稳定附着在织物表面，且具有良好的耐热性；本发明所述整理剂抗菌性强，安全可靠，绿色环保。
Description
技术领域
本发明属于纺织技术领域，涉及一种功能性织物的整理化合物，具体为一种复合抗菌整理剂及其制备方法。
背景技术
随着生活水平的提高，人们对生活质量的要求越来越高，尤其是与生活息息相关的纺织品，特别是安全、舒适、健康、清洁等观念的形成，使纺织的抗菌、防霉、防臭等后整理加工更加受到人们的重视。
多孔性纺织品易吸收人体汗腺和皮脂腺分泌的汗水、新陈代谢产物和皮脂等排泄物，从而形成微生物的营养源，极易导致微生物的滋生和繁殖。特别是在潮湿、营养和合适的温度下，微生物繁殖迅速，并在织物上生成菌斑，使纺织品产生霉变、脆化甚至变质，以致在穿着或应用过程中人体不适或对人体产生不良影响。另外，细菌还分解人体分泌物，产生氨等异味物质，从而产生肮脏体味，导致皮肤疾病的传播或感染。
现有技术中，赋予织物抗菌性能的方法是进行浸渍整理，在浸泡期间，部分或全部织物整理化合物从溶液中转移到织物上。织物从溶液中拿出并干燥后，一定量的织物整理化合物附着在织物上。然而该方式整理后的织物从浸渍液体溶液中拿出后，整理在织物表面的整理剂在水洗、烘干过程中会有部分丧失。
发明内容
本发明的目的是：为了克服现有技术的缺陷，获得一种能在织物表面稳定附着，且抗菌效果良好的整理剂，本发明提供了一种复合抗菌整理剂及其制备方法。
技术方案：一种复合抗菌整理剂，所述整理剂呈球形或椭球形，平均粒径为5～11μm，其芯材与壁材的质量比为1:0.5～1.7；所述芯材为金属或金属氧化物，壁材由琼脂和透明质酸组成。
优选的，所述金属为铜，银，锌或锡。
优选的，所述金属氧化物为氧化锌或氧化银。
优选的，所述壁材由琼脂和透明质酸按质量比1:1.5～4组成。
一种复合抗菌整理剂的制备方法，包含以下步骤：
(1)将琼脂溶于去离子水中，加热煮沸，配制成质量浓度为0.8～1.5％的琼脂溶液，凝固备用；
(2)将透明质酸溶于水中，配制成质量浓度为0.5～2％的透明质酸溶液，然后加入乳化剂、金属或金属氧化物的粉末，磁力搅拌至分散均匀得到乳液；
(3)将步骤(1)凝固后的琼脂加热融化，然后将步骤(2)得到的乳液滴加到琼脂溶液中，调节pH值为7.5～8.2，反应25～40min，再加入分散剂，搅拌均匀得到复凝乳液；
(4)将步骤(3)获得的复凝乳液置于冰水浴中降温至0～4℃，加入固化剂，固化25～40min后调节pH值6.8～7.5，再移入42～50℃水浴中固化1.5～4h得到抗菌微胶囊乳液，将抗菌微胶囊乳液离心，取沉淀，将沉淀抽滤、干燥得到抗菌整理剂。
优选的，所述乳化剂为吐温-80或OP-80。
优选的，所述分散剂为聚乙烯吡咯烷酮或聚乙烯醇。
优选的，所述固化剂为戊二醛、双醛淀粉或谷氨酰胺转氨酶。
有益效果：(1)本发明所述抗菌整理剂能够稳定附着在织物表面，且具有良好的耐热性；(2)本发明所述整理剂抗菌性强，安全可靠，绿色环保。
具体实施方式
实施例1
一种复合抗菌整理剂，所述整理剂呈球形或椭球形，平均粒径为5μm，其芯材与壁材的质量比为1:0.5；所述芯材为金属，壁材由琼脂和透明质酸组成。
所述金属为铜。
所述壁材由琼脂和透明质酸按质量比1:1.5组成。
一种复合抗菌整理剂的制备方法，包含以下步骤：
(1)将琼脂溶于去离子水中，加热煮沸，配制成质量浓度为0.8％的琼脂溶液，凝固备用；
(2)将透明质酸溶于水中，配制成质量浓度为0.5％的透明质酸溶液，然后加入乳化剂、金属或金属氧化物的粉末，磁力搅拌至分散均匀得到乳液；
(3)将步骤(1)凝固后的琼脂加热融化，然后将步骤(2)得到的乳液滴加到琼脂溶液中，调节pH值为7.5，反应25min，再加入分散剂，搅拌均匀得到复凝乳液；
(4)将步骤(3)获得的复凝乳液置于冰水浴中降温至0℃，加入固化剂，固化25min后调节pH值6.8，再移入42℃水浴中固化1.5h得到抗菌微胶囊乳液，将抗菌微胶囊乳液离心，取沉淀，将沉淀抽滤、干燥得到抗菌整理剂。
所述乳化剂为吐温-80。
所述分散剂为聚乙烯吡咯烷酮。
所述固化剂为戊二醛。
实施例2
一种复合抗菌整理剂，所述整理剂呈球形或椭球形，平均粒径为8μm，其芯材与壁材的质量比为1:1；所述芯材为金属氧化物，壁材由琼脂和透明质酸组成。
所述金属氧化物为氧化银。
所述壁材由琼脂和透明质酸按质量比1:2.2组成。
一种复合抗菌整理剂的制备方法，包含以下步骤：
(1)将琼脂溶于去离子水中，加热煮沸，配制成质量浓度为1.1％的琼脂溶液，凝固备用；
(2)将透明质酸溶于水中，配制成质量浓度为1.2％的透明质酸溶液，然后加入乳化剂、金属或金属氧化物的粉末，磁力搅拌至分散均匀得到乳液；
(3)将步骤(1)凝固后的琼脂加热融化，然后将步骤(2)得到的乳液滴加到琼脂溶液中，调节pH值为7.8，反应32min，再加入分散剂，搅拌均匀得到复凝乳液；
(4)将步骤(3)获得的复凝乳液置于冰水浴中降温至2℃，加入固化剂，固化32min后调节pH值7.2，再移入45℃水浴中固化2.5h得到抗菌微胶囊乳液，将抗菌微胶囊乳液离心，取沉淀，将沉淀抽滤、干燥得到抗菌整理剂。
所述乳化剂为OP-80。
所述分散剂为聚乙烯醇。
所述固化剂为双醛淀粉。
实施例3
一种复合抗菌整理剂，所述整理剂呈球形或椭球形，平均粒径为11μm，其芯材与壁材的质量比为1:1.7；所述芯材为金属，壁材由琼脂和透明质酸组成。
所述金属为锌。
所述壁材由琼脂和透明质酸按质量比1:4组成。
一种复合抗菌整理剂的制备方法，包含以下步骤：
(1)将琼脂溶于去离子水中，加热煮沸，配制成质量浓度为1.5％的琼脂溶液，凝固备用；
(2)将透明质酸溶于水中，配制成质量浓度为2％的透明质酸溶液，然后加入乳化剂、金属或金属氧化物的粉末，磁力搅拌至分散均匀得到乳液；
(3)将步骤(1)凝固后的琼脂加热融化，然后将步骤(2)得到的乳液滴加到琼脂溶液中，调节pH值为8.2，反应40min，再加入分散剂，搅拌均匀得到复凝乳液；
(4)将步骤(3)获得的复凝乳液置于冰水浴中降温至4℃，加入固化剂，固化40min后调节pH值7.5，再移入50℃水浴中固化4h得到抗菌微胶囊乳液，将抗菌微胶囊乳液离心，取沉淀，将沉淀抽滤、干燥得到抗菌整理剂。
所述乳化剂为OP-80。
所述分散剂为聚乙烯醇。
所述固化剂为谷氨酰胺转氨酶。
对实施例1～3制备获得的抗菌整理剂进行性能测试，检测抑菌率，结果如下：
| 大肠杆菌/％ | 绿脓杆菌/％ | 金黄色葡萄球菌/％ | |
| 实施例1 | 96.8 | 97.8 | 95.4 |
| 实施例2 | 100 | 99.9 | 98.9 |
| 实施例3 | 99.5 | 98.6 | 97.2 |
Claims (8)
1.一种复合抗菌整理剂，其特征在于，所述整理剂呈球形或椭球形，平均粒径为5～11μm，其芯材与壁材的质量比为1:0.5～1.7；所述芯材为金属或金属氧化物，壁材由琼脂和透明质酸组成。
2.根据权利要求1所述的一种复合抗菌整理剂，其特征在于，所述金属为铜，银，锌或锡。
3.根据权利要求1所述的一种复合抗菌整理剂，其特征在于，所述金属氧化物为氧化锌或氧化银。
4.根据权利要求1所述的一种复合抗菌整理剂，其特征在于，所述壁材由琼脂和透明质酸按质量比1:1.5～4组成。
5.权利要求1～4任一所述一种复合抗菌整理剂的制备方法，其特征在于，包含以下步骤：
(1)将琼脂溶于去离子水中，加热煮沸，配制成质量浓度为0.8～1.5％的琼脂溶液，凝固备用；
(2)将透明质酸溶于水中，配制成质量浓度为0.5～2％的透明质酸溶液，然后加入乳化剂、金属或金属氧化物的粉末，磁力搅拌至分散均匀得到乳液；
(3)将步骤(1)凝固后的琼脂加热融化，然后将步骤(2)得到的乳液滴加到琼脂溶液中，调节pH值为7.5～8.2，反应25～40min，再加入分散剂，搅拌均匀得到复凝乳液；
(4)将步骤(3)获得的复凝乳液置于冰水浴中降温至0～4℃，加入固化剂，固化25～40min后调节pH值6.8～7.5，再移入42～50℃水浴中固化1.5～4h得到抗菌微胶囊乳液，将抗菌微胶囊乳液离心，取沉淀，将沉淀抽滤、干燥得到抗菌整理剂。
6.根据权利要求5所述的一种复合抗菌整理剂的制备方法，其特征在于，所述乳化剂为吐温-80或OP-80。
7.根据权利要求5所述的一种复合抗菌整理剂的制备方法，其特征在于，所述分散剂为聚乙烯吡咯烷酮或聚乙烯醇。
8.根据权利要求5所述的一种复合抗菌整理剂的制备方法，其特征在于，所述固化剂为戊二醛、双醛淀粉或谷氨酰胺转氨酶。
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711240111.XA CN107916575A (zh) | 2017-11-30 | 2017-11-30 | 一种复合抗菌整理剂及其制备方法 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711240111.XA CN107916575A (zh) | 2017-11-30 | 2017-11-30 | 一种复合抗菌整理剂及其制备方法 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107916575A true CN107916575A (zh) | 2018-04-17 |
Family
ID=61897104
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201711240111.XA Pending CN107916575A (zh) | 2017-11-30 | 2017-11-30 | 一种复合抗菌整理剂及其制备方法 |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107916575A (zh) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111876897A (zh) * | 2020-08-07 | 2020-11-03 | 李潮云 | 一种基于纳米纤维的生物医用无纺布及其制备方法 |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH10251052A (ja) * | 1997-03-10 | 1998-09-22 | Kounoshima Kagaku Kogyo Kk | 珪酸カルシウム成形体及びその製造方法 |
| KR100753471B1 (ko) * | 2001-09-06 | 2007-08-31 | 주식회사 엘지생활건강 | 트리클로산을 포함하는 마이크로 캡슐의 제조방법 |
| CN102061625A (zh) * | 2009-11-16 | 2011-05-18 | 香港理工大学 | 一种艾叶油微胶囊抗菌防皱织物及其制备方法 |
| CN102405941A (zh) * | 2011-08-10 | 2012-04-11 | 华南农业大学 | 板蓝根油微胶囊和功能织物整理剂 |
| CN103147311A (zh) * | 2013-04-07 | 2013-06-12 | 江苏悦达纺织集团有限公司 | 茶树油微胶囊抗菌保健纤维及其制备方法 |
| CN104434548A (zh) * | 2014-12-16 | 2015-03-25 | 重庆小丸科贸有限公司 | 一种具有防晒功效的水凝胶微胶囊 |
-
2017
- 2017-11-30 CN CN201711240111.XA patent/CN107916575A/zh active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH10251052A (ja) * | 1997-03-10 | 1998-09-22 | Kounoshima Kagaku Kogyo Kk | 珪酸カルシウム成形体及びその製造方法 |
| KR100753471B1 (ko) * | 2001-09-06 | 2007-08-31 | 주식회사 엘지생활건강 | 트리클로산을 포함하는 마이크로 캡슐의 제조방법 |
| CN102061625A (zh) * | 2009-11-16 | 2011-05-18 | 香港理工大学 | 一种艾叶油微胶囊抗菌防皱织物及其制备方法 |
| CN102405941A (zh) * | 2011-08-10 | 2012-04-11 | 华南农业大学 | 板蓝根油微胶囊和功能织物整理剂 |
| CN103147311A (zh) * | 2013-04-07 | 2013-06-12 | 江苏悦达纺织集团有限公司 | 茶树油微胶囊抗菌保健纤维及其制备方法 |
| CN104434548A (zh) * | 2014-12-16 | 2015-03-25 | 重庆小丸科贸有限公司 | 一种具有防晒功效的水凝胶微胶囊 |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111876897A (zh) * | 2020-08-07 | 2020-11-03 | 李潮云 | 一种基于纳米纤维的生物医用无纺布及其制备方法 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN107142718B (zh) | 纳米氧化锌/银复合抗菌剂及其制备方法 | |
| CN105002729A (zh) | 一种织物抗菌整理剂 | |
| CN105019236A (zh) | 一种纺织品复合抗菌整理剂 | |
| CN104756983A (zh) | 一种鲜花保鲜剂及其制备方法 | |
| CN103668955B (zh) | 浸轧法抗菌涤纶织物及其制备方法 | |
| CN107354251A (zh) | 一种长效抗菌皮革及其制备方法 | |
| CN107197859A (zh) | 一种鲜花保鲜液及其制备方法 | |
| CN108902179A (zh) | 一种银-壳聚糖复合抗菌材料的制备方法 | |
| CN107916575A (zh) | 一种复合抗菌整理剂及其制备方法 | |
| CN107751712A (zh) | 一种饲料脱霉剂及其制备方法 | |
| CN1217059C (zh) | 纳米银系抗菌织物的制备工艺及应用 | |
| KR20120041817A (ko) | 구리 나노입자 또는 구리-은 합금 나노입자를 함유하는 항균성 라텍스 폼 및 그 제조방법 | |
| CN109055633B (zh) | 一种真皮面料整理剂的制备方法 | |
| CN111321593A (zh) | 一种天然杀菌除臭纤维及其制备方法 | |
| KR100638571B1 (ko) | 홍화씨 열수추출물을 이용한 건멸치의 제조방법 | |
| CN105249721A (zh) | 一种可改善睡眠降血脂的保健床垫及其制作方法 | |
| US20180344636A1 (en) | Method for manufacturing an anti-vaginitis suppository | |
| EP2993252A1 (en) | Impregnatable matrix of plant, animal or synthetic origin or mixtures of same, containing a uniformly distributed antimicrobial compound, method for impregnating said matrix with a compound, and use thereof in the production of antimicrobial elements | |
| CN105368608B (zh) | 一种艾蜡手工皂及其制备方法 | |
| CN107869050A (zh) | 浸轧法抗菌涤纶织物及其制备方法 | |
| CN106868327A (zh) | 一种表面具有抗菌层的镁合金智能手机壳体的制备方法 | |
| CN107669508A (zh) | 一种抗菌湿巾的制备工艺 | |
| CN107177044A (zh) | 一种胶原蛋白-茶多酚抗菌膜及其制备方法 | |
| WO1999020105A1 (fr) | Article a tendance poreuse permettant d'eliminer des micro-organismes nuisibles et procede de fabrication dudit article | |
| CN111764157A (zh) | 基于氧化石墨烯/壳聚糖的压力衣面料抗菌整理方法 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20180417 |
|
| RJ01 | Rejection of invention patent application after publication |