CN107915208A - A kind of novel energy-conserving hydrogen reclaimer - Google Patents

A kind of novel energy-conserving hydrogen reclaimer Download PDF

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Publication number
CN107915208A
CN107915208A CN201711339307.4A CN201711339307A CN107915208A CN 107915208 A CN107915208 A CN 107915208A CN 201711339307 A CN201711339307 A CN 201711339307A CN 107915208 A CN107915208 A CN 107915208A
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CN
China
Prior art keywords
wall
hydrogen
knockout drum
bolted
novel energy
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Pending
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CN201711339307.4A
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Chinese (zh)
Inventor
何建璋
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Foshan Tianyu Ambitious Creative Technology Ltd
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Foshan Tianyu Ambitious Creative Technology Ltd
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Priority to CN201711339307.4A priority Critical patent/CN107915208A/en
Publication of CN107915208A publication Critical patent/CN107915208A/en
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    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/50Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification
    • C01B3/52Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification by contacting with liquids; Regeneration of used liquids
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0415Purification by absorption in liquids
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/10Process efficiency

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Inorganic Chemistry (AREA)
  • Gas Separation By Absorption (AREA)

Abstract

The invention discloses a kind of novel energy-conserving hydrogen reclaimer, including base, the bottom outer wall of the base has been bolted universal wheel, and the top outer wall of base has been bolted booster pump, the port of export inner wall of the booster pump is socketed with air injection pipe, and the top outer wall of air injection pipe has been bolted pressure gauge, knockout drum is bolted outside the top of the base, and the one end of air injection pipe away from booster pump is socketed in the bottom of knockout drum side outer wall.The present invention is by increasing knockout drum, and the filling limewash in knockout drum, so as to depart to the mixed gas containing hydrogen, and it is stirred with paddle, so as to accelerate separated speed, by increasing Hydrogen collection tank, and increase condenser in tank, carry out the hydrogen containing moisture so as to quickly to have slept separation, the present apparatus is simple in structure, easy to operate, hydrogen recovery efficiency is high.

Description

A kind of novel energy-conserving hydrogen reclaimer
Technical field
The invention belongs to Recovery technology of hydrogen field, more particularly to a kind of novel energy-conserving hydrogen reclaimer.
Background technology
Hydrogen is generally acknowledged most clean fuel, and important chemical industry synthesis raw material.But it is not primary energy, it is will From primary energy by changing the energy carrier produced.It is a kind of gaseous fuel again, in terms of distribution is conveyed relatively There is certain difficulty.China again be a country using coal as main primary energy, so it is necessary to apply " environment, efficiency, The life cycle research method of economy ", with reference to national conditions and the reality in area, China is comprehensively assessed with the eye of system engineering The production and application of hydrogen;The reality in area is combined, selects advanced technology, rational method produces and using hydrogen, to obtain Obtain maximum economy and environmental benefit.
Hydrogen is produced primarily as a kind of intermediate products at present.It is the important original of further chemical industry synthesis hydrogenation Material.It is mainly by fossil energy natural gas, crude oil(Hydrocarbon)Reform, gasify or hydrocarbon at high temperature as raw material and water vapour with coal Class partial oxidation reforming generates.In the conversion process, the carbon in fossil energy is changed into CO first(Or CO2).In order to obtain hydrogen more, Further through water gas shift reation CO+H2O=H2+CO2, CO is further converted to CO2.So will by fossil energy hydrogen manufacturing Discharge CO2.Its CO2Discharge capacity:Coal>Oil>Natural gas, this is determined by the C/Hratio of raw material.Hydrogen also can be by electrolysis water(Salt Water)Production, but this is a kind of method costly, the usually byproduct under special production purpose, such as chlorine industry; Or in order to obtain the hydrogen of special requirement(Such as rocket fuel).Electrolysis hydrogen manufacturing is only utilizing water power or solar energy photocatalytic water When, just it can be described as rational.Oil plant and some chemical processes also can by-product some hydrogen, but these are not most important The method for producing hydrogen.
Intermediate products or raw material in Chinese hydrogen primarily as chemical industry synthesis, at present Chinese hydrogen as direct products or The amount of fuel is less.In Chinese hydrogen it is currently more expensive and relatively lacks(For other countries), it is primarily due to me State's primary energy is based on coal, and for coal than oil, natural gas hydrogen content is few, and hydrogen production process just needs with more steam, to disappear Consume more energy.The maximum amount of use of hydrogen is that about 60% hydrogen, which is used in, in the world synthesizes ratio Chinese on ammonia in synthesis ammonia Higher.Next section will specifically list the yield of China's synthesis ammonia and ratio using coal, natural gas and light oil as raw material.
In order to improve the requirement of environment, the quality requirement of vapour, diesel oil is being continuously improved at present, the hydrogenation of oil refining process is split Change and unifining process, it is also desirable to which the hydrogen for applying the process by-product such as substantial amounts of hydrogen, oil plant reformation is not nearly enough use. There is the factory being hydrocracked with hydro-refining unit, all need separately to add naphtha steam to reform(Or partial oxidation)Device for producing hydrogen.
Another larger amount of hydrogen use is to utilize synthesis gas(CO/H2)Synthesizing methanol.In the state of some technologies prosperity Family, methanol are primarily used to additives of the production MTBE as gasoline.In China since the amount of C4 alkene is limited, synthesis MTBE disappears The ratio for consuming quantity of methyl alcohol is not very high.Methanol is both important industrial chemicals, itself is also a kind of good engine fuel.Cause This, methanol is most important C1 chemical products.The application range and product downstream of methanol are opened up, will be to Optimum utilization fossil energy Source plays an important role.
C1 chemical industry process will utilize hydrogen(Synthesis gas H2/CO)Importance.Such as OXO reactions can be from alkene Produce aldehyde and further hydrogenation produces alcohol(Important plasticizer).Also can directly or indirectly synthetic liquid fuel, alkene from synthesis gas Hydrocarbon and other important oxygenatedchemicals(Other alcohol, acetic acid, aceticanhydride, dimethyl ether, formic acid, methyl formate in addition to methanol Etc.).
Hydrogen is also the raw material of other organic compound hydrogenation processes.The direct liquefaction process of coal just needs substantial amounts of hydrogen to make For intermediate raw material.The indirect liquefaction of coal(F-T is synthesized), methanation reaction, be also required for substantial amounts of hydrogen.
Due to the new development of fuel cell technology, fuel of the hydrogen as fuel cell, presents a very wide range of and potential Market.To be an earthshaking thing how from planning and the technical development for preparing and meeting this must arrive Feelings.
Hydrogen gas recovering device is to save the energy, reduce production cost, using recovery technology, will reduce process discharge A kind of device that reduction tail gas is recycled, a large amount of hydrogeneous exhaust gas of productional surplus were all burnt up as fuel or directly set fire in the past Torch is burnt up, in this way, production cost will certainly be caused excessive and the serious waste of hydrogen resources, in recent years, with market competition It is growing more intense, the awareness of saving energy of people gradually strengthens, and the recycling technique and hydrogen for setting about researching and developing hydrogeneous exhaust gas are returned Receiving apparatus, but existing hydrogen gas recovering device on the market, production cost is high, and complicated, later period maintenance is costly, and hydrogen That recycles is ineffective, causes cost not drop not only but also improves the production cost of enterprise.
The content of the invention
The purpose of the present invention is to solve shortcoming existing in the prior art, and a kind of novel energy-conserving hydrogen proposed returns Receiving unit.
To achieve these goals, present invention employs following technical solution:
A kind of novel energy-conserving hydrogen reclaimer, including base, the top outer wall of the base have been bolted booster pump, The port of export inner wall of the booster pump is socketed with air injection pipe, and the top outer wall of air injection pipe has been bolted pressure gauge, institute State and knockout drum has been bolted outside the top of base, and the one end of air injection pipe away from booster pump is socketed in outside knockout drum side The bottom of wall, the air injection pipe have been bolted check valve close to knockout drum one end outer wall, outside the bottom of the knockout drum Wall offers opening, and the inner wall that is open is socketed with bearing, and the inner wall of the bearing is socketed with rotation axis, and the outer wall weldering of rotation axis Paddle is connected to, the bottom inner wall of the base has been bolted motor, and the output shaft of motor is rolled with rotation axis and connected Connect, the knockout drum offers liquid injection port close to the top of check valve side outer wall, and the bottom of knockout drum opposite side outer wall is opened Equipped with leakage fluid dram, the top outer wall of the knockout drum is welded with collecting hood, and the top inner wall of collecting hood is socketed with appendix, institute The top outer wall for stating base has been bolted Hydrogen collection tank, and the one end of appendix away from collecting hood is socketed in hydrogen receipts Collect the bottom of tank side outer wall, the Hydrogen collection tank both sides inner wall axis line position has been bolted a logical condensation Device, the top of the Hydrogen collection tank offer Hydrogen collection mouth.
In order to further improve the performance of novel energy-conserving hydrogen reclaimer, the structure and hydrogen of the knockout drum are received The structure of collection tank is cylindrical structure, and the outside diameter of knockout drum is more than the outside diameter of Hydrogen collection tank.
In order to further improve the performance of novel energy-conserving hydrogen reclaimer, the quantity of the paddle is eight to ten Six, and in the equidistant outer wall surrounding for being welded on rotation axis of eight to ten six paddles.
In order to further improve the performance of novel energy-conserving hydrogen reclaimer, the inner cavity of the knockout drum is filled with stone Buck, and the pH value of limewash is more than 8.
In order to further improve the performance of novel energy-conserving hydrogen reclaimer, the structure of the condenser is cylinder Structure, and the outside diameter of condenser and the internal diameter of Hydrogen collection tank match.
In order to further improve the performance of novel energy-conserving hydrogen reclaimer, the collecting hood circle of position cone structure, And the outside diameter of collecting hood bottom is consistent with the outside diameter of knockout drum, the outside diameter of collecting hood top outer wall and the outside diameter phase of appendix Match somebody with somebody.
In order to further improve the performance of novel energy-conserving hydrogen reclaimer, the bottom outer wall of the base passes through spiral shell Bolt is fixed with universal wheel.
In order to further improve the performance of novel energy-conserving hydrogen reclaimer, the Hydrogen collection tank is away from appendix The bottom of side outer wall offers discharge outlet.
Compared with prior art, beneficial effects of the present invention are:
The present invention provides a kind of novel energy-conserving hydrogen reclaimer, in present device, by increasing knockout drum, and is separating Filling limewash in tank, so as to depart to the mixed gas containing hydrogen, and is stirred with paddle, so that It can accelerate separated speed, by increasing Hydrogen collection tank, and increase condenser in tank, so as to will quickly contain moisture Hydrogen carry out having slept separation, the present apparatus is simple in structure in summary, easy to operate, and hydrogen recovery efficiency is high.
Brief description of the drawings
Fig. 1 is a kind of structural front view of novel energy-conserving hydrogen reclaimer proposed by the present invention.
Fig. 2 is a kind of structure top view of novel energy-conserving hydrogen reclaimer proposed by the present invention.
Fig. 3 is a kind of partial structural diagram of novel energy-conserving hydrogen reclaimer proposed by the present invention.
In figure:1 universal wheel, 2 bases, 3 air injection pipes, 4 paddles, 5 rotation axis, 6 motors, 7 bearings, 8 leakage fluid drams, 9 condensations Device, 10 discharge outlet, 11 Hydrogen collection tanks, 12 Hydrogen collection mouths, 13 appendixs, 14 collecting hoods, 15 liquid injection ports, 16 knockout drums, 17 Check valve, 18 pressure gauges, 19 booster pumps.
Embodiment
Below in conjunction with the attached drawing in the embodiment of the present invention, the technical solution in the embodiment of the present invention is carried out clear, complete Site preparation describes, it is clear that described embodiment is only part of the embodiment of the present invention, instead of all the embodiments.
With reference to Fig. 1-3, a kind of novel energy-conserving hydrogen reclaimer, including base 2, the bottom outer wall of base 2 pass through bolt Universal wheel 1 is fixed with, and the top outer wall of base 2 has been bolted booster pump 19, the port of export inner wall sleeve of booster pump 19 Air injection pipe 3 is connected to, and the top outer wall of air injection pipe 3 has been bolted pressure gauge 18, consolidates outside the top of base 2 by bolt Surely there is knockout drum 16, and the one end of air injection pipe 3 away from booster pump 19 is socketed in the bottom of 16 side outer wall of knockout drum, air injection pipe 3 Check valve 17 is bolted close to 16 one end outer wall of knockout drum, the bottom outer wall of knockout drum 16 offers opening, and opens Mouth inner wall is socketed with bearing 7, and the inner wall of bearing 7 is socketed with rotation axis 5, and the outer wall of rotation axis 5 is welded with paddle 4, base 2 Bottom inner wall be bolted motor 6, and the output shaft of motor 6 is rolled with rotation axis 5 and connected, and knockout drum 16 is close to single Liquid injection port 15 is offered to the top of 17 side outer wall of valve, and the bottom of 16 opposite side outer wall of knockout drum offers leakage fluid dram 8, point Top outer wall from tank 16 is welded with collecting hood 14, and the top inner wall of collecting hood 14 is socketed with appendix 13, the top of base 2 Outer wall has been bolted Hydrogen collection tank 11, and the one end of appendix 13 away from collecting hood 14 is socketed in Hydrogen collection tank 11 The bottom of side outer wall, 11 both sides inner wall axis line position of Hydrogen collection tank have been bolted a logical condenser 9, and hydrogen Bottom of the gas collecting tank 11 away from 13 side outer wall of appendix offers discharge outlet 10, and the top of Hydrogen collection tank 11 offers hydrogen Gas collection port 12.
In the present invention, the structure of knockout drum 16 and the structure of Hydrogen collection tank 11 are cylindrical structure, and knockout drum 16 Outside diameter be more than the outside diameter of Hydrogen collection tank 11, the quantity of paddle 4 is eight to ten six, and eight to ten six paddles 4 etc. Distance is welded in the outer wall surrounding of rotation axis 5, and the inner cavity of knockout drum 16 is filled with limewash, and the pH value of limewash is more than 8, The structure of condenser 9 is cylindrical structure, and the outside diameter of condenser 9 and the internal diameter of Hydrogen collection tank 11 match, collecting hood 14 Circle of position cone structure, and the outside diameter of 14 bottom of collecting hood is consistent with the outside diameter of knockout drum 16, outside 14 top outer wall of collecting hood Footpath and the outside diameter of appendix 13 match.
Operation principle:Limewash is injected into knockout drum 16 by liquid injection port 15 first, then by there is mixed gas It is injected into by increasing pump 19 in knockout drum 16, motor 6 starts to drive the paddle 4 in rotation axis 5 to rotate and start blender gas Aqueous mixtures, then will be transported in Hydrogen collection tank 11, condenser 9 will contain water with water vapor hydrogen by holding up pipe 13 The hydrogen of vapour is dehydrated, and then waits until that pure hydrogen is collected by Hydrogen collection mouth 12.
The foregoing is only a preferred embodiment of the present invention, but protection scope of the present invention be not limited thereto, Any one skilled in the art the invention discloses technical scope in, technique according to the invention scheme and its Inventive concept is subject to equivalent substitution or change, should be covered by the protection scope of the present invention.

Claims (8)

1. a kind of novel energy-conserving hydrogen reclaimer, including base(2), it is characterised in that the base(2)Top outer wall lead to Cross bolt and be fixed with booster pump(19), the booster pump(19)Port of export inner wall be socketed with air injection pipe(3), and air injection pipe(3) Top outer wall be bolted pressure gauge(18), the base(2)Top outside be bolted knockout drum (16), and air injection pipe(3)Away from booster pump(19)One end be socketed in knockout drum(16)The bottom of side outer wall, the air injection pipe (3)Close to knockout drum(16)One end outer wall has been bolted check valve(17), the knockout drum(16)Bottom outer wall open Equipped with opening, and the inner wall that is open is socketed with bearing(7), the bearing(7)Inner wall be socketed with rotation axis(5), and rotation axis(5) Outer wall be welded with paddle(4), the base(2)Bottom inner wall be bolted motor(6), and motor(6)'s Output shaft and rotation axis(5)Roll connection, the knockout drum(16)Close to check valve(17)The top of side outer wall offers note Liquid mouth(15), and knockout drum(16)The bottom of opposite side outer wall offers leakage fluid dram(8), the knockout drum(16)Top outer wall It is welded with collecting hood(14), and collecting hood(14)Top inner wall be socketed with appendix(13), the base(2)Top outer wall It has been bolted Hydrogen collection tank(11), and appendix(13)Away from collecting hood(14)One end be socketed in Hydrogen collection tank (11)The bottom of side outer wall, the Hydrogen collection tank(11)Both sides inner wall axis line position be bolted logical one it is cold Condenser(9), the Hydrogen collection tank(11)Top offer Hydrogen collection mouth(12).
A kind of 2. novel energy-conserving hydrogen reclaimer according to claim 1, it is characterised in that the knockout drum(16)'s Structure and Hydrogen collection tank(11)Structure be cylindrical structure, and knockout drum(16)Outside diameter be more than Hydrogen collection tank(11) Outside diameter.
A kind of 3. novel energy-conserving hydrogen reclaimer according to claim 1, it is characterised in that the paddle(4)'s Quantity is eight to ten six, and eight to ten six paddles(4)It is equidistant to be welded on rotation axis(5)Outer wall surrounding on.
A kind of 4. novel energy-conserving hydrogen reclaimer according to claim 1, it is characterised in that the knockout drum(16)'s Inner cavity is filled with limewash, and the pH value of limewash is more than 8.
A kind of 5. novel energy-conserving hydrogen reclaimer according to claim 1, it is characterised in that the condenser(9)'s Structure is cylindrical structure, and condenser(9)Outside diameter and Hydrogen collection tank(11)Internal diameter match.
A kind of 6. novel energy-conserving hydrogen reclaimer according to claim 1, it is characterised in that the collecting hood(14)Position Conical structure, and collecting hood(14)The outside diameter and knockout drum of bottom(16)Outside diameter it is consistent, collecting hood(14)Top outer wall Outside diameter and appendix(13)Outside diameter match.
A kind of 7. novel energy-conserving hydrogen reclaimer according to claim 1, it is characterised in that the base(2)Bottom End outer wall has been bolted universal wheel(1).
A kind of 8. novel energy-conserving hydrogen reclaimer according to claim 1, it is characterised in that the Hydrogen collection tank (11)Away from appendix(13)The bottom of side outer wall offers discharge outlet(10).
CN201711339307.4A 2017-12-14 2017-12-14 A kind of novel energy-conserving hydrogen reclaimer Pending CN107915208A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN116377355A (en) * 2023-01-30 2023-07-04 安徽赛丽金属科技有限公司 Copper wire annealing and tempering equipment

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1895995A (en) * 2006-06-28 2007-01-17 杨贻方 Hydrogen recovery machine
CN101982403A (en) * 2010-10-15 2011-03-02 怀化市双阳林化有限公司 Hydrogen purification and transportation method
CN201756449U (en) * 2010-07-30 2011-03-09 赣县世瑞新材料有限公司 Atmospheric hydrogen recovery system
WO2012086363A1 (en) * 2010-12-24 2012-06-28 株式会社Ihi Method and device for reforming produced gas
CN206570029U (en) * 2017-03-06 2017-10-20 郑州水神环保科技有限公司 A kind of hydrogen gas recovering device in industrial waste gas

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1895995A (en) * 2006-06-28 2007-01-17 杨贻方 Hydrogen recovery machine
CN201756449U (en) * 2010-07-30 2011-03-09 赣县世瑞新材料有限公司 Atmospheric hydrogen recovery system
CN101982403A (en) * 2010-10-15 2011-03-02 怀化市双阳林化有限公司 Hydrogen purification and transportation method
WO2012086363A1 (en) * 2010-12-24 2012-06-28 株式会社Ihi Method and device for reforming produced gas
CN206570029U (en) * 2017-03-06 2017-10-20 郑州水神环保科技有限公司 A kind of hydrogen gas recovering device in industrial waste gas

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN116377355A (en) * 2023-01-30 2023-07-04 安徽赛丽金属科技有限公司 Copper wire annealing and tempering equipment

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Application publication date: 20180417