CN105624203A - Method for producing biogas from cassava alcohol waste liquid as raw material - Google Patents

Method for producing biogas from cassava alcohol waste liquid as raw material Download PDF

Info

Publication number
CN105624203A
CN105624203A CN201410618625.4A CN201410618625A CN105624203A CN 105624203 A CN105624203 A CN 105624203A CN 201410618625 A CN201410618625 A CN 201410618625A CN 105624203 A CN105624203 A CN 105624203A
Authority
CN
China
Prior art keywords
liquid
biogas
cassava vinasse
cassava
raw material
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201410618625.4A
Other languages
Chinese (zh)
Inventor
庄志国
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
JIANGSU HUATING BIOTECHNOLOGY Co Ltd
Original Assignee
JIANGSU HUATING BIOTECHNOLOGY Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by JIANGSU HUATING BIOTECHNOLOGY Co Ltd filed Critical JIANGSU HUATING BIOTECHNOLOGY Co Ltd
Priority to CN201410618625.4A priority Critical patent/CN105624203A/en
Publication of CN105624203A publication Critical patent/CN105624203A/en
Pending legal-status Critical Current

Links

Classifications

    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00Technologies for the production of fuel of non-fossil origin
    • Y02E50/30Fuel from waste, e.g. synthetic alcohol or diesel
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/10Process efficiency
    • Y02P20/129Energy recovery, e.g. by cogeneration, H2recovery or pressure recovery turbines

Landscapes

  • Processing Of Solid Wastes (AREA)
  • Preparation Of Compounds By Using Micro-Organisms (AREA)

Abstract

The invention discloses a method for producing biogas from a cassava alcohol waste liquid as a raw material. The method belongs to the field of cassava alcohol production. The method utilizes a cassava alcohol waste liquid and biogas fermentation microbes as raw materials and utilizes a settling tank, an adjustment tank, an anaerobic fermentation cylinder and a water-sealed tank for sand setting and impurity removal, high temperature fermentation and water-sealed tank separation so that biogas is produced. The method utilizes a high temperature fermentation method, fully utilizes cassava alcohol waste liquid waste heat, improves a reaction rate by 2-3 times and has an anaerobic COD clearance rate of 95%. The method utilizes a cycle stirring device to replace a liquid circulating pump, realizes uniform and thorough cassava alcohol waste liquid circulation, improves a biogas yield by 30%, greatly reduces electricity consumption and has a power reduction rate of 80%.

Description

A kind of method with cassava vinasse as substratum liquid for raw material production biogas
Technical field
The invention belongs to cassava alcohol production field, particularly relate to a kind of method that cassava vinasse as substratum liquid produced with Maninot esculenta crantz. for main material production ethanol is raw material production biogas.
Background technology
Biogas be organic substance under anaerobic, the one mixing gas generated through the Fermentation of microorganism, fermentable is complicated biochemical change, many microorganisms are had to participate in, reaction substantially divides two stages: (1) microorganism becomes simple material the saccharide in complicated organic substance, fat, protein degradation, such as lower fatty acid, alcohol, aldehyde, carbon dioxide etc.; (2) by the effect of methane strain, some simple materials are made to become methane. Normally to produce biogas, it is necessary to create good condition for the existence of microorganism, breeding, first, the anaerobic environment of an anaerobe activity will be caused; Second, to maintain certain temperature in methane-generating pit; 3rd, methane-generating pit to have the nutrient of abundance; 4th, fermentation raw material will containing suitable quantity of water; 5th, the pH value general control of methane-generating pit is at 7-8.5.
Biogas is the mixture of multiple gases, and its Main Ingredients and Appearance is methane (CH4), carbon dioxide (CO2), hydrogen sulfide, carbon monoxide (CO), hydrogen, oxygen, nitrogen, the gas such as hydrogen sulfide, wherein methane is maximum, account for the 50%-70% of cumulative volume, carbon dioxide accounts for 25%-40%, other several gases are less, generally add up and be only about the 2% of cumulative volume, biogas can burn, main is exactly by methane, biogas, except directly burning is used for cooking, drying agricultural byproducts, heating, illumination and gas welding etc., also can be made the fuel of internal combustion engine and produce the industrial chemicals such as methanol, formalin, carbon tetrachloride; The feed liquid discharged after firedamp gas equipment ferments and sediment, containing more rich nutrient substance, can be used as fertilizer and feedstuff.
The raw material producing biogas is a lot, the present invention produces biogas with cassava vinasse as substratum liquid for raw material, cassava vinasse as substratum liquid is the garbage produced with Maninot esculenta crantz. for raw material production edible ethanol, its main component is material (COD:5 ten thousand mg/l such as remaining starch, crude protein, cellulose, various inorganic salt and mycoprotein, BOD:2.5 ten thousand mg/l, SS:2.5 ten thousand mg/l) biodegradability is relatively strong, has the available characteristic of potential resource; The auxiliary material used is methane fermentating microorganism, methane fermentating microorganism is the antibacterial that large numbers of of a great variety, obligate anaerobic could must grow in oxygen-free environment, methane fermentating microorganism is a general designation, including zymogenic bacteria, hydrogen-producing acetogens, consumption hydrogen acetogen, food producing hydrogen and methane bacterium, the food big monoid of acetic acid and methane producing bacterium five.
Summary of the invention
The problem that present invention mainly solves is to provide a kind of method with cassava vinasse as substratum liquid for raw material production biogas, the method, with cassava vinasse as substratum liquid, methane fermentating microorganism for raw material, produces biogas with separator well, regulating reservoir, anaerobic fermentation tank, water sealed tank for equipment.
The present invention can be achieved through the following technical solutions:
A kind of method with cassava vinasse as substratum liquid for raw material production biogas, is characterized in that being made up of following steps:
(1) the cassava vinasse as substratum liquid that temperature is 100 DEG C that workshop section discharges is distilled from ethanol workshop, through two-stage flash recovery of latent heat, cassava vinasse as substratum liquid temp is down to 86-88 DEG C, after carrying out heat exchange with spiral-plate heat exchanger and fermenting-ripening wine with dregs, cassava vinasse as substratum liquid temp is down to 72-74 DEG C, then it is sent to separator well by lees exhausting tube road, cassava vinasse as substratum liquid in separator well is under the effect of gravitational field, the bigger inoganic solids natural subsidence of proportion is to bottom, and upper strata is the cassava vinasse as substratum liquid after desanding, cooling.
(2) by desanding, cassava vinasse as substratum liquid after cooling enters regulating reservoir, be adjusted in pond arrange spiral-plate heat exchanger temperature regulating be 55-60 DEG C, then contact anaerobic fermentation tank it is pumped into, it is initially charged methane fermentating microorganism at contact anaerobic fermentation tank, according to cassava vinasse as substratum liquid: the ratio of methane fermentating microorganism=7:3 is squeezed in contact anaerobic fermentation tank, control temperature between 57-67 DEG C of degree, 2 the biogas dedicated compressor utilizing 45KW connect pipeline, carry out blowing stirring with natural pond bromhidrosis body, the liquid circulation pump stirring used before replacing, the uniformly rear dedicated compressor that stops to be mixed stirring, that uses generation biogas makes methane fermentating microorganism be fully contacted with grain liquid from stirring action, carry out hot fermentation, it is continuously available mixing gas.
(3) mixing gas being sent into water water sealed tank and carry out gas-liquid separation, the gas obtained is biogas.
The further technical scheme of the present invention is:
Separator well ditch length 40 meters described in step (1), wide 0.4 meter, deep 0.8 meter.
The diameter of the anaerobic fermentation tank described in step (2) is 15 meters, high 18 meters, dome, and volume is 3000 cubic metres, periphery rock wool and color steel insulation.
Biogas dedicated compressor described in step (2) is 45kw.
Cassava vinasse as substratum liquid hot fermentation temperature described in step (2) is 62 DEG C.
The invention has the beneficial effects as follows: providing a kind of method with cassava vinasse as substratum liquid for raw material production biogas, it has the main advantage that
1. the method adopts hot fermentation, and fermentation temperature is 62 DEG C, and more traditional fermentation temperature 24 DEG C producing biogas exceeds a lot, produces following beneficial effect: (1) is the waste heat making full use of cassava vinasse as substratum liquid; (2) response speed can improve 2-3 times; (3) anaerobism COD clearance can reach 95%;
2. adopt circulation stirring: utilize 2 biogas dedicated compressor of 45KW, carry out blowing stirring with biogas, the liquid circulation pump used before replacing, its advantage is: cassava vinasse as substratum liquid circulates evenly, thoroughly, biogas output improves 30%, and electric consumption is greatly reduced, power consumption reduces amplitude and reaches 80%.
Detailed description of the invention
Embodiment 1:
The cassava vinasse as substratum liquid that temperature is 100 DEG C that workshop section discharges is distilled from ethanol workshop, through two-stage flash recovery of latent heat, cassava vinasse as substratum liquid temp is down to 86 DEG C, after carrying out heat exchange with spiral-plate heat exchanger and fermenting-ripening wine with dregs, cassava vinasse as substratum liquid temp is down to 72 DEG C, then it is sent to separator well by lees exhausting tube road, cassava vinasse as substratum liquid in separator well is under the effect of gravitational field, the bigger inoganic solids natural subsidence of proportion is to bottom, and upper strata is the cassava vinasse as substratum liquid after desanding, cooling. by desanding, cassava vinasse as substratum liquid after cooling enters regulating reservoir, be adjusted in pond arrange spiral-plate heat exchanger temperature regulating be 55 DEG C, then contact anaerobic fermentation tank it is pumped into, it is initially charged methane fermentating microorganism at contact anaerobic fermentation tank, according to cassava vinasse as substratum liquid: the ratio of methane fermentating microorganism=7:3 is squeezed in closing tank, control temperature between 57 DEG C, 2 the biogas dedicated compressor utilizing 45KW connect pipeline, carry out blowing stirring with natural pond bromhidrosis body, the liquid circulation pump stirring used before replacing, the uniformly rear dedicated compressor that stops to be mixed stirring, that uses generation biogas makes methane fermentating microorganism be fully contacted with grain liquid from stirring action, carry out hot fermentation, it is continuously available mixing gas. mixing gas being sent into water water sealed tank and carries out gas-liquid separation, the gas obtained is biogas.
Embodiment 2:
The cassava vinasse as substratum liquid that temperature is 100 DEG C that workshop section discharges is distilled from ethanol workshop, through two-stage flash recovery of latent heat, cassava vinasse as substratum liquid temp is down to 87 DEG C, after carrying out heat exchange with spiral-plate heat exchanger and fermenting-ripening wine with dregs, cassava vinasse as substratum liquid temp is down to 73 DEG C, then it is sent to separator well by lees exhausting tube road, cassava vinasse as substratum liquid in separator well is under the effect of gravitational field, the bigger inoganic solids natural subsidence of proportion is to bottom, and upper strata is the cassava vinasse as substratum liquid after desanding, cooling. by desanding, cassava vinasse as substratum liquid after cooling enters regulating reservoir, be adjusted in pond arrange spiral-plate heat exchanger temperature regulating be 57.5 DEG C, then contact anaerobic fermentation tank it is pumped into, it is initially charged methane fermentating microorganism at contact anaerobic fermentation tank, according to cassava vinasse as substratum liquid: the ratio of methane fermentating microorganism=7:3 is squeezed in closing tank, control temperature between 62 DEG C, 2 the biogas dedicated compressor utilizing 45KW connect pipeline, carry out blowing stirring with natural pond bromhidrosis body, the liquid circulation pump stirring used before replacing, the uniformly rear dedicated compressor that stops to be mixed stirring, that uses generation biogas makes methane fermentating microorganism be fully contacted with grain liquid from stirring action, carry out hot fermentation, it is continuously available mixing gas. mixing gas being sent into water water sealed tank and carries out gas-liquid separation, the gas obtained is biogas.
Embodiment 3:
The cassava vinasse as substratum liquid that temperature is 100 DEG C that workshop section discharges is distilled from ethanol workshop, through two-stage flash recovery of latent heat, cassava vinasse as substratum liquid temp is down to 88 DEG C, after carrying out heat exchange with spiral-plate heat exchanger and fermenting-ripening wine with dregs, cassava vinasse as substratum liquid temp is down to 74 DEG C, then it is sent to separator well by lees exhausting tube road, cassava vinasse as substratum liquid in separator well is under the effect of gravitational field, the bigger inoganic solids natural subsidence of proportion is to bottom, and upper strata is the cassava vinasse as substratum liquid after desanding, cooling. by desanding, cassava vinasse as substratum liquid after cooling enters regulating reservoir, be adjusted in pond arrange spiral-plate heat exchanger temperature regulating be 60 DEG C, then contact anaerobic fermentation tank it is pumped into, it is initially charged methane fermentating microorganism at contact anaerobic fermentation tank, according to cassava vinasse as substratum liquid: the ratio of methane fermentating microorganism=7:3 is squeezed in closing tank, control temperature between 67 DEG C, 2 the biogas dedicated compressor utilizing 45KW connect pipeline, carry out blowing stirring with natural pond bromhidrosis body, the liquid circulation pump stirring used before replacing, the uniformly rear dedicated compressor that stops to be mixed stirring, that uses generation biogas makes methane fermentating microorganism be fully contacted with grain liquid from stirring action, carry out hot fermentation, it is continuously available mixing gas. mixing gas being sent into water water sealed tank and carries out gas-liquid separation, the gas obtained is biogas.

Claims (5)

1. the method with cassava vinasse as substratum liquid for raw material production biogas, the raw material of use includes: cassava vinasse as substratum liquid, methane fermentating microorganism are raw material, it is characterized in that:
(1) the cassava vinasse as substratum liquid that temperature is 100 DEG C that workshop section discharges is distilled from ethanol workshop, through two-stage flash recovery of latent heat, cassava vinasse as substratum liquid temp is down to 86-88 DEG C, after carrying out heat exchange with spiral-plate heat exchanger and fermenting-ripening wine with dregs, cassava vinasse as substratum liquid temp is down to 72-74 DEG C, then it is sent to separator well by lees exhausting tube road, cassava vinasse as substratum liquid in separator well is under the effect of gravitational field, the bigger inoganic solids natural subsidence of proportion is to bottom, and upper strata is the cassava vinasse as substratum liquid after desanding, cooling;
(2) by desanding, cassava vinasse as substratum liquid after cooling enters regulating reservoir, be adjusted in pond arrange spiral-plate heat exchanger temperature regulating be 55-60 DEG C, then contact anaerobic fermentation tank it is pumped into, it is initially charged methane fermentating microorganism at contact anaerobic fermentation tank, according to cassava vinasse as substratum liquid: the ratio of methane fermentating microorganism=7:3 is squeezed in closing tank, control temperature between 57-67 DEG C of degree, 2 the biogas dedicated compressor utilizing 45KW connect pipeline, carry out blowing stirring with natural pond bromhidrosis body, the liquid circulation pump stirring used before replacing, the uniformly rear dedicated compressor that stops to be mixed stirring, that uses generation biogas makes methane fermentating microorganism be fully contacted with grain liquid from stirring action, carry out hot fermentation, it is continuously available mixing gas,
(3) mixing gas being sent into water water sealed tank and carry out gas-liquid separation, the gas obtained is biogas.
2. the method with cassava vinasse as substratum liquid for raw material production biogas according to claim 1, is characterized in that: separator well ditch length 40 meters described in step (1), wide 0.4 meter, deep 0.8 meter.
3. the method with cassava vinasse as substratum liquid for raw material production biogas according to claim 1, is characterized in that: the diameter of the anaerobic fermentation tank described in step (2) is 15 meters, high 18 meters, dome, and volume is 3000 cubic metres, periphery rock wool and color steel insulation.
4. the method with cassava vinasse as substratum liquid for raw material production biogas according to claim 1, is characterized in that: the biogas dedicated compressor described in step (2) is 45kw.
5. the method with cassava vinasse as substratum liquid for raw material production biogas according to claim 1, is characterized in that: the cassava vinasse as substratum liquid hot fermentation temperature described in step (2) is 62 DEG C.
CN201410618625.4A 2014-11-06 2014-11-06 Method for producing biogas from cassava alcohol waste liquid as raw material Pending CN105624203A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201410618625.4A CN105624203A (en) 2014-11-06 2014-11-06 Method for producing biogas from cassava alcohol waste liquid as raw material

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201410618625.4A CN105624203A (en) 2014-11-06 2014-11-06 Method for producing biogas from cassava alcohol waste liquid as raw material

Publications (1)

Publication Number Publication Date
CN105624203A true CN105624203A (en) 2016-06-01

Family

ID=56039545

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201410618625.4A Pending CN105624203A (en) 2014-11-06 2014-11-06 Method for producing biogas from cassava alcohol waste liquid as raw material

Country Status (1)

Country Link
CN (1) CN105624203A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106929541A (en) * 2017-04-27 2017-07-07 北京化工大学 A kind of method of industrial acid-sludge discarded object solid anaerobic digestion methane phase
CN111254179A (en) * 2018-11-30 2020-06-09 国投生物科技投资有限公司 Method for preparing biogas by using waste mash produced by fermenting alcohol with cassava and method for generating power by using biogas

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106929541A (en) * 2017-04-27 2017-07-07 北京化工大学 A kind of method of industrial acid-sludge discarded object solid anaerobic digestion methane phase
CN111254179A (en) * 2018-11-30 2020-06-09 国投生物科技投资有限公司 Method for preparing biogas by using waste mash produced by fermenting alcohol with cassava and method for generating power by using biogas

Similar Documents

Publication Publication Date Title
Debowski et al. Zieli nski, M
Sorathia et al. Biogas generation and factors affecting the Bio-gas generationea review study’
Guneratnam et al. Comparative study of single-and two-stage fermentation of the brown seaweed Laminaria digitata
Kigozi et al. Biogas technology: current trends, opportunities and challenges
CN101338325A (en) Process for producing methane by dry-type fermentation of stalks
CN102168109A (en) Method for producing hydrogen and methane through continuous solid state fermentation of kitchen garbage
Laikova et al. The feasibility of single-stage biohythane production in a semi-continuous thermophilic bioreactor: Influence of operating parameters on the process kinetics and microbial community dynamics
CN104388484B (en) A kind of method that microbial grease is produced using volatile fatty acid as fermenting raw materials
CN106145339A (en) A kind of mud takes off the methanogenic device of filtrate and technique
CN101665810A (en) Method for producing volatile fatty acid by anaerobic fermentation of excess sludge
CN101445810B (en) Method for preparing hydrogen by fermenting biologically pretreated straw
CN103923968B (en) Alienation metal reducing miroorganisms is utilized to promote the methanogenic method of methanogen
Lay et al. Continuous anaerobic hydrogen and methane production using water hyacinth feedstock
CN205576158U (en) Two stage of solid -liquid anaerobic fermentation device
CN111793655A (en) A rapid start-up process and stable operation method for dry fermentation of chicken manure and corn stalks
Li et al. Effect of initial sludge loading rate on the formation of ethanol type fermentation for hydrogen production in a continuous stirred‐tank reactor
CN105624203A (en) Method for producing biogas from cassava alcohol waste liquid as raw material
CN102241458A (en) Xanthan waste water treatment process
CN101456651B (en) A treatment method for primary leachate of garbage
CN101168752B (en) A method of increasing the yield of waste biomass converted into acetic acid by fed-batch mode
CN102586336A (en) Two-stage conversion method for producing bio-methane
CN108315353A (en) The method of ocean bulk kelp and microalgae mixed fermentation continuous production hydrogen and methane
CN109355314B (en) Method for producing combustible gas by using kitchen garbage and sludge
CN203128553U (en) Hydraulic compression-separation device for industrial biogas
CN204251616U (en) With the new device of cassava vinasse as substratum liquid for raw material production biogas

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
WD01 Invention patent application deemed withdrawn after publication

Application publication date: 20160601

WD01 Invention patent application deemed withdrawn after publication