CN107904026A - A kind of santal water-soluble laundry washing piece and preparation method thereof - Google Patents
A kind of santal water-soluble laundry washing piece and preparation method thereof Download PDFInfo
- Publication number
- CN107904026A CN107904026A CN201711035381.7A CN201711035381A CN107904026A CN 107904026 A CN107904026 A CN 107904026A CN 201711035381 A CN201711035381 A CN 201711035381A CN 107904026 A CN107904026 A CN 107904026A
- Authority
- CN
- China
- Prior art keywords
- washing piece
- santal
- water
- disintegrant
- laundry washing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0047—Detergents in the form of bars or tablets
- C11D17/0065—Solid detergents containing builders
- C11D17/0073—Tablets
- C11D17/0086—Laundry tablets
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/662—Carbohydrates or derivatives
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/001—Softening compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0021—Dye-stain or dye-transfer inhibiting compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0052—Gas evolving or heat producing compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/10—Carbonates ; Bicarbonates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2086—Hydroxy carboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
- C11D3/225—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin etherified, e.g. CMC
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3707—Polyethers, e.g. polyalkyleneoxides
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3757—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions
- C11D3/3761—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions in solid compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/382—Vegetable products, e.g. soya meal, wood flour, sawdust
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Emergency Medicine (AREA)
- Inorganic Chemistry (AREA)
- Detergent Compositions (AREA)
Abstract
The invention discloses a kind of santal water-soluble laundry washing piece, it is based on parts by weight of raw materials including following component：5~45 parts of alkyl glycosides, 15~30 parts of compound disintegrant, 1~3 part of sandalwood essential oil, 0.2~2 part of filming agent, 0.05~0.8 part of adhesive, 5~10 parts of solvent.The present invention is using alkyl glycosides as surfactant, it has the characteristic of nonionic and anion surface active concurrently, both there is good environment-friendly and green ecological safety activity, there is multifunction surface activity again, it is nontoxic, harmless, non-stimulated to skin, there is broad spectrum antibiotic activity, the concrete component and proportioning of compound disintegrant are adjusted at the same time, so that the clothes washing piece has excellent comprehensive performance, it is colour-fast, soft using rear clothing, and can effectively antistatic, mould proof, fungi-proofing, insect prevention, lasting.The invention also discloses the preparation method of the clothes washing piece, its technique is simple, is conducive to large-scale industrial production.
Description
Technical field
The present invention relates to clothes washing field, more particularly to a kind of clothes washing piece.
Background technology
Traditional clothes washing articles for use such as liquid detergent, washing powder, because using the surfactant and a large amount of alkali for being difficult to degrade
Property material and cause the environmental pollution that can not be ignored, and the active matter content in traditional clothes washing articles for use it is low, stablize
The not high, dirt-removing power of property is not strong, so that its washing effect still has much room for improvement.It is thus with people's living standard and comprehensive to daily necessities
The continuous improvement of the requirement of performance is closed, clothes washing piece comes into being.Clothing with detergent tablet be by detergent ingredients with flakes
Auxiliary agent mixing after suppress a kind of high density, accurate measurement, portable Novel clothes cleaning product, it is not only conformed with
Increasing life idea, and be after detergent powder and liquid the shortcomings that compensate for detergent powder and liquid detergent
Another revolutionary product after body detergent, has larger market development potential.Washed however, existing clothes washing piece exists
Wash the drawbacks such as principle is single, disintegration effect is undesirable, dissolution time is long, function is single, easy moisture absorption change tide.So how into
The comprehensive performance that one step improves clothes washing piece is of great significance.
The content of the invention
It is an object of the invention to the deficiency for above-mentioned technology, there is provided a kind of santal water-soluble laundry washing piece, at the same time
The preparation method of the washing piece is provided.
The technical solution used in the present invention is：A kind of santal water-soluble laundry washing piece, it is wrapped based on parts by weight of raw materials
Include following component：
Further as such scheme is improved, and the compound disintegrant is pressed by effervescence type disintegrant and swelling disintegrant
Weight ratio is 1:1 compounding forms.Yet further, the effervescence type disintegrant is made of sodium acid carbonate and citric acid；It is described molten
Swollen type disintegrant is selected from Sodium Polyacrylate or sodium carboxymethyl starch.Specifically, the present invention is 1 by weight:1 is disintegrated effervescence type
Agent and swelling disintegrant compounding, effervescent system used meet the carbon dioxide generated during water and promote disintegration of tablet；Used is molten
For swollen type polymer when contacting water, the increase of volume itself, producing tension force divides tablet, passes through two kinds of different principles and two kinds
The restriction of disintegrant weight ratio, drastically increases the disintegration of clothes washing piece of the present invention in water, easy to use.
Further as such scheme is improved, and the filming agent is selected from Macrogol 4000, Macrogol 6000, poly- second
One of which in enol 1788, it can effectively prevent clothes washing piece moisture absorption from making moist, while the filming agent of the present invention and santal
Essential oil acts synergistically, can be further moisture-proof so that substantially prolongs the shelf-life of the clothes washing piece.
Further as such scheme is improved, and described adhesive is pregelatinized starch.
A kind of preparation method of santal water-soluble laundry washing piece as described above, it is comprised the technical steps that：
1) take alkyl glycosides and compound disintegrant to be uniformly mixed by raw material proportioning, obtain solution I；
2) take sandalwood essential oil, filming agent and solvent to be uniformly mixed by raw material proportioning, obtain solution II；
3) solution I and solution II are mixed to be placed under 55~60 DEG C of temperature conditionss and dried, crushed, sieving, obtains pellet；
4) by pellet extrusion forming, washing piece finished product is obtained.
The beneficial effects of the invention are as follows：
(1) for the present invention using alkyl glycosides as surfactant, it has the spy of nonionic and anion surface active concurrently
Property, not only with good environment-friendly and green ecological safety activity, but also there is multifunction surface activity, it is nontoxic, harmless, stingless to skin
Swash, there is broad spectrum antibiotic activity, while adjust the concrete component and proportioning of compound disintegrant so that the clothes washing piece has excellent
Different comprehensive performance, can remove a variety of stains, such as grease, bloodstain, sweat stain, milk stain, rust stain, ink blok, use rear clothing
It is colour-fast, bright-colored, soft, and can effectively antistatic, mould proof, fungi-proofing, insect prevention, lasting, suitable for the linen fabrics, wool, mixed
The washing of the various materials such as spinning, chemical fibre, pure cotton.
(2) the preparation method technique of clothes washing piece of the present invention is simple, is conducive to large-scale industrial production.
Embodiment
The present invention is specifically described with reference to embodiment, in order to technical field personnel to the present invention
Understand.It is necessary that herein the present invention will be further described it is emphasized that embodiment is only intended to, it is impossible to be interpreted as to this
The limitation of invention protection domain, fields person skilled in the art, the non-intrinsically safe made according to foregoing invention content to the present invention
The modifications and adaptations of property, should still fall within protection scope of the present invention.Mentioned raw materials following at the same time are unspecified, are
Commercial product；The processing step or preparation method not referred in detail be processing step known to a person skilled in the art or
Preparation method.
Embodiment 1
A kind of santal water-soluble laundry washing piece, it is based on parts by weight of raw materials including following component：
The compound disintegrant is 1 by weight by effervescence type disintegrant and swelling disintegrant:1 compounding forms.Again into
One step, the effervescence type disintegrant is made of sodium acid carbonate and citric acid；The swelling disintegrant is sodium carboxymethyl starch.
Preparation method：
1) take alkyl glycosides and compound disintegrant to be uniformly mixed by raw material proportioning, obtain solution I；
2) take sandalwood essential oil, filming agent and solvent to be uniformly mixed by raw material proportioning, obtain solution II；
3) solution I and solution II are mixed to be placed under 55~60 DEG C of temperature conditionss and dried, crushed, sieving, obtains pellet；
4) by pellet extrusion forming, washing piece finished product is obtained.
Embodiment 2
A kind of santal water-soluble laundry washing piece, it is based on parts by weight of raw materials including following component：
The compound disintegrant is 1 by weight by effervescence type disintegrant and swelling disintegrant:1 compounding forms.Again into
One step, the effervescence type disintegrant is made of sodium acid carbonate and citric acid；The swelling disintegrant is Sodium Polyacrylate.
Preparation method：
1) take alkyl glycosides and compound disintegrant to be uniformly mixed by raw material proportioning, obtain solution I；
2) take sandalwood essential oil, filming agent and solvent to be uniformly mixed by raw material proportioning, obtain solution II；
3) solution I and solution II are mixed to be placed under 55~60 DEG C of temperature conditionss and dried, crushed, sieving, obtains pellet；
4) by pellet extrusion forming, washing piece finished product is obtained.
Embodiment 3
A kind of santal water-soluble laundry washing piece, it is based on parts by weight of raw materials including following component：
The compound disintegrant is 1 by weight by effervescence type disintegrant and swelling disintegrant:1 compounding forms.Again into
One step, the effervescence type disintegrant is made of sodium acid carbonate and citric acid；The swelling disintegrant is Sodium Polyacrylate.
Preparation method：
1) take alkyl glycosides and compound disintegrant to be uniformly mixed by raw material proportioning, obtain solution I；
2) take sandalwood essential oil, filming agent and solvent to be uniformly mixed by raw material proportioning, obtain solution II；
3) solution I and solution II are mixed to be placed under 55~60 DEG C of temperature conditionss and dried, crushed, sieving, obtains pellet；
4) by pellet extrusion forming, washing piece finished product is obtained.
Above-described embodiment is the preferred embodiment of the present invention, all with similar technique of the invention and the equivalence changes made,
The protection category of the present invention should all be belonged to.
Claims (7)
1. a kind of santal water-soluble laundry washing piece, it is characterised in that including following component based on parts by weight of raw materials：
A kind of 2. santal water-soluble laundry washing piece according to claim 1, it is characterised in that：The compound disintegrant by
Effervescence type disintegrant and swelling disintegrant are 1 by weight:1 compounding forms.
A kind of 3. santal water-soluble laundry washing piece according to claim 2, it is characterised in that：The effervescence type disintegrant
It is made of sodium acid carbonate and citric acid.
A kind of 4. santal water-soluble laundry washing piece according to claim 2, it is characterised in that：The swelling disintegrant
Selected from Sodium Polyacrylate or sodium carboxymethyl starch.
A kind of 5. santal water-soluble laundry washing piece according to claim 1, it is characterised in that：The filming agent is selected from poly-
One of which in ethylene glycol 4000, Macrogol 6000, polyvinyl alcohol 1788.
A kind of 6. santal water-soluble laundry washing piece according to claim 1, it is characterised in that：Described adhesive is pre- glue
Change starch.
It is 7. a kind of as the preparation method of claim 1~6 any one of them santal water-soluble laundry washing piece, its feature exist
In comprising the technical steps that：
1) take alkyl glycosides and compound disintegrant to be uniformly mixed by raw material proportioning, obtain solution I；
2) take sandalwood essential oil, filming agent and solvent to be uniformly mixed by raw material proportioning, obtain solution II；
3) solution I and solution II are mixed to be placed under 55~60 DEG C of temperature conditionss and dried, crushed, sieving, obtains pellet；
4) by pellet extrusion forming, washing piece finished product is obtained.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711035381.7A CN107904026A (en) | 2017-10-30 | 2017-10-30 | A kind of santal water-soluble laundry washing piece and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711035381.7A CN107904026A (en) | 2017-10-30 | 2017-10-30 | A kind of santal water-soluble laundry washing piece and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107904026A true CN107904026A (en) | 2018-04-13 |
Family
ID=61842091
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201711035381.7A Pending CN107904026A (en) | 2017-10-30 | 2017-10-30 | A kind of santal water-soluble laundry washing piece and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107904026A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111748422A (en) * | 2020-07-24 | 2020-10-09 | 汪红兵 | Washing machine door seal rubber ring mildew spot remover and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103966032A (en) * | 2013-01-30 | 2014-08-06 | 石家庄菠莉亚日用化工有限公司 | Environment-friendly concentrated sheet-shaped neutral detergent |
| CN106190626A (en) * | 2016-07-25 | 2016-12-07 | 南京尚易环保科技有限公司 | A kind of overlay film type clothing detergent tablet and preparation method thereof |
| JP2017101094A (en) * | 2015-11-30 | 2017-06-08 | 株式会社中川 | Manufacturing method of a tablet-type detergent composition for cleaning containing shell burning calcium |
| CN106916640A (en) * | 2017-03-13 | 2017-07-04 | 广东得到宝贝科技有限公司 | A kind of laundry detergent |
-
2017
- 2017-10-30 CN CN201711035381.7A patent/CN107904026A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103966032A (en) * | 2013-01-30 | 2014-08-06 | 石家庄菠莉亚日用化工有限公司 | Environment-friendly concentrated sheet-shaped neutral detergent |
| JP2017101094A (en) * | 2015-11-30 | 2017-06-08 | 株式会社中川 | Manufacturing method of a tablet-type detergent composition for cleaning containing shell burning calcium |
| CN106190626A (en) * | 2016-07-25 | 2016-12-07 | 南京尚易环保科技有限公司 | A kind of overlay film type clothing detergent tablet and preparation method thereof |
| CN106916640A (en) * | 2017-03-13 | 2017-07-04 | 广东得到宝贝科技有限公司 | A kind of laundry detergent |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111748422A (en) * | 2020-07-24 | 2020-10-09 | 汪红兵 | Washing machine door seal rubber ring mildew spot remover and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102965223B (en) | Nano-multifunctional washing sheet | |
| KR101936106B1 (en) | Sheet for laundry | |
| KR101358923B1 (en) | Sheet for laundry | |
| KR102075408B1 (en) | Preparation method of eco-friendly detergent | |
| KR101411559B1 (en) | Sheet for laundry | |
| CN110964607A (en) | Laundry detergent with sterilization function and preparation method thereof | |
| CN109135958A (en) | A kind of antimicrobial cleaning particle and preparation method thereof with timing | |
| CN107904026A (en) | A kind of santal water-soluble laundry washing piece and preparation method thereof | |
| CN106811330B (en) | A kind of laundry effervescent tablet and preparation method thereof | |
| CN105219541A (en) | A kind of preparation method of skin care Infant laundry detergent | |
| CN107828520A (en) | A kind of Chinese herbal medicine water-soluble laundry washing piece and preparation method thereof | |
| CN106833930A (en) | A kind of environment-friendly type light dirt liquid detergent | |
| CN102634421A (en) | Clothes washing agent and preparation method thereof | |
| KR101472533B1 (en) | Laundry sheet having continuing surface and discontinuing surface and, manufacturing methods for the laundry sheet | |
| CN105112174A (en) | Bactericidal mould-proof laundry detergent | |
| JPS62197497A (en) | Tablet detergent | |
| CN107012012A (en) | A kind of washing powder containing nanometer carbon crystal element | |
| CN107418741A (en) | Color protection laundry sheet and preparation method thereof | |
| CN104629928A (en) | Gentle and safe laundry detergent and preparation method thereof | |
| CN103602535A (en) | Synthesized soap powder | |
| CN109112020B (en) | Instant soap flakes and preparation method thereof | |
| CN103343056B (en) | A kind of multi-functional washing oxygen particle and preparation method thereof | |
| CN108264972A (en) | A kind of tea tree ethereal oil concentrated detergent China liquid and preparation method thereof | |
| CN108774591A (en) | A kind of antibacterial and mouldproof washing machine cleaning curing agent and preparation method thereof | |
| CN103710160B (en) | A kind of powdery contains the composition and method of making the same of ethoxylated alkyl sulfate |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20180413 |
|
| RJ01 | Rejection of invention patent application after publication |