CN107902767A - Domestic sewage of villages and small towns inorganic agent and preparation method thereof - Google Patents

Domestic sewage of villages and small towns inorganic agent and preparation method thereof Download PDF

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Publication number
CN107902767A
CN107902767A CN201711244357.4A CN201711244357A CN107902767A CN 107902767 A CN107902767 A CN 107902767A CN 201711244357 A CN201711244357 A CN 201711244357A CN 107902767 A CN107902767 A CN 107902767A
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parts
villages
domestic sewage
alum
small towns
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兰秋波
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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/34Biological treatment of water, waste water, or sewage characterised by the microorganisms used
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/30Aerobic and anaerobic processes
    • C02F3/302Nitrification and denitrification treatment
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00Nature of the contaminant
    • C02F2101/10Inorganic compounds
    • C02F2101/105Phosphorus compounds
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00Nature of the contaminant
    • C02F2101/10Inorganic compounds
    • C02F2101/16Nitrogen compounds, e.g. ammonia

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  • Life Sciences & Earth Sciences (AREA)
  • Microbiology (AREA)
  • Biodiversity & Conservation Biology (AREA)
  • Hydrology & Water Resources (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)

Abstract

The invention discloses a kind of domestic sewage of villages and small towns inorganic agent, is mainly made originally of following:Alum, polyvinyl alcohol, boric acid, diatomite, activated carbon, calcium gluconate, tannin, lithopone, activated carbon, microbial inoculum, coagulation agent, nano silicon dioxide, starch xanthate and alum.Domestic sewage of villages and small towns inorganic agent of the present invention, during for sewage disposal, processing is thorough, and COD, BOD and SS (suspended matter in water quality) of sewage decline to a great extent after processing, total nitrogen, total phosphorus and ammonia-nitrogen content also have different degrees of decline, alleviate the burden in the last handling process of sewage.Water after processing can reuse, and save water resource.And preparation method is simple, equipment investment is few.

Description

Domestic sewage of villages and small towns inorganic agent and preparation method thereof
Technical field
The present invention relates to sewage treatment field, more particularly to a kind of domestic sewage of villages and small towns inorganic agent and preparation method thereof.
Background technology
Produced by sanitary sewage is mainly used in human lives various water for kitchen use, slurry and use in toilet water Discharge water, be mostly nontoxic inorganic salts.The sewage produced during human lives, is one of primary pollution source of water body. Mainly excrement and wash water.Everyone sanitary sewage amount discharged daily of city is 150-400L, its amount has with living standard Substantial connection.Contain large amount of organic, such as cellulose, starch, carbohydrate and fat protein in sanitary sewage;Also often containing ill Opportunistic pathogen, virus and parasitic ovum;Chloride, sulfate, phosphate, bicarbonate and the sodium of inorganic salts, potassium, calcium, magnesium etc..Always The characteristics of be nitrogenous, sulfur-bearing and phosphorous height, in the case where anaerobic bacteria acts on, easily raw odorant.
While living standard improves, life style does not change rural resident therewith, also according to tradition Lifestyle, the sanitary sewage of rural resident is mostly directly to be poured on Around the house, the mode of this sewage effluent, no But sewage is flow over, influence look of a village, and sewage permeates the ground for a long time, nitrogenous in sanitary sewage, phosphorus, and sulphur is more, pathogenic bacteria is more, Rural groundwater quality is caused to deteriorate.The simple running water or Hand pump well in most of rural areas are directly taken without any processing Underground water is drinking water, and very big threat is caused to the health of people.
The information for being disclosed in the background section is merely intended to understanding of the increase to the general background of the present invention, without answering It has been the prior art well known to persons skilled in the art when being considered as recognizing or implying the information structure in any form.
The content of the invention
It is an object of the invention to provide a kind of domestic sewage of villages and small towns inorganic agent, so as to overcome processing sanitary sewage not reach Mark, or the shortcomings that regulation effect is undesirable.
Another object of the present invention is to the preparation method of domestic sewage of villages and small towns inorganic agent.
To achieve the above object, the present invention provides a kind of domestic sewage of villages and small towns inorganic agent, mainly it was made originally of following: Alum, polyvinyl alcohol, boric acid, diatomite, activated carbon, calcium gluconate, tannin, lithopone, activated carbon, microbial inoculum, coagulation agent, receive Rice silica, starch xanthate and alum.
Preferably, in above-mentioned technical proposal, the domestic sewage of villages and small towns inorganic agent, is counted in parts by weight, mainly by with It was made originally down:5-12 parts of alum, 7-14 parts of polyvinyl alcohol, 4-8 parts of boric acid, 8-16 parts of diatomite, 11-18 parts of activated carbon, Portugal 3-8 parts of grape Calciofon, 7-16 parts of tannin, 3-5 parts of lithopone, 9-15 parts of activated carbon, 4-9 parts of microbial inoculum, 5-14 parts of coagulation agent, nanometer 2-5 parts of 7-15 parts of silica, 3-6 parts of starch xanthate and alum.
Preferably, in above-mentioned technical proposal, the domestic sewage of villages and small towns inorganic agent, is counted in parts by weight, mainly by with It was made originally down:8 parts of alum, 11 parts of polyvinyl alcohol, 6 parts of boric acid, 12 parts of diatomite, 16 parts of activated carbon, 6 parts of calcium gluconate, 11 parts of tannin, 4 parts of lithopone, 13 parts of activated carbon, 7 parts of microbial inoculum, 7 parts of coagulation agent, 9 parts of nano silicon dioxide, starch xanthate 5 3 parts of part and alum.
Preferably, in above-mentioned technical proposal, the coagulation agent is polyacrylamide.
Preferably, in above-mentioned technical proposal, the strain is nitrobacteria, denitrifying bacteria or third generation nitration denitrification Composite bacteria.
A kind of preparation method of domestic sewage of villages and small towns inorganic agent, comprises the following steps:
(1) by diatomite and alum mixing and water adding slurrying, the particle of a diameter of 0.5-1.5mm is made;
(2) when particle being placed in calcination 4-9 is small under 400-500 DEG C of temperature conditionss, it is cooled to room temperature;
(3) by particle made from step (2) and polyvinyl alcohol, boric acid, calcium gluconate, tannin, lithopone, coagulation agent, Nano silicon dioxide, starch xanthate, alum add water to mix, and 2-3 is mixed under conditions of being 65-70 DEG C in temperature Hour;
(4) 50 DEG C are cooled to, crosslinking agent hybrid reaction is added in the mixed liquor of step (3), then is warming up to 70 DEG C, is reacted 30-60min, then dries mixture under the conditions of 120-140 DEG C;
(5) strain and activated carbon are added in mixture after the drying, is uniformly mixed, obtains at domestic sewage of villages and small towns Manage agent.
Preferably, in above-mentioned technical proposal, the crosslinking agent is N, N '-dimethyl allylidene acid amides.
Preferably, in above-mentioned technical proposal, the amount for adding crosslinking agent is the 1-5% of diatomite quality.
Compared with prior art, the present invention has the advantages that:Domestic sewage of villages and small towns inorganic agent of the present invention, for dirt During water process, processing is thorough, and COD, BOD and SS (suspended matter in water quality) of sewage decline to a great extent after processing, total nitrogen, total phosphorus Also there is different degrees of decline with ammonia-nitrogen content, alleviate the burden in the last handling process of sewage, reach discharge standard.Processing Water afterwards can reuse, and save water resource.And preparation method is simple, equipment investment is few.
Embodiment
With reference to specific embodiment, the embodiment of the present invention is described in detail, it is to be understood that this hair Bright protection domain and from the limitation of embodiment.
Embodiment 1
A kind of domestic sewage of villages and small towns inorganic agent, was mainly made originally of following:Count in parts by weight, mainly by following original It is made:8 parts of alum, 11 parts of polyvinyl alcohol, 6 parts of boric acid, 12 parts of diatomite, 16 parts of activated carbon, 6 parts of calcium gluconate, tannin 11 Part, 4 parts of lithopone, 13 parts of activated carbon, 7 parts of microbial inoculum, 7 parts of polyacrylamide, 9 parts of nano silicon dioxide, 5 parts of starch xanthate With 3 parts of alum.
The strain is third generation nitration denitrification composite bacteria.Third generation nitration denitrification composite bacteria, using A kind of sewage disposal strain of De Fengsheng owner's research and development in 2014.
A kind of preparation method of domestic sewage of villages and small towns inorganic agent, comprises the following steps:
(1) by diatomite and alum mixing and water adding slurrying, the particle of a diameter of 0.5-1.5mm is made;
(2) when particle being placed in calcination 7 is small under 400-500 DEG C of temperature conditionss, it is cooled to room temperature;
(3) by particle made from step (2) and polyvinyl alcohol, boric acid, calcium gluconate, tannin, lithopone, coagulation agent, Nano silicon dioxide, starch xanthate, alum add water to mix, and 2.5 are mixed under conditions of being 65-70 DEG C in temperature Hour;
(4) 50 DEG C are cooled to, crosslinking agent N, the mixing of N '-dimethyl allylidene acid amides are added in the mixed liquor of step (3) Reaction, the amount for adding crosslinking agent is the 3% of diatomite quality, then is warming up to 70 DEG C, reacts 50min, then mixture exists Dried under the conditions of 120-140 DEG C;
(5) strain and activated carbon are added in mixture after the drying, is uniformly mixed, obtains at domestic sewage of villages and small towns Manage agent.
Embodiment 2
A kind of domestic sewage of villages and small towns inorganic agent, was mainly made originally of following:Count in parts by weight, mainly by following original It is made:5 parts of alum, 14 parts of polyvinyl alcohol, 4 parts of boric acid, 16 parts of diatomite, 11 parts of activated carbon, 3 parts of calcium gluconate, tannin 16 Part, 3 parts of lithopone, 9 parts of activated carbon, 4 parts of microbial inoculum, 14 parts of polyacrylamide, 7 parts of nano silicon dioxide, 6 parts of starch xanthate With 2 parts of alum.The strain is nitrobacteria.
A kind of preparation method of domestic sewage of villages and small towns inorganic agent, comprises the following steps:
(1) by diatomite and alum mixing and water adding slurrying, the particle of a diameter of 0.5-1.5mm is made;
(2) when particle being placed in calcination 4 is small under 400-500 DEG C of temperature conditionss, it is cooled to room temperature;
(3) by particle made from step (2) and polyvinyl alcohol, boric acid, calcium gluconate, tannin, lithopone, coagulation agent, Nano silicon dioxide, starch xanthate, alum add water to mix, and it is small to be mixed 3 under conditions of being 65-70 DEG C in temperature When;
(4) 50 DEG C are cooled to, crosslinking agent N, the mixing of N '-dimethyl allylidene acid amides are added in the mixed liquor of step (3) Reaction, the amount for adding crosslinking agent is the 1% of diatomite quality, then is warming up to 70 DEG C, reacts 60min, then mixture exists Dried under the conditions of 120-140 DEG C;
(5) strain and activated carbon are added in mixture after the drying, is uniformly mixed, obtains at domestic sewage of villages and small towns Manage agent.
Embodiment 3
A kind of domestic sewage of villages and small towns inorganic agent, was mainly made originally of following:Count in parts by weight, mainly by following original It is made:12 parts of alum, 7 parts of polyvinyl alcohol, 8 parts of boric acid, 8 parts of diatomite, 18 parts of activated carbon, 8 parts of calcium gluconate, 7 parts of tannin, 5 parts of lithopone, 15 parts of activated carbon, 9 parts of microbial inoculum, 5 parts of polyacrylamide, 15 parts of nano silicon dioxide, 3 parts of starch xanthate and 5 parts of alum.The strain is third generation nitration denitrification composite bacteria.Third generation nitration denitrification composite bacteria, uses Be the research and development of De Fengsheng owner in 2014 a kind of sewage disposal strain.
A kind of preparation method of domestic sewage of villages and small towns inorganic agent, comprises the following steps:
(1) by diatomite and alum mixing and water adding slurrying, the particle of a diameter of 0.5-1.5mm is made;
(2) when particle being placed in calcination 9 is small under 400-500 DEG C of temperature conditionss, it is cooled to room temperature;
(3) by particle made from step (2) and polyvinyl alcohol, boric acid, calcium gluconate, tannin, lithopone, coagulation agent, Nano silicon dioxide, starch xanthate, alum add water to mix, and it is small to be mixed 2 under conditions of being 65-70 DEG C in temperature When;
(4) 50 DEG C are cooled to, crosslinking agent N, the mixing of N '-dimethyl allylidene acid amides are added in the mixed liquor of step (3) Reaction, the amount for adding crosslinking agent is the 5% of diatomite quality, then is warming up to 70 DEG C, reacts 30min, then mixture exists Dried under the conditions of 120-140 DEG C;
(5) strain and activated carbon are added in mixture after the drying, is uniformly mixed, obtains at domestic sewage of villages and small towns Manage agent.
Comparative example 1
A kind of domestic sewage of villages and small towns inorganic agent, was mainly made originally of following:Count in parts by weight, mainly by following original It is made:8 parts of alum, 11 parts of polyvinyl alcohol, 6 parts of boric acid, 12 parts of diatomite, 16 parts of activated carbon, 11 parts of tannin, 13 parts of activated carbon, 5 parts of 7 parts of microbial inoculum, 7 parts of polyacrylamide, 9 parts of nano silicon dioxide and starch xanthate.
The strain is third generation nitration denitrification composite bacteria.Third generation nitration denitrification composite bacteria, using A kind of sewage disposal strain of De Fengsheng owner's research and development in 2014.
A kind of preparation method of domestic sewage of villages and small towns inorganic agent, comprises the following steps:
(1) by diatomite and alum mixing and water adding slurrying, the particle of a diameter of 0.5-1.5mm is made;
(2) when particle being placed in calcination 7 is small under 400-500 DEG C of temperature conditionss, it is cooled to room temperature;
(3) by particle made from step (2) and polyvinyl alcohol, boric acid, tannin, coagulation agent, nano silicon dioxide, starch Huang Ortho esters adds water to mix, when mixing 2.5 is small under conditions of being 65-70 DEG C in temperature;
(4) 50 DEG C are cooled to, crosslinking agent N, the mixing of N '-dimethyl allylidene acid amides are added in the mixed liquor of step (3) Reaction, the amount for adding crosslinking agent is the 3% of diatomite quality, then is warming up to 70 DEG C, reacts 50min, then mixture exists Dried under the conditions of 120-140 DEG C;
(5) strain and activated carbon are added in mixture after the drying, is uniformly mixed, obtains at domestic sewage of villages and small towns Manage agent.
Comparative example 2
A kind of domestic sewage of villages and small towns inorganic agent, was mainly made originally of following:Count in parts by weight, mainly by following original It is made:8 parts of alum, 11 parts of polyvinyl alcohol, 6 parts of boric acid, 12 parts of diatomite, 16 parts of activated carbon, 6 parts of calcium gluconate, tannin 11 Part, 4 parts of lithopone, 13 parts of activated carbon, 7 parts of microbial inoculum, 7 parts of polyacrylamide, 9 parts of nano silicon dioxide, 5 parts of starch xanthate With 3 parts of alum.
The strain is third generation nitration denitrification composite bacteria.Third generation nitration denitrification composite bacteria, using A kind of sewage disposal strain of De Fengsheng owner's research and development in 2014.
A kind of preparation method of domestic sewage of villages and small towns inorganic agent, comprises the following steps:
(1) by diatomite and alum mixing and water adding slurrying, the particle of a diameter of 0.5-1.5mm is made;
(2) when particle being placed in calcination 7 is small under 400-500 DEG C of temperature conditionss, it is cooled to room temperature;
(3) by particle made from step (2) and polyvinyl alcohol, boric acid, calcium gluconate, tannin, lithopone, coagulation agent, Nano silicon dioxide, starch xanthate, alum add water to mix, and 2.5 are mixed under conditions of being 65-70 DEG C in temperature Hour;Mixture is dried under the conditions of 120-140 DEG C;
(4) strain and activated carbon are added in mixture after the drying, is uniformly mixed, obtains at domestic sewage of villages and small towns Manage agent.
Test example
Sanitary sewage is taken, is divided into 8 groups and tests, every group of 3 repetition, every group is tested consumption 1L sewage, the COD of sewage every time It is worth for 7400mg/L, BOD3600mg/L, suspended matter 3300mg/L, total nitrogen content 120mg/L, total phosphorus content 26mg/L.Add real Each 37g of sewage-treating agent prepared by a 1-3 and comparative example 1-2 is applied, every stirring in 30 minutes once, 24 as a child stop stirring, Stand 8 it is small when, survey each index content in water, calculate the removal rate of each index, the removal rate calculation formula of each index is (with COD Exemplified by):
(COD value after initial COD value-processing)/initial COD value × 100%
Result of the test is as shown in table 1:
Table 1
It is foregoing to the present invention specific exemplary embodiment description be in order to illustrate and illustration purpose.These descriptions It is not wishing to limit the invention to disclosed precise forms, and it will be apparent that according to the above instruction, can be much changed And change.The purpose of selecting and describing the exemplary embodiment is that explain that the certain principles of the present invention and its reality should With so that those skilled in the art can realize and utilize the present invention a variety of exemplaries and Various chooses and changes.The scope of the present invention is intended to be limited by claims and its equivalents.

Claims (8)

1. a kind of domestic sewage of villages and small towns inorganic agent, it is characterised in that be mainly made originally of following:Alum, polyvinyl alcohol, boron Acid, diatomite, activated carbon, calcium gluconate, tannin, lithopone, activated carbon, microbial inoculum, coagulation agent, nano silicon dioxide, starch Xanthate and alum.
2. domestic sewage of villages and small towns inorganic agent according to claim 1, it is characterised in that count in parts by weight, mainly by with It was made originally down:5-12 parts of alum, 7-14 parts of polyvinyl alcohol, 4-8 parts of boric acid, 8-16 parts of diatomite, 11-18 parts of activated carbon, Portugal 3-8 parts of grape Calciofon, 7-16 parts of tannin, 3-5 parts of lithopone, 9-15 parts of activated carbon, 4-9 parts of microbial inoculum, 5-14 parts of coagulation agent, nanometer 2-5 parts of 7-15 parts of silica, 3-6 parts of starch xanthate and alum.
3. domestic sewage of villages and small towns inorganic agent according to claim 1, it is characterised in that count in parts by weight, mainly by with It was made originally down:8 parts of alum, 11 parts of polyvinyl alcohol, 6 parts of boric acid, 12 parts of diatomite, 16 parts of activated carbon, 6 parts of calcium gluconate, 11 parts of tannin, 4 parts of lithopone, 13 parts of activated carbon, 7 parts of microbial inoculum, 7 parts of coagulation agent, 9 parts of nano silicon dioxide, starch xanthate 5 3 parts of part and alum.
4. domestic sewage of villages and small towns inorganic agent according to claim 1, it is characterised in that the coagulation agent is polyacrylamide Amine.
5. domestic sewage of villages and small towns inorganic agent according to claim 1, it is characterised in that the strain is nitrobacteria, instead Nitrobacteria or third generation nitration denitrification composite bacteria.
6. a kind of preparation method of domestic sewage of villages and small towns inorganic agent as claimed in claim 1, it is characterised in that including following step Suddenly:
(1) by diatomite and alum mixing and water adding slurrying, the particle of a diameter of 0.5-1.5mm is made;
(2) when particle being placed in calcination 4-9 is small under 400-500 DEG C of temperature conditionss, it is cooled to room temperature;
(3) by particle made from step (2) and polyvinyl alcohol, boric acid, calcium gluconate, tannin, lithopone, coagulation agent, nanometer Silica, starch xanthate, alum add water to mix, and it is small that 2-3 is mixed under conditions of being 65-70 DEG C in temperature When;
(4) 50 DEG C are cooled to, crosslinking agent hybrid reaction is added in the mixed liquor of step (3), then is warming up to 70 DEG C, reacts 30- 60min, then dries mixture under the conditions of 120-140 DEG C;
(5) strain and activated carbon are added in mixture after the drying, is uniformly mixed, obtains domestic sewage of villages and small towns processing Agent.
7. the preparation method of domestic sewage of villages and small towns inorganic agent according to claim 6, it is characterised in that the crosslinking agent is N, N '-dimethyl allylidene acid amides.
8. the preparation method of domestic sewage of villages and small towns inorganic agent according to claim 6, it is characterised in that add the amount of crosslinking agent For the 1-5% of diatomite quality.
CN201711244357.4A 2017-11-30 2017-11-30 Domestic sewage of villages and small towns inorganic agent and preparation method thereof Pending CN107902767A (en)

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Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103130313A (en) * 2011-11-27 2013-06-05 西安瑞捷生物科技有限公司 Inorganic sewage treating agent
CN104828917A (en) * 2015-04-28 2015-08-12 浙江长安仁恒科技股份有限公司 Multifunctional waste liquid processing agent and applications thereof
CN106395942A (en) * 2016-12-05 2017-02-15 郑州诚合信息技术有限公司 Efficient sewage treating agent specially used for sanitary sewage and preparing method thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103130313A (en) * 2011-11-27 2013-06-05 西安瑞捷生物科技有限公司 Inorganic sewage treating agent
CN104828917A (en) * 2015-04-28 2015-08-12 浙江长安仁恒科技股份有限公司 Multifunctional waste liquid processing agent and applications thereof
CN106395942A (en) * 2016-12-05 2017-02-15 郑州诚合信息技术有限公司 Efficient sewage treating agent specially used for sanitary sewage and preparing method thereof

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
王志国: "《淡水鱼类养殖技术》", 30 May 2014, 宁夏人民出版社 *

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Application publication date: 20180413