CN105776374B - Black smelly water scavengine agent of one kind and preparation method thereof - Google Patents
Black smelly water scavengine agent of one kind and preparation method thereof Download PDFInfo
- Publication number
- CN105776374B CN105776374B CN201610355908.3A CN201610355908A CN105776374B CN 105776374 B CN105776374 B CN 105776374B CN 201610355908 A CN201610355908 A CN 201610355908A CN 105776374 B CN105776374 B CN 105776374B
- Authority
- CN
- China
- Prior art keywords
- parts
- black smelly
- methyl
- catalyst
- activated carbon
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/28—Treatment of water, waste water, or sewage by sorption
- C02F1/288—Treatment of water, waste water, or sewage by sorption using composite sorbents, e.g. coated, impregnated, multi-layered
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/66—Treatment of water, waste water, or sewage by neutralisation; pH adjustment
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2103/00—Nature of the water, waste water, sewage or sludge to be treated
- C02F2103/007—Contaminated open waterways, rivers, lakes or ponds
Abstract
The invention discloses a kind of black smelly water scavengine agents, including 350~400 parts of kaolin, 170~200 parts of zeolite, 150~180 parts of land plaster, 70~80 parts of polydimethyl diallyl ammonium chloride, 30~50 parts of activated carbon, 25~50 parts of sodium carbonate, 50~70 parts of poly 3-hydroxy butyrate, 20~25 parts of cetyl pyridinium bromide, 60~75 parts of ferrous sulfide and 10~20 parts of catalyst.The invention also discloses a kind of preparation methods of above-mentioned black smelly water scavengine agent.The present invention can improve the clean-up effect of water body so as to solve the deficiencies in the prior art, extend the service life of cleanser.
Description
Technical field
The present invention relates to technical field of water body purification, especially a kind of black smelly water scavengine agent and preparation method thereof.
Background technology
Most cities river in China's has developed into black-odor riverway at present.In many cities in China, river organic contamination is general
Store-through and become increasingly conspicuous, the in line river of municipal sewage, it is seriously polluted to flow through cities and towns section, and water body occurs seasonal or black throughout the year
It is smelly, become water environmental problems urgently to be resolved hurrily in the current city river pollution problem in China, therefore, research black-odor riverway purification
The material and method of processing are of great significance.104857930 A of Chinese invention patent application CN disclose a kind of black smelly river
The dedicated modified mineral material in road, production cost are low.But this material is limited for the clean-up effect of water body, material replaces frequency
It is numerous.
Invention content
The technical problem to be solved in the present invention is to provide a kind of black smelly water scavengine agents and preparation method thereof, can solve existing
The deficiency of technology improves the clean-up effect of water body, extends the service life of cleanser.
In order to solve the above technical problems, the technical solution used in the present invention is as follows.
A kind of black smelly water scavengine agent, includes the component of following parts by weight：
350~400 parts of kaolin, 170~200 parts of zeolite, 150~180 parts of land plaster, poly- the two of 70~80 parts
Methyl diallyl ammonium chloride, 30~50 parts of activated carbon, 25~50 parts of sodium carbonate, 50~70 parts of poly- 3-hydroxybutyrate
Ester, 20~25 parts of cetyl pyridinium bromide, 60~75 parts of ferrous sulfide and 10~20 parts of catalyst.
Preferably, the catalyst includes 5 bromosalicylic acid methyl esters.
Preferably, the catalyst includes 3,4- dimethyl benzamides.
Preferably, the catalyst includes methyl -2- trichloromethyl phenyl esters.
Preferably, the catalyst includes polyethylene glycol and 2-methyl-3-biphenylmethanol.
Preferably, the catalyst includes methyl phenyl carbinyl acetate；The ratio of each component is in the catalyst,
Methyl-the 2- of the 5 bromosalicylic acid methyl esters of 23.5wt%, the 3,4- dimethyl benzamides of 39wt%, 8.5wt%
The methyl phenyl carbinyl acetate of trichloromethyl phenyl ester, the polyethylene glycol of 18.5wt%, the 2-methyl-3-biphenylmethanol of 5.5wt%, 5wt%.
A kind of preparation method of above-mentioned black smelly water scavengine agent, includes the following steps：
A, zeolite is crushed, kaolin and land plaster is added, is sufficiently stirred, base-material is made；
B, polydimethyl diallyl ammonium chloride, sodium carbonate, cetyl pyridinium bromide, ferrous sulfide are added in base-material
And catalyst, it is stirred, is sufficiently mixed；
C, activated carbon is processed into graininess, using activated carbon as kernel, covering step B mixing obtained is wrapped up in outside
Material forms the particle of 8~15mm of diameter, poly 3-hydroxy butyrate is wrapped up on the outside of particle；
D, cleanser particle made from step C is heating and curing, heating temperature is 75~85 DEG C, heating time 20
Cleanser finished product is made in~30min.
It is using advantageous effect caused by above-mentioned technical proposal：The present invention by improve cleanser carrier structure and
Active ingredient not only reduces souring of the flow to cleanser, improves the retention time of active ingredient in the carrier, and
And cleanser is integrated with the multiple effect of absorption, neutralization, decomposition, and using the superpower suction-operated of cleanser, improve net
Neutralization purifying rate of the agent for organic pollution in water body.
Specific implementation mode
In order to make objects and advantages of the present invention be more clearly understood, the present invention is carried out with reference to embodiments further
It is described in detail.It should be appreciated that described herein, specific examples are only used to explain the present invention, is not intended to limit the present invention.
Embodiment
A kind of black smelly water scavengine agent, includes the component of following parts by weight：
375 parts of kaolin, 185 parts of zeolite, 170 parts of land plaster, 75 parts of polydimethyl diallyl ammonium chloride,
45 parts of activated carbon, 40 parts of sodium carbonate, 60 parts of poly 3-hydroxy butyrate, 25 parts of cetyl pyridinium bromide, 70 parts
Ferrous sulfide and 12 parts of catalyst.The ratio of each component is in catalyst,
Methyl-the 2- of the 5 bromosalicylic acid methyl esters of 23.5wt%, the 3,4- dimethyl benzamides of 39wt%, 8.5wt%
The methyl phenyl carbinyl acetate of trichloromethyl phenyl ester, the polyethylene glycol of 18.5wt%, the 2-methyl-3-biphenylmethanol of 5.5wt%, 5wt%.
A kind of preparation method of above-mentioned black smelly water scavengine agent, includes the following steps：
A, zeolite is crushed, kaolin and land plaster is added, is sufficiently stirred, base-material is made；
B, polydimethyl diallyl ammonium chloride, sodium carbonate, cetyl pyridinium bromide, ferrous sulfide are added in base-material
And catalyst, it is stirred, is sufficiently mixed；
C, activated carbon is processed into graininess, using activated carbon as kernel, covering step B mixing obtained is wrapped up in outside
Material forms the particle of 8~15mm of diameter, poly 3-hydroxy butyrate is wrapped up on the outside of particle；
D, cleanser particle made from step C being heating and curing, heating temperature is 85 DEG C, heating time 30min,
Cleanser finished product is made.
Using cleanser provided by the present invention and background technology reference patent in embodiment 1 (prior art) for
Two samples of same black and odorous water carry out processing Experimental comparison, as a result as follows：
As seen from the above table, cleanser provided by the present invention can play black and odorous water good catharsis.In addition,
Action period of the cleanser of the present invention in water body can maintain 3~4 weeks, need to carry out weekly more compared to existing cleanser is played
It changes, manpower and material resources cost can be greatlyd save.
The above is only a preferred embodiment of the present invention, it is noted that for the ordinary skill people of the art
For member, without departing from the principle of the present invention, it can also make several improvements and retouch, these improvements and modifications are also answered
It is considered as protection scope of the present invention.
Claims (2)
1. a kind of black smelly water scavengine agent, it is characterised in that include the component of following parts by weight：
350~400 parts of kaolin, 170~200 parts of zeolite, 150~180 parts of land plaster, 70~80 parts of poly dimethyl
Diallyl ammonium chloride, 30~50 parts of activated carbon, 25~50 parts of sodium carbonate, 50~70 parts of poly 3-hydroxy butyrate, 20
~25 parts of cetyl pyridinium bromide, 60~75 parts of ferrous sulfide and 10~20 parts of catalyst；
The catalyst includes methyl phenyl carbinyl acetate；The ratio of each component is in the catalyst:
Methyl -2- the trichlorines of the 5 bromosalicylic acid methyl esters of 23.5wt%, the 3,4- dimethyl benzamides of 39wt%, 8.5wt%
The methyl phenyl carbinyl acetate of methyl phenyl ester, the polyethylene glycol of 18.5wt%, the 2-methyl-3-biphenylmethanol of 5.5wt%, 5wt%.
2. a kind of preparation method of black smelly water scavengine agent described in claim 1, it is characterised in that include the following steps：
A, zeolite is crushed, kaolin and land plaster is added, is sufficiently stirred, base-material is made；
B, polydimethyl diallyl ammonium chloride, sodium carbonate, cetyl pyridinium bromide, ferrous sulfide are added in base-material and urges
Agent is stirred, and is sufficiently mixed；
C, activated carbon is processed into graininess, using activated carbon as kernel, mixture made from covering step B is wrapped up in outside,
The particle for forming 8~15mm of diameter, wraps up poly 3-hydroxy butyrate on the outside of particle；
D, cleanser particle made from step C is heating and curing, heating temperature be 75~85 DEG C, heating time be 20~
Cleanser finished product is made in 30min.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610355908.3A CN105776374B (en) | 2016-05-25 | 2016-05-25 | Black smelly water scavengine agent of one kind and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610355908.3A CN105776374B (en) | 2016-05-25 | 2016-05-25 | Black smelly water scavengine agent of one kind and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN105776374A CN105776374A (en) | 2016-07-20 |
| CN105776374B true CN105776374B (en) | 2018-11-02 |
Family
ID=56379621
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610355908.3A Active CN105776374B (en) | 2016-05-25 | 2016-05-25 | Black smelly water scavengine agent of one kind and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105776374B (en) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106986411A (en) * | 2017-05-24 | 2017-07-28 | 浙江纺织服装职业技术学院 | A kind of use in waste water treatment Inorganic-organic Hybrid Material and preparation method thereof |
| CN107973384B (en) * | 2018-01-10 | 2020-06-05 | 东莞润源环保科技有限公司 | Metal purifying agent for wastewater |
| CN108726593A (en) * | 2018-05-22 | 2018-11-02 | 临泉县盈昌农副产品有限公司 | A kind of production technology for the clear ginger wastewater purificant being based primarily upon COD and SS |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104071861A (en) * | 2014-07-09 | 2014-10-01 | 周振坤 | Sewage purifying agent and preparation method thereof |
| CN104229957A (en) * | 2013-06-24 | 2014-12-24 | 张家领 | Compound flocculant taking natural minerals as main components |
| CN105293724A (en) * | 2015-11-27 | 2016-02-03 | 济南昊泽环保科技有限公司 | Industrial wastewater treatment agent and preparation method thereof |
-
2016
- 2016-05-25 CN CN201610355908.3A patent/CN105776374B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104229957A (en) * | 2013-06-24 | 2014-12-24 | 张家领 | Compound flocculant taking natural minerals as main components |
| CN104071861A (en) * | 2014-07-09 | 2014-10-01 | 周振坤 | Sewage purifying agent and preparation method thereof |
| CN105293724A (en) * | 2015-11-27 | 2016-02-03 | 济南昊泽环保科技有限公司 | Industrial wastewater treatment agent and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN105776374A (en) | 2016-07-20 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN105776374B (en) | Black smelly water scavengine agent of one kind and preparation method thereof | |
| CN107051377B (en) | A kind of nanocomposite and preparation method thereof for synchronous removal carbon nitrogen phosphorus | |
| CN103288164B (en) | A method for synchronous nitrogen and phosphorus removal in sewage by combining modified zeolite and modified eggshell | |
| CN102107134A (en) | Supported ion liquid active carbon as well as preparation method and application thereof | |
| CN103755107B (en) | Urban recycled water deep-treatment method | |
| CN109607721A (en) | Black and odorous water administering method | |
| CN105329956A (en) | Sewage cleanser and preparation method thereof | |
| CN105502568A (en) | Water treatment agent and preparation method thereof | |
| CN105253972A (en) | Wastewater treatment agent and application of wastewater treatment agent | |
| CN105749874A (en) | Adsorbent for mercury removal of flue gas and preparation method of adsorbent | |
| CN105111513A (en) | Composite film based on modified natural polymer and application of composite film | |
| CN105061884A (en) | Foamed polypropylene oil-absorbing composite material and preparation method thereof | |
| CN107720918A (en) | A kind of novel domestic sewage inorganic agent | |
| CN105329996A (en) | Sewage cleanser and preparation method thereof | |
| CN101259361A (en) | Method for using microemulsion to purify organic waste gases | |
| CN104891585A (en) | Industrial sewage treatment agent | |
| CN101780396B (en) | Absorbing agent of trace organic chloride pesticide in water body and preparation method thereof | |
| CN107324434A (en) | A kind of environment-protecting and non-poisonous high efficiency sewage treating agent and preparation method thereof | |
| CN104529005B (en) | The technique of a kind of multistage-combination flocculation plant and selective removal Chinese medicine preparation waste water mesaconitine class toxic component thereof | |
| CN110142021A (en) | A kind of ammonia nitrogen adsorbent based on metakaolin base geological polymer, preparation method and application | |
| CN107497394B (en) | A kind of Fe-Mg-La tri compound fluorine ion absorber and preparation method thereof | |
| CN105967346A (en) | Urban domestic wastewater treating agent and preparation method thereof | |
| CN106348363A (en) | Sewage treatment agent and preparation method thereof | |
| CN105860681A (en) | Heat-insulating waterproof coating and preparation method thereof | |
| CN109626530A (en) | A kind of synchronous dephosphorization of landscape water body with high salt is except algae built-up flocculant and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |