CN104828917A - Multifunctional waste liquid processing agent and applications thereof - Google Patents
Multifunctional waste liquid processing agent and applications thereof Download PDFInfo
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- CN104828917A CN104828917A CN201510206901.0A CN201510206901A CN104828917A CN 104828917 A CN104828917 A CN 104828917A CN 201510206901 A CN201510206901 A CN 201510206901A CN 104828917 A CN104828917 A CN 104828917A
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- waste liquid
- acrylamide
- multifunctional waste
- treatment agent
- liquid treatment
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- 239000002699 waste material Substances 0.000 title claims abstract description 21
- 239000007788 liquid Substances 0.000 title claims abstract description 20
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 claims abstract description 41
- 238000006243 chemical reaction Methods 0.000 claims abstract description 33
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 30
- 238000003756 stirring Methods 0.000 claims abstract description 27
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 claims abstract description 20
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 claims abstract description 15
- 238000010438 heat treatment Methods 0.000 claims abstract description 14
- 238000000034 method Methods 0.000 claims abstract description 13
- 239000010842 industrial wastewater Substances 0.000 claims abstract description 8
- 238000001816 cooling Methods 0.000 claims abstract description 4
- 238000001354 calcination Methods 0.000 claims description 28
- 238000010792 warming Methods 0.000 claims description 28
- 229940080314 sodium bentonite Drugs 0.000 claims description 24
- 229910000280 sodium bentonite Inorganic materials 0.000 claims description 24
- ONCZQWJXONKSMM-UHFFFAOYSA-N dialuminum;disodium;oxygen(2-);silicon(4+);hydrate Chemical compound O.[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[Na+].[Na+].[Al+3].[Al+3].[Si+4].[Si+4].[Si+4].[Si+4] ONCZQWJXONKSMM-UHFFFAOYSA-N 0.000 claims description 23
- 239000000203 mixture Substances 0.000 claims description 18
- 239000004160 Ammonium persulphate Substances 0.000 claims description 13
- 235000019395 ammonium persulphate Nutrition 0.000 claims description 13
- 238000005516 engineering process Methods 0.000 claims description 8
- 239000010813 municipal solid waste Substances 0.000 claims description 8
- 238000011049 filling Methods 0.000 claims description 5
- 229910052757 nitrogen Inorganic materials 0.000 claims description 4
- 238000001035 drying Methods 0.000 abstract description 9
- 238000006116 polymerization reaction Methods 0.000 abstract description 9
- 229910000278 bentonite Inorganic materials 0.000 abstract description 4
- 239000000440 bentonite Substances 0.000 abstract description 4
- 239000000178 monomer Substances 0.000 abstract description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 abstract 2
- 229910052708 sodium Inorganic materials 0.000 abstract 2
- 239000011734 sodium Substances 0.000 abstract 2
- 229910001870 ammonium persulfate Inorganic materials 0.000 abstract 1
- 239000003431 cross linking reagent Substances 0.000 abstract 1
- AVSXGQJYEFAQNK-UHFFFAOYSA-N prop-2-enamide;hydrate Chemical compound O.NC(=O)C=C AVSXGQJYEFAQNK-UHFFFAOYSA-N 0.000 abstract 1
- 238000007873 sieving Methods 0.000 abstract 1
- 239000000243 solution Substances 0.000 description 19
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 9
- 238000002156 mixing Methods 0.000 description 8
- 229920002401 polyacrylamide Polymers 0.000 description 6
- 238000001179 sorption measurement Methods 0.000 description 6
- 238000004132 cross linking Methods 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 239000002957 persistent organic pollutant Substances 0.000 description 4
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 231100001240 inorganic pollutant Toxicity 0.000 description 3
- 238000011068 loading method Methods 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 239000002689 soil Substances 0.000 description 3
- 238000004065 wastewater treatment Methods 0.000 description 3
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 238000005189 flocculation Methods 0.000 description 2
- 230000016615 flocculation Effects 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 238000005325 percolation Methods 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000011800 void material Substances 0.000 description 2
- 229920001661 Chitosan Polymers 0.000 description 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- 239000004113 Sepiolite Substances 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- 230000002745 absorbent Effects 0.000 description 1
- 239000002250 absorbent Substances 0.000 description 1
- 230000000274 adsorptive effect Effects 0.000 description 1
- XKMRRTOUMJRJIA-UHFFFAOYSA-N ammonia nh3 Chemical compound N.N XKMRRTOUMJRJIA-UHFFFAOYSA-N 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O ammonium group Chemical group [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 229940092782 bentonite Drugs 0.000 description 1
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 description 1
- 239000000292 calcium oxide Substances 0.000 description 1
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 1
- 238000005341 cation exchange Methods 0.000 description 1
- 239000002734 clay mineral Substances 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 description 1
- 238000009837 dry grinding Methods 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- ZOOODBUHSVUZEM-UHFFFAOYSA-N ethoxymethanedithioic acid Chemical compound CCOC(S)=S ZOOODBUHSVUZEM-UHFFFAOYSA-N 0.000 description 1
- 230000003311 flocculating effect Effects 0.000 description 1
- 238000010528 free radical solution polymerization reaction Methods 0.000 description 1
- 238000009775 high-speed stirring Methods 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 239000003999 initiator Substances 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 230000002687 intercalation Effects 0.000 description 1
- 238000009830 intercalation Methods 0.000 description 1
- RBTARNINKXHZNM-UHFFFAOYSA-K iron trichloride Chemical compound Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 description 1
- 239000001095 magnesium carbonate Substances 0.000 description 1
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 description 1
- 229960001708 magnesium carbonate Drugs 0.000 description 1
- 229910000021 magnesium carbonate Inorganic materials 0.000 description 1
- 235000014380 magnesium carbonate Nutrition 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 235000010755 mineral Nutrition 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 238000003032 molecular docking Methods 0.000 description 1
- 229910052901 montmorillonite Inorganic materials 0.000 description 1
- 230000037048 polymerization activity Effects 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 238000010526 radical polymerization reaction Methods 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 229910052624 sepiolite Inorganic materials 0.000 description 1
- 235000019355 sepiolite Nutrition 0.000 description 1
- 239000010865 sewage Substances 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000002910 solid waste Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- 229920003169 water-soluble polymer Polymers 0.000 description 1
- 239000012991 xanthate Substances 0.000 description 1
Landscapes
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Separation Of Suspended Particles By Flocculating Agents (AREA)
- Water Treatment By Sorption (AREA)
Abstract
The invention discloses a multifunctional waste liquid processing agent. The processing agent is prepared by the following steps: burning sodium-based bentonite at a temperature of 350 to 450 DEG C, then adding the burned sodium-based bentonite into an acrylamide water solution with a mass percentage of 40 to 50% according to a mass ratio of bentonite to acrylamide of 1.2 to 1.1, stirring at a high speed for 2 hours at a temperature of 40 DEG C; adding ammonium persulfate accounting for 3 to 5 wt% of the acrylamide monomers into the mixed system, heating to a temperature of 45 DEG C to trigger polymerization reactions, keeping on heating the system to a temperature of 85 to 95 DEG C, then cooling to 60 DEG C, adding a crosslinking agent, heating the system to a temperature of 70 DEG C, carrying out reactions for 30 minutes; transferring the system to an environment with a temperature of 30 DEG C, allowing the system to stand still for a while, drying through baking, grinding, and sieving by a 200-mesh sieve to obtain the multifunctional waste liquid processing agent. The provided processing agent can be applied to the percolate anti-seepage treatment in a refuse landfill and can also be used to process normal industrial wastewater.
Description
Technical field
The invention belongs to chemical industry and environmental technology field, relate to a kind of Multifunctional waste water treatment agent, can be used for the process of commonly industrial wastewater physics and chemistry, in addition, also can be used for percolate from garbage filling field Anti-seeping technology.
Background technology
The process of trade effluent and the Anti-seeping technology of garbage loading embeading percolation liquid more and more become one of the hot issue in Environmental Science and Engineering field.In recent years, along with the high speed development of urbanization process, no matter the generation of municipal wastes is that total amount or speedup all increase with exponential form.At present, the process of municipal wastes mainly with landfill and burning electricity generation for mainly to process means.In garbage loading embeading treating processes, selecting and lay efficient, safe sanitary landfill impervious material, is effectively control percolate to the important means of the environmental pollution such as Soil Surrounding, underground water source and measure.And the upgrading and transformation of industry propose more strict requirement for the harmless treatment of sewage.
Wilkinite take montmorillonite as the 2:1 type layered silicate clay mineral of main mineral constituent, there is the ability of Liquidity limit and polar organic molecule, these ions can also be remained on commutative state, can active adsorption process Persistent organic pollutants, in wastewater treatment and pollution law, have broad application prospects.Polyacrylamide is a kind of linear water soluble polymer, it is one of kind be most widely used in water-soluble high-molecular compound, owing to containing a certain amount of polar group in molecular chain, the solids suspended in energy planar water, making builds bridge between particle forms large throw out, accelerates the particle precipitation in suspension.
Modification PAM-sodium bentonite composite water absorbing water-purifying material refers to the feature based on the special laminate structure of wilkinite and polyacrylamide chemical structure, the class energy adsorbed water molecule made, the matrix material of positively charged ion and organic molecule.Both there is the characteristic that inorganic bentonite is excellent, there is again the huge specific surface area of hydrophobic oleophilic oil, and can good treatment effect have been produced in the process of trade effluent physics and chemistry and the application of garbage loading embeading percolation liquid Anti-seeping technology.
Patent CN103708631A describes a kind of sewage-treating agent standby by mixed raw materials such as sepiolite powder, wilkinite, starch xanthate, cross-linked rectorite, polymerize aluminum chloride, chitosans and preparation technology thereof; Patent CN103787473A describes a kind of high stability sewage-treating agent of preparing for raw material with citric acid, sodium carbonate, magnesiumcarbonate, iron trichloride, calcium oxide and polyacrylamide and preparation method.These sewage-treating agent flocculating properties are lower, use the solid waste of rear formation to be difficult to carry out recycling treatment; On the other hand, performance is recycled poor.
Summary of the invention
The object of this invention is to provide a kind of Multifunctional waste liquid treatment agent.
To achieve these goals, the present invention is by the following technical solutions:
A kind of Multifunctional waste liquid treatment agent, is characterized in that being prepared from by following method:
(1) by sodium bentonite calcination 1h under 350 ~ 450 DEG C of conditions;
(2) configuration quality mark is the acrylamide soln of 40 ~ 50%, in mass ratio m
wilkinite: m
acrylamidethe ratio of=1.2 ~ 1:1 adds the wilkinite after calcination, stirs 2h under 40 DEG C of conditions;
(3) get the mixed system that a certain amount of ammonium persulphate adds step (2) gained, the add-on of ammonium persulphate is 3 ~ 5 ‰ of acrylamide quality.；
(4) mixed system obtained by step (3) is warming up to 45 DEG C of reactions;
(5) step (4) reaction automatic heating to 85 DEG C ~ 90 DEG C, and after naturally cooling to 60 DEG C, add linking agent, and temperature is risen to 70 DEG C again, reaction 30min;
(6) dry under the mixture obtained by step (5) being transferred to 30 DEG C of conditions, grind rear mistake 200 mesh sieve, obtain Multifunctional waste liquid treatment agent.
Calcination temperature described in step (1) is preferably 380 DEG C.
Linking agent described in step (5) is N, N '-dimethyl allylidene acid amides; Described N, the add-on of N '-dimethyl allylidene acid amides is 2.6 ~ 6.3 ‰ of acrylamide quality.
The present invention is first by sodium bentonite calcination, add bentonitic bedding void, utilize the cation exchange properties of sodium bentonite, sodium bentonite lamellar spacing is inserted with electropositive ammonium group by acrylamide monomer, propenyl with polymerization activity is placed in environment, as Polymer-supported to the docking point of sodium bentonite, the polyacrylamide be compounded on wilkinite is formed by radical polymerization, special construction through cross-linking modified formation can organic pollutant in active adsorption percolate from garbage filling field or commonly industrial wastewater and inorganic pollutant.
The preparation method of Multifunctional waste liquid treatment agent is further described below:
1. calcination wilkinite.Wilkinite is carried out calcination at a certain temperature, removes a part of middle water and Bound moisture in wilkinite, increase wilkinite bedding void, make it loosen.Temperature will be suitable for, and ensures to remove middle water and Bound moisture, again can not be too high and sintered by wilkinite.Suitable temperature is 350 ~ 450 DEG C, preferably 380 DEG C;
2. monomer intercalation.Wilkinite after calcination is added the acrylamide solution that the wilkinite after calcination is placed in certain mass mark in proportion, is warming up to 40 DEG C, high-speed stirring 2h;
3. in acrylamide solution, the massfraction of acrylamide is 40 ~ 50%, and the sodium bentonite mass ratio after acrylamide and calcination is m
wilkinite: m
acrylamide=1.2 ~ 1:1;
4. aqueous solution polymerization.By 3 ~ 5 ‰ of acrylamide monomer quality, take ammonium persulphate as initiator, add step 2 and obtain in mixed system, be warming up to 45 DEG C and start polyreaction;
5. cross-linking modified.Step 3 polyreaction automatic heating to 85 DEG C-90 DEG C, and after naturally cooling to 60 DEG C, get N by 2.6 ~ 6.3 ‰ of acrylamide massfraction, N '-dimethyl allylidene acid amides, be added in mixed system as linking agent, bath temperature be increased to 70 DEG C, carry out crosslinking reaction;
6. dry grinding.After step 4 starts crosslinking reaction 30min, leave standstill under the system of acquisition being moved to 30 DEG C of conditions and dry, grind rear mistake 200 mesh sieve, obtain percolate from garbage filling field treatment agent.
Multifunctional waste liquid treatment agent of the present invention can be used for the physics and chemistry process of commonly industrial wastewater.Modified alta-mud and polyacrylamide act synergistically, and significantly can increase flocculation ability, can organic pollutant in active adsorption commonly industrial wastewater and inorganic pollutant.
Multifunctional waste liquid treatment agent of the present invention also can be used for the Anti-seeping technology of percolate from garbage filling field, is layed in refuse landfill as impervious material, can efficient adsorption percolate, effectively controls percolate and pollutes Soil Surrounding, underground water source.
Embodiment
Embodiment 1
Get 400kg sodium bentonite, calcination 1h at 350 DEG C.
Configuration 1000kg acrylamide massfraction is the acrylamide solution of 40%.
Sodium bentonite after calcination is added in acrylamide solution, after mixing.Mixed system is warming up to 40 DEG C, stirs, reaction 2h.
Getting 1.20kg ammonium persulphate adds in reaction system, is warming up to 45 DEG C, polymerization reaction, stirs.
Question response system automatic heating to 85 DEG C-95 DEG C also, after dropping to 60 DEG C, gets 1.04kgN, and N '-dimethyl allylidene acid amides adds in system, is warming up to 70 DEG C, stirs, reaction 30min.
Reacted mixture is extruded, and under moving to 30 DEG C of environment, leaves standstill oven dry 12h.
Mixture after drying is ground, crosses 200 mesh sieves, obtain finished product.
Embodiment 2
Get 436.80kg sodium bentonite, calcination 1h at 370 DEG C.
Configuration 1000kg acrylamide massfraction is the acrylamide solution of 42%.
Sodium bentonite after calcination is added in acrylamide solution, after mixing.Mixed system is warming up to 40 DEG C, stirs, reaction 2h.
Getting 1.43kg ammonium persulphate adds in reaction system, is warming up to 45 DEG C, polymerization reaction, stirs.
Question response system automatic heating to 85 DEG C-95 DEG C also, after dropping to 60 DEG C, gets 1.40kgN, and N '-dimethyl allylidene acid amides adds in system, is warming up to 70 DEG C, stirs, reaction 30min.
Reacted mixture is extruded, and under moving to 30 DEG C of environment, leaves standstill oven dry 12h.
Mixture after drying is ground, crosses 200 mesh sieves, obtain finished product.
Embodiment 3
Get 466.40kg sodium bentonite, calcination 1h at 390 DEG C.
Configuration 1000kg acrylamide massfraction is the acrylamide solution of 44%.
Sodium bentonite after calcination is added in acrylamide solution, after mixing.Mixed system is warming up to 40 DEG C, stirs, reaction 2h.
Getting 1.67kg ammonium persulphate adds in reaction system, is warming up to 45 DEG C, polymerization reaction, stirs.
Question response system automatic heating to 85 DEG C-95 DEG C also, after dropping to 60 DEG C, gets 1.79kgN, and N '-dimethyl allylidene acid amides adds in system, is warming up to 70 DEG C, stirs, reaction 30min.
Reacted mixture is extruded, and under moving to 30 DEG C of environment, leaves standstill oven dry 12h.
Mixture after drying is ground, crosses 200 mesh sieves, obtain finished product.
Embodiment 4
Get 496.80kg sodium bentonite, calcination 1h at 410 DEG C.
Configuration 1000kg acrylamide massfraction is the acrylamide solution of 46%.
Sodium bentonite after calcination is added in acrylamide solution, after mixing.Mixed system is warming up to 40 DEG C, stirs, reaction 2h.
Getting 1.93kg ammonium persulphate adds in reaction system, is warming up to 45 DEG C, polymerization reaction, stirs.
Question response system automatic heating to 85 DEG C-95 DEG C also, after dropping to 60 DEG C, gets 2.22kgN, and N '-dimethyl allylidene acid amides adds in system, is warming up to 70 DEG C, stirs, reaction 30min.
Reacted mixture is extruded, and under moving to 30 DEG C of environment, leaves standstill oven dry 12h.
Mixture after drying is ground, crosses 200 mesh sieves, obtain finished product.
Embodiment 5
Get 556.80kg sodium bentonite, calcination 1h at 430 DEG C.
Configuration 1000kg acrylamide massfraction is the acrylamide solution of 48%.
Sodium bentonite after calcination is added in acrylamide solution, after mixing.Mixed system is warming up to 40 DEG C, stirs, reaction 2h.
Getting 2.21kg ammonium persulphate adds in reaction system, is warming up to 45 DEG C, polymerization reaction, stirs.
Question response system automatic heating to 85 DEG C-95 DEG C also, after dropping to 60 DEG C, gets 2.67kgN, and N '-dimethyl allylidene acid amides adds in system, is warming up to 70 DEG C, stirs, reaction 30min.
Reacted mixture is extruded, and under moving to 30 DEG C of environment, leaves standstill oven dry 12h.
Mixture after drying is ground, crosses 200 mesh sieves, obtain finished product.
Embodiment 6
Get 600kg sodium bentonite, calcination 1h at 450 DEG C.
Configuration 1000kg acrylamide massfraction is the acrylamide solution of 50%.
Sodium bentonite after calcination is added in acrylamide solution, after mixing.Mixed system is warming up to 40 DEG C, stirs, reaction 2h.
Getting 2.50kg ammonium persulphate adds in reaction system, is warming up to 45 DEG C, polymerization reaction, stirs.
Question response system automatic heating to 85 DEG C-95 DEG C also, after dropping to 60 DEG C, gets 3.15kgN, and N '-dimethyl allylidene acid amides adds in system, is warming up to 70 DEG C, stirs, reaction 30min.
Reacted mixture is extruded, and under moving to 30 DEG C of environment, leaves standstill oven dry 12h.
Mixture after drying is ground, crosses 200 mesh sieves, obtain finished product.
Embodiment 7
Get 480kg sodium bentonite, calcination 1h at 380 DEG C.
Configuration 1000kg acrylamide massfraction is the acrylamide solution of 40%.
Sodium bentonite after calcination is added in acrylamide solution, after mixing.Mixed system is warming up to 40 DEG C, stirs, reaction 2h.
Getting 1.20kg ammonium persulphate adds in reaction system, is warming up to 45 DEG C, polymerization reaction, stirs.
Question response system automatic heating to 85 DEG C-95 DEG C also, after dropping to 60 DEG C, gets 1.04kgN, and N '-dimethyl allylidene acid amides adds in system, is warming up to 70 DEG C, stirs, reaction 30min.
Reacted mixture is extruded, and under moving to 30 DEG C of environment, leaves standstill oven dry 12h.
Mixture after drying is ground, crosses 200 mesh sieves, obtain finished product.
Embodiment 8
Get 600kg sodium bentonite, calcination 1h at 380 DEG C.
Configuration 1000kg acrylamide massfraction is the acrylamide solution of 50%.
Sodium bentonite after calcination is added in acrylamide solution, after mixing.Mixed system is warming up to 40 DEG C, stirs, reaction 2h.
Getting 2.50kg ammonium persulphate adds in reaction system, is warming up to 45 DEG C, polymerization reaction, stirs.
Question response system automatic heating to 85 DEG C-95 DEG C also, after dropping to 60 DEG C, gets 3.15kgN, and N '-dimethyl allylidene acid amides adds in system, is warming up to 70 DEG C, stirs, reaction 30min.
Reacted mixture is extruded, and under moving to 30 DEG C of environment, leaves standstill oven dry 12h.
Mixture after drying is ground, crosses 200 mesh sieves, obtain finished product.
The effect of waste liquor treating agent of the present invention in Industrial Wastewater Treatment sees the following form:
| Water absorbent rate (g/g) | COD clearance (%) | Ammonia nitrogen removal frank (%) | Pb 2+Adsorptive capacity (mg/g) | Zn 2+Clearance (%) | TCr clearance (%) | TFe clearance (%) | |
| Embodiment 1 | 36.21 | 81.4 | 91.23 | 118.43 | 54.12 | 57.13 | 64.12 |
| Embodiment 2 | 36.56 | 82.3 | 92.43 | 119.21 | 54.65 | 57.85 | 64.76 |
| Embodiment 3 | 37.43 | 84.7 | 91.76 | 119.54 | 55.21 | 58.31 | 65.21 |
| Embodiment 4 | 38.34 | 82.6 | 93.54 | 120.49 | 55.54 | 59.20 | 65.87 |
| Embodiment 5 | 36.54 | 87.3 | 93.76 | 120.76 | 56.06 | 59.31 | 66.12 |
| Embodiment 6 | 37.78 | 83.4 | 94.43 | 122.05 | 56.72 | 60.62 | 66.84 |
| Embodiment 7 | 38.96 | 86.3 | 96.65 | 124.47 | 58.21 | 61.24 | 68.23 |
| Embodiment 8 | 39.08 | 85.2 | 95.24 | 123.65 | 54.14 | 60.48 | 67.92 |
Multifunctional waste liquid treatment agent of the present invention acts synergistically due to modified alta-mud and polyacrylamide, significantly can increase flocculation ability, can organic pollutant in active adsorption commonly industrial wastewater and inorganic pollutant.Also can be used as impervious material and be layed in refuse landfill, can efficient adsorption percolate, effectively control percolate and Soil Surrounding, underground water source are polluted.
Claims (6)
1. a Multifunctional waste liquid treatment agent, is characterized in that being prepared from by following method:
(1) by sodium bentonite calcination 1h under 350 ~ 450 DEG C of conditions;
(2) configuration quality mark is the acrylamide soln of 40 ~ 50%, in mass ratio m
wilkinite: m
acrylamidethe ratio of=1.2 ~ 1:1 adds the wilkinite after calcination, stirs 2h under 40 DEG C of conditions;
(3) get the mixed system that a certain amount of ammonium persulphate adds step (2) gained, the add-on of ammonium persulphate is 3 ~ 5 ‰ of acrylamide quality;
(4) mixed system obtained by step (3) is warming up to 45 DEG C of reactions;
(5) step (4) reaction automatic heating to 85 DEG C ~ 90 DEG C, and after naturally cooling to 60 DEG C, add linking agent, and temperature is risen to 70 DEG C again, reaction 30min;
(6) dry under the mixture obtained by step (5) being transferred to 30 DEG C of conditions, grind rear mistake 200 mesh sieve, obtain Multifunctional waste liquid treatment agent.
2. Multifunctional waste liquid treatment agent as claimed in claim 1, it is characterized in that, the calcination temperature described in step (1) is 380 DEG C.
3. Multifunctional waste liquid treatment agent as claimed in claim 1, it is characterized in that, the linking agent described in step (5) is N, N '-dimethyl allylidene acid amides.
4. Multifunctional waste liquid treatment agent as claimed in claim 3, it is characterized in that, described N, the add-on of N '-dimethyl allylidene acid amides is 2.6 ~ 6.3 ‰ of acrylamide quality.
5. the application of the described Multifunctional waste liquid treatment agent of one of claim 1-4 in the physics and chemistry process of commonly industrial wastewater.
6. the application of the described Multifunctional waste liquid treatment agent of one of claim 1-4 in the Anti-seeping technology of percolate from garbage filling field.
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106975464A (en) * | 2017-03-30 | 2017-07-25 | 天长市天达纸箱纸品厂 | A kind of preparation method of paper-making waste water treating agent |
| CN107739105A (en) * | 2017-11-30 | 2018-02-27 | 天峨县平昌生态农业有限公司 | Domestic sewage treating compound and preparation method thereof |
| CN107777785A (en) * | 2017-11-30 | 2018-03-09 | 天峨县平昌生态农业有限公司 | Silk reeling wastewater inorganic agent and preparation method thereof |
| CN107902767A (en) * | 2017-11-30 | 2018-04-13 | 兰秋波 | Domestic sewage of villages and small towns inorganic agent and preparation method thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2008079652A1 (en) * | 2006-12-22 | 2008-07-03 | General Electric Company | Tannin based polymeric coagulants composition and method of use |
| CN101564676A (en) * | 2009-04-03 | 2009-10-28 | 河北工业大学 | Compound bentonite for removing fluorine from water and preparation method thereof |
| CN101961642A (en) * | 2010-08-31 | 2011-02-02 | 浙江长安仁恒科技股份有限公司 | Method for preparing organic pollutant adsorbent for papermaking wastewater |
| CN102584056A (en) * | 2012-01-09 | 2012-07-18 | 沈阳化工大学 | Preparation method for bentonite anti-seepage material |
| CN102631898A (en) * | 2012-04-26 | 2012-08-15 | 西北师范大学 | Preparation of bentonite-based copolymer and use of bentonite-based copolymer as adsorbent |
-
2015
- 2015-04-28 CN CN201510206901.0A patent/CN104828917B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2008079652A1 (en) * | 2006-12-22 | 2008-07-03 | General Electric Company | Tannin based polymeric coagulants composition and method of use |
| CN101564676A (en) * | 2009-04-03 | 2009-10-28 | 河北工业大学 | Compound bentonite for removing fluorine from water and preparation method thereof |
| CN101961642A (en) * | 2010-08-31 | 2011-02-02 | 浙江长安仁恒科技股份有限公司 | Method for preparing organic pollutant adsorbent for papermaking wastewater |
| CN102584056A (en) * | 2012-01-09 | 2012-07-18 | 沈阳化工大学 | Preparation method for bentonite anti-seepage material |
| CN102631898A (en) * | 2012-04-26 | 2012-08-15 | 西北师范大学 | Preparation of bentonite-based copolymer and use of bentonite-based copolymer as adsorbent |
Non-Patent Citations (2)
| Title |
|---|
| 杜秀娟等: "聚丙烯酰胺-钠基复合膨润土合成及其吸附铅离子性能", 《过程工程学报》 * |
| 赖红伟等: "膨润土复合丙烯酰胺超强吸水剂的合成与性能研究", 《云南化工》 * |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106975464A (en) * | 2017-03-30 | 2017-07-25 | 天长市天达纸箱纸品厂 | A kind of preparation method of paper-making waste water treating agent |
| CN107739105A (en) * | 2017-11-30 | 2018-02-27 | 天峨县平昌生态农业有限公司 | Domestic sewage treating compound and preparation method thereof |
| CN107777785A (en) * | 2017-11-30 | 2018-03-09 | 天峨县平昌生态农业有限公司 | Silk reeling wastewater inorganic agent and preparation method thereof |
| CN107902767A (en) * | 2017-11-30 | 2018-04-13 | 兰秋波 | Domestic sewage of villages and small towns inorganic agent and preparation method thereof |
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| CN104828917B (en) | 2017-11-07 |
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Denomination of invention: A multifunctional waste liquid treatment agent and its application Effective date of registration: 20231115 Granted publication date: 20171107 Pledgee: Changxin Zhejiang rural commercial bank Limited by Share Ltd. Pledgor: ZHEJIANG CHANGAN RENHENG TECHNOLOGY CO.,LTD. Registration number: Y2023980065649 |