CN107892863A - 一种pvc地板塑胶抗菌型uv涂料 - Google Patents

一种pvc地板塑胶抗菌型uv涂料 Download PDF

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CN107892863A
CN107892863A CN201711338533.0A CN201711338533A CN107892863A CN 107892863 A CN107892863 A CN 107892863A CN 201711338533 A CN201711338533 A CN 201711338533A CN 107892863 A CN107892863 A CN 107892863A
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coating
pvc floor
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喻湘浩
夏育林
童罗生
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HUNAN SUNLIGHT NEW MATERIALS CO Ltd
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Abstract

本发明公开了一种PVC地板塑胶抗菌型UV涂料，其组分及质量百分比如下：光敏树脂40%～50%；交联剂20%～30%；光引发剂5%～10%；流平剂1%～5%；添加剂5%～15%，所述的添加剂包括耐磨剂、防腐剂、强化剂，所述的耐磨剂为氧化硅颗粒，所述的防腐剂为炭黑颗粒，所述的强化剂为石墨碳纤维，所述的光敏树脂的制备方法为将预聚体和稀释剂混合并搅拌均匀，再加入聚羟基脂肪酸酯、光敏剂和添加剂，在40‑50℃水浴中加热搅拌，并抽真空制得。本发明提供的一种PVC地板塑胶抗菌型UV涂料，针对PVC地板塑胶添加了添加剂，其中的氧化硅颗粒大大增加了表面的耐磨性能，而炭黑材料使得涂料与外界隔离，菌类无法生存，石墨碳纤维让涂层形成网状，强度得到增强。

Description

一种PVC地板塑胶抗菌型UV涂料
技术领域
本发明涉及墙面粉刷技术领域，具体为一种PVC地板塑胶抗菌型UV涂料。
背景技术
传统的涂料固化通常是通过加热即物理干燥的方法除去高分子溶液中的溶剂，得到硬化的漆膜。UV固化则是利用紫外光的能量引发涂料中的低分子预聚体或齐聚体及作为活性稀释剂的单体分子之间的聚合及交联反应，得到硬化漆膜，实质上是通过形成化学键实现化学干燥。
PVC塑胶地板是当今世界上非常流行的一种新型轻体地面装饰材料，也称为轻体地材。是一种在欧美及亚洲的日韩广受欢迎的产品，风靡国外，PVC塑胶地板有聚氯乙烯卷材地板和聚氯乙烯块状地板两种,PVC塑胶地板是一个广泛的称谓。在室内家庭、医院、学校、办公楼、工厂、公共场所、超市、商业、体育场馆等各种场所被大量的应用。
为了进一步的提高PVC塑胶地板的性能，如耐磨性能，抗菌性，需要在其表面喷涂涂层，而传统的涂料固化慢，而紫外固化涂料，在耐磨性能，抗菌性的方面表现较差。
发明内容
本发明的目的在于提供一种PVC地板塑胶抗菌型UV涂料，以解决上述背景技术中提出的问题。
为实现上述目的，本发明提供如下技术方案：一种PVC地板塑胶抗菌型UV涂料，其组分及质量百分比如下：
光敏树脂 40%～50%；
交联剂 20%～30%；
光引发剂 5%～10%；
流平剂 1%～5%；
添加剂 5%～15%。
所述的光敏树脂的预聚体为环氧丙烯酸酯、聚氨酯丙烯酸酯、不饱和聚酯、水性丙烯酸酯、聚醚丙烯酸酯中的至少一种或多种。
优选的，所述的添加剂包括耐磨剂、防腐剂、强化剂，所述的耐磨剂为氧化硅颗粒，所述的防腐剂为炭黑颗粒，所述的强化剂为石墨碳纤维。
优选的，所述的光敏树脂的制备方法为将预聚体和稀释剂混合并搅拌均匀，再加入聚羟基脂肪酸酯、光敏剂和添加剂，在40-50℃水浴中加热搅拌，并抽真空制得。
优选的，所述的交联剂为三丙二醇二丙烯酸酯、三羟甲基丙烷三丙烯酸酯、季戊四醇三丙烯酸酯、季戊四醇四丙烯酸酯、季戊四醇六丙烯酸酯、丙烯酸羟乙酯、甲基丙烯酸羟乙酯中一种或多种。
优选的，所述的光引发剂为2-羟基-2-甲基-1-苯基-1-丙基酮、2,4,6-三甲基苯甲酰基二苯基氧化膦、1-羟基-环乙基-苯基甲酮、安息香双甲醚、二苯甲酮中一种或多种。
与现有技术相比，本发明的有益效果是：本发明提供的一种PVC地板塑胶抗菌型UV涂料，针对PVC地板塑胶添加了添加剂，添加剂包括耐磨剂、防腐剂、强化剂，分别为氧化硅颗粒、炭黑颗粒、石墨碳纤维，其中的氧化硅颗粒大大增加了表面的耐磨性能，而炭黑材料使得涂料与外界隔离，菌类无法生存，石墨碳纤维让涂层形成网状，强度得到增强。本发明为紫外固话，与传统的涂料相比固化效果快，通过添加添加剂，在耐磨性能，抗菌性的方面的性能大大提高。
具体实施方式
下面将结合本发明实施例，对本发明实施例中的技术方案进行清楚、完整地描述，显然，所描述的实施例仅仅是本发明一部分实施例，而不是全部的实施例。基于本发明中的实施例，本领域普通技术人员在没有做出创造性劳动前提下所获得的所有其他实施例，都属于本发明保护的范围。
本发明提供了一种PVC地板塑胶抗菌型UV涂料，其组分及质量百分比如下：
光敏树脂 40%～50%；
交联剂 20%～30%；
光引发剂 5%～10%；
流平剂 1%～5%；
添加剂 5%～15%。
所述的光敏树脂的预聚体为环氧丙烯酸酯、聚氨酯丙烯酸酯、不饱和聚酯、水性丙烯酸酯、聚醚丙烯酸酯中的至少一种或多种。
优选的，所述的添加剂包括耐磨剂、防腐剂、强化剂，所述的耐磨剂为氧化硅颗粒，所述的防腐剂为炭黑颗粒，所述的强化剂为石墨碳纤维。
优选的，所述的光敏树脂的制备方法为将预聚体和稀释剂混合并搅拌均匀，再加入聚羟基脂肪酸酯、光敏剂和添加剂，在40-50℃水浴中加热搅拌，并抽真空制得。
优选的，所述的交联剂为三丙二醇二丙烯酸酯、三羟甲基丙烷三丙烯酸酯、季戊四醇三丙烯酸酯、季戊四醇四丙烯酸酯、季戊四醇六丙烯酸酯、丙烯酸羟乙酯、甲基丙烯酸羟乙酯中一种或多种。
优选的，所述的光引发剂为2-羟基-2-甲基-1-苯基-1-丙基酮、2,4,6-三甲基苯甲酰基二苯基氧化膦、1-羟基-环乙基-苯基甲酮、安息香双甲醚、二苯甲酮中一种或多种。
实施例1
光敏树脂 45份；交联剂 24份；光引发剂 7份；流平剂 3份；添加剂 11份。
所述的光敏树脂的预聚体为环氧丙烯酸酯、聚氨酯丙烯酸酯、不饱和聚酯、水性丙烯酸酯、聚醚丙烯酸酯中的至少一种或多种。
优选的，所述的添加剂包括耐磨剂、防腐剂、强化剂，所述的耐磨剂为氧化硅颗粒，所述的防腐剂为炭黑颗粒，所述的强化剂为石墨碳纤维。
优选的，所述的光敏树脂的制备方法为将预聚体和稀释剂混合并搅拌均匀，再加入聚羟基脂肪酸酯、光敏剂和添加剂，在40-50℃水浴中加热搅拌，并抽真空制得。
优选的，所述的交联剂为三丙二醇二丙烯酸酯、三羟甲基丙烷三丙烯酸酯、季戊四醇三丙烯酸酯、季戊四醇四丙烯酸酯、季戊四醇六丙烯酸酯、丙烯酸羟乙酯、甲基丙烯酸羟乙酯中一种或多种。
优选的，所述的光引发剂为2-羟基-2-甲基-1-苯基-1-丙基酮、2,4,6-三甲基苯甲酰基二苯基氧化膦、1-羟基-环乙基-苯基甲酮、安息香双甲醚、二苯甲酮中一种或多种。
实施例2
光敏树脂 46份；交联剂 22份；光引发剂 9份；流平剂 2份；添加剂 7份。
所述的光敏树脂的预聚体为环氧丙烯酸酯、聚氨酯丙烯酸酯、不饱和聚酯、水性丙烯酸酯、聚醚丙烯酸酯中的至少一种或多种。
优选的，所述的添加剂包括耐磨剂、防腐剂、强化剂，所述的耐磨剂为氧化硅颗粒，所述的防腐剂为炭黑颗粒，所述的强化剂为石墨碳纤维。
优选的，所述的光敏树脂的制备方法为将预聚体和稀释剂混合并搅拌均匀，再加入聚羟基脂肪酸酯、光敏剂和添加剂，在40-50℃水浴中加热搅拌，并抽真空制得。
优选的，所述的交联剂为三丙二醇二丙烯酸酯、三羟甲基丙烷三丙烯酸酯、季戊四醇三丙烯酸酯、季戊四醇四丙烯酸酯、季戊四醇六丙烯酸酯、丙烯酸羟乙酯、甲基丙烯酸羟乙酯中一种或多种。
优选的，所述的光引发剂为2-羟基-2-甲基-1-苯基-1-丙基酮、2,4,6-三甲基苯甲酰基二苯基氧化膦、1-羟基-环乙基-苯基甲酮、安息香双甲醚、二苯甲酮中一种或多种。
实施例3
光敏树脂 47份；交联剂 20份；光引发剂11份；流平剂 4份；添加剂 14份。
所述的光敏树脂的预聚体为环氧丙烯酸酯、聚氨酯丙烯酸酯、不饱和聚酯、水性丙烯酸酯、聚醚丙烯酸酯中的至少一种或多种。
优选的，所述的添加剂包括耐磨剂、防腐剂、强化剂，所述的耐磨剂为氧化硅颗粒，所述的防腐剂为炭黑颗粒，所述的强化剂为石墨碳纤维。
优选的，所述的光敏树脂的制备方法为将预聚体和稀释剂混合并搅拌均匀，再加入聚羟基脂肪酸酯、光敏剂和添加剂，在40-50℃水浴中加热搅拌，并抽真空制得。
优选的，所述的交联剂为三丙二醇二丙烯酸酯、三羟甲基丙烷三丙烯酸酯、季戊四醇三丙烯酸酯、季戊四醇四丙烯酸酯、季戊四醇六丙烯酸酯、丙烯酸羟乙酯、甲基丙烯酸羟乙酯中一种或多种。
优选的，所述的光引发剂为2-羟基-2-甲基-1-苯基-1-丙基酮、2,4,6-三甲基苯甲酰基二苯基氧化膦、1-羟基-环乙基-苯基甲酮、安息香双甲醚、二苯甲酮中一种或多种。
尽管已经示出和描述了本发明的实施例，对于本领域的普通技术人员而言，可以理解在不脱离本发明的原理和精神的情况下可以对这些实施例进行多种变化、修改、替换和变型，本发明的范围由所附权利要求及其等同物限。

Claims (5)

1.一种PVC地板塑胶抗菌型UV涂料，其特征在于：其组分及质量百分比如下：
光敏树脂 40%～50%；
交联剂 20%～30%；
光引发剂 5%～10%；
流平剂 1%～5%；
添加剂 5%～15%。
所述的光敏树脂的预聚体为环氧丙烯酸酯、聚氨酯丙烯酸酯、不饱和聚酯、水性丙烯酸酯、聚醚丙烯酸酯中的至少一种或多种。
2.根据权利要求1所述的一种PVC地板塑胶抗菌型UV涂料，其特征在于：所述的添加剂包括耐磨剂、防腐剂、强化剂，所述的耐磨剂为氧化硅颗粒，所述的防腐剂为炭黑颗粒，所述的强化剂为石墨碳纤维。
3.根据权利要求1所述的一种PVC地板塑胶抗菌型UV涂料，其特征在于：所述的光敏树脂的制备方法为将预聚体和稀释剂混合并搅拌均匀，再加入聚羟基脂肪酸酯、光敏剂和添加剂，在40-50℃水浴中加热搅拌，并抽真空制得。
4.根据权利要求1所述的一种PVC地板塑胶抗菌型UV涂料，其特征在于：所述的交联剂为三丙二醇二丙烯酸酯、三羟甲基丙烷三丙烯酸酯、季戊四醇三丙烯酸酯、季戊四醇四丙烯酸酯、季戊四醇六丙烯酸酯、丙烯酸羟乙酯、甲基丙烯酸羟乙酯中一种或多种。
5.根据权利要求1所述的一种PVC地板塑胶抗菌型UV涂料，其特征在于：所述的光引发剂为2-羟基-2-甲基-1-苯基-1-丙基酮、2,4,6-三甲基苯甲酰基二苯基氧化膦、1-羟基-环乙基-苯基甲酮、安息香双甲醚、二苯甲酮中一种或多种。
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Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106894007A (zh) * 2017-02-28 2017-06-27 河南工程学院 一种基于静电纺丝纤维的光敏型无铬钝化液及其制备方法
CN109337561A (zh) * 2018-10-15 2019-02-15 唐山市丰润区米乐感光新材料有限公司 人造革无溶剂uv涂料
CN109355019A (zh) * 2018-10-15 2019-02-19 唐山市丰润区米乐感光新材料有限公司 Pvc地板抗静电无溶剂uv涂料
CN109370393A (zh) * 2018-06-08 2019-02-22 湖南阳光新材料有限公司 一种户外高耐候性地坪组合物
CN109401404A (zh) * 2018-10-15 2019-03-01 唐山市丰润区米乐感光新材料有限公司 Pvc地板抗菌耐碘酒uv涂料
CN109468016A (zh) * 2018-10-15 2019-03-15 唐山市丰润区米乐感光新材料有限公司 Pvc地板抗污防烟烫剂uv涂料
CN109593444A (zh) * 2018-11-28 2019-04-09 湖南阳光新材料有限公司 一种家居地板高耐污紫外固化涂料及其制备工艺
CN109796853A (zh) * 2018-11-28 2019-05-24 湖南阳光新材料有限公司 一种紫外光固化导热散热车辆反射罩涂料及其制备方法
WO2021083042A1 (zh) * 2019-10-28 2021-05-06 苏州科逸住宅设备股份有限公司 纳米抗菌墙板的制备方法及纳米抗菌墙板
CN113122092A (zh) * 2021-04-07 2021-07-16 广州雷诺丽特塑料有限公司 一种抗菌涂料及其制备方法与应用
CN113637344A (zh) * 2021-05-17 2021-11-12 肇庆市哈力化工有限公司 一种适用于ps塑件的高附着力uv底漆及其制备方法

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102101972A (zh) * 2010-12-31 2011-06-22 上海参爱贸易有限公司 一种高耐磨紫外光固化涂料
CN103450414A (zh) * 2012-05-28 2013-12-18 比亚迪股份有限公司 一种光敏树脂的组合物及其制备方法和光敏树脂

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102101972A (zh) * 2010-12-31 2011-06-22 上海参爱贸易有限公司 一种高耐磨紫外光固化涂料
CN103450414A (zh) * 2012-05-28 2013-12-18 比亚迪股份有限公司 一种光敏树脂的组合物及其制备方法和光敏树脂

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
林建好等: "《土木工程材料（第二版）》", 31 August 2017, 哈尔滨工程大学出版社 *

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CN106894007A (zh) * 2017-02-28 2017-06-27 河南工程学院 一种基于静电纺丝纤维的光敏型无铬钝化液及其制备方法
CN109370393A (zh) * 2018-06-08 2019-02-22 湖南阳光新材料有限公司 一种户外高耐候性地坪组合物
CN109468016A (zh) * 2018-10-15 2019-03-15 唐山市丰润区米乐感光新材料有限公司 Pvc地板抗污防烟烫剂uv涂料
CN109355019A (zh) * 2018-10-15 2019-02-19 唐山市丰润区米乐感光新材料有限公司 Pvc地板抗静电无溶剂uv涂料
CN109401404A (zh) * 2018-10-15 2019-03-01 唐山市丰润区米乐感光新材料有限公司 Pvc地板抗菌耐碘酒uv涂料
CN109337561A (zh) * 2018-10-15 2019-02-15 唐山市丰润区米乐感光新材料有限公司 人造革无溶剂uv涂料
CN109593444A (zh) * 2018-11-28 2019-04-09 湖南阳光新材料有限公司 一种家居地板高耐污紫外固化涂料及其制备工艺
CN109796853A (zh) * 2018-11-28 2019-05-24 湖南阳光新材料有限公司 一种紫外光固化导热散热车辆反射罩涂料及其制备方法
WO2021083042A1 (zh) * 2019-10-28 2021-05-06 苏州科逸住宅设备股份有限公司 纳米抗菌墙板的制备方法及纳米抗菌墙板
CN113122092A (zh) * 2021-04-07 2021-07-16 广州雷诺丽特塑料有限公司 一种抗菌涂料及其制备方法与应用
CN113637344A (zh) * 2021-05-17 2021-11-12 肇庆市哈力化工有限公司 一种适用于ps塑件的高附着力uv底漆及其制备方法
CN113637344B (zh) * 2021-05-17 2022-07-15 肇庆市哈力化工有限公司 一种适用于ps塑件的高附着力uv底漆及其制备方法

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