CN107880720A - A kind of steel pipe corrosion-proof composite coating and preparation method thereof - Google Patents
A kind of steel pipe corrosion-proof composite coating and preparation method thereof Download PDFInfo
- Publication number
- CN107880720A CN107880720A CN201711195656.3A CN201711195656A CN107880720A CN 107880720 A CN107880720 A CN 107880720A CN 201711195656 A CN201711195656 A CN 201711195656A CN 107880720 A CN107880720 A CN 107880720A
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- China
- Prior art keywords
- steel pipe
- composite coating
- proof composite
- pipe corrosion
- coating according
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/32—Phosphorus-containing compounds
- C08K2003/321—Phosphates
- C08K2003/324—Alkali metal phosphate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
One kind is used for steel pipe anticorrosion paint and preparation method thereof, belongs to chemical material technical field, includes the component of following percentage by weight:Pigment 5~12%, filler 3~8%, dispersant 8~12%, coalescents 6~12%, defoamer 5~8%, polyphenylene oxide resin powder 2~6%; butadiene-styrene rubber 5~8%; toluene 3~6%, plasticizer 1~3%, coupling agent 1~3%; auxiliary material 2~4%; fire retardant 1~3%, white carbon 2~4%, remaining is modifying epoxy resin by organosilicon.Preparation principle of the present invention is clear, methodological science, modifying epoxy resin by organosilicon has the advantages that cohesive force is strong, chemical reagent-resistant performance is good, and modified epoxy can enhance the ability that coating resists water, ion penetrates into, improve the adhesion between coating and metallic matrix, so as to improve the protective capacities of coating, the high temperature resistant and abrasion resistance properties of steel pipe are enhanced, the safety in utilization of steel pipe is increased substantially.
Description
Technical field
The invention belongs to chemical material technical field, is related to a kind of anti-corrosion composite coating and preparation method thereof, particularly relates to
It is and a kind of for steel pipe anticorrosion paint and preparation method thereof.
Background technology
Metal material is under field conditions (factors) or under working condition, due to chemistry or electrochemistry occurs with its local environment medium
Degenerate and destroy caused by effect, this phenomenon is referred to as corroding.Etching problem is throughout each department and industry, to national economy
Development, human lives and social environment generate significant damage.According to statistics, loss of the whole world every year caused by corrosion is up to
1000000000000 dollars, various countries due to annual economical losses caused by corrosion failure account for national economy total output value then 2%~
4%, corrosion control level is different because of the different economic development level in various countries.According to《Chinese Investigation On Corrosion report》Data, I
The year corrosion economic loss of state in recent years is about 500,000,000,000 yuan, and this loss is huge.Except corrosion economy problems it
Outside, corrosion process and result are actually also the significant wastage to limited resources on the earth and the energy, to the serious of natural environment
Pollution, the great interference lived to normal production and people, and people are brought with very important social safety sex chromosome mosaicism.
Etching problem can also turn into the important restriction factor for hindering hi-tech development and national sustained economic development.It is estimated that generation
20% metal material is there are about in boundary can not reclaim because being corroded, thus to cause the world each for corrosion of metal and protection question
The most attention of state.
The method for preventing pipe corrosion is a lot, such as paint coatings anti-corrosion, from corrosion resisting alloy, plating, cathodic protection, heat
Zinc immersion and metal thermal spraying etc., wherein most widely used is paint coatings anti-corrosion.Compared with other method, paint coatings are prevented
Corruption is most effective, most economical, using most common method.The complexity but existing many paint coatings are constructed in anti-corrosion, is prepared
Paint coatings tedious process, cost are high, pollute the environment during preparation, and paint coatings corrosion resistance is inadequate, researches and develops a kind of anti-corrosion
Coating and preparation method thereof turns into those skilled in the art's technical problem urgently to be resolved hurrily.
The content of the invention
The present invention construct complexity for existing paint coatings in anti-corrosion, prepares paint coatings tedious process, cost height, makes
Polluted the environment when standby, and the deficiencies of paint coatings corrosion resistance is inadequate, propose a kind of steel pipe corrosion-proof composite coating and its preparation
Method, can solve above-mentioned deficiency of the prior art, high temperature resistant, the abrasion resistance properties of steel pipe, the safety that steel pipe uses can be strengthened
Property can be increased substantially.
Technical scheme:A kind of steel pipe corrosion-proof composite coating, it is characterised in that including following percentage by weight
Component:Pigment 5~12%, filler 3~8%, dispersant 8~12%, coalescents 6~12%, defoamer 5~8%, polyphenylene oxide
Resin-oatmeal 2~6%, butadiene-styrene rubber 5~8%, toluene 3~6%, plasticizer 1~3%, coupling agent 1~3%, auxiliary material 2~4%,
Fire retardant 1~3%, white carbon 2~4%, remaining is modifying epoxy resin by organosilicon.
The pigment is one kind in titanium dioxide, iron oxide red, carbon black, barium sulfate or chrome oxide green.
The filler glass flake.
The plasticizer is tricresyl phosphate.
The dispersant is sodium tripolyphosphate.
The coalescents are ethylene glycol ethyl ether.
The defoamer is acid amides.
The coupling agent is silane coupler.
The preparation method of steel pipe corrosion-proof composite coating, it is characterised in that including following operating procedure:
(1) pigment, filler, modifying epoxy resin by organosilicon are delivered to and 30min are stirred in agitator, mixing speed be 100~
120r/min, waits and sequentially adds dispersant, coalescents and defoamer after being sufficiently mixed uniformly, finally adds plasticizer regulation and applies
Expect to suitable viscosity;
(2) butadiene-styrene rubber, auxiliary material, fire retardant and polyphenylene oxide resin powder are added into toluene and is sent into mixer, stirs 30min,
Mixing speed is 100~120r/min, waits and adds coupling agent in mixer after being sufficiently mixed uniformly, high-speed stirred 15min, stirs
It is 250~350r/min to mix speed;
(3) will be obtained after stirring, dry, broken, grinding in the material mixing prepared in step (2) to step (1) compound
Epoxy anticorrosion powdery coating.
Beneficial effects of the present invention are:A kind of steel pipe corrosion-proof composite coating proposed by the present invention and preparation method thereof, prepare
Clear principle, methodological science, epoxy resin have excellent adhesive force and low-shrinkage, are respectively provided with various execution conditions good
Filming performance, a series of conventional anticorrosive paints can be configured to good miscible of various resins, filler and auxiliary agent;Organosilicon
Modified epoxy has the advantages that cohesive force is strong, chemical reagent-resistant performance is good, and modified epoxy can enhance coating resist water,
The ability that ion penetrates into, improves the adhesion between coating and metallic matrix, so as to improve the protective capacities of coating, enhances steel
The high temperature resistant and abrasion resistance properties of pipe, the safety in utilization of steel pipe are increased substantially.
Embodiment
With reference to embodiment, the invention will be further described:
A kind of steel pipe corrosion-proof composite coating, include the component of following percentage by weight:Pigment 5~12%, filler 3~8%, disperse
Agent 8~12%, coalescents 6~12%, defoamer 5~8%, polyphenylene oxide resin powder 2~6%, butadiene-styrene rubber 5~8%, toluene
3~6%, plasticizer 1~3%, coupling agent 1~3%, auxiliary material 2~4%, fire retardant 1~3%, white carbon 2~4%, remaining is to have
Machine silicon modified epoxy resin.Pigment is one kind in titanium dioxide, iron oxide red, carbon black, barium sulfate or chrome oxide green.Filler glass
Scale.Plasticizer is tricresyl phosphate.Dispersant is sodium tripolyphosphate.Coalescents are ethylene glycol ethyl ether.Defoamer is acyl
Amine.Coupling agent is silane coupler.
A kind of preparation method of steel pipe corrosion-proof composite coating, including following operating procedure:
(1) pigment, filler, modifying epoxy resin by organosilicon are delivered to and 30min are stirred in agitator, mixing speed be 100~
120r/min, waits and sequentially adds dispersant, coalescents and defoamer after being sufficiently mixed uniformly, finally adds plasticizer regulation and applies
Expect to suitable viscosity;
(2) butadiene-styrene rubber, auxiliary material, fire retardant and polyphenylene oxide resin powder are added into toluene and is sent into mixer, stirs 30min,
Mixing speed is 100~120r/min, waits and adds coupling agent in mixer after being sufficiently mixed uniformly, high-speed stirred 15min, stirs
It is 250~350r/min to mix speed;
(3) will be obtained after stirring, dry, broken, grinding in the material mixing prepared in step (2) to step (1) compound
Epoxy anticorrosion powdery coating.
Claims (9)
1. a kind of steel pipe corrosion-proof composite coating, it is characterised in that include the component of following percentage by weight:Pigment 5~12%, is filled out
Material 3~8%, dispersant 8~12%, coalescents 6~12%, defoamer 5~8%, polyphenylene oxide resin powder 2~6%, butylbenzene rubber
Glue 5~8%, toluene 3~6%, plasticizer 1~3%, coupling agent 1~3%, auxiliary material 2~4%, fire retardant 1~3%, white carbon 2
~4%, remaining is modifying epoxy resin by organosilicon.
A kind of 2. steel pipe corrosion-proof composite coating according to claim 1, it is characterised in that:The pigment is titanium dioxide, oxygen
Change one kind in iron oxide red, carbon black, barium sulfate or chrome oxide green.
A kind of 3. steel pipe corrosion-proof composite coating according to claim 1, it is characterised in that:The filler glass flake.
A kind of 4. steel pipe corrosion-proof composite coating according to claim 1, it is characterised in that:The plasticizer is tripotassium phosphate
Phenyl ester.
A kind of 5. steel pipe corrosion-proof composite coating according to claim 1, it is characterised in that:Described dispersant is trimerization phosphorus
Sour sodium.
A kind of 6. steel pipe corrosion-proof composite coating according to claim 1, it is characterised in that:Described coalescents are second two
Alcohol ether.
A kind of 7. steel pipe corrosion-proof composite coating according to claim 1, it is characterised in that:Described defoamer is acid amides.
A kind of 8. steel pipe corrosion-proof composite coating according to claim 1, it is characterised in that:Described coupling agent is that silane is even
Join agent.
9. the preparation method of any one steel pipe corrosion-proof composite coating as described in claim 1-8, it is characterised in that including such as
Lower operating procedure:
(1) pigment, filler, modifying epoxy resin by organosilicon are delivered to and 30min are stirred in agitator, mixing speed be 100~
120r/min, waits and sequentially adds dispersant, coalescents and defoamer after being sufficiently mixed uniformly, finally adds plasticizer regulation and applies
Expect to suitable viscosity;
(2) butadiene-styrene rubber, auxiliary material, fire retardant and polyphenylene oxide resin powder are added into toluene and is sent into mixer, stirs 30min,
Mixing speed is 100~120r/min, waits and adds coupling agent in mixer after being sufficiently mixed uniformly, high-speed stirred 15min, stirs
It is 250~350r/min to mix speed;
(3) will be obtained after stirring, dry, broken, grinding in the material mixing prepared in step (2) to step (1) compound
Epoxy anticorrosion powdery coating.
Priority Applications (1)
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CN201711195656.3A CN107880720A (en) | 2017-11-24 | 2017-11-24 | A kind of steel pipe corrosion-proof composite coating and preparation method thereof |
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CN201711195656.3A CN107880720A (en) | 2017-11-24 | 2017-11-24 | A kind of steel pipe corrosion-proof composite coating and preparation method thereof |
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Publication Number | Publication Date |
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CN107880720A true CN107880720A (en) | 2018-04-06 |
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CN201711195656.3A Withdrawn CN107880720A (en) | 2017-11-24 | 2017-11-24 | A kind of steel pipe corrosion-proof composite coating and preparation method thereof |
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN110157331A (en) * | 2019-05-30 | 2019-08-23 | 广州市维思涂料科技有限公司 | A kind of corrosion-resistant epoxy paint and preparation method thereof |
Citations (5)
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---|---|---|---|---|
CN104231857A (en) * | 2014-09-18 | 2014-12-24 | 江苏海晟涂料有限公司 | Composite epoxy anticorrosive paint and preparation method thereof |
CN105885622A (en) * | 2016-04-28 | 2016-08-24 | 宁国市开源电力耐磨材料有限公司 | Anti-corrosion composite paint for casting heat treatment and preparation method thereof |
CN106246235A (en) * | 2016-08-30 | 2016-12-21 | 南京赛达机械制造有限公司 | A kind of anticorrosion steam turbine blade and preparation method thereof |
CN106497187A (en) * | 2016-10-13 | 2017-03-15 | 南京创贝高速传动机械有限公司 | A kind of anticorrosion high-speed gear box and preparation method thereof |
CN106752201A (en) * | 2016-12-09 | 2017-05-31 | 苏州科胜仓储物流设备有限公司 | A kind of corrosion-resistant metal shelf and preparation method thereof |
-
2017
- 2017-11-24 CN CN201711195656.3A patent/CN107880720A/en not_active Withdrawn
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104231857A (en) * | 2014-09-18 | 2014-12-24 | 江苏海晟涂料有限公司 | Composite epoxy anticorrosive paint and preparation method thereof |
CN105885622A (en) * | 2016-04-28 | 2016-08-24 | 宁国市开源电力耐磨材料有限公司 | Anti-corrosion composite paint for casting heat treatment and preparation method thereof |
CN106246235A (en) * | 2016-08-30 | 2016-12-21 | 南京赛达机械制造有限公司 | A kind of anticorrosion steam turbine blade and preparation method thereof |
CN106497187A (en) * | 2016-10-13 | 2017-03-15 | 南京创贝高速传动机械有限公司 | A kind of anticorrosion high-speed gear box and preparation method thereof |
CN106752201A (en) * | 2016-12-09 | 2017-05-31 | 苏州科胜仓储物流设备有限公司 | A kind of corrosion-resistant metal shelf and preparation method thereof |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN110157331A (en) * | 2019-05-30 | 2019-08-23 | 广州市维思涂料科技有限公司 | A kind of corrosion-resistant epoxy paint and preparation method thereof |
CN110157331B (en) * | 2019-05-30 | 2021-02-02 | 上海博歌建材有限公司 | Epoxy anticorrosive paint and preparation method thereof |
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Application publication date: 20180406 |