CN107880720A - A kind of steel pipe corrosion-proof composite coating and preparation method thereof - Google Patents

A kind of steel pipe corrosion-proof composite coating and preparation method thereof Download PDF

Info

Publication number
CN107880720A
CN107880720A CN201711195656.3A CN201711195656A CN107880720A CN 107880720 A CN107880720 A CN 107880720A CN 201711195656 A CN201711195656 A CN 201711195656A CN 107880720 A CN107880720 A CN 107880720A
Authority
CN
China
Prior art keywords
steel pipe
composite coating
proof composite
pipe corrosion
coating according
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
CN201711195656.3A
Other languages
Chinese (zh)
Inventor
毛立新
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Jingjiang Sintong Machinery Parts Manufacturing Co Ltd
Original Assignee
Jingjiang Sintong Machinery Parts Manufacturing Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Jingjiang Sintong Machinery Parts Manufacturing Co Ltd filed Critical Jingjiang Sintong Machinery Parts Manufacturing Co Ltd
Priority to CN201711195656.3A priority Critical patent/CN107880720A/en
Publication of CN107880720A publication Critical patent/CN107880720A/en
Withdrawn legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D163/00Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08Anti-corrosive paints
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/32Phosphorus-containing compounds
    • C08K2003/321Phosphates
    • C08K2003/324Alkali metal phosphate
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Paints Or Removers (AREA)

Abstract

One kind is used for steel pipe anticorrosion paint and preparation method thereof, belongs to chemical material technical field, includes the component of following percentage by weight:Pigment 5~12%, filler 3~8%, dispersant 8~12%, coalescents 6~12%, defoamer 5~8%, polyphenylene oxide resin powder 2~6%; butadiene-styrene rubber 5~8%; toluene 3~6%, plasticizer 1~3%, coupling agent 1~3%; auxiliary material 2~4%; fire retardant 1~3%, white carbon 2~4%, remaining is modifying epoxy resin by organosilicon.Preparation principle of the present invention is clear, methodological science, modifying epoxy resin by organosilicon has the advantages that cohesive force is strong, chemical reagent-resistant performance is good, and modified epoxy can enhance the ability that coating resists water, ion penetrates into, improve the adhesion between coating and metallic matrix, so as to improve the protective capacities of coating, the high temperature resistant and abrasion resistance properties of steel pipe are enhanced, the safety in utilization of steel pipe is increased substantially.

Description

A kind of steel pipe corrosion-proof composite coating and preparation method thereof
Technical field
The invention belongs to chemical material technical field, is related to a kind of anti-corrosion composite coating and preparation method thereof, particularly relates to It is and a kind of for steel pipe anticorrosion paint and preparation method thereof.
Background technology
Metal material is under field conditions (factors) or under working condition, due to chemistry or electrochemistry occurs with its local environment medium Degenerate and destroy caused by effect, this phenomenon is referred to as corroding.Etching problem is throughout each department and industry, to national economy Development, human lives and social environment generate significant damage.According to statistics, loss of the whole world every year caused by corrosion is up to 1000000000000 dollars, various countries due to annual economical losses caused by corrosion failure account for national economy total output value then 2%~ 4%, corrosion control level is different because of the different economic development level in various countries.According to《Chinese Investigation On Corrosion report》Data, I The year corrosion economic loss of state in recent years is about 500,000,000,000 yuan, and this loss is huge.Except corrosion economy problems it Outside, corrosion process and result are actually also the significant wastage to limited resources on the earth and the energy, to the serious of natural environment Pollution, the great interference lived to normal production and people, and people are brought with very important social safety sex chromosome mosaicism. Etching problem can also turn into the important restriction factor for hindering hi-tech development and national sustained economic development.It is estimated that generation 20% metal material is there are about in boundary can not reclaim because being corroded, thus to cause the world each for corrosion of metal and protection question The most attention of state.
The method for preventing pipe corrosion is a lot, such as paint coatings anti-corrosion, from corrosion resisting alloy, plating, cathodic protection, heat Zinc immersion and metal thermal spraying etc., wherein most widely used is paint coatings anti-corrosion.Compared with other method, paint coatings are prevented Corruption is most effective, most economical, using most common method.The complexity but existing many paint coatings are constructed in anti-corrosion, is prepared Paint coatings tedious process, cost are high, pollute the environment during preparation, and paint coatings corrosion resistance is inadequate, researches and develops a kind of anti-corrosion Coating and preparation method thereof turns into those skilled in the art's technical problem urgently to be resolved hurrily.
The content of the invention
The present invention construct complexity for existing paint coatings in anti-corrosion, prepares paint coatings tedious process, cost height, makes Polluted the environment when standby, and the deficiencies of paint coatings corrosion resistance is inadequate, propose a kind of steel pipe corrosion-proof composite coating and its preparation Method, can solve above-mentioned deficiency of the prior art, high temperature resistant, the abrasion resistance properties of steel pipe, the safety that steel pipe uses can be strengthened Property can be increased substantially.
Technical scheme:A kind of steel pipe corrosion-proof composite coating, it is characterised in that including following percentage by weight Component:Pigment 5~12%, filler 3~8%, dispersant 8~12%, coalescents 6~12%, defoamer 5~8%, polyphenylene oxide Resin-oatmeal 2~6%, butadiene-styrene rubber 5~8%, toluene 3~6%, plasticizer 1~3%, coupling agent 1~3%, auxiliary material 2~4%, Fire retardant 1~3%, white carbon 2~4%, remaining is modifying epoxy resin by organosilicon.
The pigment is one kind in titanium dioxide, iron oxide red, carbon black, barium sulfate or chrome oxide green.
The filler glass flake.
The plasticizer is tricresyl phosphate.
The dispersant is sodium tripolyphosphate.
The coalescents are ethylene glycol ethyl ether.
The defoamer is acid amides.
The coupling agent is silane coupler.
The preparation method of steel pipe corrosion-proof composite coating, it is characterised in that including following operating procedure:
(1) pigment, filler, modifying epoxy resin by organosilicon are delivered to and 30min are stirred in agitator, mixing speed be 100~ 120r/min, waits and sequentially adds dispersant, coalescents and defoamer after being sufficiently mixed uniformly, finally adds plasticizer regulation and applies Expect to suitable viscosity;
(2) butadiene-styrene rubber, auxiliary material, fire retardant and polyphenylene oxide resin powder are added into toluene and is sent into mixer, stirs 30min, Mixing speed is 100~120r/min, waits and adds coupling agent in mixer after being sufficiently mixed uniformly, high-speed stirred 15min, stirs It is 250~350r/min to mix speed;
(3) will be obtained after stirring, dry, broken, grinding in the material mixing prepared in step (2) to step (1) compound Epoxy anticorrosion powdery coating.
Beneficial effects of the present invention are:A kind of steel pipe corrosion-proof composite coating proposed by the present invention and preparation method thereof, prepare Clear principle, methodological science, epoxy resin have excellent adhesive force and low-shrinkage, are respectively provided with various execution conditions good Filming performance, a series of conventional anticorrosive paints can be configured to good miscible of various resins, filler and auxiliary agent;Organosilicon Modified epoxy has the advantages that cohesive force is strong, chemical reagent-resistant performance is good, and modified epoxy can enhance coating resist water, The ability that ion penetrates into, improves the adhesion between coating and metallic matrix, so as to improve the protective capacities of coating, enhances steel The high temperature resistant and abrasion resistance properties of pipe, the safety in utilization of steel pipe are increased substantially.
Embodiment
With reference to embodiment, the invention will be further described:
A kind of steel pipe corrosion-proof composite coating, include the component of following percentage by weight:Pigment 5~12%, filler 3~8%, disperse Agent 8~12%, coalescents 6~12%, defoamer 5~8%, polyphenylene oxide resin powder 2~6%, butadiene-styrene rubber 5~8%, toluene 3~6%, plasticizer 1~3%, coupling agent 1~3%, auxiliary material 2~4%, fire retardant 1~3%, white carbon 2~4%, remaining is to have Machine silicon modified epoxy resin.Pigment is one kind in titanium dioxide, iron oxide red, carbon black, barium sulfate or chrome oxide green.Filler glass Scale.Plasticizer is tricresyl phosphate.Dispersant is sodium tripolyphosphate.Coalescents are ethylene glycol ethyl ether.Defoamer is acyl Amine.Coupling agent is silane coupler.
A kind of preparation method of steel pipe corrosion-proof composite coating, including following operating procedure:
(1) pigment, filler, modifying epoxy resin by organosilicon are delivered to and 30min are stirred in agitator, mixing speed be 100~ 120r/min, waits and sequentially adds dispersant, coalescents and defoamer after being sufficiently mixed uniformly, finally adds plasticizer regulation and applies Expect to suitable viscosity;
(2) butadiene-styrene rubber, auxiliary material, fire retardant and polyphenylene oxide resin powder are added into toluene and is sent into mixer, stirs 30min, Mixing speed is 100~120r/min, waits and adds coupling agent in mixer after being sufficiently mixed uniformly, high-speed stirred 15min, stirs It is 250~350r/min to mix speed;
(3) will be obtained after stirring, dry, broken, grinding in the material mixing prepared in step (2) to step (1) compound Epoxy anticorrosion powdery coating.

Claims (9)

1. a kind of steel pipe corrosion-proof composite coating, it is characterised in that include the component of following percentage by weight:Pigment 5~12%, is filled out Material 3~8%, dispersant 8~12%, coalescents 6~12%, defoamer 5~8%, polyphenylene oxide resin powder 2~6%, butylbenzene rubber Glue 5~8%, toluene 3~6%, plasticizer 1~3%, coupling agent 1~3%, auxiliary material 2~4%, fire retardant 1~3%, white carbon 2 ~4%, remaining is modifying epoxy resin by organosilicon.
A kind of 2. steel pipe corrosion-proof composite coating according to claim 1, it is characterised in that:The pigment is titanium dioxide, oxygen Change one kind in iron oxide red, carbon black, barium sulfate or chrome oxide green.
A kind of 3. steel pipe corrosion-proof composite coating according to claim 1, it is characterised in that:The filler glass flake.
A kind of 4. steel pipe corrosion-proof composite coating according to claim 1, it is characterised in that:The plasticizer is tripotassium phosphate Phenyl ester.
A kind of 5. steel pipe corrosion-proof composite coating according to claim 1, it is characterised in that:Described dispersant is trimerization phosphorus Sour sodium.
A kind of 6. steel pipe corrosion-proof composite coating according to claim 1, it is characterised in that:Described coalescents are second two Alcohol ether.
A kind of 7. steel pipe corrosion-proof composite coating according to claim 1, it is characterised in that:Described defoamer is acid amides.
A kind of 8. steel pipe corrosion-proof composite coating according to claim 1, it is characterised in that:Described coupling agent is that silane is even Join agent.
9. the preparation method of any one steel pipe corrosion-proof composite coating as described in claim 1-8, it is characterised in that including such as Lower operating procedure:
(1) pigment, filler, modifying epoxy resin by organosilicon are delivered to and 30min are stirred in agitator, mixing speed be 100~ 120r/min, waits and sequentially adds dispersant, coalescents and defoamer after being sufficiently mixed uniformly, finally adds plasticizer regulation and applies Expect to suitable viscosity;
(2) butadiene-styrene rubber, auxiliary material, fire retardant and polyphenylene oxide resin powder are added into toluene and is sent into mixer, stirs 30min, Mixing speed is 100~120r/min, waits and adds coupling agent in mixer after being sufficiently mixed uniformly, high-speed stirred 15min, stirs It is 250~350r/min to mix speed;
(3) will be obtained after stirring, dry, broken, grinding in the material mixing prepared in step (2) to step (1) compound Epoxy anticorrosion powdery coating.
CN201711195656.3A 2017-11-24 2017-11-24 A kind of steel pipe corrosion-proof composite coating and preparation method thereof Withdrawn CN107880720A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201711195656.3A CN107880720A (en) 2017-11-24 2017-11-24 A kind of steel pipe corrosion-proof composite coating and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201711195656.3A CN107880720A (en) 2017-11-24 2017-11-24 A kind of steel pipe corrosion-proof composite coating and preparation method thereof

Publications (1)

Publication Number Publication Date
CN107880720A true CN107880720A (en) 2018-04-06

Family

ID=61775151

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201711195656.3A Withdrawn CN107880720A (en) 2017-11-24 2017-11-24 A kind of steel pipe corrosion-proof composite coating and preparation method thereof

Country Status (1)

Country Link
CN (1) CN107880720A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110157331A (en) * 2019-05-30 2019-08-23 广州市维思涂料科技有限公司 A kind of corrosion-resistant epoxy paint and preparation method thereof

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104231857A (en) * 2014-09-18 2014-12-24 江苏海晟涂料有限公司 Composite epoxy anticorrosive paint and preparation method thereof
CN105885622A (en) * 2016-04-28 2016-08-24 宁国市开源电力耐磨材料有限公司 Anti-corrosion composite paint for casting heat treatment and preparation method thereof
CN106246235A (en) * 2016-08-30 2016-12-21 南京赛达机械制造有限公司 A kind of anticorrosion steam turbine blade and preparation method thereof
CN106497187A (en) * 2016-10-13 2017-03-15 南京创贝高速传动机械有限公司 A kind of anticorrosion high-speed gear box and preparation method thereof
CN106752201A (en) * 2016-12-09 2017-05-31 苏州科胜仓储物流设备有限公司 A kind of corrosion-resistant metal shelf and preparation method thereof

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104231857A (en) * 2014-09-18 2014-12-24 江苏海晟涂料有限公司 Composite epoxy anticorrosive paint and preparation method thereof
CN105885622A (en) * 2016-04-28 2016-08-24 宁国市开源电力耐磨材料有限公司 Anti-corrosion composite paint for casting heat treatment and preparation method thereof
CN106246235A (en) * 2016-08-30 2016-12-21 南京赛达机械制造有限公司 A kind of anticorrosion steam turbine blade and preparation method thereof
CN106497187A (en) * 2016-10-13 2017-03-15 南京创贝高速传动机械有限公司 A kind of anticorrosion high-speed gear box and preparation method thereof
CN106752201A (en) * 2016-12-09 2017-05-31 苏州科胜仓储物流设备有限公司 A kind of corrosion-resistant metal shelf and preparation method thereof

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110157331A (en) * 2019-05-30 2019-08-23 广州市维思涂料科技有限公司 A kind of corrosion-resistant epoxy paint and preparation method thereof
CN110157331B (en) * 2019-05-30 2021-02-02 上海博歌建材有限公司 Epoxy anticorrosive paint and preparation method thereof

Similar Documents

Publication Publication Date Title
CN104231857B (en) A kind of composite epoxy anticorrosive paint and preparation method thereof
CN102533061B (en) High-solid-content superhigh-corrosion-resistant water-based epoxy static conductive paint and preparation method thereof
CN102533029B (en) Aqueous asphalt imitation anticorrosion coating for container chassis and preparation method thereof
CN102627905B (en) Waterborne epoxy anti-corrosive coating and preparation method thereof
CN109181476A (en) A kind of graphene anticorrosive paint and its application method
CN108659589B (en) Water-based inorganic high-temperature-resistant anticorrosive paint for rust removal on rusty surface and preparation method thereof
CN103614074B (en) A kind of heatproof high voltage resistant corrosion dual-component coating
CN106221563A (en) A kind of two component epoxy class anti-corrosive organic coatings and preparation method thereof and using method
CN107189618A (en) A kind of waterborne inorganic einc-rich primer and preparation method thereof
CN105925178A (en) Water-based organic and inorganic hybrid anticorrosive paint composition and preparing method thereof
CN106497269A (en) A kind of water-repellent preservation fire prevention integrative paint
CN107916024A (en) A kind of ultrafast dry precoated prime for workplace of waterborne normal-temperature and its preparation method and application
CN105802432A (en) Waterborne epoxy anticorrosive antirust paint and preparation method thereof
CN104387916A (en) Coating composition for rapidly repairing damaged skin coat of spacecraft
CN106978018A (en) A kind of epoxy resin metal heavy anticorrosion paint and preparation method thereof
CN109897413A (en) Aqueous inorganic paint and preparation method
CN104725977B (en) Double-component aqueous epoxy zinc rich primer of heavy antisepsis and preparation method thereof
CN107880720A (en) A kind of steel pipe corrosion-proof composite coating and preparation method thereof
CN105219215A (en) A kind of preparation method of engineering machinery high-performance epoxy primer
CN102838919A (en) Solvent-free water-tolerant special anticorrosive coating and preparation method thereof
CN110511647A (en) A kind of aqueous double-component epoxy anticorrosion primer and preparation method thereof
CN108912964A (en) Heat distribution pipeline inner wall high temperature resistant drag-reduction energy-saving anticorrosive paint
CN211488435U (en) Natural gas line anticorrosion equipment
CN107779002A (en) A kind of high temperature resistant steel pipe anticorrosion paint
CN108441081A (en) A kind of preparation method of graphene anticorrosive paint

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
WW01 Invention patent application withdrawn after publication
WW01 Invention patent application withdrawn after publication

Application publication date: 20180406